JP6212542B2 - トリフルオロエチレンの制御フリーラジカル共重合 - Google Patents

トリフルオロエチレンの制御フリーラジカル共重合 Download PDF

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JP6212542B2
JP6212542B2 JP2015507585A JP2015507585A JP6212542B2 JP 6212542 B2 JP6212542 B2 JP 6212542B2 JP 2015507585 A JP2015507585 A JP 2015507585A JP 2015507585 A JP2015507585 A JP 2015507585A JP 6212542 B2 JP6212542 B2 JP 6212542B2
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copolymer
units
trifluoroethylene
vinylidene fluoride
block
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JP2015514854A (ja
JP2015514854A5 (enExample
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アメディール,ブルーノ
アラディーン,アリ
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Arkema France SA
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/44Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • C08F214/182Monomers containing fluorine not covered by the groups C08F214/20 - C08F214/28
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18Monomers containing fluorine
    • C08F214/22Vinylidene fluoride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20Manufacture of shaped structures of ion-exchange resins
    • C08J5/22Films, membranes or diaphragms
    • C08J5/2206Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218Synthetic macromolecular compounds
    • C08J5/2231Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2237Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/16Homopolymers or copolymers of vinylidene fluoride
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D153/00Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N15/00Thermoelectric devices without a junction of dissimilar materials; Thermomagnetic devices, e.g. using the Nernst-Ettingshausen effect
    • H10N15/10Thermoelectric devices using thermal change of the dielectric constant, e.g. working above and below the Curie point
    • H10N15/15Thermoelectric active materials
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10NELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00Piezoelectric or electrostrictive devices
    • H10N30/80Constructional details
    • H10N30/85Piezoelectric or electrostrictive active materials
    • H10N30/857Macromolecular compositions
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00Living radical polymerisation
    • C08F2438/03Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
JP2015507585A 2012-04-26 2013-04-25 トリフルオロエチレンの制御フリーラジカル共重合 Expired - Fee Related JP6212542B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1253838 2012-04-26
FR1253838A FR2989972B1 (fr) 2012-04-26 2012-04-26 Copolymerisation radicalaire controlee a partir de trifluoroethylene
PCT/FR2013/050920 WO2013160621A1 (fr) 2012-04-26 2013-04-25 Copolymerisation radicalaire controlee a partir de trifluoroethylene

Publications (3)

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JP2015514854A JP2015514854A (ja) 2015-05-21
JP2015514854A5 JP2015514854A5 (enExample) 2016-01-07
JP6212542B2 true JP6212542B2 (ja) 2017-10-11

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JP2015507585A Expired - Fee Related JP6212542B2 (ja) 2012-04-26 2013-04-25 トリフルオロエチレンの制御フリーラジカル共重合

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US (1) US9708419B2 (enExample)
EP (1) EP2841474A1 (enExample)
JP (1) JP6212542B2 (enExample)
KR (1) KR20150006865A (enExample)
CN (1) CN104540861B (enExample)
FR (1) FR2989972B1 (enExample)
WO (1) WO2013160621A1 (enExample)

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Publication number Priority date Publication date Assignee Title
FR3004185B1 (fr) * 2013-04-03 2017-10-13 Arkema France Terpolymeres contenant du fluorure de vinylidene et du trifluoroethylene
WO2015173194A1 (en) * 2014-05-12 2015-11-19 Solvay Specialty Polymers Italy S.P.A. Fluoroelastomers
US10377843B2 (en) * 2014-05-12 2019-08-13 Solvay Specialty Polymers Italy S.P.A. Method for the controlled polymerization of fluoromonomers
WO2016149238A1 (en) * 2015-03-16 2016-09-22 Arkema Inc. Modified fluoropolymers
JP6722754B2 (ja) * 2015-08-05 2020-07-15 ゼロックス コーポレイションXerox Corporation PVDF−TrFE共重合体の末端基の交換法
FR3041348B1 (fr) * 2015-09-23 2019-05-03 Arkema France Terpolymeres du fluorure de vinylidene, du trifluoroethylene et du 1,3,3,3-tetrafluoropropene
FR3042502B1 (fr) * 2015-10-19 2019-04-05 Arkema France Copolymeres fluores fonctionnalises
EP3594250B1 (en) 2017-03-09 2025-06-25 AGC Inc. Method for producing polymer
FR3065217B1 (fr) * 2017-04-14 2020-02-28 Arkema France Compositions reticulables a base de copolymeres fluores electroactifs
EP3639307B1 (en) 2017-06-16 2022-03-23 Carrier Corporation Electrocaloric heat transfer system comprising copolymers
MX2020003337A (es) * 2017-09-27 2020-10-28 Arkema Inc Copolimeros de olefinas halogenadas y co-monomeros halogenados.
FR3071500B1 (fr) * 2017-09-27 2020-05-15 Arkema France Synthese de latex de poly(fluorure de vinylidene) sans tensioactif par polymerisation en emulsion raft
EP3898717B1 (en) * 2018-12-20 2023-09-06 Solvay Specialty Polymers Italy S.p.A. Vinylidene fluoride polymer dispersion
CN109851705A (zh) * 2019-03-20 2019-06-07 济南大学 一种一锅法制备分子量可控的四氟乙烯共聚物的方法
CN118027319A (zh) * 2019-05-08 2024-05-14 大金工业株式会社 含氟聚合物
WO2021045209A1 (ja) * 2019-09-04 2021-03-11 ダイキン工業株式会社 含フッ素共重合体
EP4190828A4 (en) * 2020-07-30 2024-10-30 Daikin Industries, Ltd. METHOD FOR PRODUCING AN AQUEOUS DISPERSION OF FLUORINE-CONTAINING ELASTOMER, FLUORINE-CONTAINING ELASTOMER AND AQUEOUS DISPERSION
JP7137106B2 (ja) * 2020-09-03 2022-09-14 ダイキン工業株式会社 硬化性組成物
CN112226119A (zh) * 2020-09-19 2021-01-15 复旦大学 一种发光防水聚合物涂层的制备方法
KR102526902B1 (ko) 2021-07-02 2023-04-28 정세진 고내열 유연성 정온도계수 자율제어형 히팅케이블 제조방법
FR3125957A1 (fr) 2021-08-04 2023-02-10 Piezomedic Dispositif et système de localisation d’un implant ou d’un organe dans un corps humain ou animal, par émission-réception de signaux ultrasons via des transducteurs piézoélectriques et/ou capacitifs
US20250059308A1 (en) * 2021-12-17 2025-02-20 Solvay Specialty Polymers Italy S.P.A. Method for the emulsion polymerization of fluoromonomer
WO2025053275A1 (ja) * 2023-09-06 2025-03-13 ダイキン工業株式会社 ポリマーおよび成形品

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US9193810B2 (en) * 2012-02-23 2015-11-24 University Of Connecticut Free radical and controlled radical polymerization processes using hypervalent iodide radical initiators

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Publication number Publication date
FR2989972A1 (fr) 2013-11-01
US9708419B2 (en) 2017-07-18
EP2841474A1 (fr) 2015-03-04
JP2015514854A (ja) 2015-05-21
US20150119523A1 (en) 2015-04-30
FR2989972B1 (fr) 2015-03-27
CN104540861A (zh) 2015-04-22
WO2013160621A1 (fr) 2013-10-31
KR20150006865A (ko) 2015-01-19
CN104540861B (zh) 2016-08-24

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