JP5942447B2 - ポリエステル樹脂組成物、該樹脂組成物を成形してなるフィルム、および該フィルムを成形してなる袋 - Google Patents
ポリエステル樹脂組成物、該樹脂組成物を成形してなるフィルム、および該フィルムを成形してなる袋 Download PDFInfo
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- JP5942447B2 JP5942447B2 JP2012019993A JP2012019993A JP5942447B2 JP 5942447 B2 JP5942447 B2 JP 5942447B2 JP 2012019993 A JP2012019993 A JP 2012019993A JP 2012019993 A JP2012019993 A JP 2012019993A JP 5942447 B2 JP5942447 B2 JP 5942447B2
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- Prior art keywords
- polyester resin
- acid
- aliphatic
- resin composition
- film
- Prior art date
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- 239000004645 polyester resin Substances 0.000 title claims description 190
- 229920001225 polyester resin Polymers 0.000 title claims description 184
- 239000011342 resin composition Substances 0.000 title claims description 66
- 239000000203 mixture Substances 0.000 title claims description 29
- 125000001931 aliphatic group Chemical group 0.000 claims description 60
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid group Chemical group C(CCC(=O)O)(=O)O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 47
- 239000002253 acid Substances 0.000 claims description 42
- 239000000945 filler Substances 0.000 claims description 37
- 239000002245 particle Substances 0.000 claims description 27
- 229920005989 resin Polymers 0.000 claims description 26
- 239000011347 resin Substances 0.000 claims description 26
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical group CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 claims description 19
- 238000000465 moulding Methods 0.000 claims description 15
- 125000001142 dicarboxylic acid group Chemical group 0.000 claims description 9
- 239000000314 lubricant Substances 0.000 claims description 8
- 229920001634 Copolyester Polymers 0.000 claims description 4
- -1 miscellaneous goods Substances 0.000 description 38
- 238000000034 method Methods 0.000 description 33
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 22
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 22
- 150000001875 compounds Chemical group 0.000 description 22
- 238000004519 manufacturing process Methods 0.000 description 22
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 20
- 238000002844 melting Methods 0.000 description 19
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 18
- 230000008018 melting Effects 0.000 description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 17
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 16
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 15
- 229920003232 aliphatic polyester Polymers 0.000 description 14
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 14
- 230000000694 effects Effects 0.000 description 14
- 239000001384 succinic acid Substances 0.000 description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 13
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 229910000019 calcium carbonate Inorganic materials 0.000 description 11
- 235000014113 dietary fatty acids Nutrition 0.000 description 11
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- 125000003118 aryl group Chemical group 0.000 description 10
- 229920001577 copolymer Polymers 0.000 description 10
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- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 9
- 229920006167 biodegradable resin Polymers 0.000 description 9
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 9
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- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 8
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- NGEWQZIDQIYUNV-UHFFFAOYSA-N 2-hydroxy-3-methylbutyric acid Chemical compound CC(C)C(O)C(O)=O NGEWQZIDQIYUNV-UHFFFAOYSA-N 0.000 description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 150000002148 esters Chemical class 0.000 description 6
- 150000004665 fatty acids Chemical class 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
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- 239000007864 aqueous solution Substances 0.000 description 5
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- 125000005442 diisocyanate group Chemical group 0.000 description 5
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- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 4
- 239000003054 catalyst Substances 0.000 description 4
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- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
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- 239000008107 starch Substances 0.000 description 4
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- 238000003756 stirring Methods 0.000 description 4
- TYFQFVWCELRYAO-UHFFFAOYSA-N suberic acid Chemical compound OC(=O)CCCCCCC(O)=O TYFQFVWCELRYAO-UHFFFAOYSA-N 0.000 description 4
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 4
- AFENDNXGAFYKQO-VKHMYHEASA-N (S)-2-hydroxybutyric acid Chemical compound CC[C@H](O)C(O)=O AFENDNXGAFYKQO-VKHMYHEASA-N 0.000 description 3
- 238000005160 1H NMR spectroscopy Methods 0.000 description 3
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- NYHNVHGFPZAZGA-UHFFFAOYSA-N 2-hydroxyhexanoic acid Chemical compound CCCCC(O)C(O)=O NYHNVHGFPZAZGA-UHFFFAOYSA-N 0.000 description 3
- IWHLYPDWHHPVAA-UHFFFAOYSA-N 6-hydroxyhexanoic acid Chemical compound OCCCCCC(O)=O IWHLYPDWHHPVAA-UHFFFAOYSA-N 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 229920002261 Corn starch Polymers 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
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- LYRFLYHAGKPMFH-UHFFFAOYSA-N octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(N)=O LYRFLYHAGKPMFH-UHFFFAOYSA-N 0.000 description 3
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- UQDJGEHQDNVPGU-UHFFFAOYSA-N serine phosphoethanolamine Chemical compound [NH3+]CCOP([O-])(=O)OCC([NH3+])C([O-])=O UQDJGEHQDNVPGU-UHFFFAOYSA-N 0.000 description 3
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- RMVRSNDYEFQCLF-UHFFFAOYSA-N thiophenol Chemical compound SC1=CC=CC=C1 RMVRSNDYEFQCLF-UHFFFAOYSA-N 0.000 description 3
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- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 3
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- BDNKZNFMNDZQMI-UHFFFAOYSA-N 1,3-diisopropylcarbodiimide Chemical compound CC(C)N=C=NC(C)C BDNKZNFMNDZQMI-UHFFFAOYSA-N 0.000 description 2
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- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 description 1
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- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
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- JNXDCMUUZNIWPQ-UHFFFAOYSA-N trioctyl benzene-1,2,4-tricarboxylate Chemical compound CCCCCCCCOC(=O)C1=CC=C(C(=O)OCCCCCCCC)C(C(=O)OCCCCCCCC)=C1 JNXDCMUUZNIWPQ-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
- Y10T428/1334—Nonself-supporting tubular film or bag [e.g., pouch, envelope, packet, etc.]
- Y10T428/1345—Single layer [continuous layer]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
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| JP2016532017A (ja) * | 2013-08-09 | 2016-10-13 | アムテック リサーチ インターナショナル エルエルシー | 即時的に濡れるポリマー繊維シート |
| JP6394181B2 (ja) * | 2013-08-29 | 2018-09-26 | 三菱ケミカル株式会社 | 脂肪族ポリエステル樹脂組成物 |
| JP6174453B2 (ja) * | 2013-10-28 | 2017-08-02 | 帝人フィルムソリューション株式会社 | 白色ポリエステルフィルム |
| EP3252103B1 (en) * | 2015-01-30 | 2020-09-09 | Toyobo Co., Ltd. | Polylactic acid-containing aqueous dispersion |
| ITUB20152688A1 (it) | 2015-07-31 | 2017-01-31 | Novamont Spa | Composizione polimerica per la realizzazione di articoli stampati biodegradabili in compostaggio industriale. |
| JP6683007B2 (ja) * | 2016-05-13 | 2020-04-15 | 昭和電工株式会社 | 樹脂組成物および生分解性フィルム |
| JP6717657B2 (ja) * | 2016-05-13 | 2020-07-01 | 昭和電工株式会社 | 生分解性フィルム |
| JP6885826B2 (ja) * | 2016-09-15 | 2021-06-16 | デクセリアルズ株式会社 | 水浄化剤の製造方法、及び排水処理方法 |
| JP6885147B2 (ja) * | 2017-03-28 | 2021-06-09 | 三菱ケミカル株式会社 | 樹脂組成物及び該樹脂組成物を成形してなる樹脂成形品 |
| US20200390944A1 (en) | 2018-03-01 | 2020-12-17 | Tepha, Inc. | Medical devices containing compositions of poly(butylene succinate) and copolymers thereof |
| WO2019169296A1 (en) | 2018-03-01 | 2019-09-06 | Tepha, Inc. | Medical devices containing poly(butylene succinate) and copolymers thereof |
| CN112585512B (zh) * | 2018-08-17 | 2023-06-30 | 大阪燃气化学有限公司 | 相位差膜及其制造方法 |
| KR102229124B1 (ko) * | 2018-12-06 | 2021-03-16 | 에스케이씨 주식회사 | 폴리에스테르 수지 조성물, 폴리에스테르 필름 및 이의 제조방법 |
| KR102176955B1 (ko) * | 2019-03-27 | 2020-11-10 | 한국생산기술연구원 | 생분해성 고분자 조성물, 그를 포함하는 멀칭 필름 및 그의 제조방법 |
| US12410313B2 (en) * | 2019-06-28 | 2025-09-09 | Covestro Deutschland Ag | Mineral-reinforced co-polyester blend |
| BR112022003620A2 (pt) | 2019-08-29 | 2022-05-24 | Tepha Inc | Dispositivos médicos contendo poli(succinato de butileno) e copolímeros do mesmo |
| JP6675700B1 (ja) * | 2019-10-31 | 2020-04-01 | 株式会社Ｔｂｍ | 樹脂組成物、及び樹脂成形品の製造方法 |
| IT202000007963A1 (it) * | 2020-04-15 | 2021-10-15 | Novamont Spa | Composizione polimerica biodegradabile per la realizzazione di articoli stampati. |
| CN116490290B (zh) * | 2020-11-18 | 2024-09-13 | 关西涂料株式会社 | 高固体含量涂料组合物及多层涂膜形成方法 |
| JP6916571B1 (ja) * | 2021-03-25 | 2021-08-11 | 株式会社Tbm | 樹脂組成物、及び成形品 |
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| JP2006117749A (ja) * | 2004-10-20 | 2006-05-11 | Sekisui Seikei Ltd | プラスチック材の変形保持性改良方法 |
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| JP2008195788A (ja) * | 2007-02-09 | 2008-08-28 | Sumitomo Electric Fine Polymer Inc | 電子機器用の外装部材、該外装部材からなる外部接続端子用キャップを備えた電子機器 |
| JP2008195784A (ja) * | 2007-02-09 | 2008-08-28 | Mitsubishi Chemicals Corp | ポリエステル系樹脂組成物及びその成形体 |
| JP2009221337A (ja) * | 2008-03-14 | 2009-10-01 | Mitsubishi Chemicals Corp | 樹脂組成物並びに該樹脂組成物からなる成形品及びフィルム |
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| CN103339195A (zh) | 2013-10-02 |
| US20130316106A1 (en) | 2013-11-28 |
| EP2671921B1 (en) | 2016-10-19 |
| CN103339195B (zh) | 2015-08-12 |
| EP2671921A4 (en) | 2014-12-17 |
| CN104945861A (zh) | 2015-09-30 |
| EP2671921A1 (en) | 2013-12-11 |
| WO2012105626A1 (ja) | 2012-08-09 |
| US8747974B2 (en) | 2014-06-10 |
| JP2016106171A (ja) | 2016-06-16 |
| JP2013040321A (ja) | 2013-02-28 |
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