JP2628812B2 - 洗剤組成物 - Google Patents
洗剤組成物Info
- Publication number
- JP2628812B2 JP2628812B2 JP3271277A JP27127791A JP2628812B2 JP 2628812 B2 JP2628812 B2 JP 2628812B2 JP 3271277 A JP3271277 A JP 3271277A JP 27127791 A JP27127791 A JP 27127791A JP 2628812 B2 JP2628812 B2 JP 2628812B2
- Authority
- JP
- Japan
- Prior art keywords
- tablet
- detergent
- weight
- sodium
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003599 detergent Substances 0.000 title claims description 79
- 239000000203 mixture Substances 0.000 title claims description 67
- 239000007844 bleaching agent Substances 0.000 claims description 35
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 34
- 229940045872 sodium percarbonate Drugs 0.000 claims description 34
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 32
- 150000001875 compounds Chemical class 0.000 claims description 19
- -1 alkali metal aluminosilicate Chemical class 0.000 claims description 15
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 13
- 239000012190 activator Substances 0.000 claims description 11
- 239000011230 binding agent Substances 0.000 claims description 10
- 229910017053 inorganic salt Inorganic materials 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 7
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 7
- 239000011976 maleic acid Substances 0.000 claims description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 7
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 6
- 229920001577 copolymer Polymers 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 230000001627 detrimental effect Effects 0.000 claims description 3
- 239000003085 diluting agent Substances 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- RIZPLDXMQXJTTJ-UHFFFAOYSA-N phosphane;prop-2-enoic acid Chemical compound [PH4+].[O-]C(=O)C=C RIZPLDXMQXJTTJ-UHFFFAOYSA-N 0.000 claims 1
- 239000003826 tablet Substances 0.000 description 80
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 22
- 238000003860 storage Methods 0.000 description 16
- 239000002585 base Substances 0.000 description 13
- 239000002245 particle Substances 0.000 description 13
- 239000004615 ingredient Substances 0.000 description 12
- 239000010457 zeolite Substances 0.000 description 10
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 9
- 108090000790 Enzymes Proteins 0.000 description 8
- 102000004190 Enzymes Human genes 0.000 description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 8
- 238000007906 compression Methods 0.000 description 8
- 230000006835 compression Effects 0.000 description 8
- 229940088598 enzyme Drugs 0.000 description 8
- 239000002736 nonionic surfactant Substances 0.000 description 8
- 239000000843 powder Substances 0.000 description 8
- 229910021536 Zeolite Inorganic materials 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- 238000005406 washing Methods 0.000 description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 6
- 235000014113 dietary fatty acids Nutrition 0.000 description 6
- 239000000194 fatty acid Substances 0.000 description 6
- 229930195729 fatty acid Natural products 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 229910052938 sodium sulfate Inorganic materials 0.000 description 6
- 235000011152 sodium sulphate Nutrition 0.000 description 6
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 5
- 239000003945 anionic surfactant Substances 0.000 description 5
- 239000011159 matrix material Substances 0.000 description 5
- 229920005646 polycarboxylate Polymers 0.000 description 5
- 239000000344 soap Substances 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 235000012149 noodles Nutrition 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 229960001922 sodium perborate Drugs 0.000 description 4
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 4
- 239000007916 tablet composition Substances 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 3
- 150000001340 alkali metals Chemical class 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 238000007922 dissolution test Methods 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 150000003333 secondary alcohols Chemical class 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000000429 sodium aluminium silicate Substances 0.000 description 3
- 235000012217 sodium aluminium silicate Nutrition 0.000 description 3
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 3
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 3
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 3
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 108091005804 Peptidases Proteins 0.000 description 2
- 102000035195 Peptidases Human genes 0.000 description 2
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- 239000004365 Protease Substances 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 108010056079 Subtilisins Proteins 0.000 description 2
- 102000005158 Subtilisins Human genes 0.000 description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 230000003254 anti-foaming effect Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000009833 condensation Methods 0.000 description 2
- 230000005494 condensation Effects 0.000 description 2
- 239000007884 disintegrant Substances 0.000 description 2
- PMPJQLCPEQFEJW-GNTLFSRWSA-L disodium;2-[(z)-2-[4-[4-[(z)-2-(2-sulfonatophenyl)ethenyl]phenyl]phenyl]ethenyl]benzenesulfonate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)C1=CC=CC=C1\C=C/C1=CC=C(C=2C=CC(\C=C/C=3C(=CC=CC=3)S([O-])(=O)=O)=CC=2)C=C1 PMPJQLCPEQFEJW-GNTLFSRWSA-L 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 238000007580 dry-mixing Methods 0.000 description 2
- 229910001385 heavy metal Inorganic materials 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 150000003138 primary alcohols Chemical class 0.000 description 2
- 239000003352 sequestering agent Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- 238000001694 spray drying Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- CIOXZGOUEYHNBF-UHFFFAOYSA-N (carboxymethoxy)succinic acid Chemical compound OC(=O)COC(C(O)=O)CC(O)=O CIOXZGOUEYHNBF-UHFFFAOYSA-N 0.000 description 1
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
- BLKPFVWYBFDTPX-UHFFFAOYSA-N 2-(6,6-dimethyl-4-bicyclo[3.1.1]hept-3-enyl)acetaldehyde Chemical compound C1C2C(C)(C)C1CC=C2CC=O BLKPFVWYBFDTPX-UHFFFAOYSA-N 0.000 description 1
- LVVZBNKWTVZSIU-UHFFFAOYSA-N 2-(carboxymethoxy)propanedioic acid Chemical compound OC(=O)COC(C(O)=O)C(O)=O LVVZBNKWTVZSIU-UHFFFAOYSA-N 0.000 description 1
- ZTGKHKPZSMMHNM-UHFFFAOYSA-N 3-(2-phenylethenyl)benzene-1,2-disulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC(C=CC=2C=CC=CC=2)=C1S(O)(=O)=O ZTGKHKPZSMMHNM-UHFFFAOYSA-N 0.000 description 1
- YNJSNEKCXVFDKW-UHFFFAOYSA-N 3-(5-amino-1h-indol-3-yl)-2-azaniumylpropanoate Chemical compound C1=C(N)C=C2C(CC(N)C(O)=O)=CNC2=C1 YNJSNEKCXVFDKW-UHFFFAOYSA-N 0.000 description 1
- YGUMVDWOQQJBGA-VAWYXSNFSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[(e)-2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(\C=C\C=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-VAWYXSNFSA-N 0.000 description 1
- XSVSPKKXQGNHMD-UHFFFAOYSA-N 5-bromo-3-methyl-1,2-thiazole Chemical compound CC=1C=C(Br)SN=1 XSVSPKKXQGNHMD-UHFFFAOYSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 102000005575 Cellulases Human genes 0.000 description 1
- 108010084185 Cellulases Proteins 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 description 1
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920000896 Ethulose Polymers 0.000 description 1
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- 235000003222 Helianthus annuus Nutrition 0.000 description 1
- 239000005639 Lauric acid Substances 0.000 description 1
- 108090001060 Lipase Proteins 0.000 description 1
- 239000004367 Lipase Substances 0.000 description 1
- 102000004882 Lipase Human genes 0.000 description 1
- BLSKPZCBDOVSEF-UHFFFAOYSA-N O[PH2]=O.OC(=O)C=C Chemical class O[PH2]=O.OC(=O)C=C BLSKPZCBDOVSEF-UHFFFAOYSA-N 0.000 description 1
- 240000008607 Opuntia megacantha Species 0.000 description 1
- 235000002840 Opuntia megacantha Nutrition 0.000 description 1
- 235000006538 Opuntia tuna Nutrition 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- 235000019484 Rapeseed oil Nutrition 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical class OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 1
- DUJHUESDNVWCBZ-UHFFFAOYSA-N [acetyloxy(2-hydroxyethyl)amino] acetate Chemical compound CC(=O)ON(CCO)OC(C)=O DUJHUESDNVWCBZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 125000005466 alkylenyl group Chemical group 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 229940025131 amylases Drugs 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
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- 125000002091 cationic group Chemical group 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000007891 compressed tablet Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
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- 230000000593 degrading effect Effects 0.000 description 1
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- 230000001687 destabilization Effects 0.000 description 1
- WJJMNDUMQPNECX-UHFFFAOYSA-N dipicolinic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=N1 WJJMNDUMQPNECX-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
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- 229940050410 gluconate Drugs 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000001165 hydrophobic group Chemical group 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 229910052816 inorganic phosphate Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 235000019421 lipase Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- 108010003855 mesentericopeptidase Proteins 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 108010020132 microbial serine proteinases Proteins 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 235000019271 petrolatum Nutrition 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000021148 sequestering of metal ion Effects 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 150000003385 sodium Chemical class 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000342 sodium bisulfate Inorganic materials 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 159000000000 sodium salts Chemical group 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- RPQSWSMNPBZEHT-UHFFFAOYSA-M sodium;2-acetyloxybenzenesulfonate Chemical compound [Na+].CC(=O)OC1=CC=CC=C1S([O-])(=O)=O RPQSWSMNPBZEHT-UHFFFAOYSA-M 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0047—Detergents in the form of bars or tablets
- C11D17/0065—Solid detergents containing builders
- C11D17/0073—Tablets
- C11D17/0078—Multilayered tablets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3942—Inorganic per-compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9022724.0 | 1990-10-19 | ||
| GB909022724A GB9022724D0 (en) | 1990-10-19 | 1990-10-19 | Detergent compositions |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH04285698A JPH04285698A (ja) | 1992-10-09 |
| JP2628812B2 true JP2628812B2 (ja) | 1997-07-09 |
Family
ID=10683979
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3271277A Expired - Lifetime JP2628812B2 (ja) | 1990-10-19 | 1991-10-18 | 洗剤組成物 |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0481793B1 (enExample) |
| JP (1) | JP2628812B2 (enExample) |
| KR (1) | KR950005384B1 (enExample) |
| AU (1) | AU632713B2 (enExample) |
| BR (1) | BR9104512A (enExample) |
| CA (1) | CA2053434C (enExample) |
| DE (1) | DE69101896T2 (enExample) |
| ES (1) | ES2052337T3 (enExample) |
| GB (1) | GB9022724D0 (enExample) |
| TW (1) | TW224135B (enExample) |
| ZA (1) | ZA918338B (enExample) |
Families Citing this family (64)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9224015D0 (en) * | 1992-11-16 | 1993-01-06 | Unilever Plc | Detergent compositions |
| GB9422924D0 (en) * | 1994-11-14 | 1995-01-04 | Unilever Plc | Detergent compositions |
| GB9422925D0 (en) * | 1994-11-14 | 1995-01-04 | Unilever Plc | Detergent compositions |
| ES2201162T3 (es) * | 1995-04-12 | 2004-03-16 | Cleantabs A/S | Comprimido de agentes blanqueantes. |
| AU6413096A (en) | 1995-07-13 | 1997-02-10 | Joh. A. Benckiser Gmbh | Dish washer product in tablet form |
| US5837663A (en) * | 1996-12-23 | 1998-11-17 | Lever Brothers Company, Division Of Conopco, Inc. | Machine dishwashing tablets containing a peracid |
| US6465413B1 (en) * | 1997-01-10 | 2002-10-15 | Gerald Thomas Hinton | Detergent |
| GB2324495A (en) * | 1997-04-22 | 1998-10-28 | Procter & Gamble | Multi-layer detergent tablet |
| GB9711829D0 (en) | 1997-06-06 | 1997-08-06 | Unilever Plc | Detergent compositions |
| GB9711831D0 (en) † | 1997-06-06 | 1997-08-06 | Unilever Plc | Cleaning compositions |
| GB2327949A (en) * | 1997-08-02 | 1999-02-10 | Procter & Gamble | Detergent tablet |
| US6451754B1 (en) | 1997-08-02 | 2002-09-17 | The Procter & Gamble Company | Process for preparing detergent tablet |
| DE19739384A1 (de) * | 1997-09-09 | 1999-03-11 | Henkel Kgaa | Wasch- und Reinigungsmittelformkörper mit verbesserter Löslichkeit |
| KR100247735B1 (ko) * | 1997-09-11 | 2000-03-15 | 하진규 | 폐합성수지재를 이용한 건설골재 및 그의 제조방법 |
| TR200001042T2 (tr) * | 1997-10-22 | 2000-08-21 | Unilever N.V. | Tablet şeklindeki deterjan bileşikleri |
| WO1999024549A1 (en) * | 1997-11-10 | 1999-05-20 | The Procter & Gamble Company | Multi-layer detergent tablet having both compressed and non-compressed portions |
| US6413928B1 (en) | 1997-11-10 | 2002-07-02 | The Procter & Gamble Company | Process for preparing a detergent tablet |
| EP1032642B1 (en) | 1997-11-10 | 2003-07-02 | The Procter & Gamble Company | Process for making a detergent tablet |
| ES2227900T3 (es) * | 1997-11-26 | 2005-04-01 | THE PROCTER & GAMBLE COMPANY | Procedimiento para fabricar una pastilla detergente. |
| ATE317002T1 (de) * | 1997-11-26 | 2006-02-15 | Procter & Gamble | Waschmitteltablette |
| ES2244096T3 (es) | 1997-11-26 | 2005-12-01 | THE PROCTER & GAMBLE COMPANY | Pastilla detergente. |
| WO1999027063A1 (en) * | 1997-11-26 | 1999-06-03 | The Procter & Gamble Company | Multi-layer detergent tablet having both compressed and non-compressed portions |
| EP1034250B1 (en) * | 1997-11-26 | 2005-01-26 | The Procter & Gamble Company | Detergent tablet |
| DE19758173A1 (de) * | 1997-12-30 | 1999-07-01 | Henkel Kgaa | Geschirrspülmittelformkörper mit spezifischer Geometrie |
| DE19758176A1 (de) * | 1997-12-30 | 1999-07-01 | Henkel Kgaa | Geschirrspülmittelformkörper mit Tensiden |
| DE19758183A1 (de) * | 1997-12-30 | 1999-07-01 | Henkel Kgaa | Waschaktiver Formkörper mit spezifischer Oberfläche |
| DE19758171A1 (de) * | 1997-12-30 | 1999-07-01 | Henkel Kgaa | Geschirrspülmittelformkörper mit spezifischem Volumenverhältnis |
| BR9814807A (pt) | 1998-01-26 | 2000-10-17 | Procter & Gamble | Tablete detergente com camadas múltiplas |
| DE19803410A1 (de) * | 1998-01-28 | 1999-07-29 | Henkel Kgaa | Mehrphasige Waschmitteltabletten |
| GB9802390D0 (en) * | 1998-02-04 | 1998-04-01 | Unilever Plc | Detergent compositions |
| US6534473B1 (en) | 1998-02-10 | 2003-03-18 | Unilever Patent Holdings Bv | Process for the manufacture of tablet detergent compositions |
| DE19806220A1 (de) * | 1998-02-16 | 1999-08-19 | Henkel Kgaa | Mehrphasen-Formkörper mit optimiertem Phasensplit |
| DE19806200A1 (de) * | 1998-02-16 | 1999-08-19 | Henkel Kgaa | Wasch- und Reinigungsmittelformkörper mit Bleichmittel |
| GB9814968D0 (en) | 1998-07-10 | 1998-09-09 | Hinton Gerald T | Detergent |
| GB2340842A (en) * | 1998-08-28 | 2000-03-01 | Procter & Gamble | Detergent tablet |
| DE29911484U1 (de) * | 1998-07-17 | 2000-02-24 | The Procter & Gamble Co., Cincinnati, Ohio | Reinigungsmitteltablette |
| US6589932B1 (en) * | 1998-07-17 | 2003-07-08 | The Procter & Gamble Company | Detergent tablet |
| GB9815525D0 (en) * | 1998-07-17 | 1998-09-16 | Procter & Gamble | Detergent tablet |
| US6551981B1 (en) * | 1998-07-17 | 2003-04-22 | Patrizio Ricci | Detergent tablet |
| US6551982B1 (en) | 1998-07-17 | 2003-04-22 | Procter & Gamble Company | Detergent tablet |
| ES2208477T3 (es) * | 1998-07-17 | 2004-06-16 | Procter & Gamble | Tableta detergente. |
| PT979865E (pt) * | 1998-07-17 | 2002-09-30 | Procter & Gamble | Pastilhas detergentes |
| DE69900736T2 (de) * | 1998-07-17 | 2002-08-29 | THE PROCTER & GAMBLE COMPANY, CINCINNATI | Verfahren zur Herstellung von Waschmitteltabletten |
| DE29911486U1 (de) * | 1998-07-17 | 1999-11-18 | The Procter & Gamble Co., Cincinnati, Ohio | Reinigungsmitteltablette |
| FR2781810B1 (fr) * | 1998-07-31 | 2000-09-15 | Chimiotechnic | Tablette detergente multicouches pour le lavage du linge et procede de fabrication |
| DE19841362A1 (de) * | 1998-09-10 | 2000-03-16 | Henkel Kgaa | ABS-haltige Wasch- und Reinigungsmittelformkörper |
| DE19843778A1 (de) * | 1998-09-24 | 2000-03-30 | Henkel Kgaa | Wasch- und Reinigungsmittelformkörper mit Natriumpercarbonat |
| EP0999261A1 (en) * | 1998-11-05 | 2000-05-10 | The Procter & Gamble Company | Coloured tablet |
| EP0999262A1 (en) * | 1998-11-05 | 2000-05-10 | The Procter & Gamble Company | Multilayered detergent tablets |
| DE19855381A1 (de) * | 1998-12-01 | 2000-06-08 | Henkel Kgaa | Tensidmischung in fester Form zum Einsatz als Wasch- und Reinigungsmittel |
| DE19856214C1 (de) | 1998-12-05 | 2000-03-09 | Henkel Kgaa | Punkttablette |
| GB9901688D0 (en) | 1999-01-26 | 1999-03-17 | Unilever Plc | Detergent compositions |
| DE19914353A1 (de) * | 1999-03-31 | 2000-10-05 | Henkel Kgaa | Wasch- und Reinigungsmittelformkörper mit speziellen Bleichaktivatoren |
| DE19914812A1 (de) * | 1999-03-31 | 2000-10-05 | Henkel Kgaa | Ein- oder mehrphasige Wasch- und Reinigungsmittelformkörper mit speziellen Bleichaktivatoren |
| DE19920119A1 (de) * | 1999-05-03 | 2000-11-09 | Henkel Kgaa | Waschverfahren mit Waschmitteltabletten |
| GB9911949D0 (en) | 1999-05-21 | 1999-07-21 | Unilever Plc | Detergent compositions |
| US6818606B1 (en) | 1999-06-16 | 2004-11-16 | Kao Corporation | Article for use in washing in sheet form |
| DE19948669A1 (de) * | 1999-10-08 | 2001-04-19 | Cognis Deutschland Gmbh | Waschmitteltabletten |
| KR20010064564A (ko) * | 1999-12-29 | 2001-07-09 | 김형철 | 폐플라스틱 종말처리품을 이용한 경량 인조골재의제조방법 |
| DE10038845A1 (de) * | 2000-08-04 | 2002-02-21 | Henkel Kgaa | Teilchenförmig konfektionierte Acetonitril-Derivate als Bleichaktivatoren in festen Waschmitteln |
| JP5207161B2 (ja) * | 2006-08-10 | 2013-06-12 | ディバーシー株式会社 | 自動食器洗浄機への洗浄剤供給方法およびそれに用いられる自動食器洗浄機用タブレット洗浄剤組成物、並びにそれを用いた洗浄方法 |
| DE102007059968A1 (de) | 2007-12-11 | 2009-06-18 | Henkel Ag & Co. Kgaa | Reinigungsmittel |
| DE102007059970A1 (de) | 2007-12-11 | 2009-09-10 | Henkel Ag & Co. Kgaa | Reinigungsmittel |
| JP6695103B2 (ja) * | 2015-06-25 | 2020-05-20 | 株式会社ニイタカ | カートリッジ洗浄剤 |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB911204A (en) * | 1960-07-28 | 1962-11-21 | Unilever Ltd | Bleaching compositions |
| DE2263939C2 (de) * | 1972-07-03 | 1983-01-13 | Henkel KGaA, 4000 Düsseldorf | Zur Verwendung in perhydrathaltigen Textilwaschmitteln geeignete Bleichaktivator-Tablette |
| JPS5070286A (enExample) * | 1973-10-25 | 1975-06-11 | ||
| LU72575A1 (enExample) * | 1975-05-23 | 1977-02-10 | ||
| JPS58217599A (ja) * | 1982-06-10 | 1983-12-17 | 花王株式会社 | 漂白洗浄剤組成物 |
| JPS59145300A (ja) * | 1983-02-07 | 1984-08-20 | 日本パ−オキサイド株式会社 | 漂白洗剤 |
| JPS59194000A (ja) * | 1983-04-18 | 1984-11-02 | 花王株式会社 | 漂白洗浄剤組成物 |
| JPS6015500A (ja) * | 1983-07-08 | 1985-01-26 | ライオン株式会社 | 高嵩密度洗剤組成物 |
| DE3417820A1 (de) * | 1984-05-14 | 1985-11-14 | Henkel KGaA, 4000 Düsseldorf | Verfahren zur herstellung eines waschzusatzes in tablettenform |
| JPS614879A (ja) * | 1984-06-15 | 1986-01-10 | Atsugi Motor Parts Co Ltd | モ−タ自己冷却型エアポンプ |
| GB8727135D0 (en) * | 1987-11-19 | 1987-12-23 | Unilever Plc | Machine dishwashing composition |
| AU643077B2 (en) * | 1990-10-19 | 1993-11-04 | Unilever Plc | Detergent compositions |
-
1990
- 1990-10-19 GB GB909022724A patent/GB9022724D0/en active Pending
-
1991
- 1991-10-14 TW TW080108090A patent/TW224135B/zh active
- 1991-10-15 AU AU85842/91A patent/AU632713B2/en not_active Ceased
- 1991-10-15 CA CA002053434A patent/CA2053434C/en not_active Expired - Fee Related
- 1991-10-17 DE DE69101896T patent/DE69101896T2/de not_active Revoked
- 1991-10-17 EP EP91309598A patent/EP0481793B1/en not_active Revoked
- 1991-10-17 BR BR919104512A patent/BR9104512A/pt not_active IP Right Cessation
- 1991-10-17 KR KR1019910018254A patent/KR950005384B1/ko not_active Expired - Fee Related
- 1991-10-17 ES ES91309598T patent/ES2052337T3/es not_active Expired - Lifetime
- 1991-10-18 JP JP3271277A patent/JP2628812B2/ja not_active Expired - Lifetime
- 1991-10-18 ZA ZA918338A patent/ZA918338B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR950005384B1 (ko) | 1995-05-23 |
| EP0481793A1 (en) | 1992-04-22 |
| AU632713B2 (en) | 1993-01-07 |
| DE69101896D1 (de) | 1994-06-09 |
| DE69101896T2 (de) | 1994-08-11 |
| JPH04285698A (ja) | 1992-10-09 |
| BR9104512A (pt) | 1992-06-09 |
| KR920008176A (ko) | 1992-05-27 |
| GB9022724D0 (en) | 1990-12-05 |
| ZA918338B (en) | 1993-04-19 |
| CA2053434A1 (en) | 1992-04-20 |
| TW224135B (enExample) | 1994-05-21 |
| ES2052337T3 (es) | 1994-07-01 |
| EP0481793B1 (en) | 1994-05-04 |
| CA2053434C (en) | 1997-07-22 |
| AU8584291A (en) | 1992-06-25 |
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