JP5477819B2 - コーティングされた粒状発泡性ポリ乳酸 - Google Patents
コーティングされた粒状発泡性ポリ乳酸 Download PDFInfo
- Publication number
- JP5477819B2 JP5477819B2 JP2010503996A JP2010503996A JP5477819B2 JP 5477819 B2 JP5477819 B2 JP 5477819B2 JP 2010503996 A JP2010503996 A JP 2010503996A JP 2010503996 A JP2010503996 A JP 2010503996A JP 5477819 B2 JP5477819 B2 JP 5477819B2
- Authority
- JP
- Japan
- Prior art keywords
- polylactic acid
- granular
- coating
- acid according
- foamable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000004626 polylactic acid Substances 0.000 title claims description 175
- 229920000747 poly(lactic acid) Polymers 0.000 title claims description 174
- 238000000576 coating method Methods 0.000 claims description 60
- 239000002245 particle Substances 0.000 claims description 55
- 239000011248 coating agent Substances 0.000 claims description 52
- 238000000034 method Methods 0.000 claims description 26
- 238000005187 foaming Methods 0.000 claims description 16
- 239000004604 Blowing Agent Substances 0.000 claims description 13
- PEDCQBHIVMGVHV-UHFFFAOYSA-N glycerol group Chemical group OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 12
- 239000006260 foam Substances 0.000 claims description 10
- 239000004014 plasticizer Substances 0.000 claims description 10
- 239000011118 polyvinyl acetate Substances 0.000 claims description 10
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 10
- 239000004970 Chain extender Substances 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 239000002667 nucleating agent Substances 0.000 claims description 8
- 238000000465 moulding Methods 0.000 claims description 7
- -1 cyclic dianhydrides Chemical class 0.000 claims description 6
- 235000011187 glycerol Nutrition 0.000 claims description 6
- 239000000314 lubricant Substances 0.000 claims description 6
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical group [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims description 6
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 5
- 239000005018 casein Substances 0.000 claims description 5
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 claims description 5
- 235000021240 caseins Nutrition 0.000 claims description 5
- 229920001610 polycaprolactone Polymers 0.000 claims description 5
- 239000004632 polycaprolactone Substances 0.000 claims description 5
- 239000000600 sorbitol Substances 0.000 claims description 5
- 239000001856 Ethyl cellulose Substances 0.000 claims description 4
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 claims description 4
- 235000019325 ethyl cellulose Nutrition 0.000 claims description 4
- 229920001249 ethyl cellulose Polymers 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 229920002988 biodegradable polymer Polymers 0.000 claims description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 2
- 239000004621 biodegradable polymer Substances 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 125000005442 diisocyanate group Chemical group 0.000 claims description 2
- 239000012802 nanoclay Substances 0.000 claims description 2
- 150000004893 oxazines Chemical class 0.000 claims description 2
- 150000002918 oxazolines Chemical class 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims 2
- 150000001451 organic peroxides Chemical class 0.000 claims 1
- 230000004927 fusion Effects 0.000 description 25
- 239000001993 wax Substances 0.000 description 8
- 239000000178 monomer Substances 0.000 description 7
- JVTAAEKCZFNVCJ-UWTATZPHSA-N D-lactic acid Chemical compound C[C@@H](O)C(O)=O JVTAAEKCZFNVCJ-UWTATZPHSA-N 0.000 description 6
- 229920004482 WACKER® Polymers 0.000 description 6
- 238000009776 industrial production Methods 0.000 description 6
- 229930182843 D-Lactic acid Natural products 0.000 description 5
- 229940022769 d- lactic acid Drugs 0.000 description 5
- 239000004088 foaming agent Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- JVTAAEKCZFNVCJ-REOHCLBHSA-N L-lactic acid Chemical compound C[C@H](O)C(O)=O JVTAAEKCZFNVCJ-REOHCLBHSA-N 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 4
- 229920000573 polyethylene Polymers 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 238000001125 extrusion Methods 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 235000019698 starch Nutrition 0.000 description 3
- 239000008107 starch Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000001030 gas--liquid chromatography Methods 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 239000004310 lactic acid Substances 0.000 description 2
- 235000014655 lactic acid Nutrition 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000011325 microbead Substances 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 108010076119 Caseins Proteins 0.000 description 1
- 229920001661 Chitosan Polymers 0.000 description 1
- 102000008186 Collagen Human genes 0.000 description 1
- 108010035532 Collagen Proteins 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- 239000004605 External Lubricant Substances 0.000 description 1
- 229920002148 Gellan gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- BZLVMXJERCGZMT-UHFFFAOYSA-N Methyl tert-butyl ether Chemical compound COC(C)(C)C BZLVMXJERCGZMT-UHFFFAOYSA-N 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- 108010073771 Soybean Proteins Proteins 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- 239000004204 candelilla wax Substances 0.000 description 1
- 235000013868 candelilla wax Nutrition 0.000 description 1
- 229940073532 candelilla wax Drugs 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 235000010418 carrageenan Nutrition 0.000 description 1
- 239000000679 carrageenan Substances 0.000 description 1
- 229920001525 carrageenan Polymers 0.000 description 1
- 229940113118 carrageenan Drugs 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229940045110 chitosan Drugs 0.000 description 1
- 229920001436 collagen Polymers 0.000 description 1
- 238000009264 composting Methods 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 238000012936 correction and preventive action Methods 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 229920005839 ecoflex® Polymers 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000010097 foam moulding Methods 0.000 description 1
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 1
- 235000010492 gellan gum Nutrition 0.000 description 1
- 239000000216 gellan gum Substances 0.000 description 1
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 235000019809 paraffin wax Nutrition 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 229960000292 pectin Drugs 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 235000018102 proteins Nutrition 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000012776 robust process Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940001941 soy protein Drugs 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/16—Making expandable particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/22—After-treatment of expandable particles; Forming foamed products
- C08J9/224—Surface treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
- C08J2201/03—Extrusion of the foamable blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/04—Polyesters derived from hydroxy carboxylic acids, e.g. lactones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2401/00—Characterised by the use of cellulose, modified cellulose or cellulose derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2425/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/10—Esters of organic acids, i.e. acylates
- C08L1/12—Cellulose acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2991—Coated
- Y10T428/2998—Coated including synthetic resin or polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Biological Depolymerization Polymers (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Fertilizers (AREA)
- Glanulating (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL1033719A NL1033719C2 (nl) | 2007-04-19 | 2007-04-19 | Deeltjesvormig expandeerbaar polymelkzuur, werkwijze voor het vervaardigen hiervan, geschuimd vormdeel op basis van deeltjesvormig expandeerbaar polymelkzuur evenals werkwijze voor het vervaardigen hiervan. |
| NL1033719 | 2007-04-19 | ||
| PCT/NL2008/000109 WO2008130226A2 (en) | 2007-04-19 | 2008-04-21 | Coated particulate expandable polyactic acid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2010525099A JP2010525099A (ja) | 2010-07-22 |
| JP5477819B2 true JP5477819B2 (ja) | 2014-04-23 |
Family
ID=38748134
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010503996A Expired - Fee Related JP5477819B2 (ja) | 2007-04-19 | 2008-04-21 | コーティングされた粒状発泡性ポリ乳酸 |
| JP2010503995A Pending JP2010526163A (ja) | 2007-04-19 | 2008-04-21 | ポリ乳酸および60℃超のtgを有するポリマーを含むポリマー混合物 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2010503995A Pending JP2010526163A (ja) | 2007-04-19 | 2008-04-21 | ポリ乳酸および60℃超のtgを有するポリマーを含むポリマー混合物 |
Country Status (16)
| Country | Link |
|---|---|
| US (2) | US8268901B2 (enExample) |
| EP (2) | EP2137250B1 (enExample) |
| JP (2) | JP5477819B2 (enExample) |
| KR (1) | KR101443721B1 (enExample) |
| CN (1) | CN101668798B (enExample) |
| AU (1) | AU2008241682B2 (enExample) |
| DK (1) | DK2137250T3 (enExample) |
| ES (1) | ES2651446T3 (enExample) |
| HR (1) | HRP20171681T1 (enExample) |
| HU (1) | HUE037488T2 (enExample) |
| NL (1) | NL1033719C2 (enExample) |
| NO (1) | NO2137250T3 (enExample) |
| NZ (1) | NZ580424A (enExample) |
| PL (1) | PL2137250T3 (enExample) |
| PT (1) | PT2137250T (enExample) |
| WO (2) | WO2008130225A2 (enExample) |
Families Citing this family (57)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201022328A (en) | 2008-06-25 | 2010-06-16 | Metabolix Inc | Branched PHA compositions, methods for their production, and use in applications |
| JP5339857B2 (ja) * | 2008-11-05 | 2013-11-13 | ユニチカ株式会社 | 生分解性難燃ポリエステル発泡用樹脂組成物、及びそれより得られる発泡体、その成形体 |
| EP2370508A1 (en) * | 2008-12-02 | 2011-10-05 | Metalbolix Inc. | Production of polyhydroxyalkanoate foam |
| US20110217430A1 (en) * | 2010-03-08 | 2011-09-08 | Chieh-Chun Chau | Thermoplastic and biodegradable polymer foams containing oxygen scavenger |
| AT509268A1 (de) | 2009-12-30 | 2011-07-15 | Sunpor Kunststoff Gmbh | Expandierbare polymerisate aus celluloseacetatbutyrat |
| ES2558062T3 (es) * | 2010-01-14 | 2016-02-01 | Basf Se | Método para la producción de granulados que contienen poliácido láctico que pueden expandirse |
| US20120009420A1 (en) | 2010-07-07 | 2012-01-12 | Lifoam Industries | Compostable or Biobased Foams |
| US8962706B2 (en) | 2010-09-10 | 2015-02-24 | Lifoam Industries, Llc | Process for enabling secondary expansion of expandable beads |
| EP2613836B1 (en) | 2010-09-10 | 2023-03-08 | Fisher & Paykel Healthcare Limited | A component for conveying gases |
| US9045611B2 (en) | 2011-03-04 | 2015-06-02 | Cryovac, Inc. | Process for preparing a heat resistant polylactic acid foamed article |
| SK262011A3 (sk) * | 2011-04-11 | 2012-11-05 | Ustav Polymerov Sav | Biologically degradable polymeric composition having improved properties |
| AT511509A1 (de) | 2011-04-18 | 2012-12-15 | Sunpor Kunststoff Gmbh | Expandierbare polymerisate aus celluloseacetatbutyrat und styrolpolymerisat |
| NL1039140C2 (nl) * | 2011-10-29 | 2013-05-06 | Synbra Tech Bv | Groeisubstraat voor planten. |
| NL2008240C2 (nl) | 2012-02-06 | 2013-08-08 | Synbra Tech Bv | Werkwijze voor het vervaardigen van schuimvormdelen. |
| US8975305B2 (en) | 2012-02-10 | 2015-03-10 | Kimberly-Clark Worldwide, Inc. | Rigid renewable polyester compositions having a high impact strength and tensile elongation |
| US8980964B2 (en) | 2012-02-10 | 2015-03-17 | Kimberly-Clark Worldwide, Inc. | Renewable polyester film having a low modulus and high tensile elongation |
| US10858762B2 (en) | 2012-02-10 | 2020-12-08 | Kimberly-Clark Worldwide, Inc. | Renewable polyester fibers having a low density |
| US8637130B2 (en) | 2012-02-10 | 2014-01-28 | Kimberly-Clark Worldwide, Inc. | Molded parts containing a polylactic acid composition |
| US9040598B2 (en) | 2012-02-10 | 2015-05-26 | Kimberly-Clark Worldwide, Inc. | Renewable polyester compositions having a low density |
| KR101436200B1 (ko) * | 2012-03-30 | 2014-09-01 | (주)엘지하우시스 | 사슬이 연장된 폴리락트산을 이용한 발포 시트 및 이의 제조방법 |
| US9353258B2 (en) | 2012-06-05 | 2016-05-31 | Metabolix, Inc. | Low glass transition polyhydroxyalkanoates for modification of biodegradable polymers |
| US9475930B2 (en) | 2012-08-17 | 2016-10-25 | Metabolix, Inc. | Biobased rubber modifiers for polymer blends |
| WO2014194220A1 (en) | 2013-05-30 | 2014-12-04 | Metabolix, Inc. | Recyclate blends |
| JP6538659B2 (ja) * | 2013-06-18 | 2019-07-03 | トタル リサーチ アンド テクノロジー フエリユイ | ポリマー組成物 |
| KR101762996B1 (ko) * | 2013-08-29 | 2017-07-28 | (주)엘지하우시스 | 발포 시트용 발포성 수지 조성물, 발포 시트, 입자상의 폴리락트산 수지의 제조 방법 및 발포 시트의 제조 방법 |
| KR101762997B1 (ko) | 2013-08-29 | 2017-07-28 | (주)엘지하우시스 | 폴리락트산 수지의 섬유상 입자를 제조하는 방법, 발포 시트 형성용 콜로이드 조성물, 발포 시트 및 발포 시트의 제조 방법 |
| EP3055352B1 (de) | 2013-10-09 | 2017-09-13 | Basf Se | Verfahren zur herstellung von expandierten polyester-schaumstoffpartikeln |
| US10266754B2 (en) | 2014-03-05 | 2019-04-23 | Halliburton Energy Services, Inc. | Degradable reticulated foam particulates for use in forming highly conductive proppant packs |
| US10611903B2 (en) | 2014-03-27 | 2020-04-07 | Cj Cheiljedang Corporation | Highly filled polymer systems |
| DE102014216992A1 (de) * | 2014-08-26 | 2016-03-03 | Adidas Ag | Expandierte Polymerpellets |
| EP3041892B1 (en) * | 2014-08-26 | 2023-08-16 | Adidas AG | Method for manufacturing molded components |
| WO2016032513A1 (en) | 2014-08-29 | 2016-03-03 | Halliburton Energy Services, Inc. | Reticulated materials for the formation of proppant-free channels |
| EP3233992B1 (de) * | 2014-12-17 | 2019-02-20 | Basf Se | Verfahren zur herstellung von expandierbaren polymilchsäure-haltigen granulaten |
| WO2016105998A1 (en) | 2014-12-22 | 2016-06-30 | 3M Innovative Properties Company | Compositions and films comprising polylactic acid polymer, polyvinyl acetate polymer and plasticizer |
| NL2014258B1 (en) * | 2015-02-06 | 2016-10-13 | Synbra Tech B V | A process for producing foam mouldings. |
| JP6468021B2 (ja) * | 2015-03-20 | 2019-02-13 | 株式会社リコー | 立体造形用粉末材料、及び立体造形用材料セット、並びに、立体造形物、立体造形物の製造方法及び製造装置 |
| EP4467610A3 (en) | 2015-11-17 | 2025-02-19 | CJ CheilJedang Corporation | Polymer blends with controllable biodegradation rates |
| CN108699272B (zh) * | 2016-02-15 | 2021-10-26 | 3M创新有限公司 | 包括结构化表面的聚乳酸聚合物基膜和制品 |
| NL2016774B1 (nl) | 2016-05-13 | 2017-11-16 | Synbra Tech B V | Een op polymelkzuur gebaseerde samenstelling. |
| US11066551B2 (en) | 2016-05-20 | 2021-07-20 | 3M Innovative Properties Company | Oriented polylactic acid polymer based film |
| JP6918025B2 (ja) * | 2016-06-07 | 2021-08-11 | ビーエイエスエフ・ソシエタス・エウロパエアBasf Se | 膨張可能なポリ乳酸含有顆粒の製造方法 |
| US10982090B2 (en) | 2016-06-21 | 2021-04-20 | 3M Innovative Properties Company | Graphic articles comprising polylactic acid polymer based film |
| EP3472232B1 (en) * | 2016-06-21 | 2023-04-12 | 3M Innovative Properties Company | Foam compositions comprising polylactic acid polymer, polyvinyl acetate polymer and plasticizer, articles, and methods of making and using same |
| NL2017214B1 (en) | 2016-07-22 | 2018-01-31 | Synbra Tech B V | Artificial turf suitable for sports fields |
| NL2018864B1 (en) | 2017-05-08 | 2018-11-14 | Synbra Tech B V | Artificial turf suitable for sports fields |
| CN107163264B (zh) * | 2017-05-27 | 2019-07-09 | 青岛大学 | 一种以爆发成核法制备壳聚糖微球的方法 |
| CN108149509A (zh) * | 2017-12-22 | 2018-06-12 | 合肥洁诺无纺布制品有限公司 | 一种用于医用擦手纸的高吸湿聚乳酸纤维 |
| CN109021515B (zh) * | 2018-06-15 | 2020-03-17 | 金发科技股份有限公司 | 一种聚乳酸3d打印材料及其制备方法 |
| CN109776848B (zh) * | 2019-01-08 | 2020-06-30 | 恒天纤维集团有限公司 | 聚乳酸聚合熔体直接制备聚乳酸发泡制品的方法及装置 |
| ES2974543T3 (es) | 2019-08-21 | 2024-06-27 | Lilly Co Eli | Métodos y aparatos para aspectos de un sistema de detección de dosis |
| CN111004484B (zh) * | 2019-11-04 | 2022-03-15 | 苏州德龙复合材料有限公司 | 一种聚乳酸发泡珠粒及其制备方法 |
| CN110746635A (zh) * | 2019-11-20 | 2020-02-04 | 湖南工业大学 | 一种复合淀粉发泡微珠及其制备方法 |
| JP2021165169A (ja) * | 2020-04-08 | 2021-10-14 | 積水化成品工業株式会社 | 熱可塑性樹脂シート及び熱可塑性樹脂容器 |
| KR20220048123A (ko) * | 2020-10-12 | 2022-04-19 | (주)엘엑스하우시스 | 표면 개질된 폴리락틱산 입자 및 이의 제조방법 |
| US11420367B2 (en) * | 2020-11-19 | 2022-08-23 | Dongguan Hailex New Material Science And Technology Co., Ltd. | Foam molding process by modifying amorphous PLA |
| CN116355369B (zh) * | 2023-03-21 | 2025-07-15 | 万华化学(宁波)有限公司 | 一种抗压缩变形改性聚乳酸发泡材料及其制备方法 |
| WO2025136904A1 (en) * | 2023-12-18 | 2025-06-26 | Eastman Chemical Company | Injection molded articles and methods of manufacturing thereof |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH469756A (de) * | 1965-07-10 | 1969-03-15 | Basf Ag | Verfahren zur Herstellung von Schaumstofformkörpern |
| NL6511455A (enExample) * | 1965-09-02 | 1967-03-03 | ||
| GB1289466A (enExample) * | 1970-01-26 | 1972-09-20 | ||
| US4251400A (en) * | 1971-11-03 | 1981-02-17 | Borden, Inc. | Hot and cold water redispersible polyvinyl acetate adhesives |
| US4020133A (en) * | 1976-08-02 | 1977-04-26 | Arco Polymers, Inc. | Anti-lumping coating for polystyrene beads |
| US4452837A (en) * | 1979-06-11 | 1984-06-05 | H. B. Fuller Company | Web reinforced with string-type adhesive and method of manufacturing same |
| JPS58196239A (ja) * | 1982-05-11 | 1983-11-15 | Sekisui Plastics Co Ltd | 二次成形に適したポリスチレン系発泡シ−ト |
| US5216050A (en) * | 1988-08-08 | 1993-06-01 | Biopak Technology, Ltd. | Blends of polyactic acid |
| CN1185797A (zh) * | 1996-03-26 | 1998-06-24 | 大赛璐化学工业株式会社 | 苯乙烯树脂组合物及其模(塑)制品 |
| JPH10265607A (ja) * | 1997-03-25 | 1998-10-06 | Teijin Ltd | 生分解性発泡体成形物の製造方法 |
| JP3424500B2 (ja) * | 1997-05-27 | 2003-07-07 | 凸版印刷株式会社 | 発泡ビーズの集合成型体及びその製造方法 |
| JP3773342B2 (ja) * | 1997-12-02 | 2006-05-10 | 三井化学株式会社 | 発泡性粒子 |
| JP2001098104A (ja) * | 1999-09-30 | 2001-04-10 | Kanebo Ltd | 生分解を有する発泡粒子及びその成形物 |
| JP4293489B2 (ja) * | 1999-09-30 | 2009-07-08 | 株式会社カネカ | 生分解を有する発泡成形物の製造方法 |
| JP4413350B2 (ja) * | 1999-12-14 | 2010-02-10 | 日本合成化学工業株式会社 | エチレン−酢酸ビニル共重合体ケン化物の連続処理方法 |
| JP2002096824A (ja) * | 2000-07-17 | 2002-04-02 | Ekoro Pack:Kk | シート材及びシート材の製造方法及び物品収納箱 |
| JP2002302567A (ja) * | 2001-04-05 | 2002-10-18 | Achilles Corp | 生分解性を有するポリエステル系樹脂予備発泡粒子の連続製造方法 |
| JP2005068306A (ja) * | 2003-08-26 | 2005-03-17 | Kanebo Ltd | 発泡性ポリ乳酸系樹脂組成物、及び該樹脂組成物の製造方法 |
| WO2005052056A1 (ja) * | 2003-11-25 | 2005-06-09 | Asahi Kasei Life & Living Corporation | 艶消しフィルム |
| AU2004314664B2 (en) * | 2004-01-30 | 2007-11-15 | Oh, Seung-Yeop | Expanded polystyrene bead having functional skin layer, manufacturing process thereof, and functional EPS product and manufacturing process thereof using the same |
| JP2006028374A (ja) * | 2004-07-16 | 2006-02-02 | Hitachi Chem Co Ltd | 予備発泡樹脂粒子、該予備発泡樹脂粒子から得られる発泡樹脂成形体、およびそれらの製造方法 |
| JP2006117859A (ja) * | 2004-10-25 | 2006-05-11 | Kanebo Ltd | 帯電防止性ポリ乳酸系樹脂組成物 |
| US7863343B2 (en) | 2005-01-25 | 2011-01-04 | Jsp Corporation | Expandable polylactic acid resin particles, expanded polylactic acid resin beads and molded article obtained from expanded polylactic acid resin beads |
| JP2006249384A (ja) * | 2005-03-14 | 2006-09-21 | Sumitomo Electric Fine Polymer Inc | ポリ乳酸製架橋材の製造方法およびポリ乳酸製架橋材 |
| JP4794216B2 (ja) * | 2005-05-30 | 2011-10-19 | シーピー化成株式会社 | 熱可塑性樹脂製発泡シート、およびこの発泡シート製容器 |
| TWI432517B (zh) * | 2005-07-08 | 2014-04-01 | Toray Industries | 樹脂組成物及其成形品 |
| JP4570533B2 (ja) * | 2005-08-09 | 2010-10-27 | シャープ株式会社 | 熱可塑性樹脂組成物廃材の再資源化方法、プラスチック組成物原料の製造方法、プラスチック組成物原料、プラスチック部材の製造方法、及びプラスチック部材 |
| JP4820641B2 (ja) * | 2005-12-20 | 2011-11-24 | 積水化成品工業株式会社 | 型内発泡成形用ポリ乳酸系樹脂発泡粒子の製造方法 |
| JP4773870B2 (ja) * | 2006-04-27 | 2011-09-14 | 積水化成品工業株式会社 | ポリ乳酸系樹脂発泡成形体の製造方法 |
-
2007
- 2007-04-19 NL NL1033719A patent/NL1033719C2/nl not_active IP Right Cessation
-
2008
- 2008-04-21 NZ NZ580424A patent/NZ580424A/en unknown
- 2008-04-21 JP JP2010503996A patent/JP5477819B2/ja not_active Expired - Fee Related
- 2008-04-21 EP EP08753738.7A patent/EP2137250B1/en active Active
- 2008-04-21 EP EP08753737A patent/EP2137249A2/en not_active Withdrawn
- 2008-04-21 HU HUE08753738A patent/HUE037488T2/hu unknown
- 2008-04-21 DK DK08753738.7T patent/DK2137250T3/da active
- 2008-04-21 NO NO08753738A patent/NO2137250T3/no unknown
- 2008-04-21 PL PL08753738T patent/PL2137250T3/pl unknown
- 2008-04-21 ES ES08753738.7T patent/ES2651446T3/es active Active
- 2008-04-21 AU AU2008241682A patent/AU2008241682B2/en not_active Ceased
- 2008-04-21 JP JP2010503995A patent/JP2010526163A/ja active Pending
- 2008-04-21 PT PT87537387T patent/PT2137250T/pt unknown
- 2008-04-21 WO PCT/NL2008/000108 patent/WO2008130225A2/en not_active Ceased
- 2008-04-21 US US12/595,719 patent/US8268901B2/en active Active
- 2008-04-21 HR HRP20171681TT patent/HRP20171681T1/hr unknown
- 2008-04-21 US US12/595,926 patent/US20100098928A1/en not_active Abandoned
- 2008-04-21 CN CN2008800126572A patent/CN101668798B/zh not_active Expired - Fee Related
- 2008-04-21 KR KR1020097021681A patent/KR101443721B1/ko not_active Expired - Fee Related
- 2008-04-21 WO PCT/NL2008/000109 patent/WO2008130226A2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| US20100098928A1 (en) | 2010-04-22 |
| KR101443721B1 (ko) | 2014-09-23 |
| US20100087556A1 (en) | 2010-04-08 |
| DK2137250T3 (da) | 2017-11-27 |
| WO2008130225A2 (en) | 2008-10-30 |
| HRP20171681T1 (hr) | 2018-02-23 |
| PT2137250T (pt) | 2017-12-15 |
| US8268901B2 (en) | 2012-09-18 |
| EP2137250B1 (en) | 2017-09-13 |
| NL1033719C2 (nl) | 2008-10-21 |
| EP2137250A2 (en) | 2009-12-30 |
| WO2008130226A2 (en) | 2008-10-30 |
| CN101668798B (zh) | 2012-07-25 |
| WO2008130226A3 (en) | 2009-02-26 |
| HUE037488T2 (hu) | 2018-08-28 |
| EP2137249A2 (en) | 2009-12-30 |
| PL2137250T3 (pl) | 2018-03-30 |
| JP2010526163A (ja) | 2010-07-29 |
| AU2008241682A1 (en) | 2008-10-30 |
| NO2137250T3 (enExample) | 2018-02-10 |
| CN101668798A (zh) | 2010-03-10 |
| JP2010525099A (ja) | 2010-07-22 |
| WO2008130225A3 (en) | 2010-04-29 |
| NZ580424A (en) | 2012-01-12 |
| AU2008241682B2 (en) | 2012-10-04 |
| KR20100015654A (ko) | 2010-02-12 |
| ES2651446T3 (es) | 2018-01-26 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5477819B2 (ja) | コーティングされた粒状発泡性ポリ乳酸 | |
| JP5572559B2 (ja) | 生分解性またはバイオ系の重合体および合成重合体のポリマーブレンドおよびその発泡体 | |
| US7872056B2 (en) | Polymer blends of biodegradable or bio-based and synthetic polymers and foams thereof | |
| EP3053947B1 (en) | A process for producing foam mouldings | |
| WO2017196176A1 (en) | A composition based on polyactic acid | |
| CA2738068A1 (en) | Polylactic acid foam composition | |
| KR102665935B1 (ko) | 폴리락트산 수지 발포 시트, 수지 성형품, 및 폴리락트산 수지 발포 시트의 제조 방법 | |
| AU2013311315B2 (en) | Manufacture of polylactic acid foams using liquid carbon dioxide | |
| JP4954461B2 (ja) | ポリ乳酸系樹脂組成物およびその発泡粒子およびその発泡成形体 | |
| US8962706B2 (en) | Process for enabling secondary expansion of expandable beads | |
| JP3773342B2 (ja) | 発泡性粒子 | |
| JP2025502660A (ja) | ポリマー発泡体、方法及びそれらに関連する使用 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20110225 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20130227 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130305 |
|
| RD04 | Notification of resignation of power of attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7424 Effective date: 20130305 |
|
| A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20130530 |
|
| A602 | Written permission of extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A602 Effective date: 20130606 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130904 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20140114 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20140204 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5477819 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| LAPS | Cancellation because of no payment of annual fees |