JP5952192B2 - フルオロシリコーン配合剥離剤材料 - Google Patents
フルオロシリコーン配合剥離剤材料 Download PDFInfo
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
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- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
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- C09J7/00—Adhesives in the form of films or foils
- C09J7/40—Adhesives in the form of films or foils characterised by release liners
- C09J7/401—Adhesives in the form of films or foils characterised by release liners characterised by the release coating composition
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- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/12—Polysiloxanes containing silicon bound to hydrogen
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- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/22—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen
- C08G77/24—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen and oxygen halogen-containing groups
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/06—Ethers; Acetals; Ketals; Ortho-esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/07—Aldehydes; Ketones
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/5406—Silicon-containing compounds containing elements other than oxygen or nitrogen
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2483/00—Presence of polysiloxane
- C09J2483/005—Presence of polysiloxane in the release coating
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/28—Web or sheet containing structurally defined element or component and having an adhesive outermost layer
- Y10T428/2839—Web or sheet containing structurally defined element or component and having an adhesive outermost layer with release or antistick coating
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Description
H−SiMe2−O−(SiMeH−O)n−(SiMe(C2H4CF3)−O)m−SiMe2−H、
H−SiMe2−O−(SiMeH−O)n−(SiMe(C2H4C4F9)−O)m−SiMe2−H、
H−SiMe2−O−(SiMeH−O)n−(SiMe(C2H4C6F13)−O)m−SiMe2−H、
H−SiEt2−O−(SiEtH−O)n−(SiMe(C2H4CF3)−O)m−SiEt2−H、
H−SiEt2−O−(SiEtH−O)n−(SiMe(C2H4C4F9)−O)m−SiEt2−H、
H−SiMe2−O−(SiMeH−O)n−(SiMe(C2H4CF3)−O)m−(SiMe2−O)p−SiMe2−H、
H−SiMe2−O−(SiMeH−O)n−(SiMe(C2H4C4F9−O)m−(SiMe2−O)p−SiMe2−H、
H−SiMe2−O−(SiMeH−O)n−(SiMe(C2H4C6F13)−O)m−(SiMe2−O)o−SiMe2−H、
H−SiMe2−O−(SiMeH−O)n−(SiMe(C2H4CF3)−O)m−(SiMePh−O)o−SiMe2−H、
H−SiMe2−O−(SiMeH−O)n−(SiMe(C2H4C4F9)−O)m−(SiMePh−O)o−SiMe2−H、
Me3Si−O−(SiMeH−O)n−(SiMe(C2H4CF3)−O)m−SiMe3、
Me3Si−O−(SiMeH−O)n−(SiMe(C2H4C4F9)−O)m−SiMe3、
Me3Si−O−(SiMeH−O)n−(SiMe(C2H4C6F13)−O)m−SiMe3、
Me3Si−O−(SiMeH−O)n−(SiMe(C2H4CF3)−O)m−SiMe2−O)p−SiMe3、
Me3Si−O−(SiMeH−O)n−(SiMe(C2H4C4F9)−O)m−(SiMe2−O)p−SiMe3、
Me3Si−O−(SiMeH−O)n−(SiMe(C2H4C6F13)−O)m−(SiMe2−O)p−SiMe3、
Me3Si−O−(SiMeH−O)n−(SiMe(C2H4CF3)−O)m−(SiMePh−O)p−SiMe3及び
Me3Si−O−(SiMeH−O)n−(SiMe(C2H4C4F9)−O)m−(SiMePh−O)p−SiMe3。
H−SiMe2−(O−SiMe2)n−OSiMe2−H、
H−SiMe2−(O−SiHMe)n−OSiMe2−H、
H−SiMe2−O−(SiHMe−O)n−(SiMe2−O)m−SiMe2−H、
H−SiMe2−O−(SiPh(OSiHMe2)−O)n−SiMe2−H、
H−SiMe2−O−(SiHMe−O)n−(SiMePh−O)m−SiMe2−H、
Me3Si−O−(SiHMe−O)n−SiMe3、
Me3Si−O−(SiHMe−O)n−(SiMe2−O)m−SiMe3、
Me3Si−O−(SiHMe−O)n−(SiMePh−O)m−SiMe3、
Et3Si−O−(SiHEt−O)n−SiEt3及び
Me3Si−O−(SiHMe−O)n−(SiMeC8H17−O)m−SiMe3。
Rf2=−CH2CH2CF2CF2CF2CF3
ADH−1このポリ(ジメチルシロキサン)(「PDMS」)系シリコーン接着剤を以下のように調製した。3.0gの過酸化物ペースト(GelestのSID 3352.0)、7.2gのトルエン、及び1.8gのMEKを加えることにより、過酸化物溶液を作製した。このペーストは、50%過酸化ジクロロベンゾイル及び50%シリコーン流体を含有していた。得られた過酸化物溶液は、25%固形分であり、トルエン:MEKの重量比が80:20であった。100gのQ2−7735シリコーン感圧接着剤(56%固形分、Dow Chemical Co.から入手可能)、58.6gのトルエン及び2.24gのペルオキシド溶液を混合した。これにより、最終固形分含有量が35%で、(接着剤固形分に基づき)0.5重量%の活性過酸化ジクロロベンゾイルを含有する接着剤溶液を得た。組成物をジャーローラー上に一晩おいて溶解させ、接着剤溶液を製造した。
一般式MViDxMViを有するベースポリマー(式中、xは重合度(「DP」)である)をGelest,Inc.から入手し、表1Aに要約する。150ppmの白金(Dow Corningからの4000Pt触媒、およそ5000ppmのPt濃度)をビニル末端ポリジメチルシロキサンベースポリマーの各々に添加することにより、シリコーン系剥離剤コーティングを製造した。これに0.25重量%のジアリルマレエート阻害物質を添加した。得られた溶液を均質になるまで混合した。
FOPS−7785 97重量%のFOPS−7785ビニル末端及び側枝官能性フルオロシリコーンと3重量%の7560水素化側枝官能性フッ素化架橋剤とを、4:1の酢酸エチルとヘプタンの溶媒系の10重量%溶液として組み合わせることにより、フッ素化オルガノポリシロキサン溶液を調製した。供給時、FOPS−7785は、白金触媒及び阻害物質を含む。
データセットB.NFOPS−2非フッ素化オルガノポリシロキサン(DMS−V21ベース)をFOPS−7785フルオロオルガノポリシロキサン材料と配合し、三菱の2.0ミル(50マイクロメートル)3SACプライミング済みPETフィルム上に#6 Mayerバーを用いてコーティングし、120℃にて5分にわたって硬化させた。サンプル調製手順に従って、硬化済み剥離剤コーティング上にADH−1をドライラミネートし、ウェットキャスティングした。これらの構造体を22℃にて7日(7d−CT)にわたって又は70℃にて7日にわたって(7d−HT)調湿した。剥離試験手順及び再接着試験手順を用いて、調湿済みサンプルを評価した。ドライラミネートしたサンプルの結果を表3Aに要約する。ウェットキャスティングしたサンプルの結果を表3Bに要約する。
(b)7560との重量比97:3の配合物の、10重量%溶液(4:1の酢酸エチル:ヘプタンを溶媒とする)
(b)7560との重量比97:3の配合物の、10重量%溶液(4:1の酢酸エチル:ヘプタンを溶媒とする)
データセットH表9Aに要約するように、97重量%のDOW 7850ヘキセニル末端及び末端官能性非フッ素化PDMSと3重量%のDOW 7488水素化側枝官能性非フッ素化架橋剤の配合物をFOPS−7785と組み合わせた。表9Aに要約した組成物を三菱の2.0ミル(50マイクロメートル)3SACプライミング済みPETフィルム上に#6 Mayerバーを用いてコーティングし、120℃にて10分にわたって硬化させた。
(b)官能性フルオロシリコーンとフッ素化架橋剤の配合物
サンプル調製手順に従って、硬化済み剥離剤コーティング上にADH−1をドライラミネートし、ウェットキャスティングした。これらの構造体を22℃にて7日(7d−CT)にわたって又は70℃にて7日にわたって(7d−HT)調湿した。剥離試験手順及び再接着試験手順を用いて、サンプルを評価した。ドライラミネートしたサンプルの結果を表9Bに要約する。ウェットキャスティングしたサンプルの結果を表9Cに要約する。
Claims (4)
- 溶媒と、該溶媒に溶解した硬化性剥離剤組成物と、を含む、コーティング可能剥離剤溶液であって、前記硬化性剥離剤組成物が、
(a)エチレン性不飽和フルオロオルガノポリシロキサンポリマーと、
(b)平均して少なくとも2つのエチレン性不飽和有機基を含む非フッ素化オルガノポリシロキサンポリマーと、
(c)ヒドロシリル化反応触媒と、
(d)
(i)フルオロオルガノハイドロジェンポリシロキサン架橋剤、及び
(ii)非フッ素化オルガノハイドロジェンポリシロキサン架橋剤
の両者、を含む、コーティング可能剥離剤溶液。 - (a)少なくとも1つのエチレン性不飽和フルオロオルガノポリシロキサンポリマーと、
(b)平均して少なくとも2つのエチレン性不飽和有機基を含む少なくとも1つの非フッ素化オルガノポリシロキサンポリマーと、
(c)少なくとも1つのヒドロシリル化反応触媒と、
(d)
(i)フルオロオルガノハイドロジェンポリシロキサン架橋剤、及び
(ii)非フッ素化オルガノハイドロジェンポリシロキサン架橋剤
の両者と、並びに
(e)少なくとも1つの硬化阻害物質と、
を含む、硬化性剥離剤組成物。 - 基材と該基材に結合した剥離剤層とを備える剥離ライナーであって、前記剥離剤層が請求項2に記載の硬化済みコーティング可能剥離剤組成物を含む、剥離ライナー。
- 請求項3に記載の剥離ライナーの前記剥離剤層に結合した接着剤を含む、接着物品。
Applications Claiming Priority (3)
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US26158609P | 2009-11-16 | 2009-11-16 | |
US61/261,586 | 2009-11-16 | ||
PCT/US2009/067839 WO2011059462A1 (en) | 2009-11-16 | 2009-12-14 | Fluorosilicone blend release materials |
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JP2015084188A Division JP6030693B2 (ja) | 2009-11-16 | 2015-04-16 | フルオロシリコーン配合剥離剤材料 |
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JP5952192B2 true JP5952192B2 (ja) | 2016-07-13 |
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JP2015084188A Expired - Fee Related JP6030693B2 (ja) | 2009-11-16 | 2015-04-16 | フルオロシリコーン配合剥離剤材料 |
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US (1) | US9206317B2 (ja) |
JP (2) | JP5952192B2 (ja) |
CN (1) | CN102597118B (ja) |
BR (1) | BR112012011534A2 (ja) |
DE (1) | DE112009005372T5 (ja) |
RU (1) | RU2539296C2 (ja) |
WO (1) | WO2011059462A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2015147935A (ja) * | 2009-11-16 | 2015-08-20 | スリーエム イノベイティブ プロパティズ カンパニー | フルオロシリコーン配合剥離剤材料 |
Families Citing this family (34)
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US9117757B2 (en) | 2012-10-16 | 2015-08-25 | Brewer Science Inc. | Silicone polymers with high refractive indices and extended pot life |
JP6006632B2 (ja) * | 2012-12-18 | 2016-10-12 | 信越化学工業株式会社 | 付加硬化型シリコーン組成物及び光学素子 |
WO2014193654A1 (en) * | 2013-05-31 | 2014-12-04 | 3M Innovative Properties Company | Fluoroalkyl silicones |
US20150085043A1 (en) * | 2013-09-24 | 2015-03-26 | Xerox Corporation | Varying material surface energies via inhomogeneous networks for indirect printing method |
CN105593270B (zh) | 2013-10-04 | 2018-08-07 | 3M创新有限公司 | 氟代烷基有机硅组合物 |
CN105612165B (zh) | 2013-10-04 | 2018-05-25 | 3M创新有限公司 | 氟代烷基硅烷及其涂层 |
KR20160097324A (ko) * | 2013-12-16 | 2016-08-17 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 블렌딩된 이형 재료 |
US10442897B2 (en) | 2014-03-31 | 2019-10-15 | 3M Innovative Properties Company | Fluoroalkyl silicones |
CN106574168B (zh) * | 2014-07-10 | 2019-09-10 | 陶氏东丽株式会社 | 离型控制剂、含有该离型控制剂的有机硅离型剂组合物、离型片及叠层体 |
CN104263238B (zh) * | 2014-09-11 | 2016-09-07 | 天津大学 | 一种氟化poss复合有机硅涂层及制备方法与防覆冰应用 |
CN104277713B (zh) * | 2014-09-11 | 2016-10-26 | 天津大学 | 一种poss交联改性氟硅涂层的制备方法及疏水防冰应用 |
JP6413878B2 (ja) * | 2015-03-26 | 2018-10-31 | 信越化学工業株式会社 | シリコーン粘着剤用剥離剤組成物及び剥離フィルム |
US10563063B2 (en) | 2015-03-26 | 2020-02-18 | Shin-Etsu Chemical Co., Ltd. | Release agent composition for silicone adhesive, release film, and laminate |
JP6471579B2 (ja) * | 2015-03-26 | 2019-02-20 | 信越化学工業株式会社 | 積層体、その作製方法、基材レス粘着シートの使用方法及び物品 |
WO2016163069A1 (ja) | 2015-04-10 | 2016-10-13 | 東レ・ダウコーニング株式会社 | フルオロアルキル基含有硬化性オルガノポリシロキサン組成物、その硬化物および当該硬化物を備えた電子部品または表示装置 |
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JP2015147935A (ja) * | 2009-11-16 | 2015-08-20 | スリーエム イノベイティブ プロパティズ カンパニー | フルオロシリコーン配合剥離剤材料 |
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JP2013510921A (ja) | 2013-03-28 |
WO2011059462A1 (en) | 2011-05-19 |
US20120219794A1 (en) | 2012-08-30 |
CN102597118A (zh) | 2012-07-18 |
BR112012011534A2 (pt) | 2016-06-28 |
US9206317B2 (en) | 2015-12-08 |
CN102597118B (zh) | 2016-05-11 |
RU2012116203A (ru) | 2013-12-27 |
JP2015147935A (ja) | 2015-08-20 |
DE112009005372T5 (de) | 2012-11-22 |
JP6030693B2 (ja) | 2016-11-24 |
RU2539296C2 (ru) | 2015-01-20 |
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