JP2017531048A5 - - Google Patents
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- JP2017531048A5 JP2017531048A5 JP2017502199A JP2017502199A JP2017531048A5 JP 2017531048 A5 JP2017531048 A5 JP 2017531048A5 JP 2017502199 A JP2017502199 A JP 2017502199A JP 2017502199 A JP2017502199 A JP 2017502199A JP 2017531048 A5 JP2017531048 A5 JP 2017531048A5
- Authority
- JP
- Japan
- Prior art keywords
- binder composition
- acid
- aqueous curable
- curable binder
- binder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000011230 binding agent Substances 0.000 claims description 220
- 239000000203 mixture Substances 0.000 claims description 216
- 229920000642 polymer Polymers 0.000 claims description 100
- -1 aliphatic isocyanate Chemical class 0.000 claims description 77
- 239000002253 acid Substances 0.000 claims description 49
- 239000011159 matrix material Substances 0.000 claims description 43
- 239000000835 fiber Substances 0.000 claims description 37
- 238000001723 curing Methods 0.000 claims description 31
- 235000014633 carbohydrates Nutrition 0.000 claims description 29
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims description 29
- 239000002023 wood Substances 0.000 claims description 29
- 150000001720 carbohydrates Chemical class 0.000 claims description 28
- 239000002245 particle Substances 0.000 claims description 26
- 235000000346 sugar Nutrition 0.000 claims description 26
- 229920000768 polyamine Polymers 0.000 claims description 25
- 229920001661 Chitosan Polymers 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 24
- 229920002678 cellulose Polymers 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 20
- 239000000178 monomer Substances 0.000 claims description 20
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 19
- 229920001577 copolymer Polymers 0.000 claims description 19
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 18
- 239000001913 cellulose Substances 0.000 claims description 18
- 235000010980 cellulose Nutrition 0.000 claims description 18
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 18
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 18
- 150000004676 glycans Chemical class 0.000 claims description 16
- 150000003863 ammonium salts Chemical group 0.000 claims description 15
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 15
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 15
- 229920001282 polysaccharide Polymers 0.000 claims description 15
- 239000005017 polysaccharide Substances 0.000 claims description 15
- 239000000047 product Substances 0.000 claims description 15
- 150000007513 acids Chemical class 0.000 claims description 14
- 150000008163 sugars Chemical class 0.000 claims description 14
- 229920002873 Polyethylenimine Polymers 0.000 claims description 12
- 150000008064 anhydrides Chemical class 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 12
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 11
- HONIICLYMWZJFZ-UHFFFAOYSA-O azetidin-1-ium Chemical compound C1C[NH2+]C1 HONIICLYMWZJFZ-UHFFFAOYSA-O 0.000 claims description 11
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 claims description 11
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 11
- 229920000728 polyester Polymers 0.000 claims description 11
- 229920005989 resin Polymers 0.000 claims description 11
- 239000011347 resin Substances 0.000 claims description 11
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 10
- 229920001187 thermosetting polymer Polymers 0.000 claims description 10
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 9
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 9
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 9
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 9
- 238000009413 insulation Methods 0.000 claims description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 8
- 239000012948 isocyanate Substances 0.000 claims description 8
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 150000007522 mineralic acids Chemical class 0.000 claims description 8
- 239000007858 starting material Substances 0.000 claims description 8
- CWSZBVAUYPTXTG-UHFFFAOYSA-N 5-[6-[[3,4-dihydroxy-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxymethyl]-3,4-dihydroxy-5-[4-hydroxy-3-(2-hydroxyethoxy)-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxyoxan-2-yl]oxy-6-(hydroxymethyl)-2-methyloxane-3,4-diol Chemical compound O1C(CO)C(OC)C(O)C(O)C1OCC1C(OC2C(C(O)C(OC)C(CO)O2)OCCO)C(O)C(O)C(OC2C(OC(C)C(O)C2O)CO)O1 CWSZBVAUYPTXTG-UHFFFAOYSA-N 0.000 claims description 7
- 229920002472 Starch Polymers 0.000 claims description 7
- 239000000654 additive Substances 0.000 claims description 7
- 125000001931 aliphatic group Chemical group 0.000 claims description 7
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- 238000011065 in-situ storage Methods 0.000 claims description 7
- 239000002105 nanoparticle Substances 0.000 claims description 7
- 229920002635 polyurethane Polymers 0.000 claims description 7
- 239000004814 polyurethane Substances 0.000 claims description 7
- 239000008107 starch Substances 0.000 claims description 7
- 235000019698 starch Nutrition 0.000 claims description 7
- 229920001046 Nanocellulose Polymers 0.000 claims description 6
- 239000011093 chipboard Substances 0.000 claims description 6
- 125000004122 cyclic group Chemical group 0.000 claims description 6
- 150000004985 diamines Chemical class 0.000 claims description 6
- 150000002386 heptoses Chemical class 0.000 claims description 6
- 150000002402 hexoses Chemical class 0.000 claims description 6
- 239000011859 microparticle Substances 0.000 claims description 6
- 239000011490 mineral wool Substances 0.000 claims description 6
- 150000002772 monosaccharides Chemical class 0.000 claims description 6
- 150000002972 pentoses Chemical class 0.000 claims description 6
- 150000003538 tetroses Chemical class 0.000 claims description 6
- 150000003641 trioses Chemical class 0.000 claims description 6
- KIUKXJAPPMFGSW-DNGZLQJQSA-N (2S,3S,4S,5R,6R)-6-[(2S,3R,4R,5S,6R)-3-Acetamido-2-[(2S,3S,4R,5R,6R)-6-[(2R,3R,4R,5S,6R)-3-acetamido-2,5-dihydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-2-carboxy-4,5-dihydroxyoxan-3-yl]oxy-5-hydroxy-6-(hydroxymethyl)oxan-4-yl]oxy-3,4,5-trihydroxyoxane-2-carboxylic acid Chemical compound CC(=O)N[C@H]1[C@H](O)O[C@H](CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O[C@H]3[C@@H]([C@@H](O)[C@H](O)[C@H](O3)C(O)=O)O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@@H](C(O)=O)O1 KIUKXJAPPMFGSW-DNGZLQJQSA-N 0.000 claims description 5
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 claims description 5
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 claims description 5
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 5
- 150000001323 aldoses Chemical class 0.000 claims description 5
- 229940072056 alginate Drugs 0.000 claims description 5
- 229920000615 alginic acid Polymers 0.000 claims description 5
- 235000010443 alginic acid Nutrition 0.000 claims description 5
- 125000003277 amino group Chemical group 0.000 claims description 5
- 239000007822 coupling agent Substances 0.000 claims description 5
- 238000001704 evaporation Methods 0.000 claims description 5
- 239000011094 fiberboard Substances 0.000 claims description 5
- 229920002674 hyaluronan Polymers 0.000 claims description 5
- 229960003160 hyaluronic acid Drugs 0.000 claims description 5
- 229910010272 inorganic material Inorganic materials 0.000 claims description 5
- 239000011147 inorganic material Substances 0.000 claims description 5
- 150000002584 ketoses Chemical group 0.000 claims description 5
- 239000012802 nanoclay Substances 0.000 claims description 5
- 229920001296 polysiloxane Polymers 0.000 claims description 5
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 5
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 5
- JZUHIOJYCPIVLQ-UHFFFAOYSA-N 2-methylpentane-1,5-diamine Chemical compound NCC(C)CCCN JZUHIOJYCPIVLQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 4
- 239000004254 Ammonium phosphate Substances 0.000 claims description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 4
- 108010039918 Polylysine Proteins 0.000 claims description 4
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 claims description 4
- IMUDHTPIFIBORV-UHFFFAOYSA-N aminoethylpiperazine Chemical compound NCCN1CCNCC1 IMUDHTPIFIBORV-UHFFFAOYSA-N 0.000 claims description 4
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims description 4
- 235000019289 ammonium phosphates Nutrition 0.000 claims description 4
- 229940121375 antifungal agent Drugs 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 239000000440 bentonite Substances 0.000 claims description 4
- 229910000278 bentonite Inorganic materials 0.000 claims description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 4
- 239000007795 chemical reaction product Substances 0.000 claims description 4
- 239000002131 composite material Substances 0.000 claims description 4
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 4
- 239000000975 dye Substances 0.000 claims description 4
- 229910052621 halloysite Inorganic materials 0.000 claims description 4
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims description 4
- 229910000271 hectorite Inorganic materials 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052622 kaolinite Inorganic materials 0.000 claims description 4
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 4
- 229920005615 natural polymer Polymers 0.000 claims description 4
- 229910017604 nitric acid Inorganic materials 0.000 claims description 4
- 229920001542 oligosaccharide Polymers 0.000 claims description 4
- 150000002482 oligosaccharides Chemical class 0.000 claims description 4
- 229920000656 polylysine Polymers 0.000 claims description 4
- 150000003628 tricarboxylic acids Chemical class 0.000 claims description 4
- KSSJBGNOJJETTC-UHFFFAOYSA-N COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC Chemical compound COC1=C(C=CC=C1)N(C1=CC=2C3(C4=CC(=CC=C4C=2C=C1)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC(=CC=C1C=1C=CC(=CC=13)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)N(C1=CC=C(C=C1)OC)C1=C(C=CC=C1)OC)C1=CC=C(C=C1)OC KSSJBGNOJJETTC-UHFFFAOYSA-N 0.000 claims description 3
- 229920002522 Wood fibre Polymers 0.000 claims description 3
- MRNZSTMRDWRNNR-UHFFFAOYSA-N bis(hexamethylene)triamine Chemical compound NCCCCCCNCCCCCCN MRNZSTMRDWRNNR-UHFFFAOYSA-N 0.000 claims description 3
- 150000001991 dicarboxylic acids Chemical group 0.000 claims description 3
- 239000011120 plywood Substances 0.000 claims description 3
- 229940032147 starch Drugs 0.000 claims description 3
- 229920001059 synthetic polymer Polymers 0.000 claims description 3
- 239000002025 wood fiber Substances 0.000 claims description 3
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 claims description 2
- 229920000881 Modified starch Polymers 0.000 claims description 2
- HONIICLYMWZJFZ-UHFFFAOYSA-N azetidine Chemical compound C1CNC1 HONIICLYMWZJFZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 125000002993 cycloalkylene group Chemical group 0.000 claims description 2
- 238000013007 heat curing Methods 0.000 claims description 2
- 125000004474 heteroalkylene group Chemical group 0.000 claims description 2
- 235000019426 modified starch Nutrition 0.000 claims description 2
- 239000004599 antimicrobial Substances 0.000 claims 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 1
- SPFMQWBKVUQXJV-BTVCFUMJSA-N (2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanal;hydrate Chemical compound O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O SPFMQWBKVUQXJV-BTVCFUMJSA-N 0.000 description 35
- 229960000673 dextrose monohydrate Drugs 0.000 description 35
- 239000005696 Diammonium phosphate Substances 0.000 description 25
- 229910000388 diammonium phosphate Inorganic materials 0.000 description 25
- 235000019838 diammonium phosphate Nutrition 0.000 description 25
- 239000000463 material Substances 0.000 description 21
- 239000000243 solution Substances 0.000 description 15
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 14
- 229960001031 glucose Drugs 0.000 description 14
- 239000008121 dextrose Substances 0.000 description 13
- 229920002125 Sokalan® Polymers 0.000 description 11
- 229920002689 polyvinyl acetate Polymers 0.000 description 11
- 239000011118 polyvinyl acetate Substances 0.000 description 11
- 239000000376 reactant Substances 0.000 description 11
- 239000007787 solid Substances 0.000 description 10
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 9
- 238000010521 absorption reaction Methods 0.000 description 9
- 125000000217 alkyl group Chemical group 0.000 description 9
- UVRCNEIYXSRHNT-UHFFFAOYSA-N 3-ethylpent-2-enamide Chemical compound CCC(CC)=CC(N)=O UVRCNEIYXSRHNT-UHFFFAOYSA-N 0.000 description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 description 7
- 150000001412 amines Chemical class 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- 239000004584 polyacrylic acid Substances 0.000 description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- WHNPOQXWAMXPTA-UHFFFAOYSA-N 3-methylbut-2-enamide Chemical compound CC(C)=CC(N)=O WHNPOQXWAMXPTA-UHFFFAOYSA-N 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 229920000954 Polyglycolide Polymers 0.000 description 6
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 6
- 239000011521 glass Substances 0.000 description 6
- 229920002239 polyacrylonitrile Polymers 0.000 description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 5
- SJIXRGNQPBQWMK-UHFFFAOYSA-N 2-(diethylamino)ethyl 2-methylprop-2-enoate Chemical compound CCN(CC)CCOC(=O)C(C)=C SJIXRGNQPBQWMK-UHFFFAOYSA-N 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 5
- 150000001732 carboxylic acid derivatives Chemical group 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 229920002401 polyacrylamide Polymers 0.000 description 5
- 229920000058 polyacrylate Polymers 0.000 description 5
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- 230000004580 weight loss Effects 0.000 description 5
- 239000004606 Fillers/Extenders Substances 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 229920003086 cellulose ether Polymers 0.000 description 4
- 229960004106 citric acid Drugs 0.000 description 4
- 150000002009 diols Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003365 glass fiber Substances 0.000 description 4
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- 229920000193 polymethacrylate Polymers 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- 229920003043 Cellulose fiber Polymers 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000001361 adipic acid Substances 0.000 description 3
- 235000011037 adipic acid Nutrition 0.000 description 3
- 239000003242 anti bacterial agent Substances 0.000 description 3
- 239000003429 antifungal agent Substances 0.000 description 3
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
- 229940077731 carbohydrate nutrients Drugs 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical compound O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 description 3
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 3
- 229920001519 homopolymer Polymers 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 3
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 3
- 239000002557 mineral fiber Substances 0.000 description 3
- 229920001568 phenolic resin Polymers 0.000 description 3
- 229920000747 poly(lactic acid) Polymers 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 239000004626 polylactic acid Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 3
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- DJKKWVGWYCKUFC-UHFFFAOYSA-N 2-butoxyethyl 2-methylprop-2-enoate Chemical compound CCCCOCCOC(=O)C(C)=C DJKKWVGWYCKUFC-UHFFFAOYSA-N 0.000 description 2
- FWWXYLGCHHIKNY-UHFFFAOYSA-N 2-ethoxyethyl prop-2-enoate Chemical compound CCOCCOC(=O)C=C FWWXYLGCHHIKNY-UHFFFAOYSA-N 0.000 description 2
- LPNSCOVIJFIXTJ-UHFFFAOYSA-N 2-methylidenebutanamide Chemical compound CCC(=C)C(N)=O LPNSCOVIJFIXTJ-UHFFFAOYSA-N 0.000 description 2
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| ES2870662T3 (es) | 2016-01-28 | 2021-10-27 | Ursa Insulation Sa | Resina curable mejorada para lana mineral |
| GB201609616D0 (en) * | 2016-06-02 | 2016-07-20 | Knauf Insulation Ltd | Method of manufacturing composite products |
| GB201701569D0 (en) * | 2017-01-31 | 2017-03-15 | Knauf Insulation Ltd | Improved binder compositions and uses thereof |
| KR101922644B1 (ko) | 2017-04-13 | 2018-11-27 | 씨제이제일제당 주식회사 | 바인더 조성물, 물품 및 물품 제조방법 |
| US12179379B2 (en) | 2017-06-29 | 2024-12-31 | Ecosynthetix Inc. | Adhesive with tack and use in wood composite products |
| KR102594229B1 (ko) | 2017-10-09 | 2023-10-25 | 오웬스 코닝 인텔렉츄얼 캐피탈 엘엘씨 | 수성 결합제 조성물 |
| JP7219270B2 (ja) | 2017-10-09 | 2023-02-07 | オウェンス コーニング インテレクチュアル キャピタル リミテッド ライアビリティ カンパニー | 水性バインダー組成物 |
| GB201721306D0 (en) * | 2017-12-19 | 2018-01-31 | Knauf Insulation Ltd | Mineral fiber based composites |
| US11214714B2 (en) * | 2018-05-08 | 2022-01-04 | Iowa State University Research Foundation, Inc. | Thermoplastic poly acrylated glycerol adhesives useful in cellulosic products |
| CN108729308B (zh) * | 2018-06-11 | 2020-02-11 | 杭州西红柿环保科技有限公司 | 一种纸浆模塑产品及其制备方法 |
| CN109207070B (zh) * | 2018-11-07 | 2020-12-04 | 深圳市浩力新材料技术有限公司 | 一种高耐水性的丙烯酸酯胶黏剂及其制备方法 |
| JP7482148B2 (ja) | 2019-04-09 | 2024-05-13 | オウェンス コーニング インテレクチュアル キャピタル リミテッド ライアビリティ カンパニー | 水性バインダー組成物を用いて形成される断熱材製品 |
| CN110394869B (zh) * | 2019-05-23 | 2020-11-20 | 山东省工艺美术研究所 | 一种桃木除胶除虫防裂防变形的木材处理技术工艺 |
| TWI860370B (zh) * | 2019-07-12 | 2024-11-01 | 美商陶氏全球科技有限責任公司 | 無溶劑組合物 |
| EP4010425A4 (en) * | 2019-07-29 | 2023-09-20 | LRBG Chemicals Inc. | Binder for insulation and non-woven mats |
| US11813833B2 (en) | 2019-12-09 | 2023-11-14 | Owens Corning Intellectual Capital, Llc | Fiberglass insulation product |
| WO2021118960A1 (en) | 2019-12-09 | 2021-06-17 | Owens Corning Intellectual Capital, Llc | Fiberglass insulation product |
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2014
- 2014-07-17 GB GBGB1412709.6A patent/GB201412709D0/en not_active Ceased
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2015
- 2015-07-17 CN CN202011547567.2A patent/CN112662339A/zh active Pending
- 2015-07-17 KR KR1020177004287A patent/KR102542973B1/ko active Active
- 2015-07-17 US US15/326,532 patent/US20170210952A1/en not_active Abandoned
- 2015-07-17 DK DK15738380.3T patent/DK3169741T3/da active
- 2015-07-17 PL PL15738380.3T patent/PL3169741T3/pl unknown
- 2015-07-17 AU AU2015289030A patent/AU2015289030B2/en active Active
- 2015-07-17 CN CN201580038717.8A patent/CN106536660A/zh active Pending
- 2015-07-17 EP EP15738380.3A patent/EP3169741B1/en not_active Revoked
- 2015-07-17 MX MX2017000726A patent/MX2017000726A/es unknown
- 2015-07-17 WO PCT/EP2015/066455 patent/WO2016009062A1/en not_active Ceased
- 2015-07-17 RU RU2017105098A patent/RU2694345C2/ru active
- 2015-07-17 JP JP2017502199A patent/JP2017531048A/ja active Pending
- 2015-07-17 CA CA2954960A patent/CA2954960C/en active Active
- 2015-07-17 SI SI201531920T patent/SI3169741T1/sl unknown
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2021
- 2021-10-11 US US17/498,146 patent/US12351738B2/en active Active
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