JP3817604B2 - ポリイミド広角化層 - Google Patents
ポリイミド広角化層 Download PDFInfo
- Publication number
- JP3817604B2 JP3817604B2 JP54228997A JP54228997A JP3817604B2 JP 3817604 B2 JP3817604 B2 JP 3817604B2 JP 54228997 A JP54228997 A JP 54228997A JP 54228997 A JP54228997 A JP 54228997A JP 3817604 B2 JP3817604 B2 JP 3817604B2
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- JP
- Japan
- Prior art keywords
- group
- polyimide
- layer
- bis
- fluorene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920001721 polyimide Polymers 0.000 title claims description 96
- 239000004642 Polyimide Substances 0.000 title claims description 90
- 239000010410 layer Substances 0.000 claims description 83
- 239000004973 liquid crystal related substance Substances 0.000 claims description 54
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 claims description 48
- 125000004432 carbon atom Chemical group C* 0.000 claims description 42
- 125000003118 aryl group Chemical group 0.000 claims description 39
- 229920000642 polymer Polymers 0.000 claims description 38
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 claims description 33
- 230000003287 optical effect Effects 0.000 claims description 25
- -1 3-methyl-4-aminophenyl Chemical group 0.000 claims description 24
- 125000005001 aminoaryl group Chemical group 0.000 claims description 19
- 125000000217 alkyl group Chemical group 0.000 claims description 18
- 150000004984 aromatic diamines Chemical class 0.000 claims description 14
- 125000001424 substituent group Chemical group 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 210000002858 crystal cell Anatomy 0.000 claims description 12
- 125000006158 tetracarboxylic acid group Chemical group 0.000 claims description 12
- KIFDSGGWDIVQGN-UHFFFAOYSA-N 4-[9-(4-aminophenyl)fluoren-9-yl]aniline Chemical compound C1=CC(N)=CC=C1C1(C=2C=CC(N)=CC=2)C2=CC=CC=C2C2=CC=CC=C21 KIFDSGGWDIVQGN-UHFFFAOYSA-N 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 11
- 239000012790 adhesive layer Substances 0.000 claims description 8
- 229910052801 chlorine Inorganic materials 0.000 claims description 8
- 239000000460 chlorine Substances 0.000 claims description 8
- 150000004985 diamines Chemical class 0.000 claims description 8
- 229910052731 fluorine Inorganic materials 0.000 claims description 8
- 239000000178 monomer Substances 0.000 claims description 8
- VLDPXPPHXDGHEW-UHFFFAOYSA-N 1-chloro-2-dichlorophosphoryloxybenzene Chemical compound ClC1=CC=CC=C1OP(Cl)(Cl)=O VLDPXPPHXDGHEW-UHFFFAOYSA-N 0.000 claims description 7
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 229910052736 halogen Inorganic materials 0.000 claims description 7
- 150000002367 halogens Chemical class 0.000 claims description 7
- 229920006254 polymer film Polymers 0.000 claims description 7
- 239000011521 glass Substances 0.000 claims description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 5
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- 239000011737 fluorine Substances 0.000 claims description 5
- 125000002950 monocyclic group Chemical group 0.000 claims description 5
- BWAPJIHJXDYDPW-UHFFFAOYSA-N 2,5-dimethyl-p-phenylenediamine Chemical compound CC1=CC(N)=C(C)C=C1N BWAPJIHJXDYDPW-UHFFFAOYSA-N 0.000 claims description 4
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 4
- 230000001747 exhibiting effect Effects 0.000 claims description 4
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000000047 product Substances 0.000 claims description 4
- QHHKLPCQTTWFSS-UHFFFAOYSA-N 5-[2-(1,3-dioxo-2-benzofuran-5-yl)-1,1,1,3,3,3-hexafluoropropan-2-yl]-2-benzofuran-1,3-dione Chemical compound C1=C2C(=O)OC(=O)C2=CC(C(C=2C=C3C(=O)OC(=O)C3=CC=2)(C(F)(F)F)C(F)(F)F)=C1 QHHKLPCQTTWFSS-UHFFFAOYSA-N 0.000 claims description 3
- 125000005843 halogen group Chemical group 0.000 claims description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
- 239000011241 protective layer Substances 0.000 claims description 3
- MJGXYJUUKICJFL-UHFFFAOYSA-N 2,5-diethylbenzene-1,4-diamine Chemical compound CCC1=CC(N)=C(CC)C=C1N MJGXYJUUKICJFL-UHFFFAOYSA-N 0.000 claims description 2
- ZSIMBMYNZHSZGJ-UHFFFAOYSA-N 2-ethylbenzene-1,4-diamine Chemical compound CCC1=CC(N)=CC=C1N ZSIMBMYNZHSZGJ-UHFFFAOYSA-N 0.000 claims description 2
- OBCSAIDCZQSFQH-UHFFFAOYSA-N 2-methyl-1,4-phenylenediamine Chemical compound CC1=CC(N)=CC=C1N OBCSAIDCZQSFQH-UHFFFAOYSA-N 0.000 claims description 2
- UMAXFCDSAXELAT-UHFFFAOYSA-N 4-[9-(4-amino-3,5-diethylphenyl)fluoren-9-yl]-2,6-diethylaniline Chemical compound CCC1=C(N)C(CC)=CC(C2(C3=CC=CC=C3C3=CC=CC=C32)C=2C=C(CC)C(N)=C(CC)C=2)=C1 UMAXFCDSAXELAT-UHFFFAOYSA-N 0.000 claims description 2
- LRQNMTUEZUJDMA-UHFFFAOYSA-N 4-[9-(4-amino-3,5-dimethylphenyl)fluoren-9-yl]-2,6-dimethylaniline Chemical compound CC1=C(N)C(C)=CC(C2(C3=CC=CC=C3C3=CC=CC=C32)C=2C=C(C)C(N)=C(C)C=2)=C1 LRQNMTUEZUJDMA-UHFFFAOYSA-N 0.000 claims description 2
- UYFUZBQJAJGLEE-UHFFFAOYSA-N 4-[9-(4-amino-3-ethyl-5-methylphenyl)fluoren-9-yl]-2-ethyl-6-methylaniline Chemical compound CC1=C(N)C(CC)=CC(C2(C3=CC=CC=C3C3=CC=CC=C32)C=2C=C(CC)C(N)=C(C)C=2)=C1 UYFUZBQJAJGLEE-UHFFFAOYSA-N 0.000 claims description 2
- VQVIHDPBMFABCQ-UHFFFAOYSA-N 5-(1,3-dioxo-2-benzofuran-5-carbonyl)-2-benzofuran-1,3-dione Chemical compound C1=C2C(=O)OC(=O)C2=CC(C(C=2C=C3C(=O)OC(=O)C3=CC=2)=O)=C1 VQVIHDPBMFABCQ-UHFFFAOYSA-N 0.000 claims description 2
- 238000010276 construction Methods 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims description 2
- 125000004434 sulfur atom Chemical group 0.000 claims description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 claims 1
- 239000003205 fragrance Substances 0.000 claims 1
- 150000000000 tetracarboxylic acids Chemical class 0.000 claims 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 21
- 239000002904 solvent Substances 0.000 description 17
- 229920001577 copolymer Polymers 0.000 description 16
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 12
- 238000000576 coating method Methods 0.000 description 12
- 239000000853 adhesive Substances 0.000 description 10
- 230000001070 adhesive effect Effects 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 10
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 10
- 239000004926 polymethyl methacrylate Substances 0.000 description 10
- WFDIJRYMOXRFFG-UHFFFAOYSA-N Acetic anhydride Chemical compound CC(=O)OC(C)=O WFDIJRYMOXRFFG-UHFFFAOYSA-N 0.000 description 9
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 8
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 8
- 125000006159 dianhydride group Chemical group 0.000 description 8
- CBCKQZAAMUWICA-UHFFFAOYSA-N 1,4-phenylenediamine Chemical compound NC1=CC=C(N)C=C1 CBCKQZAAMUWICA-UHFFFAOYSA-N 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 210000004027 cell Anatomy 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 230000015572 biosynthetic process Effects 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- 125000003545 alkoxy group Chemical group 0.000 description 4
- 125000003710 aryl alkyl group Chemical group 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- UQUPIHHYKUEXQD-UHFFFAOYSA-N n,n′-dimethyl-1,3-propanediamine Chemical compound CNCCCNC UQUPIHHYKUEXQD-UHFFFAOYSA-N 0.000 description 4
- 229920005575 poly(amic acid) Polymers 0.000 description 4
- 229920000515 polycarbonate Polymers 0.000 description 4
- 239000004417 polycarbonate Substances 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 125000002877 alkyl aryl group Chemical group 0.000 description 3
- 150000008064 anhydrides Chemical class 0.000 description 3
- 150000001448 anilines Chemical class 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 229920001903 high density polyethylene Polymers 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 150000003141 primary amines Chemical group 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 2
- GEYOCULIXLDCMW-UHFFFAOYSA-N 1,2-phenylenediamine Chemical class NC1=CC=CC=C1N GEYOCULIXLDCMW-UHFFFAOYSA-N 0.000 description 2
- YBRVSVVVWCFQMG-UHFFFAOYSA-N 4,4'-diaminodiphenylmethane Chemical class C1=CC(N)=CC=C1CC1=CC=C(N)C=C1 YBRVSVVVWCFQMG-UHFFFAOYSA-N 0.000 description 2
- ZYEDGEXYGKWJPB-UHFFFAOYSA-N 4-[2-(4-aminophenyl)propan-2-yl]aniline Chemical class C=1C=C(N)C=CC=1C(C)(C)C1=CC=C(N)C=C1 ZYEDGEXYGKWJPB-UHFFFAOYSA-N 0.000 description 2
- KMKWGXGSGPYISJ-UHFFFAOYSA-N 4-[4-[2-[4-(4-aminophenoxy)phenyl]propan-2-yl]phenoxy]aniline Chemical compound C=1C=C(OC=2C=CC(N)=CC=2)C=CC=1C(C)(C)C(C=C1)=CC=C1OC1=CC=C(N)C=C1 KMKWGXGSGPYISJ-UHFFFAOYSA-N 0.000 description 2
- QQGYZOYWNCKGEK-UHFFFAOYSA-N 5-[(1,3-dioxo-2-benzofuran-5-yl)oxy]-2-benzofuran-1,3-dione Chemical compound C1=C2C(=O)OC(=O)C2=CC(OC=2C=C3C(=O)OC(C3=CC=2)=O)=C1 QQGYZOYWNCKGEK-UHFFFAOYSA-N 0.000 description 2
- ZHBXLZQQVCDGPA-UHFFFAOYSA-N 5-[(1,3-dioxo-2-benzofuran-5-yl)sulfonyl]-2-benzofuran-1,3-dione Chemical compound C1=C2C(=O)OC(=O)C2=CC(S(=O)(=O)C=2C=C3C(=O)OC(C3=CC=2)=O)=C1 ZHBXLZQQVCDGPA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N N-phenyl amine Natural products NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- GRSMWKLPSNHDHA-UHFFFAOYSA-N Naphthalic anhydride Chemical class C1=CC(C(=O)OC2=O)=C3C2=CC=CC3=C1 GRSMWKLPSNHDHA-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- RDOXTESZEPMUJZ-UHFFFAOYSA-N anisole Chemical compound COC1=CC=CC=C1 RDOXTESZEPMUJZ-UHFFFAOYSA-N 0.000 description 2
- 125000004653 anthracenylene group Chemical group 0.000 description 2
- HFACYLZERDEVSX-UHFFFAOYSA-N benzidine Chemical class C1=CC(N)=CC=C1C1=CC=C(N)C=C1 HFACYLZERDEVSX-UHFFFAOYSA-N 0.000 description 2
- IDVDAZFXGGNIDQ-UHFFFAOYSA-N benzo[e][2]benzofuran-1,3-dione Chemical compound C1=CC2=CC=CC=C2C2=C1C(=O)OC2=O IDVDAZFXGGNIDQ-UHFFFAOYSA-N 0.000 description 2
- WKDNYTOXBCRNPV-UHFFFAOYSA-N bpda Chemical compound C1=C2C(=O)OC(=O)C2=CC(C=2C=C3C(=O)OC(C3=CC=2)=O)=C1 WKDNYTOXBCRNPV-UHFFFAOYSA-N 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 125000006165 cyclic alkyl group Chemical group 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 150000002220 fluorenes Chemical class 0.000 description 2
- 125000005567 fluorenylene group Chemical group 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 125000004957 naphthylene group Chemical group 0.000 description 2
- 150000004989 p-phenylenediamines Chemical class 0.000 description 2
- 239000002798 polar solvent Substances 0.000 description 2
- 125000003367 polycyclic group Chemical group 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical compound FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 description 1
- VZXTWGWHSMCWGA-UHFFFAOYSA-N 1,3,5-triazine-2,4-diamine Chemical compound NC1=NC=NC(N)=N1 VZXTWGWHSMCWGA-UHFFFAOYSA-N 0.000 description 1
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- VOZKAJLKRJDJLL-UHFFFAOYSA-N 2,4-diaminotoluene Chemical compound CC1=CC=C(N)C=C1N VOZKAJLKRJDJLL-UHFFFAOYSA-N 0.000 description 1
- HGUYBLVGLMAUFF-UHFFFAOYSA-N 2-methoxybenzene-1,4-diamine Chemical compound COC1=CC(N)=CC=C1N HGUYBLVGLMAUFF-UHFFFAOYSA-N 0.000 description 1
- FKHKSWSHWLYDOI-UHFFFAOYSA-N 2-phenylbenzene-1,4-diamine Chemical compound NC1=CC=C(N)C(C=2C=CC=CC=2)=C1 FKHKSWSHWLYDOI-UHFFFAOYSA-N 0.000 description 1
- TYKLCAKICHXQNE-UHFFFAOYSA-N 3-[(2,3-dicarboxyphenyl)methyl]phthalic acid Chemical compound OC(=O)C1=CC=CC(CC=2C(=C(C(O)=O)C=CC=2)C(O)=O)=C1C(O)=O TYKLCAKICHXQNE-UHFFFAOYSA-N 0.000 description 1
- UCQABCHSIIXVOY-UHFFFAOYSA-N 3-[4-[4-(3-aminophenoxy)phenyl]phenoxy]aniline Chemical group NC1=CC=CC(OC=2C=CC(=CC=2)C=2C=CC(OC=3C=C(N)C=CC=3)=CC=2)=C1 UCQABCHSIIXVOY-UHFFFAOYSA-N 0.000 description 1
- XTEBLARUAVEBRF-UHFFFAOYSA-N 4-(1,1,1,3,3,3-hexafluoropropan-2-yl)aniline Chemical compound NC1=CC=C(C(C(F)(F)F)C(F)(F)F)C=C1 XTEBLARUAVEBRF-UHFFFAOYSA-N 0.000 description 1
- WIVUEBNYALSDOC-UHFFFAOYSA-N 4-(methylamino)phthalic acid Chemical compound CNC1=CC=C(C(O)=O)C(C(O)=O)=C1 WIVUEBNYALSDOC-UHFFFAOYSA-N 0.000 description 1
- HLBLWEWZXPIGSM-UHFFFAOYSA-N 4-Aminophenyl ether Chemical compound C1=CC(N)=CC=C1OC1=CC=C(N)C=C1 HLBLWEWZXPIGSM-UHFFFAOYSA-N 0.000 description 1
- ZWUBBMDHSZDNTA-UHFFFAOYSA-N 4-Chloro-meta-phenylenediamine Chemical compound NC1=CC=C(Cl)C(N)=C1 ZWUBBMDHSZDNTA-UHFFFAOYSA-N 0.000 description 1
- PWQPPMAQPRGFIS-UHFFFAOYSA-N 4-[(3,4-dicarboxyphenyl)-diethylsilyl]phthalic acid Chemical compound C=1C=C(C(O)=O)C(C(O)=O)=CC=1[Si](CC)(CC)C1=CC=C(C(O)=O)C(C(O)=O)=C1 PWQPPMAQPRGFIS-UHFFFAOYSA-N 0.000 description 1
- GEYAGBVEAJGCFB-UHFFFAOYSA-N 4-[2-(3,4-dicarboxyphenyl)propan-2-yl]phthalic acid Chemical compound C=1C=C(C(O)=O)C(C(O)=O)=CC=1C(C)(C)C1=CC=C(C(O)=O)C(C(O)=O)=C1 GEYAGBVEAJGCFB-UHFFFAOYSA-N 0.000 description 1
- JCRRFJIVUPSNTA-UHFFFAOYSA-N 4-[4-(4-aminophenoxy)phenoxy]aniline Chemical compound C1=CC(N)=CC=C1OC(C=C1)=CC=C1OC1=CC=C(N)C=C1 JCRRFJIVUPSNTA-UHFFFAOYSA-N 0.000 description 1
- HHLMWQDRYZAENA-UHFFFAOYSA-N 4-[4-[2-[4-(4-aminophenoxy)phenyl]-1,1,1,3,3,3-hexafluoropropan-2-yl]phenoxy]aniline Chemical compound C1=CC(N)=CC=C1OC1=CC=C(C(C=2C=CC(OC=3C=CC(N)=CC=3)=CC=2)(C(F)(F)F)C(F)(F)F)C=C1 HHLMWQDRYZAENA-UHFFFAOYSA-N 0.000 description 1
- HYDATEKARGDBKU-UHFFFAOYSA-N 4-[4-[4-(4-aminophenoxy)phenyl]phenoxy]aniline Chemical group C1=CC(N)=CC=C1OC1=CC=C(C=2C=CC(OC=3C=CC(N)=CC=3)=CC=2)C=C1 HYDATEKARGDBKU-UHFFFAOYSA-N 0.000 description 1
- YRKVLGUIGNRYJX-UHFFFAOYSA-N 4-[9-(4-amino-3-methylphenyl)fluoren-9-yl]-2-methylaniline Chemical compound C1=C(N)C(C)=CC(C2(C3=CC=CC=C3C3=CC=CC=C32)C=2C=C(C)C(N)=CC=2)=C1 YRKVLGUIGNRYJX-UHFFFAOYSA-N 0.000 description 1
- FJVIHKKXPLPDSV-UHFFFAOYSA-N 4-phenoxybenzene-1,2-diamine Chemical compound C1=C(N)C(N)=CC=C1OC1=CC=CC=C1 FJVIHKKXPLPDSV-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 229920002284 Cellulose triacetate Polymers 0.000 description 1
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 description 1
- 206010011878 Deafness Diseases 0.000 description 1
- 229920001875 Ebonite Polymers 0.000 description 1
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Images
Classifications
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- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1335—Structural association of cells with optical devices, e.g. polarisers or reflectors
- G02F1/13363—Birefringent elements, e.g. for optical compensation
- G02F1/133634—Birefringent elements, e.g. for optical compensation the refractive index Nz perpendicular to the element surface being different from in-plane refractive indices Nx and Ny, e.g. biaxial or with normal optical axis
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1039—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors comprising halogen-containing substituents
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1042—Copolyimides derived from at least two different tetracarboxylic compounds or two different diamino compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1075—Partially aromatic polyimides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1075—Partially aromatic polyimides
- C08G73/1078—Partially aromatic polyimides wholly aromatic in the diamino moiety
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/06—Polycondensates having nitrogen-containing heterocyclic rings in the main chain of the macromolecule
- C08G73/10—Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors
- C08G73/1075—Partially aromatic polyimides
- C08G73/1082—Partially aromatic polyimides wholly aromatic in the tetracarboxylic moiety
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/30—Polarising elements
- G02B5/3083—Birefringent or phase retarding elements
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/02—Alignment layer characterised by chemical composition
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/02—Alignment layer characterised by chemical composition
- C09K2323/027—Polyimide
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/02—Alignment layer characterised by chemical composition
- C09K2323/027—Polyimide
- C09K2323/0271—Polyimidfluoride
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2323/00—Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
- C09K2323/03—Viewing layer characterised by chemical composition
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31721—Of polyimide
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Physics & Mathematics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nonlinear Science (AREA)
- Optics & Photonics (AREA)
- General Physics & Mathematics (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mathematical Physics (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polarising Elements (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/652,886 US5750641A (en) | 1996-05-23 | 1996-05-23 | Polyimide angularity enhancement layer |
| US08/652,886 | 1996-05-23 | ||
| PCT/US1996/015273 WO1997044704A1 (en) | 1996-05-23 | 1996-09-24 | Polyimide angularity enhancement layer |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2000511296A JP2000511296A (ja) | 2000-08-29 |
| JP2000511296A5 JP2000511296A5 (enExample) | 2004-10-14 |
| JP3817604B2 true JP3817604B2 (ja) | 2006-09-06 |
Family
ID=24618611
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP54228997A Expired - Fee Related JP3817604B2 (ja) | 1996-05-23 | 1996-09-24 | ポリイミド広角化層 |
Country Status (7)
| Country | Link |
|---|---|
| US (5) | US5750641A (enExample) |
| EP (1) | EP0900406B1 (enExample) |
| JP (1) | JP3817604B2 (enExample) |
| CN (1) | CN1219247A (enExample) |
| AU (1) | AU7369996A (enExample) |
| DE (1) | DE69634931T2 (enExample) |
| WO (1) | WO1997044704A1 (enExample) |
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| US5907378A (en) * | 1993-12-15 | 1999-05-25 | Ois Optical Imaging Systems, Inc. | Normally white twisted nematic liquid crystal display including retardation films for improving viewing characteristics |
| US5750641A (en) | 1996-05-23 | 1998-05-12 | Minnesota Mining And Manufacturing Company | Polyimide angularity enhancement layer |
| US6426372B1 (en) | 1998-07-22 | 2002-07-30 | 3M Innovative Properties Company | Method of producing porous calcined polyimide |
| TW416011B (en) * | 1998-08-28 | 2000-12-21 | Toray Industries | Colored polymer film, color filter and liquid crystal display device |
| US6399958B1 (en) * | 1998-12-09 | 2002-06-04 | Advanced Micro Devices, Inc. | Apparatus for visual inspection during device analysis |
| US6365266B1 (en) * | 1999-12-07 | 2002-04-02 | Air Products And Chemicals, Inc. | Mesoporous films having reduced dielectric constants |
| US6592980B1 (en) * | 1999-12-07 | 2003-07-15 | Air Products And Chemicals, Inc. | Mesoporous films having reduced dielectric constants |
| JP2004503392A (ja) * | 2000-06-15 | 2004-02-05 | スリーエム イノベイティブ プロパティズ カンパニー | マイクロ流体製品を製造するためのプロセス |
| EP1303791B1 (en) * | 2000-06-15 | 2009-08-19 | 3M Innovative Properties Company | Multicolor imaging using multiphoton photochemical processes |
| US6852766B1 (en) * | 2000-06-15 | 2005-02-08 | 3M Innovative Properties Company | Multiphoton photosensitization system |
| KR100810547B1 (ko) * | 2000-06-15 | 2008-03-18 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 캡슐화 광학 부재의 제작방법, 광학소자 및 이의 커플링 방법 |
| EP1292861B1 (en) * | 2000-06-15 | 2014-11-19 | 3M Innovative Properties Company | Multidirectional photoreactive absorption method |
| US7166409B2 (en) * | 2000-06-15 | 2007-01-23 | 3M Innovative Properties Company | Multipass multiphoton absorption method and apparatus |
| KR100810546B1 (ko) * | 2000-06-15 | 2008-03-18 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 삼차원 광학 소자의 가공 방법 |
| US6887525B2 (en) | 2000-06-30 | 2005-05-03 | 3M Innovative Properties Company | Insulation material for use in high-frequency electronic parts |
| US6391932B1 (en) | 2000-08-08 | 2002-05-21 | Shipley Company, L.L.C. | Porous materials |
| US6392004B1 (en) * | 2000-08-21 | 2002-05-21 | 3M Innovative Properties Company | Polyimides for high-frequency applications |
| US6417321B1 (en) * | 2000-08-21 | 2002-07-09 | 3M Innovative Properties Company | Cured fluorenyl polyimides |
| JP2002173640A (ja) * | 2000-11-30 | 2002-06-21 | Three M Innovative Properties Co | ポリイミド含有コーティング組成物及びそれから形成されたフィルム |
| US20040012872A1 (en) * | 2001-06-14 | 2004-01-22 | Fleming Patrick R | Multiphoton absorption method using patterned light |
| WO2003008475A2 (en) * | 2001-07-20 | 2003-01-30 | University Of Rochester | Light-emitting organic oligomer compositions |
| US7074344B2 (en) * | 2001-10-03 | 2006-07-11 | Jsr Corporation | Liquid crystal aligning agent and liquid crystal display element |
| US7002662B2 (en) * | 2001-10-16 | 2006-02-21 | Dai Nippon Printing Co., Ltd. | Method of producing optical element by patterning liquid crystal films |
| JP2003306558A (ja) * | 2001-11-02 | 2003-10-31 | Nitto Denko Corp | 光学フィルムとその製造方法、および光学素子、画像表示装置 |
| WO2003062875A1 (en) | 2002-01-23 | 2003-07-31 | Nitto Denko Corporation | Optical film, multilayer polarization plate, liquid crystal display comprising them, and spontaneous emission display |
| US6819382B2 (en) * | 2002-01-24 | 2004-11-16 | Nitto Denko Corporation | Method for producing substrate of liquid crystal cell and method for producing liquid crystal panel |
| CN1316305C (zh) * | 2002-02-19 | 2007-05-16 | 日东电工株式会社 | 倾斜的光学补偿薄膜、其生产方法以及包括所述薄膜的液晶显示器 |
| TW200305507A (en) | 2002-04-26 | 2003-11-01 | Nitto Denko Corp | Process for producing birefringent film |
| JP2004004150A (ja) * | 2002-05-13 | 2004-01-08 | Sumitomo Chem Co Ltd | 積層位相差フィルム及びそれを用いた液晶表示装置 |
| CN1296733C (zh) * | 2002-05-24 | 2007-01-24 | 日东电工株式会社 | 光学薄膜 |
| WO2004011970A1 (ja) | 2002-07-30 | 2004-02-05 | Nitto Denko Corporation | 光学フィルムおよびその製造方法 |
| US6964795B2 (en) * | 2002-08-02 | 2005-11-15 | Eastman Kodak Company | Multilayer optical compensator, liquid crystal display, and process |
| EP1387210A1 (en) * | 2002-08-02 | 2004-02-04 | Eastman Kodak Company | Compensator layer and liquid crystal cell with such a layer |
| TW200506467A (en) * | 2002-12-19 | 2005-02-16 | Nitto Denko Corp | Birefringent optical film, elliptically polarizing plate using the same, and liquid crystal |
| TW200500746A (en) * | 2002-12-19 | 2005-01-01 | Nitto Denko Corp | Birefringent optical film, elliptically polarizing plate using the same, and liquid crystal display using the same |
| TW200420616A (en) * | 2003-01-10 | 2004-10-16 | Nitto Denko Corp | Polyimide film and process for producing the same |
| JP4044485B2 (ja) * | 2003-05-02 | 2008-02-06 | 日東電工株式会社 | 光学フィルム、その製造方法、およびそれを用いた偏光板 |
| US6937310B2 (en) * | 2003-05-16 | 2005-08-30 | Eastman Kodak Company | Compensation films for LCDs |
| US7794831B2 (en) * | 2003-07-28 | 2010-09-14 | Vampire Optical Coating, Inc. | Anti-reflective coating |
| US7083851B2 (en) * | 2003-07-28 | 2006-08-01 | Vampire Optical Coatings, Inc. | High refractive index layers |
| US7211304B2 (en) * | 2004-06-03 | 2007-05-01 | Nitto Denko Corporation | Multilayer optical compensator, liquid crystal display, and process |
| US7083835B2 (en) * | 2003-07-31 | 2006-08-01 | Eastman Kodak Company | Multilayer optical compensator, liquid crystal display, and process |
| JP4236098B2 (ja) | 2003-08-01 | 2009-03-11 | 日東電工株式会社 | 複屈折性光学フィルム |
| TWI267527B (en) * | 2003-08-22 | 2006-12-01 | Ind Tech Res Inst | Vertical alignment polyimide and vertical alignment film compositions for LCD |
| JP3783958B2 (ja) | 2003-09-01 | 2006-06-07 | 日東電工株式会社 | 複合複屈折部材 |
| JP4236101B2 (ja) | 2003-09-16 | 2009-03-11 | 日東電工株式会社 | Vaモード液晶表示装置用視角補償フィルムの製造方法 |
| JP2005181450A (ja) | 2003-12-16 | 2005-07-07 | Nitto Denko Corp | 複屈折フィルムの製造方法、およびそれを用いた光学フィルムおよび画像表示装置 |
| US7157736B2 (en) * | 2003-12-23 | 2007-01-02 | Eastman Kodak Company | Multi-layer compensation film including stretchable barrier layers |
| JP4530256B2 (ja) * | 2004-01-19 | 2010-08-25 | 日東電工株式会社 | 位相差フィルム、その製造方法、およびこれを用いた光学フィルム |
| US7327422B2 (en) * | 2004-03-09 | 2008-02-05 | Nitto Denko Corporation | Optical compensation film, display, and process |
| JP2006058540A (ja) * | 2004-08-19 | 2006-03-02 | Jsr Corp | 光学フィルム、偏光板および液晶ディスプレイ |
| JP2006133720A (ja) | 2004-10-07 | 2006-05-25 | Nitto Denko Corp | 複屈折フィルムの製造方法、およびそれを用いた光学フィルム、液晶パネル、液晶表示装置、画像表示装置 |
| JP3811175B2 (ja) * | 2004-11-22 | 2006-08-16 | 日東電工株式会社 | 光学フィルム、偏光板、液晶セル、液晶表示装置、画像表示装置及び光学フィルムの製造方法 |
| US7274458B2 (en) | 2005-03-07 | 2007-09-25 | 3M Innovative Properties Company | Thermoplastic film having metallic nanoparticle coating |
| JPWO2006118176A1 (ja) * | 2005-04-28 | 2008-12-18 | 株式会社カネカ | 光学部品用ポリイミド、光学部品および光導波路 |
| US7666494B2 (en) * | 2005-05-04 | 2010-02-23 | 3M Innovative Properties Company | Microporous article having metallic nanoparticle coating |
| KR101226399B1 (ko) | 2005-06-21 | 2013-01-24 | 니폰 제온 가부시키가이샤 | 편광판용 보호필름 |
| US7438957B2 (en) | 2005-07-18 | 2008-10-21 | Akon Polymer Systems | Poly(aryletherimides) for negative birefringent films for LCDs |
| WO2007011911A2 (en) * | 2005-07-18 | 2007-01-25 | Akron Polymer Systems | Poly(aryletherimides) for negative birefringent films for lcds |
| TW200712692A (en) * | 2005-09-15 | 2007-04-01 | Optimax Tech Corp | Fabrication method of optical compensation films |
| TWI259287B (en) * | 2005-10-27 | 2006-08-01 | Optimax Tech Corp | Fabrication method of optical compensation film |
| US7655486B2 (en) * | 2006-05-17 | 2010-02-02 | 3M Innovative Properties Company | Method of making light emitting device with multilayer silicon-containing encapsulant |
| TW200811492A (en) * | 2006-07-12 | 2008-03-01 | Nitto Denko Corp | Polarizing plate with optical compensation layer, method of producing the same, and liquid crystal panel, liquid crystal display, and image display including the same |
| JP4993581B2 (ja) * | 2006-10-02 | 2012-08-08 | 日東電工株式会社 | 光学フィルム及び画像表示装置 |
| JP2009015279A (ja) * | 2006-11-27 | 2009-01-22 | Nitto Denko Corp | 液晶パネルおよび液晶表示装置 |
| JP4995618B2 (ja) * | 2007-04-17 | 2012-08-08 | 日東電工株式会社 | 光学フィルム、及び画像表示装置 |
| JP5133034B2 (ja) | 2007-05-24 | 2013-01-30 | 日東電工株式会社 | 光学フィルム、画像表示装置、ジエチニルフルオレン及びそのポリマー |
| JP5630013B2 (ja) * | 2009-01-30 | 2014-11-26 | ソニー株式会社 | 液晶表示装置の製造方法 |
| JP5630014B2 (ja) | 2009-01-30 | 2014-11-26 | ソニー株式会社 | 液晶表示装置の製造方法 |
| CN103608382B (zh) * | 2011-06-13 | 2015-09-30 | 株式会社钟化 | 聚酰胺酸、聚酰亚胺、聚酰胺酸溶液、聚酰亚胺溶液、和由这些溶液获得的聚酰亚胺膜、以及聚酰亚胺膜的利用 |
| CN102352039B (zh) * | 2011-07-22 | 2013-07-24 | 中山大学 | 基于芴结构的可溶性功能聚酰亚胺及其制备方法和应用 |
| JP6174580B2 (ja) * | 2011-08-19 | 2017-08-02 | アクロン ポリマー システムズ,インコーポレイテッド | 耐熱性低複屈折ポリイミド共重合体膜 |
| JP6230308B2 (ja) | 2013-07-16 | 2017-11-15 | ソマール株式会社 | 透明ポリイミド共重合体、ポリイミド樹脂組成物及び成形体、並びにこの共重合体の製造方法 |
| DE102014012095A1 (de) * | 2014-08-13 | 2016-02-18 | Steinbichler Optotechnik Gmbh | Verfahren und Vorrichtung zum Prüfen eines Reifens |
| JP6588100B2 (ja) * | 2015-02-11 | 2019-10-09 | コーロン インダストリーズ インク | ポリイミドフィルム |
| TWI649591B (zh) * | 2016-05-31 | 2019-02-01 | 南韓商Skc股份有限公司 | 偏光件用保護膜、包含該膜之偏光板及具有該偏光板之顯示裝置 |
| EP3299878B1 (en) | 2016-09-23 | 2020-03-25 | Samsung Electronics Co., Ltd. | Liquid crystal display |
| CN106842670B (zh) * | 2017-04-10 | 2021-03-26 | Tcl华星光电技术有限公司 | 柔性基板 |
| TWI710585B (zh) * | 2017-06-30 | 2020-11-21 | 奇美實業股份有限公司 | 液晶配向劑、液晶配向膜及液晶顯示元件 |
| JP2019049661A (ja) * | 2017-09-11 | 2019-03-28 | シャープ株式会社 | 配向膜、液晶パネル及び液晶パネルの製造方法 |
| CN108129836B (zh) * | 2017-12-15 | 2020-06-12 | 天津市天缘电工材料股份有限公司 | 一种高折射率、高透明聚酰亚胺薄膜及其制备方法 |
| US10572070B2 (en) * | 2018-06-25 | 2020-02-25 | Vanguard International Semiconductor Corporation | Optical devices and fabrication method thereof |
| CN112457866B (zh) * | 2020-10-29 | 2021-07-27 | 深圳清荷科技有限公司 | 一种液晶取向剂、液晶取向膜以及液晶显示元件 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4684678A (en) | 1985-05-30 | 1987-08-04 | Minnesota Mining And Manufacturing Company | Epoxy resin curing agent, process, and composition |
| US4845185A (en) * | 1986-04-22 | 1989-07-04 | Nippon Steel Corporation | Soluble copolyimide from 9,9-bis (4-amino phenyl) fluorene |
| JPS62292836A (ja) * | 1986-06-13 | 1987-12-19 | Nippon Steel Corp | 可溶性ポリイミドの製造方法 |
| JPS63295633A (ja) * | 1987-05-28 | 1988-12-02 | Nippon Steel Corp | 熱可塑性ポリイミド |
| JPH01165623A (ja) | 1987-12-22 | 1989-06-29 | Kanegafuchi Chem Ind Co Ltd | 光透過性が高いポリイミドおよびその前駆体 |
| US5026822A (en) * | 1988-07-12 | 1991-06-25 | Hoechst Celanese Corp. | High molecular weight polyimide, method of making same and articles formed therefrom |
| US4897092A (en) * | 1989-02-27 | 1990-01-30 | Air Products And Chemicals, Inc. | Polyimide membrane having improved flux |
| FR2650829B1 (fr) * | 1989-08-08 | 1991-10-31 | Etud Mat Organ Technol Av Cent | Polyimides aromatiques comportant des groupes trifluoromethyl, leurs preparations et leurs applications |
| US5055616A (en) * | 1990-01-29 | 1991-10-08 | Air Products And Chemicals, Inc. | Ortho-alkylated bisanilines having fluorenylidene bridging groups |
| JPH0413763A (ja) | 1990-05-07 | 1992-01-17 | Toray Ind Inc | 高屈折高透明耐熱性光学材料 |
| JPH0531341A (ja) | 1991-07-26 | 1993-02-09 | Nippon Steel Corp | ポリイミドガス分離膜 |
| US5196953A (en) * | 1991-11-01 | 1993-03-23 | Rockwell International Corporation | Compensator for liquid crystal display, having two types of layers with different refractive indices alternating |
| JPH05181120A (ja) | 1991-12-27 | 1993-07-23 | Sharp Corp | 液晶表示装置およびその製造方法 |
| JPH0625529A (ja) | 1992-07-06 | 1994-02-01 | Nippon Telegr & Teleph Corp <Ntt> | 低抵抗透明ポリイミド及びその前駆体 |
| US5344916A (en) * | 1993-04-21 | 1994-09-06 | The University Of Akron | Negative birefringent polyimide films |
| DE69424937T2 (de) * | 1993-04-21 | 2001-01-11 | The University Of Akron, Akron | Polyamidfolie mit negativer doppelbrechung |
| KR100312150B1 (ko) * | 1994-05-17 | 2001-12-28 | 마쯔모또 에이찌 | 액정배향제및액정표시소자 |
| JPH0883515A (ja) | 1994-09-13 | 1996-03-26 | Fujimori Kogyo Kk | 透明導電性シート |
| JP3299869B2 (ja) * | 1995-09-27 | 2002-07-08 | シャープ株式会社 | 液晶表示装置とその製造方法 |
| US5750641A (en) * | 1996-05-23 | 1998-05-12 | Minnesota Mining And Manufacturing Company | Polyimide angularity enhancement layer |
-
1996
- 1996-05-23 US US08/652,886 patent/US5750641A/en not_active Expired - Lifetime
- 1996-09-24 DE DE69634931T patent/DE69634931T2/de not_active Expired - Fee Related
- 1996-09-24 CN CN96180303A patent/CN1219247A/zh active Pending
- 1996-09-24 JP JP54228997A patent/JP3817604B2/ja not_active Expired - Fee Related
- 1996-09-24 EP EP96935924A patent/EP0900406B1/en not_active Expired - Lifetime
- 1996-09-24 WO PCT/US1996/015273 patent/WO1997044704A1/en not_active Ceased
- 1996-09-24 AU AU73699/96A patent/AU7369996A/en not_active Abandoned
-
1998
- 1998-05-05 US US09/072,908 patent/US6074709A/en not_active Expired - Fee Related
- 1998-05-05 US US09/073,335 patent/US5969088A/en not_active Expired - Lifetime
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2000
- 2000-03-23 US US09/534,148 patent/US6238753B1/en not_active Expired - Lifetime
-
2001
- 2001-04-03 US US09/825,562 patent/US6383578B2/en not_active Expired - Lifetime
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| Publication number | Publication date |
|---|---|
| DE69634931T2 (de) | 2006-04-27 |
| US5750641A (en) | 1998-05-12 |
| US20020012758A1 (en) | 2002-01-31 |
| DE69634931D1 (de) | 2005-08-18 |
| US6238753B1 (en) | 2001-05-29 |
| US6383578B2 (en) | 2002-05-07 |
| CN1219247A (zh) | 1999-06-09 |
| US5969088A (en) | 1999-10-19 |
| EP0900406B1 (en) | 2005-07-13 |
| AU7369996A (en) | 1997-12-09 |
| JP2000511296A (ja) | 2000-08-29 |
| US6074709A (en) | 2000-06-13 |
| WO1997044704A1 (en) | 1997-11-27 |
| EP0900406A1 (en) | 1999-03-10 |
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