JP5480148B2 - マグネシウム化合物担持非メタロセン触媒およびその製造 - Google Patents

マグネシウム化合物担持非メタロセン触媒およびその製造 Download PDF

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JP5480148B2
JP5480148B2 JP2010529215A JP2010529215A JP5480148B2 JP 5480148 B2 JP5480148 B2 JP 5480148B2 JP 2010529215 A JP2010529215 A JP 2010529215A JP 2010529215 A JP2010529215 A JP 2010529215A JP 5480148 B2 JP5480148 B2 JP 5480148B2
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magnesium compound
nonmetallocene
molar ratio
ligand
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JP2011500901A5 (https=
JP2011500901A (ja
Inventor
越峰 顧
小利 姚
傳峰 李
忠林 馬
峰 郭
波 劉
亞明 王
韶輝 陳
曉強 李
基業 柏
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Sinopec Yangzi Petrochemical Co Ltd
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Sinopec Yangzi Petrochemical Co Ltd
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Priority claimed from CN2007101626671A external-priority patent/CN101412766B/zh
Priority claimed from CN2007101626760A external-priority patent/CN101412768B/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
JP2010529215A 2007-10-16 2008-10-15 マグネシウム化合物担持非メタロセン触媒およびその製造 Active JP5480148B2 (ja)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
CN2007101626671A CN101412766B (zh) 2007-10-16 2007-10-16 一种镁化合物负载型非茂金属催化剂及其制备方法
CN200710162667.1 2007-10-16
CN200710162676.0 2007-10-16
CN2007101626760A CN101412768B (zh) 2007-10-16 2007-10-16 一种镁化合物负载型非茂金属催化剂及其制备方法
PCT/CN2008/001739 WO2009052701A1 (en) 2007-10-16 2008-10-15 Non-metallocene catalyst supported on magnesium compound and its preparation method

Publications (3)

Publication Number Publication Date
JP2011500901A JP2011500901A (ja) 2011-01-06
JP2011500901A5 JP2011500901A5 (https=) 2011-03-10
JP5480148B2 true JP5480148B2 (ja) 2014-04-23

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JP2010529215A Active JP5480148B2 (ja) 2007-10-16 2008-10-15 マグネシウム化合物担持非メタロセン触媒およびその製造

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Country Link
US (1) US8716416B2 (https=)
EP (1) EP2202246B1 (https=)
JP (1) JP5480148B2 (https=)
KR (1) KR101206940B1 (https=)
WO (1) WO2009052701A1 (https=)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2202247B1 (en) * 2007-10-16 2012-12-12 Sinopec Yangzi Petrochemical Company Ltd. Supported non-metallocene catalyst and its preparation method
MY156621A (en) 2009-08-21 2016-03-15 China Petroleum & Chemical A catalyst component for ethylene polymerization, preparation thereof and a catalyst comprising the catalyst component
JP5670460B2 (ja) 2009-10-26 2015-02-18 中国石油化工股▲ふん▼有限公司 担持型非メタロセン触媒、その製造方法およびその使用
WO2011050566A1 (zh) * 2009-10-26 2011-05-05 中国石油化工股份有限公司 负载型非茂金属催化剂、其制备方法及其应用
EP2500365B1 (en) * 2009-11-13 2020-05-06 China Petroleum & Chemical Corporation Supported non-metallocene catalyst and preparation method and uses thereof
WO2011057468A1 (zh) * 2009-11-13 2011-05-19 中国石油化工股份有限公司 负载型非茂金属催化剂、其制备方法及其应用
CN103304694B (zh) * 2012-03-06 2016-02-24 中国石油化工股份有限公司 负载型非茂金属催化剂、其制备方法及其应用
US10221264B2 (en) * 2012-04-27 2019-03-05 W. R. Grace & Co.-Conn. Activator compositions, their preparation, and their use in catalysts
EP2900702B1 (en) * 2012-09-30 2018-05-02 Bridgestone Corporation Polymerization method employing an organometallic catalyst complex
SG2014001325A (en) * 2013-05-21 2014-12-30 China Petroleum & Chemical A supported nonmetallocene catalyst, preparation and use thereof
JP5902210B2 (ja) 2013-06-08 2016-04-13 中国石油化工股▲ふん▼有限公司 担持型非メタロセン触媒、その製造方法およびその使用
CN109485763A (zh) * 2017-09-11 2019-03-19 中国石油化工股份有限公司 负载型非茂金属催化剂、其制备方法及其应用
CN110964137B (zh) * 2018-09-28 2023-08-01 中国石油化工股份有限公司 镁化合物负载型非茂金属催化剂、其制备方法及其应用
CN110964138B (zh) * 2018-09-28 2023-08-01 中国石油化工股份有限公司 镁单载体分段原位负载型非茂金属催化剂及其制备方法
CN110964140B (zh) * 2018-09-28 2023-08-04 中国石油化工股份有限公司 一种原位负载型非茂金属催化剂、其制备方法及其应用
CN110964136B (zh) * 2018-09-28 2023-08-04 中国石油化工股份有限公司 复合载体负载型非茂金属催化剂、其制备方法及其应用
CN110964132B (zh) * 2018-09-28 2023-08-04 中国石油化工股份有限公司 复合载体分段原位负载型非茂金属催化剂及其制备方法
CN110964139B (zh) * 2018-09-28 2023-05-16 中国石油化工股份有限公司 镁单载体原位负载型非茂金属催化剂、其制备方法及应用

Family Cites Families (52)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US574417A (en) 1897-01-05 George w
US4808561A (en) 1985-06-21 1989-02-28 Exxon Chemical Patents Inc. Supported polymerization catalyst
CA1268754A (en) 1985-06-21 1990-05-08 Howard Curtis Welborn, Jr. Supported polymerization catalyst
US5077255A (en) 1986-09-09 1991-12-31 Exxon Chemical Patents Inc. New supported polymerization catalyst
US4871705A (en) * 1988-06-16 1989-10-03 Exxon Chemical Patents Inc. Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst
CN1053673A (zh) 1989-07-12 1991-08-07 雷晓磊 改传统击发为电击发的枪枝及其子弹
GR1000753B (el) 1989-08-07 1992-12-30 Basf Ag Αποφυλλωτικο μεσο για τη βαμβακια.
IT1237812B (it) 1989-12-22 1993-06-17 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
CA2032543A1 (en) * 1989-12-26 1991-06-27 Robert Olds Hagerty Dimethylaluminum chloride-activated olefin polymerisation catalyst composition
IT1245249B (it) 1991-03-27 1994-09-13 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
CN1060179A (zh) 1991-09-29 1992-04-08 武学诗 全膜真空电容器和局部浸渍电容器
US5240894A (en) 1992-05-18 1993-08-31 Exxon Chemical Patents Inc. Method for making and using a supported metallocene catalyst system
BE1007148A3 (fr) 1993-05-17 1995-04-11 Solvay Support pour catalyseurs, procede pour la fabrication d'un gel precurseur d'un support pour catalyseurs, procede de preparation d'un support pour catalyseurs, catalyseur pour la polymerisation d'olefines et procede pour la polymerisation d'olefines au moyen de ce catalyseur.
IT1264680B1 (it) 1993-07-07 1996-10-04 Spherilene Srl Catalizzatori supportati per la polimerizzazione delle olefine
DE69409813T2 (de) 1993-08-09 1999-01-07 Livien Domien Antwerpen Ven Dampfkraftmaschine
DE59503827D1 (de) 1994-06-03 1998-11-12 Pcd Polymere Ag Katalysatorträger, geträgerte Metallocenkatalysatoren und deren Verwendung für die Herstellung von Polyolefinen
FR2725993B1 (fr) 1994-10-21 1996-11-29 Atochem Elf Sa Composante catalytique solide contenant du zirconium et des groupements cycloalcadienyles, son procede d'obtention et procede de polymerisation des olefines en sa presence
US5840808A (en) * 1995-02-07 1998-11-24 Mitsui Petrochemical Industries, Ltd. Process for preparing olefin polymer
JPH08274669A (ja) 1995-03-30 1996-10-18 Sanyo Electric Co Ltd Ｆｍ受信機およびこれに用いられる信号処理装置
CN1049439C (zh) 1996-08-26 2000-02-16 中国石油化工总公司 负载型金属茂催化剂、其制备及应用
KR100223105B1 (ko) * 1996-10-09 1999-10-15 유현식 올레핀 중합용 촉매와 이를 이용한 올레핀 중합방법
CN1060179C (zh) 1998-05-08 2001-01-03 中国石油化工集团公司 一种负载型茂金属催化剂的制备方法
FI981148A7 (fi) 1998-05-25 1999-11-26 Borealis As Uusia aktivaattorijärjestelmä metalloseeniyhdisteitä varten
KR100430979B1 (ko) 1999-02-04 2004-05-12 삼성아토피나주식회사 올레핀 중합용 킬레이트 촉매의 제조방법
EP1194432A1 (en) 1999-06-30 2002-04-10 Union Carbide Chemicals & Plastics Technology Corporation Magnesium-zirconium alkoxide complexes and polymerization catalysts made therefrom
CN1363537A (zh) 2001-01-08 2002-08-14 柳忠奇 复合硼镁肥及其制备工艺
CN1136239C (zh) 2001-01-18 2004-01-28 中国石油化工股份有限公司 卤化镁/二氧化硅负载的半茂金属催化剂及其制备与应用
EP1229055A1 (en) 2001-02-06 2002-08-07 BP Chemicals S.N.C. Process for the gas-phase (co)-polymerisation of olefins in a fluidised bed reactor
CN1218970C (zh) 2002-02-09 2005-09-14 中国科学院上海有机化学研究所 新型烯烃聚合催化剂
CN1256351C (zh) 2001-07-23 2006-05-17 中国科学院上海有机化学研究所 烯烃聚合及共聚合催化剂、合成方法及其用途
EP1426385B1 (en) 2001-07-23 2012-08-22 Shanghai Institute Of Organic Chemistry, Chinese Academy Of Sciences Catalyst for polymerization or copolymerization of olefins, preparation and use of the same
CN1160380C (zh) 2001-09-03 2004-08-04 中国石油天然气股份有限公司 一种合成负载型茂金属催化剂的方法
CN1137909C (zh) 2001-10-26 2004-02-11 中国科学院长春应用化学研究所 插层型负载茂金属催化剂及其催化烯烃聚合
AU2002365867A1 (en) 2001-11-30 2003-06-17 Exxonmobil Chemical Patents Inc. Method of making mixed ziegler-natta/metallocene catalysts
CN1691979A (zh) 2001-11-30 2005-11-02 埃克森美孚化学专利公司 具有高活性的双金属催化剂
CN1179982C (zh) 2002-12-13 2004-12-15 中国科学院上海有机化学研究所 烯烃聚合催化剂、合成方法及其用途
KR100491627B1 (ko) 2002-12-31 2005-05-27 삼성토탈 주식회사 카르보디이미드계열 리간드에 의해 킬레이트 결합된촉매를 이용한 에틸렌 중합 및 공중합방법
US20080116179A1 (en) * 2003-04-11 2008-05-22 Hypertherm, Inc. Method and apparatus for alignment of components of a plasma arc torch
CN1281634C (zh) 2003-10-29 2006-10-25 扬子石油化工股份有限公司 复合载体负载的非茂金属催化剂的负载化方法和聚合应用
CN1269852C (zh) 2003-10-29 2006-08-16 扬子石油化工股份有限公司 负载型非茂金属催化剂的负载化方法和聚合应用
US7348383B2 (en) 2003-11-20 2008-03-25 Union Carbide Chemicals And Plastics Technology Corporation Spray-dried, mixed metal ziegler catalyst compositions
CN100362024C (zh) 2004-12-17 2008-01-16 扬子石油化工股份有限公司 非茂金属催化剂的高活性负载化方法
CN1789291A (zh) 2004-12-17 2006-06-21 扬子石油化工股份有限公司 负载型非茂金属催化剂的烯烃聚合和共聚合方法
KR101075404B1 (ko) * 2004-12-17 2011-10-24 양지 페트로케미컬 컴퍼니 코., 리미티드. 지지된 비메탈로센 올레핀 중합 촉매, 제조 방법 및 그용도
CN1789292A (zh) 2004-12-17 2006-06-21 扬子石油化工股份有限公司 负载型非茂金属催化剂在淤浆法乙烯聚合工艺中的应用方法
US7491781B2 (en) * 2005-03-08 2009-02-17 Ineos Usa Llc Propylene polymer catalyst donor component
CN100569808C (zh) 2005-03-31 2009-12-16 中国石油化工股份有限公司 一种负载型非茂金属催化剂及其制备方法
CN100460423C (zh) 2005-06-30 2009-02-11 中国石油化工股份有限公司 原位合成的负载型钒系非茂聚烯烃催化剂及制备与应用
CN1962702B (zh) 2005-11-10 2010-10-27 中国石化扬子石油化工有限公司 一种负载型非茂金属烯烃聚合催化剂、其制备方法及其应用
CN100569734C (zh) 2006-05-22 2009-12-16 中国科学院上海有机化学研究所 一类含杂原子的有机化合物及其在齐格勒-纳塔催化剂中的应用
CN100482697C (zh) 2006-05-22 2009-04-29 中国科学院上海有机化学研究所 一类单活性中心齐格勒-纳塔烯烃聚合催化剂
EP2202247B1 (en) 2007-10-16 2012-12-12 Sinopec Yangzi Petrochemical Company Ltd. Supported non-metallocene catalyst and its preparation method

Also Published As

Publication number Publication date
US20110237764A1 (en) 2011-09-29
EP2202246A1 (en) 2010-06-30
KR20100105533A (ko) 2010-09-29
EP2202246B1 (en) 2016-06-15
JP2011500901A (ja) 2011-01-06
EP2202246A4 (en) 2012-08-08
KR101206940B1 (ko) 2012-11-30
WO2009052701A1 (en) 2009-04-30
US8716416B2 (en) 2014-05-06

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