JP2020502327A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2020502327A5 JP2020502327A5 JP2019531971A JP2019531971A JP2020502327A5 JP 2020502327 A5 JP2020502327 A5 JP 2020502327A5 JP 2019531971 A JP2019531971 A JP 2019531971A JP 2019531971 A JP2019531971 A JP 2019531971A JP 2020502327 A5 JP2020502327 A5 JP 2020502327A5
- Authority
- JP
- Japan
- Prior art keywords
- butylfluorene
- cyclopentadienyl
- methylene
- tert
- isopropylphenyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003054 catalyst Substances 0.000 claims 14
- 238000000034 method Methods 0.000 claims 8
- 125000003118 aryl group Chemical group 0.000 claims 6
- 229920006395 saturated elastomer Polymers 0.000 claims 6
- 125000005842 heteroatom Chemical group 0.000 claims 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 5
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 5
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 claims 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 4
- 125000002877 alkyl aryl group Chemical group 0.000 claims 4
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims 4
- 238000006116 polymerization reaction Methods 0.000 claims 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 3
- 229910052796 boron Inorganic materials 0.000 claims 3
- 229920001038 ethylene copolymer Polymers 0.000 claims 3
- 125000005843 halogen group Chemical group 0.000 claims 3
- 125000001072 heteroaryl group Chemical group 0.000 claims 3
- 229930195733 hydrocarbon Natural products 0.000 claims 3
- 150000002430 hydrocarbons Chemical class 0.000 claims 3
- 125000006546 (C4-C10) cycloalkyl group Chemical group 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 2
- 239000005977 Ethylene Substances 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 2
- 239000003426 co-catalyst Substances 0.000 claims 2
- 125000000753 cycloalkyl group Chemical group 0.000 claims 2
- 239000004711 α-olefin Substances 0.000 claims 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims 1
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 1
- QWUWMCYKGHVNAV-UHFFFAOYSA-N 1,2-dihydrostilbene Chemical group C=1C=CC=CC=1CCC1=CC=CC=C1 QWUWMCYKGHVNAV-UHFFFAOYSA-N 0.000 claims 1
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 claims 1
- SVYKKECYCPFKGB-UHFFFAOYSA-N N,N-dimethylcyclohexylamine Chemical compound CN(C)C1CCCCC1 SVYKKECYCPFKGB-UHFFFAOYSA-N 0.000 claims 1
- ONMVTOSZWOATRS-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)C1=CC=C(C=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCC1 Chemical compound [Cl-].[Cl-].C(C)(C)C1=CC=C(C=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCC1 ONMVTOSZWOATRS-UHFFFAOYSA-L 0.000 claims 1
- YRCJJVYPPMVDNA-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)C1=CC=C(C=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCC1 Chemical compound [Cl-].[Cl-].C(C)(C)C1=CC=C(C=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCC1 YRCJJVYPPMVDNA-UHFFFAOYSA-L 0.000 claims 1
- LSVZCIRHRWZPTE-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)C1=CC=C(C=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCCC1 Chemical compound [Cl-].[Cl-].C(C)(C)C1=CC=C(C=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCCC1 LSVZCIRHRWZPTE-UHFFFAOYSA-L 0.000 claims 1
- OEHSYQRZNOODOH-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)C=1C=C(C=C(C=1)C(C)C)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCC1 Chemical compound [Cl-].[Cl-].C(C)(C)C=1C=C(C=C(C=1)C(C)C)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCC1 OEHSYQRZNOODOH-UHFFFAOYSA-L 0.000 claims 1
- WADHYVLTBPIBEK-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)C=1C=C(C=C(C=1)C(C)C)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCC1 Chemical compound [Cl-].[Cl-].C(C)(C)C=1C=C(C=C(C=1)C(C)C)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCC1 WADHYVLTBPIBEK-UHFFFAOYSA-L 0.000 claims 1
- PURJWWPDSBUQGG-UHFFFAOYSA-L [Cl-].[Cl-].C(C)(C)C=1C=C(C=C(C=1)C(C)C)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCCC1 Chemical compound [Cl-].[Cl-].C(C)(C)C=1C=C(C=C(C=1)C(C)C)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCCC1 PURJWWPDSBUQGG-UHFFFAOYSA-L 0.000 claims 1
- MOTSWIZLEAPLMJ-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCC1 Chemical compound [Cl-].[Cl-].C1(=CC=CC=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCC1 MOTSWIZLEAPLMJ-UHFFFAOYSA-L 0.000 claims 1
- DHQQPROSBWJUIU-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCC1 Chemical compound [Cl-].[Cl-].C1(=CC=CC=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCC1 DHQQPROSBWJUIU-UHFFFAOYSA-L 0.000 claims 1
- NCJFTUWQPXPFID-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCCC1 Chemical compound [Cl-].[Cl-].C1(=CC=CC=C1)C(=[Hf+2](C1C2=CC(=CC=C2C=2C=CC(=CC1=2)C(C)(C)C)C(C)(C)C)C1C=CC=C1)C1CCCCC1 NCJFTUWQPXPFID-UHFFFAOYSA-L 0.000 claims 1
- 125000002015 acyclic group Chemical group 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 239000003849 aromatic solvent Substances 0.000 claims 1
- 230000003197 catalytic effect Effects 0.000 claims 1
- 125000001309 chloro group Chemical group Cl* 0.000 claims 1
- 238000007334 copolymerization reaction Methods 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- 239000003085 diluting agent Substances 0.000 claims 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-O dimethyl(phenyl)azanium Chemical compound C[NH+](C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-O 0.000 claims 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 claims 1
- 229910052735 hafnium Inorganic materials 0.000 claims 1
- 239000003446 ligand Substances 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 239000000203 mixture Substances 0.000 claims 1
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000007787 solid Substances 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- OLFPYUPGPBITMH-UHFFFAOYSA-N tritylium Chemical compound C1=CC=CC=C1[C+](C=1C=CC=CC=1)C1=CC=CC=C1 OLFPYUPGPBITMH-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16204328.5 | 2016-12-15 | ||
| EP16204328 | 2016-12-15 | ||
| PCT/EP2017/082434 WO2018108918A1 (en) | 2016-12-15 | 2017-12-12 | Catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2020502327A JP2020502327A (ja) | 2020-01-23 |
| JP2020502327A5 true JP2020502327A5 (https=) | 2021-01-28 |
| JP7130644B2 JP7130644B2 (ja) | 2022-09-05 |
Family
ID=57614134
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019531971A Active JP7130644B2 (ja) | 2016-12-15 | 2017-12-12 | 高温溶液重合プロセスでポリエチレンコポリマーを製造する為の新規な触媒系 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US11279781B2 (https=) |
| EP (1) | EP3555148B1 (https=) |
| JP (1) | JP7130644B2 (https=) |
| KR (1) | KR102534541B1 (https=) |
| CN (1) | CN110234665B (https=) |
| ES (1) | ES2943392T3 (https=) |
| WO (1) | WO2018108918A1 (https=) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102505086B1 (ko) | 2016-11-18 | 2023-02-28 | 보레알리스 아게 | 촉매 |
| EP3562831B1 (en) | 2016-12-29 | 2021-10-20 | Borealis AG | Catalysts |
| EP3768735B1 (en) | 2018-03-19 | 2021-12-29 | Borealis AG | Catalysts for olefin polymerization |
| KR20210027401A (ko) | 2018-06-28 | 2021-03-10 | 보레알리스 아게 | 촉매 |
| WO2020156989A1 (en) | 2019-01-28 | 2020-08-06 | Borealis Ag | Polymer composition |
| CN113329858B (zh) | 2019-01-28 | 2024-01-12 | 博里利斯股份公司 | 用于生产聚合物组合物的方法 |
| WO2020178010A1 (en) | 2019-03-04 | 2020-09-10 | Borealis Ag | Polymerization process |
| EP3763745A1 (en) | 2019-07-10 | 2021-01-13 | Borealis AG | High temperature solution process for the copolymerization of alpha-olefins |
| WO2021052797A1 (en) * | 2019-09-20 | 2021-03-25 | Sabic Global Technologies B.V. | Compounds for use in catalyst compositions for the production of polyolefins |
| EP3838933A1 (en) | 2019-12-20 | 2021-06-23 | Borealis AG | Polymerization process and reactor for controlling molecular weight distribution and comonomer composition distribution |
| EP3845572A1 (en) | 2020-01-02 | 2021-07-07 | Borealis AG | Process for the polymerization of olefins in solution with controlled activity of catalyst in reactor outlet stream |
| EP3845569A1 (en) | 2020-01-02 | 2021-07-07 | Borealis AG | Process for the polymerization of olefins in solution comprising deactivating the polymerization catalyst by heat |
| KR102926344B1 (ko) | 2020-07-13 | 2026-02-11 | 보레알리스 게엠베하 | 접착성 폴리에틸렌 조성물 |
| CN115803411A (zh) | 2020-07-13 | 2023-03-14 | 博里利斯股份公司 | 粘合剂聚乙烯组合物 |
| EP4185622A1 (en) * | 2020-07-23 | 2023-05-31 | Borealis AG | Metallocene complexes and catalysts made therefrom |
| CN116194494B (zh) * | 2020-09-30 | 2025-04-08 | 博里利斯股份公司 | 改善性能特征的乙烯-辛烯共聚物 |
| KR102897897B1 (ko) | 2020-09-30 | 2025-12-08 | 보레알리스 게엠베하 | 개선된 용융 및 유리 전이 온도를 갖는 에틸렌 코폴리머 |
| BR112023006045A2 (pt) | 2020-09-30 | 2023-05-09 | Borealis Ag | Copolímero de etileno e uma alfa-olefina |
| CA3196953A1 (en) | 2020-09-30 | 2022-04-07 | Borealis Ag | Plant and method for the production of an in-line blended polymer |
| WO2022073805A1 (en) | 2020-10-05 | 2022-04-14 | Borealis Ag | High temperature solution process for the copolymerization of ethylene with one ore more α-Olefin comonomer(s) |
| CN114437261B (zh) * | 2020-11-02 | 2024-03-26 | 中国石油化工股份有限公司 | 一种烯烃聚合茂金属催化剂及其制备方法和应用 |
| US20240002552A1 (en) | 2020-12-08 | 2024-01-04 | Borealis Ag | Polymerization Process and Arrangement |
| CA3199325A1 (en) * | 2020-12-11 | 2022-06-16 | Nova Chemicals Corporation | High crystallinity ethylene-vinylcyclohexane copolymers |
| US20240002561A1 (en) * | 2020-12-11 | 2024-01-04 | Nova Chemicals (International) S.A. | Low crystallinity ethylene-vinylcyclohexane copolymers |
| BR112023021116A2 (pt) | 2021-04-16 | 2023-12-12 | Borealis Ag | Copolímeros de etileno com estruturas moleculares homogêneas melhoradas |
| EP4137521A1 (en) | 2021-08-16 | 2023-02-22 | Borealis AG | Process for producing a polyolefin with low volatile content |
| EP4219599B1 (en) | 2022-01-28 | 2026-04-22 | Borealis GmbH | Polyethylene blend for a film layer |
| EP4424414A1 (en) | 2023-02-28 | 2024-09-04 | Borealis AG | Rapid mixing polymerization reactor and process |
| EP4424413A1 (en) | 2023-02-28 | 2024-09-04 | Borealis AG | Rapid mixing polymerization process |
| KR102869729B1 (ko) * | 2023-12-26 | 2025-10-14 | 디엘케미칼 주식회사 | 에틸렌/알파올레핀 공중합체 및 이의 제조방법 |
| EP4732940A1 (en) | 2024-10-04 | 2026-04-29 | Borealis GmbH | Process for producing a polyolefin with highly efficient recycling of 1-butene |
Family Cites Families (58)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5571880A (en) | 1991-05-09 | 1996-11-05 | Phillips Petroleum Company | Organometallic fluorenyl compounds and use thereof in an alpha-olefin polymerization process |
| US5332706A (en) | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
| FI96866C (fi) | 1993-11-05 | 1996-09-10 | Borealis As | Tuettu olefiinipolymerointikatalyytti, sen valmistus ja käyttö |
| US5756609A (en) | 1995-10-19 | 1998-05-26 | Amoco Corporation | Homogeneous metallocene-based olefin polymerization system with increased activity |
| DE19544828A1 (de) | 1995-12-01 | 1997-06-05 | Hoechst Ag | Hochmolekulare Copolymere |
| KR100624632B1 (ko) | 1997-03-07 | 2006-09-15 | 타고르 게엠베하 | 메탈로센 및 그의 제조 방법 |
| US6252019B1 (en) | 1997-05-13 | 2001-06-26 | Montell Technology Company Bv | Process for polymerizing tactioselective polyolefins in condensed phase using hafnocenes |
| DE69902548T2 (de) | 1998-08-11 | 2003-04-10 | The Dow Chemical Co., Midland | Katalysatoraktivatorverbindung |
| ES2233109T3 (es) | 1998-10-23 | 2005-06-01 | Exxonmobil Chemical Patents Inc. | Metalocenos puenteados para la copolimerizacion de olefinas. |
| KR100621299B1 (ko) | 1998-10-23 | 2006-09-13 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 브릿지된 하프노센에 의한 올레핀 공중합 방법 |
| DE60034308T2 (de) | 1999-10-08 | 2007-12-20 | Mitsui Chemicals, Inc. | Metallocene, ein Verfahren zur deren Herstellung, Olefinpolymerisationskatalysator, und ein Verfahren zur Herstellung von Polyolefinen |
| JP2004502699A (ja) | 2000-06-30 | 2004-01-29 | エクソンモービル・ケミカル・パテンツ・インク | 架橋ビス（インデニル）メタロセン化合物 |
| AU2002362036A1 (en) | 2001-12-05 | 2003-06-23 | Exxonmobil Chemical Patents Inc. | Bulky borate activations |
| EP1323747A1 (en) | 2001-12-19 | 2003-07-02 | Borealis Technology Oy | Production of olefin polymerisation catalysts |
| US6756455B2 (en) | 2002-05-31 | 2004-06-29 | Equistar Chemicals, Lp | High-temperature solution process for polyolefin manufacture |
| WO2004029062A1 (ja) * | 2002-09-27 | 2004-04-08 | Mitsui Chemicals, Inc. | オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法 |
| JP4367686B2 (ja) * | 2002-11-22 | 2009-11-18 | 三井化学株式会社 | オレフィン重合用の架橋メタロセン化合物およびそれを用いたオレフィンの重合方法 |
| WO2004104055A1 (ja) | 2003-05-20 | 2004-12-02 | Mitsui Chemicals, Inc. | エチレン系重合体 |
| JP2005008711A (ja) | 2003-06-17 | 2005-01-13 | Mitsui Chemicals Inc | 超高分子量オレフィン系重合体の製造方法 |
| US20050288461A1 (en) | 2004-06-25 | 2005-12-29 | Jensen Michael D | Polymerization catalysts for producing polymers with low levels of long chain branching |
| US7795194B2 (en) | 2004-11-26 | 2010-09-14 | Mitsui Chemicals, Inc. | Synthetic lubricating oil and lubricating oil composition |
| KR101286307B1 (ko) | 2004-12-31 | 2013-07-15 | 보레알리스 테크놀로지 오와이. | 공정 |
| RU2410388C2 (ru) | 2005-03-18 | 2011-01-27 | Базелль Полиолефине Гмбх | Металлоценовые соединения |
| US7312283B2 (en) | 2005-08-22 | 2007-12-25 | Chevron Phillips Chemical Company Lp | Polymerization catalysts and process for producing bimodal polymers in a single reactor |
| US7619047B2 (en) | 2006-02-22 | 2009-11-17 | Chevron Phillips Chemical Company, Lp | Dual metallocene catalysts for polymerization of bimodal polymers |
| US7834205B2 (en) | 2006-04-12 | 2010-11-16 | Basell Polyolifine GmbH | Metallocene compounds |
| EP2010580B1 (en) | 2006-04-21 | 2016-07-13 | Basell Polyolefine GmbH | Process for the preparation of ethylene copolymers |
| JPWO2009081794A1 (ja) | 2007-12-21 | 2011-05-06 | 三井化学株式会社 | エチレン／α−オレフィン／非共役ポリエン共重合体の製造方法 |
| ES2619729T3 (es) | 2008-11-07 | 2017-06-26 | Borealis Ag | Composición de catalizador sólida |
| WO2010052264A1 (en) | 2008-11-07 | 2010-05-14 | Borealis Ag | Solid catalyst composition |
| EP2361267B1 (en) | 2008-11-07 | 2015-03-04 | Borealis AG | Process to prepare a solid catalyst composition |
| WO2011076780A1 (en) | 2009-12-22 | 2011-06-30 | Borealis Ag | Catalysts |
| EP2516484A1 (en) | 2009-12-22 | 2012-10-31 | Borealis AG | Preparation of polypropylene in the presence of a single-site catalyst |
| US8729206B2 (en) | 2010-04-28 | 2014-05-20 | Borealis Ag | Solid particulate catalysts comprising bridged metallocenes |
| KR101626069B1 (ko) | 2010-04-28 | 2016-05-31 | 보레알리스 아게 | 브릿지된 메탈로센을 포함하는 고체 미립자 촉매 |
| EP2402353B1 (en) | 2010-07-01 | 2018-04-25 | Borealis AG | Group 4 metallocenes useful as catalysts for the polymerization of olefins |
| ES2565438T3 (es) | 2010-07-01 | 2016-04-04 | Borealis Ag | Proceso para la polimerización de olefinas usando metalocenos del grupo 4 como catalizadores |
| CN103339158B (zh) | 2010-12-01 | 2017-02-22 | 道达尔研究技术弗吕公司 | 包含丙烯无规共聚物的帽和封闭件及其制造方法 |
| CA2724943A1 (en) | 2010-12-10 | 2012-06-10 | Nova Chemicals Corporation | Catalyst activation in a dual reactor process |
| EP2655431A1 (en) | 2010-12-22 | 2013-10-30 | Borealis AG | Bridged metallocene catalysts |
| EP2532687A3 (en) | 2011-06-10 | 2013-04-10 | Borealis AG | Bridged Metallocene Catalysts |
| CN103649101A (zh) | 2011-07-08 | 2014-03-19 | 博瑞立斯有限公司 | 催化剂 |
| WO2013161833A1 (ja) * | 2012-04-26 | 2013-10-31 | 三井化学株式会社 | オレフィン重合体の製造方法 |
| EP2722346A1 (en) | 2012-10-18 | 2014-04-23 | Borealis AG | Polymerisation process and catalyst |
| ES2606684T3 (es) | 2012-11-07 | 2017-03-27 | Chevron Phillips Chemical Company Lp | Resinas de poliolefina de baja densidad y películas preparadas a partir de éstas |
| WO2014096282A1 (en) | 2012-12-21 | 2014-06-26 | Borealis Ag | Catalyst |
| ES2589053T3 (es) | 2013-06-10 | 2016-11-08 | Borealis Ag | Procedimiento para la preparación de un polímero de propileno |
| JP2015137352A (ja) * | 2014-01-24 | 2015-07-30 | 三井化学株式会社 | オレフィン重合体の製造方法 |
| JP2015147862A (ja) | 2014-02-06 | 2015-08-20 | 東ソー株式会社 | ポリエチレン系重合体製造用触媒及びそれを用いてなるポリエチレン系重合体の製造方法 |
| US9969827B2 (en) * | 2014-02-13 | 2018-05-15 | Mitsui Chemicals, Inc. | Process for producing ethylene/α-olefin copolymer |
| WO2015158790A2 (en) | 2014-04-17 | 2015-10-22 | Borealis Ag | Improved catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process |
| EP2933277A1 (en) | 2014-04-17 | 2015-10-21 | Borealis AG | New catalyst system for producing polyethylene copolymers in a high temperature solution polymerization process |
| EP2995629B1 (en) | 2014-09-12 | 2018-03-07 | Borealis AG | Process for producing propylene copolymers in gas phase |
| WO2016038211A1 (en) | 2014-09-12 | 2016-03-17 | Borealis Ag | Process for the preparation of copolymers of propylene |
| WO2016114915A1 (en) * | 2015-01-14 | 2016-07-21 | Exxonmobil Chemical Patents Inc. | Polymer compositions and processes for their production |
| JP6545813B2 (ja) * | 2015-11-09 | 2019-07-17 | 三井化学株式会社 | 潤滑油用粘度調整剤、潤滑油用添加剤組成物および潤滑油組成物 |
| US10730783B2 (en) * | 2016-09-30 | 2020-08-04 | Corning Incorporated | Apparatuses and methods for laser processing transparent workpieces using non-axisymmetric beam spots |
| KR102505086B1 (ko) | 2016-11-18 | 2023-02-28 | 보레알리스 아게 | 촉매 |
-
2017
- 2017-12-12 JP JP2019531971A patent/JP7130644B2/ja active Active
- 2017-12-12 CN CN201780085191.8A patent/CN110234665B/zh active Active
- 2017-12-12 EP EP17811610.9A patent/EP3555148B1/en active Active
- 2017-12-12 ES ES17811610T patent/ES2943392T3/es active Active
- 2017-12-12 KR KR1020197020143A patent/KR102534541B1/ko active Active
- 2017-12-12 WO PCT/EP2017/082434 patent/WO2018108918A1/en not_active Ceased
- 2017-12-12 US US16/469,617 patent/US11279781B2/en active Active
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2020502327A5 (https=) | ||
| JP5887361B2 (ja) | オレフィンブロック共重合体 | |
| RU2010120915A (ru) | Рацемоселективный синтез анса-металлоценовых соединений, анса-маталлоценовые соединения, катализаторы, содержащие их, способ получения олефинового полимера с использованием катализаторов и олефиновые гомо- и сополимеры | |
| PE20201027A1 (es) | Un proceso mejorado para fabricar productos de interpolimero de etileno | |
| JP5782131B2 (ja) | オレフィンブロック共重合体およびその製造方法 | |
| KR101170492B1 (ko) | 올레핀 블록 공중합체 | |
| KR20120085201A (ko) | 올레핀 블록 공중합체 및 이의 제조 방법 | |
| CN104448062B (zh) | 一种茂金属催化剂的制备方法 | |
| CN108137739A (zh) | 烯烃聚合物及其制备方法 | |
| CN105518034B (zh) | 聚烯烃 | |
| JP2018502046A (ja) | メタロセン化合物、メタロセン担持触媒およびこれを用いるポリオレフィンの製造方法 | |
| JP6499280B2 (ja) | メタロセン担持触媒およびこれを用いるポリオレフィンの製造方法 | |
| KR102028736B1 (ko) | 혼성 담지 메탈로센 촉매의 제조방법 및 이를 이용하여 제조된 혼성 담지 메탈로센 촉매 | |
| KR101725349B1 (ko) | 혼성 담지 촉매 및 이를 이용하는 올레핀 중합체의 제조 방법 | |
| JP2017160196A5 (https=) | ||
| RU2009128975A (ru) | Способ получения разветвленного полипропилена | |
| CN105308060B (zh) | 双核茂金属化合物及其制备方法 | |
| JP6453483B2 (ja) | メタロセン担持触媒およびこれを用いるポリオレフィンの製造方法 | |
| RU2012128353A (ru) | Способы уменьшения статического заряда катализатора и способы применения такого катализатора для производства полиолефинов | |
| CN107663248B (zh) | 一种用于长链α-烯烃聚合的催化剂组合物及其催化长链α-烯烃聚合的方法 | |
| KR20140012488A (ko) | 가교 구조를 갖는 올레핀 블록 공중합체 및 이의 제조 방법 | |
| CN108191910A (zh) | 单茂金属化合物及制备方法和烯烃聚合用催化剂组合物及应用和制备丙烯均聚物的方法 | |
| KR20200090039A (ko) | 에틸렌-알파올레핀의 제조 방법 및 사출 성형품의 제조 방법 | |
| KR101170491B1 (ko) | 올레핀 블록 공중합체 및 시트상 성형체 | |
| JP6366256B2 (ja) | エチレン−ビニルアダマンタン共重合体及びその製造方法 |