JP2014506783A - レバウディオサイド−モグロサイドv混合物 - Google Patents
レバウディオサイド−モグロサイドv混合物 Download PDFInfo
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- JP2014506783A JP2014506783A JP2013551285A JP2013551285A JP2014506783A JP 2014506783 A JP2014506783 A JP 2014506783A JP 2013551285 A JP2013551285 A JP 2013551285A JP 2013551285 A JP2013551285 A JP 2013551285A JP 2014506783 A JP2014506783 A JP 2014506783A
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- mogroside
- rebaudioside
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- GHBNZZJYBXQAHG-KUVSNLSMSA-N (2r,3r,4s,5s,6r)-2-[[(2r,3s,4s,5r,6r)-6-[[(3s,8s,9r,10r,11r,13r,14s,17r)-17-[(2r,5r)-5-[(2s,3r,4s,5s,6r)-4,5-dihydroxy-3-[(2r,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy-6-[[(2r,3r,4s,5s,6r)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxy Chemical compound C([C@H]1O[C@H]([C@@H]([C@@H](O)[C@@H]1O)O[C@H]1[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O1)O)O[C@H](CC[C@@H](C)[C@@H]1[C@]2(C[C@@H](O)[C@@]3(C)[C@H]4C(C([C@@H](O[C@H]5[C@@H]([C@@H](O)[C@H](O)[C@@H](CO[C@H]6[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O6)O)O5)O)CC4)(C)C)=CC[C@H]3[C@]2(C)CC1)C)C(C)(C)O)O[C@@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O GHBNZZJYBXQAHG-KUVSNLSMSA-N 0.000 claims abstract description 48
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Abstract
【選択図】図1
Description
ここで、レバウディオサイド成分は、レバウディオサイドA、レバウディオサイドB及びレバウディオサイドDから成る群より選ばれる1又はそれ以上の化合物を含む、組成物を提供する。
定義
本発明において、語句「甘味ステビオール配糖体」とは、1以上のサッカライド残基が環上に化学結合した通常のステビオールジテルペン環系構造を有する天然化合物を意味する。
ここに開示されるのは、モグロサイドVと、レバウディオサイドA、B及びDのうち1又はそれ以上を含むレバウディオサイド成分との混合物は優れた風味特性を提供し、多くの場合、同程度の甘味料と比較して、レバウディオサイド成分又はモグロサイドVの何れか単独でも優れた効果を示すことである。幾つかの系では、pH約2〜pH約8において最も明確に風味の向上が示される。
詳細な研究の結果、現在では、ラカンカ(Luo Han Guo)抽出物中にある程度不純物が存在することにより、結果的に味覚試験者が「カビ臭い」と称する異臭をもたらすことが見出された。さらなるカビ臭及び他の異臭成分も存在し得るものの、特に芳香族配糖体及び半揮発性有機化合物が、当該望ましくない臭いを産生することが同定されている。ある特定の芳香族系配糖体は分子量502ダルトンを有し、特定のカビ臭い風味を産生することが明らかとされている。当該化合物は分子式C26H30O10に一致し、当該分子式を有する全ての化合物の全体が、幾つかの実施態様において本発明により限定される。当該化合物の十分に低濃度を達成させるための任意の手段は、本発明の目的のために適切である。ある1つの適切な方法は、モグロサイドV水溶液を、例えば、場合により精製且つ/又は濃縮されたラカンカ抽出物の形態で、粒状活性炭のカラムを通すものである。活性炭の他の形態として、例えば粉末を用いることができる。また炭素処理は、さらにカビ臭又はその他の異臭成分のほかに、残留農薬及び原材料において消費者にとって望ましくない物質も除去する。典型的には、炭素処理において水のみが担体として用いられ、有機溶媒は加えられない。幾つかの実施態様では、ラカンカ抽出物を、マクロ多孔性高分子吸着樹脂、イオン交換樹脂、及び活性炭素で処理される。典型的には当該処理はこの順番で行われるが、必ずしもそうでなくてもよい。あるマクロ多孔性高分子吸着樹脂の例として、商品名AMBERLITE(登録商標) XAD1180N、Rohm and Haas(Philadelphia, PA)より市販されている。適切なイオン交換樹脂の例では、アニオン性樹脂であって商品名AMBERLITE(登録商標) FPA90 CLとして、同じくRohm and Haasより市販されている。
レバウディオサイド-モグロサイドV混合物を含む甘味組成物は粒子系や物理学的形状を変更する公知の方法により生産されてもよい。凝集、スプレー乾燥、ドラム乾燥及びその他の物理学的製法のような方法を用い、より優れた流動性、吸湿性又は溶解性をもたらすために粒子径を調節してもよい。該組成物は液状で供給され、場合により1又はそれ以上
特定の用途において使い勝手の良い保存料及び/又は処理補助剤を含んでいてもよい。レバウディオサイド-モグロサイドV混合物を含む組成物は、甘味、用量、活性及び操作性が制御された製品を供給するために、マルトデキストリン及びその類似化合物のような、増量剤とともに製造されてもよい。
ダルコサイドA(dulcoside A),ダルコサイドB(dulcoside B)(ともにレバウディオサイドCとしても知られる)、ルブソサイド(rubusoside)、モグロサイドIII(mogroside III)、モグロサイドIV(mogroside IV),モグロサイドVI(mogroside VI)、シアメノサイド(siamenoside)、モナチン(monatin)及びその塩(monatinSS,RR、RS、SR)、クルクリン(curculin)、グリチルリチン酸(glycyrrhizic acid)及びその塩、ソーマチン(thaumatin)、モネリン(monellin)、マビンリン(mabinlin)、ブラゼイン(brazzein)、ハーナンダルシン(hernandulcin)、フィロダルシン(phyllodulcin)、グリシフィリン(glycyphyllin)及びフロリジン(phloridzin);
及び人工の高活性甘味料を含み、例えば:
サッカリン、アスパルテーム、スクラロース、ネオテーム、シクラメート及びアセスルフェームカルシウム、
が挙げられる。
嗜好試験
移動相:アセトニトリル/水 体積% 線形分割勾配
時間[分] アセトニトリル 水
0 20 80
15 30 70
20 50 50
25 50 50
30 20 80
Combi PAL Autosampler
モード: Headspace
シリンジ容積: 1 mL
シリンジ温度: 85°C
振動温度(Agitator Temperature): 80°C
プレインキュベーション時間(Pre-incubation Time): 30 分
プレインキュベーション振動速度
(Pre-incubation Agitator Speed): 500 rpm (5 秒 on, 2 秒 off)
吸引パイプ充填速度(Plunger Fill Speed): 200 ・L/秒
粘性遅延(Viscosity Delay): 12 秒
注入前遅延(Pre-injection Delay): 0 sec
吸引パイプ注入速度(Plunger Inject Speed): 100 ・L/秒
注入後遅延(Post-injection Delay): 10 秒
シリンジ充填時間(Syringe Flush Time): 3 min
GC 回転時間(GC Cycle Time): 54 min
Varian 3800 GC
オーブン:
初期温度: 40°C
初期保持時間: 5 分
Ramp: 7.5°C/min
最終温度: 235°C
最終保持時間: 14 分
前部流入(1177):
温度: 250°C
モード: Splitless
カラム:
型: Rtx-624 (30 m x 0.25 mm x 1.4 ・m) - Restek Cat # 10968
モード: Constant Flow
流速: 1.0 mL/分(Helium)
中間バルブオーブン:
温度: 250°C
Varian 4000 FID
温度: 250°C
補給ガス: 2 mL/分 (He)
H2流速: 40 mL/分
空気流速: 450 mL/分
Varian 4000 Ion Trap MS
スキャン型: Full
質量範囲: 25〜275 m/z
スキャン時間: 0.00 〜45.00 時間
イオン化の型: EI
標的TIC: 20000 カウント
最大イオン時間: 25000 ・秒
排出流量: 10 ・amps
平均スキャン: 3 ・scans (0.60 秒/scan)
データ転送速度: 1.67 Hz
乗数補正: 0 V
移動相:アセトニトリル/水 体積 % 直線的勾配(linear gradient)
時間[分] アセトニトリル 水
0 10 90
10 10 90
20 20 80
25 20 80
30 30 70
35 30 70
55 95 5
65 95 5
75 10 90
Claims (27)
- モグロサイドV(Mogroside V)及びレバウディオサイド成分(Rebaudioside component)を、重量比1:1以上6:1以下の範囲で含む組成物であって、
ここで、レバウディオサイド成分は、レバウディオサイドA、レバウディオサイドB及びレバウディオサイドDから成る群より選ばれる化合物である、組成物。 - 該重量比が1.5:1以上である、請求項1の組成物。
- レバウディオサイド成分が、甘味を有するステビオール配糖体を含むステビア抽出物の形態で供給され、該レバウディオサイド成分が、甘味を有するステビオール配糖体の少なくとも70重量%を占める、請求項1〜2の何れか1項の組成物。
- モグロサイドVがラカンカ抽出物の形態で供給され、該モグロサイドVが、ラカンカ抽出物の少なくとも40重量%を占める、請求項1〜3の何れか1項の組成物。
- ラカンカ抽出物が活性炭で処理されたものである、請求項4の組成物。
- モグロサイドVがラカンカ抽出物成分として供給され、該モグロサイドVが該ラカンカ抽出物成分の40重量%〜60重量%を占める、請求項1〜5の何れか1項の組成物。
- 組成物が、芳香族系配糖体を、モグロサイドVに対し総量で0〜13重量%含む、請求項1〜6の何れか1項の組成物。
- 組成物が、分子量502ダルトンの化合物を、モグロサイドVに対し総量で0〜13重量%含む、請求項1〜7の何れか1項の組成物。
- 組成物が、分子式C26H30O10の化合物を、モグロサイドVに対し総量で0〜13重量%である、請求項1〜8の何れか1項の組成物。
- 組成物が、半揮発性有機化合物を、モグロサイドVに対し総量で0〜15ppm含む、請求項1〜9の何れか1項の組成物。
- さらにカロリー甘味料を含む、請求項1〜10の組成物。
- さらに追加の高甘味度甘味料(high potency sweetner)を含む、請求項1〜11の組成物。
- 請求項1〜12の何れか1項の組成物を含む、飲料。
- 請求項1〜12の何れか1項の組成物を含む、食品。
- 請求項1〜12の何れか1つの組成物を含む、口腔ケア製品。
- 請求項1〜12の何れか1つの組成物を含む、たばこ製品。
- 請求項1〜12の何れか1つの組成物を含む、医薬品。
- 請求項1〜12の何れか1つの組成物を含む、栄養補助食品。
- ラカンカ抽出物を含む組成物であって、モグロサイドVがラカンカ抽出物の50重量%〜75重量%を占めるとともに、組成物が更に、芳香族系配糖体を、モグロサイドVに対し総量で0〜13重量%含み、半揮発性有機化合物を、モグロサイドVに対し総量で0〜15ppm含む、組成物。
- ラカンカ抽出物を含む組成物であって、モグロサイドVがラカンカ抽出物の50重量%〜75重量%を占めるとともに、組成物が更に、分子量502ダルトンの化合物を、モグロサイドVに対し総量で0〜13重量%含み、半揮発性有機化合物を、モグロサイドVに対し総量で0〜15ppm含む、組成物。
- ラカンカ抽出物を含む組成物であって、モグロサイドVがラカンカ抽出物の50重量%〜75重量%を占めるとともに、組成物が更に、分子式がC26H30O10の化合物を、モグロサイドVに対し総量で0〜13重量%含み、半揮発性有機化合物を、モグロサイドVに対し総量で0〜15ppm含む、組成物。
- ラカンカ抽出物の精製方法であって、ラカンカ抽出物を活性炭に接触させる工程を含み、当該接触させるラカンカ抽出物はマクロ多孔性高分子吸着樹脂、イオン交換樹脂又はその両方と予め接触させたものである、方法。
- ラカンカ抽出物が、予め該マクロ多孔性高分子吸着樹脂と接触させたものである、請求項22の方法。
- ラカンカ抽出物の精製方法であって、ラカンカ抽出物をマクロ多孔性高分子吸着樹脂、イオン交換樹脂及び活性炭と接触させる工程を含む、方法。
- 前記のラカンカ抽出物とマクロ多孔性高分子吸着樹脂、イオン交換樹脂及び活性炭との接触が、記載された順に行われる、請求項24の方法。
- 請求項22〜25の何れか一項の方法により製造される、精製ラカンカ抽出物。
- モグロサイドV(Mogroside V)及びレバウディオサイド成分(Rebaudioside component)を、重量比1:1以上6:1以下の範囲で含む組成物であって、
ここで、レバウディオサイド成分は、レバウディオサイドA、レバウディオサイドB及びレバウディオサイドDから成る群より選ばれる化合物であり;
当該モグロサイドVはラカンカ抽出物の形態で供給され、該モグロサイドVはラカンカ抽出物の少なくとも少なくとも40重量%を占め;
該ラカンカ抽出物は請求項26の精製ラカンカ抽出物である、組成物。
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JPS5871868A (ja) * | 1981-10-22 | 1983-04-28 | Maruzen Kasei Kk | 羅漢果の甘味物質を精製する方法 |
JP2010502213A (ja) * | 2006-09-07 | 2010-01-28 | バイオヴィットリア リミテッド | 甘味組成物およびそれらの調製方法 |
WO2009063921A1 (ja) * | 2007-11-12 | 2009-05-22 | San-Ei Gen F.F.I., Inc. | ステビア抽出物の甘味質改善 |
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JPWO2016088700A1 (ja) * | 2014-12-02 | 2017-10-19 | 横浜油脂工業株式会社 | 羅漢果甘味成分含有組成物の製造方法 |
JP2016158514A (ja) * | 2015-02-27 | 2016-09-05 | 横浜油脂工業株式会社 | 羅漢果甘味成分含有組成物、及びその製造方法 |
JPWO2016194809A1 (ja) * | 2015-05-29 | 2018-03-01 | サラヤ株式会社 | 農薬を含まない羅漢果抽出物およびその調製方法 |
JP2019165728A (ja) * | 2015-05-29 | 2019-10-03 | サラヤ株式会社 | 農薬を含まない羅漢果抽出物およびその調製方法 |
JP2017205100A (ja) * | 2016-05-11 | 2017-11-24 | 三栄源エフ・エフ・アイ株式会社 | 甘味料組成物及びステビア抽出物の味質改善方法 |
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