JP4211318B2 - フィルドスクッテルダイト系合金、その製造方法および熱電変換素子 - Google Patents
フィルドスクッテルダイト系合金、その製造方法および熱電変換素子 Download PDFInfo
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- JP4211318B2 JP4211318B2 JP2002235312A JP2002235312A JP4211318B2 JP 4211318 B2 JP4211318 B2 JP 4211318B2 JP 2002235312 A JP2002235312 A JP 2002235312A JP 2002235312 A JP2002235312 A JP 2002235312A JP 4211318 B2 JP4211318 B2 JP 4211318B2
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- Prior art keywords
- filled skutterudite
- thermoelectric conversion
- alloy
- phase
- based alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229910045601 alloy Inorganic materials 0.000 title claims description 99
- 239000000956 alloy Substances 0.000 title claims description 99
- 238000006243 chemical reaction Methods 0.000 title claims description 36
- 238000004519 manufacturing process Methods 0.000 title claims description 24
- 229910052751 metal Inorganic materials 0.000 claims description 30
- 239000002184 metal Substances 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 24
- 150000002910 rare earth metals Chemical class 0.000 claims description 18
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 15
- 239000002994 raw material Substances 0.000 claims description 14
- 238000005266 casting Methods 0.000 claims description 13
- 229910052742 iron Inorganic materials 0.000 claims description 13
- 229910052787 antimony Inorganic materials 0.000 claims description 11
- 238000001816 cooling Methods 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052723 transition metal Inorganic materials 0.000 claims description 6
- 150000003624 transition metals Chemical class 0.000 claims description 6
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052684 Cerium Inorganic materials 0.000 claims description 3
- 229910052693 Europium Inorganic materials 0.000 claims description 3
- 229910052779 Neodymium Inorganic materials 0.000 claims description 3
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 3
- 229910052772 Samarium Inorganic materials 0.000 claims description 3
- 229910052769 Ytterbium Inorganic materials 0.000 claims description 3
- 239000011261 inert gas Substances 0.000 claims description 3
- 229910052746 lanthanum Inorganic materials 0.000 claims description 3
- 229910052763 palladium Inorganic materials 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 229910052707 ruthenium Inorganic materials 0.000 claims description 2
- 239000011888 foil Substances 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 26
- 239000000463 material Substances 0.000 description 14
- 229910052802 copper Inorganic materials 0.000 description 12
- 239000010949 copper Substances 0.000 description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 11
- 239000013078 crystal Substances 0.000 description 11
- 238000000634 powder X-ray diffraction Methods 0.000 description 10
- 238000005259 measurement Methods 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 229910052785 arsenic Inorganic materials 0.000 description 5
- 238000005245 sintering Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 238000002441 X-ray diffraction Methods 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000005191 phase separation Methods 0.000 description 3
- 238000010298 pulverizing process Methods 0.000 description 3
- 229910001122 Mischmetal Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 229910000765 intermetallic Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000010791 quenching Methods 0.000 description 2
- 230000000171 quenching effect Effects 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 229910002909 Bi-Te Inorganic materials 0.000 description 1
- 229910018989 CoSb Inorganic materials 0.000 description 1
- 230000005678 Seebeck effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
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Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002235312A JP4211318B2 (ja) | 2002-08-13 | 2002-08-13 | フィルドスクッテルダイト系合金、その製造方法および熱電変換素子 |
| PCT/JP2003/010058 WO2004017435A1 (en) | 2002-08-13 | 2003-08-07 | Filled skutterudite-based alloy, production method thereof and thermoelectric conversion device fabricated using the alloy |
| HK05111384.6A HK1079617B (en) | 2002-08-13 | 2003-08-07 | Filled skutterudite-based alloy, production method thereof and thermoelectric conversion device using the same |
| US10/524,546 US7705233B2 (en) | 2002-08-13 | 2003-08-07 | Filled skutterudite-based alloy, production method thereof and thermoelectric conversion device fabricated using the alloy |
| CNB038231743A CN100477309C (zh) | 2002-08-13 | 2003-08-07 | 填充方钴矿基合金、其形成方法及利用其的热电转换器件 |
| AU2003253430A AU2003253430A1 (en) | 2002-08-13 | 2003-08-07 | Filled skutterudite-based alloy, production method thereof and thermoelectric conversion device fabricated using the alloy |
| RU2005106872/28A RU2300160C2 (ru) | 2002-08-13 | 2003-08-07 | Сплав внедрения на основе скуттерудита, способ его получения и термоэлектрическое преобразовательное устройство, изготовленное с использованием такого сплава |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002235312A JP4211318B2 (ja) | 2002-08-13 | 2002-08-13 | フィルドスクッテルダイト系合金、その製造方法および熱電変換素子 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2004076046A JP2004076046A (ja) | 2004-03-11 |
| JP2004076046A5 JP2004076046A5 (https=) | 2005-10-20 |
| JP4211318B2 true JP4211318B2 (ja) | 2009-01-21 |
Family
ID=32019824
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002235312A Expired - Fee Related JP4211318B2 (ja) | 2002-08-13 | 2002-08-13 | フィルドスクッテルダイト系合金、その製造方法および熱電変換素子 |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP4211318B2 (https=) |
| CN (1) | CN100477309C (https=) |
Families Citing this family (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4518881B2 (ja) * | 2003-09-03 | 2010-08-04 | 昭和電工株式会社 | p形オーミック電極、それを備えた化合物半導体素子、化合物半導体発光素子及びそれらの製造方法 |
| JP4920199B2 (ja) * | 2004-04-21 | 2012-04-18 | 昭和電工株式会社 | 希土類含有合金、その製造方法及び熱電変換材料 |
| JP2006086512A (ja) * | 2004-08-16 | 2006-03-30 | Showa Denko Kk | フィルドスクッテルダイト系合金を用いた熱電変換システム。 |
| JP4365813B2 (ja) | 2004-09-22 | 2009-11-18 | オリンパス株式会社 | 攪拌装置、容器および攪拌装置を備えた分析装置 |
| FR2884353B1 (fr) | 2005-04-06 | 2007-07-13 | Centre Nat Rech Scient | Realisation de materiaux thermoelectriques par mecanosynthese |
| KR100663975B1 (ko) | 2005-10-19 | 2007-01-02 | 충주대학교 산학협력단 | Fe가 도핑된 스커테루다이트계 고효율 열전소재 및 그제조방법 |
| CN100344544C (zh) * | 2005-11-29 | 2007-10-24 | 武汉理工大学 | 乙醇Sol-Gel法制备方钴矿热电化合物纳米粉体的方法 |
| KR100689253B1 (ko) | 2006-02-14 | 2007-03-02 | 충주대학교 산학협력단 | 스커테루다이트 열전재료의 제조방법 |
| US20100071741A1 (en) * | 2008-03-14 | 2010-03-25 | Gm Global Technology Operations, Inc. | Thermoelectric material including a filled skutterudite crystal structure |
| KR101538067B1 (ko) * | 2009-02-18 | 2015-07-20 | 삼성전자주식회사 | 열전재료 및 이를 포함하는 열전소자와 열전 모듈 |
| KR101072299B1 (ko) | 2010-02-22 | 2011-10-11 | 한국전기연구원 | La가 도핑된 AgSbTe₂열전재료의 제조방법 및 그 열전재료 |
| KR101680763B1 (ko) | 2010-03-31 | 2016-11-29 | 삼성전자주식회사 | 열전재료, 이를 포함하는 열전모듈과 열전장치 |
| KR101296813B1 (ko) | 2011-12-30 | 2013-08-14 | 한국전기연구원 | 희토류 원소가 첨가된 AgSbTe₂계 열전재료의 제조방법 |
| KR102122573B1 (ko) | 2017-03-09 | 2020-06-12 | 주식회사 엘지화학 | 신규한 화합물 반도체 및 그 활용 |
| EP3742504A4 (en) | 2018-01-15 | 2021-10-20 | Hitachi Metals, Ltd. | MATERIAL FOR THERMOELECTRIC CONVERSION, MODULE FOR THERMOELECTRIC CONVERSION AND METHOD FOR MANUFACTURING A MATERIAL FOR THERMOELECTRIC CONVERSION |
| EP3859798B1 (en) | 2018-09-26 | 2025-01-29 | Proterial, Ltd. | Thermoelectric conversion material, thermoelectric conversion module using same, and method of manufacturing thermoelectric conversion material |
| CN111341902B (zh) * | 2020-04-02 | 2021-07-06 | 台州智奥通信设备有限公司 | 一种高强度高性能复合热电材料的制备方法 |
| CN112538579A (zh) * | 2020-12-07 | 2021-03-23 | 安徽工业大学 | 一种降低p型Ce填充铁基方钴矿热电材料热导率的方法 |
| JPWO2023277028A1 (https=) * | 2021-06-30 | 2023-01-05 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6069312A (en) * | 1994-01-28 | 2000-05-30 | California Institute Of Technology | Thermoelectric materials with filled skutterudite structure for thermoelectric devices |
| US6207886B1 (en) * | 1998-06-30 | 2001-03-27 | Matsushita Electric Industrial Co., Ltd. | Skutterudite thermoelectric material thermoelectric couple and method of producing the same |
| US7002071B1 (en) * | 1999-03-10 | 2006-02-21 | Sumitomo Special Metals Co. Ltd. | Thermoelectric conversion material and method of producing the same |
-
2002
- 2002-08-13 JP JP2002235312A patent/JP4211318B2/ja not_active Expired - Fee Related
-
2003
- 2003-08-07 CN CNB038231743A patent/CN100477309C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1685533A (zh) | 2005-10-19 |
| JP2004076046A (ja) | 2004-03-11 |
| HK1079617A1 (zh) | 2006-06-09 |
| CN100477309C (zh) | 2009-04-08 |
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