KR20150006865A - 트리플루오로에틸렌의 제어된 자유―라디칼 공중합 - Google Patents

트리플루오로에틸렌의 제어된 자유―라디칼 공중합 Download PDF

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Publication number
KR20150006865A
KR20150006865A KR1020147033297A KR20147033297A KR20150006865A KR 20150006865 A KR20150006865 A KR 20150006865A KR 1020147033297 A KR1020147033297 A KR 1020147033297A KR 20147033297 A KR20147033297 A KR 20147033297A KR 20150006865 A KR20150006865 A KR 20150006865A
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South Korea
Prior art keywords
copolymer
trifluoroethylene
units
vinylidene fluoride
block
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KR1020147033297A
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English (en)
Korean (ko)
Inventor
브루노 아메두리
알리 아라에딘
Original Assignee
아르끄마 프랑스
에꼴 나쇼날 쉬페리에르 드 시미에 드 몽펠리에
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Publication of KR20150006865A publication Critical patent/KR20150006865A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/182—Monomers containing fluorine not covered by the groups C08F214/20 - C08F214/28
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/18—Monomers containing fluorine
    • C08F214/22—Vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2231—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds
    • C08J5/2237—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions involving unsaturated carbon-to-carbon bonds containing fluorine
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
    • C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
    • C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C09D127/16—Homopolymers or copolymers of vinylidene fluoride
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D153/00—Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N15/00—Thermoelectric devices without a junction of dissimilar materials; Thermomagnetic devices, e.g. using the Nernst-Ettingshausen effect
    • H10N15/10—Thermoelectric devices using thermal change of the dielectric constant, e.g. working above and below the Curie point
    • H10N15/15—Thermoelectric active materials
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N—ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10N30/00—Piezoelectric or electrostrictive devices
    • H10N30/80—Constructional details
    • H10N30/85—Piezoelectric or electrostrictive active materials
    • H10N30/857—Macromolecular compositions
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Graft Or Block Polymers (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
KR1020147033297A 2012-04-26 2013-04-25 트리플루오로에틸렌의 제어된 자유―라디칼 공중합 Withdrawn KR20150006865A (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR1253838 2012-04-26
FR1253838A FR2989972B1 (fr) 2012-04-26 2012-04-26 Copolymerisation radicalaire controlee a partir de trifluoroethylene
PCT/FR2013/050920 WO2013160621A1 (fr) 2012-04-26 2013-04-25 Copolymerisation radicalaire controlee a partir de trifluoroethylene

Publications (1)

Publication Number Publication Date
KR20150006865A true KR20150006865A (ko) 2015-01-19

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KR1020147033297A Withdrawn KR20150006865A (ko) 2012-04-26 2013-04-25 트리플루오로에틸렌의 제어된 자유―라디칼 공중합

Country Status (7)

Country Link
US (1) US9708419B2 (enExample)
EP (1) EP2841474A1 (enExample)
JP (1) JP6212542B2 (enExample)
KR (1) KR20150006865A (enExample)
CN (1) CN104540861B (enExample)
FR (1) FR2989972B1 (enExample)
WO (1) WO2013160621A1 (enExample)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20220007664A (ko) * 2019-09-04 2022-01-18 다이킨 고교 가부시키가이샤 불소 함유 공중합체
KR20230006414A (ko) 2021-07-02 2023-01-10 정세진 고내열 유연성 정온도계수 조성물

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FR3004185B1 (fr) * 2013-04-03 2017-10-13 Arkema France Terpolymeres contenant du fluorure de vinylidene et du trifluoroethylene
WO2015173194A1 (en) * 2014-05-12 2015-11-19 Solvay Specialty Polymers Italy S.P.A. Fluoroelastomers
US10377843B2 (en) * 2014-05-12 2019-08-13 Solvay Specialty Polymers Italy S.P.A. Method for the controlled polymerization of fluoromonomers
WO2016149238A1 (en) * 2015-03-16 2016-09-22 Arkema Inc. Modified fluoropolymers
JP6722754B2 (ja) * 2015-08-05 2020-07-15 ゼロックス コーポレイションＸｅｒｏｘ Ｃｏｒｐｏｒａｔｉｏｎ ＰＶＤＦ−ＴｒＦＥ共重合体の末端基の交換法
FR3041348B1 (fr) * 2015-09-23 2019-05-03 Arkema France Terpolymeres du fluorure de vinylidene, du trifluoroethylene et du 1,3,3,3-tetrafluoropropene
FR3042502B1 (fr) * 2015-10-19 2019-04-05 Arkema France Copolymeres fluores fonctionnalises
EP3594250B1 (en) 2017-03-09 2025-06-25 AGC Inc. Method for producing polymer
FR3065217B1 (fr) * 2017-04-14 2020-02-28 Arkema France Compositions reticulables a base de copolymeres fluores electroactifs
EP3639307B1 (en) 2017-06-16 2022-03-23 Carrier Corporation Electrocaloric heat transfer system comprising copolymers
MX2020003337A (es) * 2017-09-27 2020-10-28 Arkema Inc Copolimeros de olefinas halogenadas y co-monomeros halogenados.
FR3071500B1 (fr) * 2017-09-27 2020-05-15 Arkema France Synthese de latex de poly(fluorure de vinylidene) sans tensioactif par polymerisation en emulsion raft
EP3898717B1 (en) * 2018-12-20 2023-09-06 Solvay Specialty Polymers Italy S.p.A. Vinylidene fluoride polymer dispersion
CN109851705A (zh) * 2019-03-20 2019-06-07 济南大学 一种一锅法制备分子量可控的四氟乙烯共聚物的方法
CN118027319A (zh) * 2019-05-08 2024-05-14 大金工业株式会社 含氟聚合物
EP4190828A4 (en) * 2020-07-30 2024-10-30 Daikin Industries, Ltd. METHOD FOR PRODUCING AN AQUEOUS DISPERSION OF FLUORINE-CONTAINING ELASTOMER, FLUORINE-CONTAINING ELASTOMER AND AQUEOUS DISPERSION
JP7137106B2 (ja) * 2020-09-03 2022-09-14 ダイキン工業株式会社 硬化性組成物
CN112226119A (zh) * 2020-09-19 2021-01-15 复旦大学 一种发光防水聚合物涂层的制备方法
FR3125957A1 (fr) 2021-08-04 2023-02-10 Piezomedic Dispositif et système de localisation d’un implant ou d’un organe dans un corps humain ou animal, par émission-réception de signaux ultrasons via des transducteurs piézoélectriques et/ou capacitifs
US20250059308A1 (en) * 2021-12-17 2025-02-20 Solvay Specialty Polymers Italy S.P.A. Method for the emulsion polymerization of fluoromonomer
WO2025053275A1 (ja) * 2023-09-06 2025-03-13 ダイキン工業株式会社 ポリマーおよび成形品

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US8288492B2 (en) 2007-10-23 2012-10-16 E I Du Pont De Nemours And Company Difunctional oligomers of perfluoro(methyl vinyl ether)
US9493595B2 (en) * 2008-07-07 2016-11-15 Arkema Inc. Vinylidene fluoride copolymers
CN101691412B (zh) * 2009-09-30 2012-11-07 西安交通大学 一种由聚(偏氟乙烯-三氟氯乙烯)制备聚(偏氟乙烯-三氟氯乙烯-三氟乙烯)或聚(偏氟乙烯-三氟乙烯)的方法
US9193810B2 (en) * 2012-02-23 2015-11-24 University Of Connecticut Free radical and controlled radical polymerization processes using hypervalent iodide radical initiators

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20220007664A (ko) * 2019-09-04 2022-01-18 다이킨 고교 가부시키가이샤 불소 함유 공중합체
KR20230006414A (ko) 2021-07-02 2023-01-10 정세진 고내열 유연성 정온도계수 조성물
KR20230006766A (ko) 2021-07-02 2023-01-11 정세진 고내열 유연성 정온도계수 자율제어형 히팅케이블
KR20230006697A (ko) 2021-07-02 2023-01-11 정세진 고내열 유연성 정온도계수 자율제어형 히팅케이블 제조방법

Also Published As

Publication number Publication date
FR2989972A1 (fr) 2013-11-01
US9708419B2 (en) 2017-07-18
EP2841474A1 (fr) 2015-03-04
JP2015514854A (ja) 2015-05-21
US20150119523A1 (en) 2015-04-30
FR2989972B1 (fr) 2015-03-27
CN104540861A (zh) 2015-04-22
JP6212542B2 (ja) 2017-10-11
WO2013160621A1 (fr) 2013-10-31
CN104540861B (zh) 2016-08-24

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