CN107074566A - 沸石材料的固热合成以及由此得到的沸石 - Google Patents

沸石材料的固热合成以及由此得到的沸石 Download PDF

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Publication number
CN107074566A
CN107074566A CN201580055841.5A CN201580055841A CN107074566A CN 107074566 A CN107074566 A CN 107074566A CN 201580055841 A CN201580055841 A CN 201580055841A CN 107074566 A CN107074566 A CN 107074566A
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weight
mixture
zeolitic material
less
fluoride
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S·毛雷尔
U·米勒
F-S·肖
孟祥举
吴勤明
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BASF SE
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BASF SE
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    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C01B39/48—Other types characterised by their X-ray diffraction pattern and their defined composition using at least one organic template directing agent
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/18—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the mordenite type
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7023—EUO-type, e.g. EU-1, TPZ-3 or ZSM-50
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7042—TON-type, e.g. Theta-1, ISI-1, KZ-2, NU-10 or ZSM-22
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    • C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
    • C01B37/02—Crystalline silica-polymorphs, e.g. silicalites dealuminated aluminosilicate zeolites
    • C—CHEMISTRY; METALLURGY
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    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/04—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof using at least one organic template directing agent, e.g. an ionic quaternary ammonium compound or an aminated compound
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    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
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    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/06—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis
    • C01B39/08—Preparation of isomorphous zeolites characterised by measures to replace the aluminium or silicon atoms in the lattice framework by atoms of other elements, i.e. by direct or secondary synthesis the aluminium atoms being wholly replaced
    • C01B39/087—Ferrosilicates
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    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/20—Faujasite type, e.g. type X or Y
    • C01B39/205—Faujasite type, e.g. type X or Y using at least one organic template directing agent; Hexagonal faujasite; Intergrowth products of cubic and hexagonal faujasite
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    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
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    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/36—Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
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    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Catalysts (AREA)
CN201580055841.5A 2014-10-15 2015-10-15 沸石材料的固热合成以及由此得到的沸石 Pending CN107074566A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CNPCT/CN2014/088647 2014-10-15
CN2014088647 2014-10-15
PCT/CN2015/091979 WO2016058541A1 (en) 2014-10-15 2015-10-15 Solidothermal synthesis of zeolitic materials and zeolites obtained therefrom

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CN107074566A true CN107074566A (zh) 2017-08-18

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US (1) US10301185B2 (enExample)
EP (1) EP3206991A4 (enExample)
JP (1) JP6656242B2 (enExample)
KR (1) KR20170070052A (enExample)
CN (1) CN107074566A (enExample)
WO (1) WO2016058541A1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113979448A (zh) * 2020-07-27 2022-01-28 中国石油化工股份有限公司 含氟zsm-35分子筛及其制备方法

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6656242B2 (ja) 2014-10-15 2020-03-04 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ゼオライト材料の固体熱合成方法及びそれから得られるゼオライト
US10556801B2 (en) 2015-02-12 2020-02-11 Basf Se Process for the preparation of a dealuminated zeolitic material having the BEA framework structure
WO2016177814A1 (en) 2015-05-04 2016-11-10 Basf Se Process for the preparation of melonal
JP2018522009A (ja) 2015-07-15 2018-08-09 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ アリールプロペンの調製方法
CN108290134A (zh) 2015-11-27 2018-07-17 巴斯夫欧洲公司 金属-有机骨架的超快高空时产率合成
EP3178788A1 (en) 2015-12-08 2017-06-14 Basf Se A tin-containing zeolitic material having a bea framework structure
JP7039472B2 (ja) 2015-12-08 2022-03-22 ビーエーエスエフ ソシエタス・ヨーロピア Ｂｅａ骨格構造を有するスズ含有ゼオライト材料
JP6786876B2 (ja) * 2016-05-23 2020-11-18 東ソー株式会社 Ｃｈａ型ゼオライトの製造方法
KR102470492B1 (ko) * 2016-09-06 2022-11-23 바스프 에스이 Mww 골격 구조를 갖는 붕소 함유 제올라이트의 고체열 합성
EP3519355A4 (en) * 2016-09-27 2020-04-22 Basf Se HIGHLY EFFICIENT SOLIDOTHERMAL SYNTHESIS OF ZEOLITHIC MATERIALS
WO2020021054A1 (en) * 2018-07-27 2020-01-30 Basf Se Process for preparing a zeolitic material having a framework type fer
JP2022548975A (ja) * 2019-09-20 2022-11-22 ビーエーエスエフ ソシエタス・ヨーロピア 骨格構造型ｉｔｈを有するゼオライト材料の合成方法および使用方法
EP4288385A4 (en) * 2021-02-03 2025-04-16 BASF Corporation ZEOLITHIC MATERIAL COMPRISING A CHA-TYPE FRAMEWORK STRUCTURE AND ITS SYNTHESIS
CN115210181A (zh) * 2021-02-09 2022-10-18 巴斯夫公司 使用有机结构导向剂混合物合成的沸石结构
US11565943B2 (en) * 2021-02-11 2023-01-31 Chevron U.S.A. Inc. Synthesis of ton framework type molecular sieves
US20220347663A1 (en) * 2021-04-27 2022-11-03 Chevron U.S.A. Inc. Ferrosilicate ssz-70 molcular sieve, its synthesis and use
JP2023156098A (ja) * 2022-04-12 2023-10-24 東ソー株式会社 Ｆａｕ型ゼオライトの製造方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4407872A1 (de) * 1994-03-04 1996-02-15 Vaw Ver Aluminium Werke Ag Verfahren zur Herstellung von hochsiliciumhaltigen Zeolithen
CN1483671A (zh) * 2003-03-20 2004-03-24 吉林大学 具有超高水热稳定的有序介孔分子筛材料及其合成方法
WO2008058398A1 (en) * 2006-11-16 2008-05-22 UNIVERSITé LAVAL Nanozeolites and process for preparation thereof
US8226925B2 (en) * 2007-02-01 2012-07-24 Consejo Superior De Investigaciones Cientificas Microporous crystalline material of zeolitic nature, zeolite ITQ-39, method of preparation and uses

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5278866B2 (ja) * 2006-12-03 2013-09-04 独立行政法人産業技術総合研究所 Ｃｄｏ型高シリカゼオライトの前駆体となる層状ケイ酸塩及びその製造方法
WO2011158218A1 (en) * 2010-06-18 2011-12-22 Basf Se Zeolitic materials of lev-type structure and methods for their production
CN102627287B (zh) 2012-04-20 2014-04-16 浙江大学 通过固相原料研磨无溶剂条件下合成分子筛的方法
BR112015008391B1 (pt) 2012-10-18 2022-03-29 Basf Se Processo para o pós-tratamento de um material zeolítico, material zeolítico e uso de um material zeolítico
RU2638851C2 (ru) 2012-10-18 2017-12-18 Басф Се Последующая обработка деборированного цеолита mww
WO2014060982A2 (en) 2012-10-19 2014-04-24 Basf Se Catalyst for the Conversion of Syngas to Olefins and Preparation Thereof
CN102992343A (zh) * 2012-12-09 2013-03-27 浙江大学 无有机模板固相法合成沸石分子筛的方法
CN103121698B (zh) * 2013-02-01 2014-11-05 浙江大学 一种固相研磨合成sapo-34的方法
US20150090610A1 (en) 2013-09-27 2015-04-02 Basf Corporation Processes for filling containers in adsorbed gas systems
CN104556087B (zh) 2013-10-29 2017-11-28 中国石油化工股份有限公司 一种全硅分子筛及其合成方法
SG10201407071SA (en) 2013-10-29 2015-05-28 China Petroleum & Chemical A Full-Si Molecular Sieve and its Synthesis Process
CN103979574B (zh) * 2014-06-05 2016-03-30 郑州大学 固相合成分子筛的方法
JP6656242B2 (ja) 2014-10-15 2020-03-04 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ゼオライト材料の固体熱合成方法及びそれから得られるゼオライト
CN104891520B (zh) * 2015-06-02 2017-08-29 中国科学院上海高等研究院 一种固相合成多级孔分子筛的方法

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4407872A1 (de) * 1994-03-04 1996-02-15 Vaw Ver Aluminium Werke Ag Verfahren zur Herstellung von hochsiliciumhaltigen Zeolithen
CN1483671A (zh) * 2003-03-20 2004-03-24 吉林大学 具有超高水热稳定的有序介孔分子筛材料及其合成方法
WO2008058398A1 (en) * 2006-11-16 2008-05-22 UNIVERSITé LAVAL Nanozeolites and process for preparation thereof
US8226925B2 (en) * 2007-02-01 2012-07-24 Consejo Superior De Investigaciones Cientificas Microporous crystalline material of zeolitic nature, zeolite ITQ-39, method of preparation and uses

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
U.DEFORTH ET AL.: "Dry synthesis of B-MFI, MTN- and MTW-type materials", 《MICROPOROUS MATERIALS》 *

Cited By (1)

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