JP2013538936A5 - - Google Patents
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- Publication number
- JP2013538936A5 JP2013538936A5 JP2013518940A JP2013518940A JP2013538936A5 JP 2013538936 A5 JP2013538936 A5 JP 2013538936A5 JP 2013518940 A JP2013518940 A JP 2013518940A JP 2013518940 A JP2013518940 A JP 2013518940A JP 2013538936 A5 JP2013538936 A5 JP 2013538936A5
- Authority
- JP
- Japan
- Prior art keywords
- manganese
- manganese dioxide
- electrolytic
- stage
- washing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- NUJOXMJBOLGQSY-UHFFFAOYSA-N Manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 122
- 238000002386 leaching Methods 0.000 claims description 48
- PWHULOQIROXLJO-UHFFFAOYSA-N manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 45
- 229910052748 manganese Inorganic materials 0.000 claims description 45
- 239000011572 manganese Substances 0.000 claims description 45
- 238000005406 washing Methods 0.000 claims description 44
- 229940099596 manganese sulfate Drugs 0.000 claims description 36
- 235000007079 manganese sulphate Nutrition 0.000 claims description 36
- 239000011702 manganese sulphate Substances 0.000 claims description 36
- ISPYRSDWRDQNSW-UHFFFAOYSA-L manganese(II) sulfate monohydrate Chemical compound O.[Mn+2].[O-]S([O-])(=O)=O ISPYRSDWRDQNSW-UHFFFAOYSA-L 0.000 claims description 36
- 238000004519 manufacturing process Methods 0.000 claims description 28
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 27
- 238000005868 electrolysis reaction Methods 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 23
- 229910000468 manganese oxide Inorganic materials 0.000 claims description 22
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese(II,III) oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 17
- 239000000843 powder Substances 0.000 claims description 17
- 238000000746 purification Methods 0.000 claims description 17
- 239000007788 liquid Substances 0.000 claims description 16
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 13
- 239000011575 calcium Substances 0.000 claims description 13
- 229910052791 calcium Inorganic materials 0.000 claims description 13
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 13
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 13
- 239000011777 magnesium Substances 0.000 claims description 13
- 229910052749 magnesium Inorganic materials 0.000 claims description 13
- 239000000047 product Substances 0.000 claims description 13
- 239000012535 impurity Substances 0.000 claims description 12
- 239000002245 particle Substances 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 11
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 claims description 11
- 229910052683 pyrite Inorganic materials 0.000 claims description 11
- 239000011028 pyrite Substances 0.000 claims description 11
- BQCADISMDOOEFD-UHFFFAOYSA-N silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 10
- 229910052709 silver Inorganic materials 0.000 claims description 10
- 239000004332 silver Substances 0.000 claims description 10
- 239000003518 caustics Substances 0.000 claims description 9
- 238000006386 neutralization reaction Methods 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 230000005591 charge neutralization Effects 0.000 claims description 6
- 239000008187 granular material Substances 0.000 claims description 6
- 230000001264 neutralization Effects 0.000 claims description 6
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 5
- 235000015450 Tilia cordata Nutrition 0.000 claims description 5
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 5
- 239000003995 emulsifying agent Substances 0.000 claims description 5
- 239000004571 lime Substances 0.000 claims description 5
- 239000002244 precipitate Substances 0.000 claims description 5
- 239000002699 waste material Substances 0.000 claims description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 3
- 229910052753 mercury Inorganic materials 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000007670 refining Methods 0.000 claims description 3
- AGVJBLHVMNHENQ-UHFFFAOYSA-N Calcium sulfide Chemical compound [S-2].[Ca+2] AGVJBLHVMNHENQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 239000003513 alkali Substances 0.000 claims description 2
- 229940055700 calcium sulfide Drugs 0.000 claims description 2
- 230000005484 gravity Effects 0.000 claims description 2
- 229910001414 potassium ion Inorganic materials 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- 238000007664 blowing Methods 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 238000000265 homogenisation Methods 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- 238000001914 filtration Methods 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 7
- 239000000706 filtrate Substances 0.000 description 6
- 239000002994 raw material Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 5
- 239000010949 copper Substances 0.000 description 4
- 239000004088 foaming agent Substances 0.000 description 4
- 239000011133 lead Substances 0.000 description 4
- XMWCXZJXESXBBY-UHFFFAOYSA-L Manganese(II) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 3
- QSLZFPQJJGGNFN-UHFFFAOYSA-N calcium;sulfane Chemical compound S.[Ca+2] QSLZFPQJJGGNFN-UHFFFAOYSA-N 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 229910052803 cobalt Inorganic materials 0.000 description 3
- 239000010941 cobalt Substances 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 235000006748 manganese carbonate Nutrition 0.000 description 3
- 239000011656 manganese carbonate Substances 0.000 description 3
- 229940093474 manganese carbonate Drugs 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- 230000003247 decreasing Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- VASIZKWUTCETSD-UHFFFAOYSA-N manganese(II) oxide Inorganic materials [Mn]=O VASIZKWUTCETSD-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000003638 reducing agent Substances 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010227988.7 | 2010-07-15 | ||
| CN2010102279887A CN101892384B (zh) | 2010-07-15 | 2010-07-15 | 无汞碱锰型电解二氧化锰的生产方法 |
| PCT/CN2011/077011 WO2012006935A1 (zh) | 2010-07-15 | 2011-07-09 | 无汞碱锰型电解二氧化锰的生产方法 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2013538936A JP2013538936A (ja) | 2013-10-17 |
| JP2013538936A5 true JP2013538936A5 (fi) | 2015-06-18 |
| JP5764207B2 JP5764207B2 (ja) | 2015-08-12 |
Family
ID=43101728
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013518940A Active JP5764207B2 (ja) | 2010-07-15 | 2011-07-09 | 無水銀アルカリマンガン電池用電解二酸化マンガンの製造法 |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US20130037416A1 (fi) |
| JP (1) | JP5764207B2 (fi) |
| CN (1) | CN101892384B (fi) |
| WO (1) | WO2012006935A1 (fi) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7666593B2 (en) | 2005-08-26 | 2010-02-23 | Helicos Biosciences Corporation | Single molecule sequencing of captured nucleic acids |
| CN101892384B (zh) * | 2010-07-15 | 2011-09-21 | 广西有色金属集团汇元锰业有限公司 | 无汞碱锰型电解二氧化锰的生产方法 |
| CN102560526B (zh) * | 2011-12-23 | 2015-03-25 | 苏州大学 | 一种高功率电解二氧化锰的制备方法 |
| CN103074490B (zh) * | 2013-01-09 | 2014-03-12 | 广西有色金属集团汇元锰业有限公司 | 一种多矿法生产电解金属锰过程中的净化方法 |
| CN103205772B (zh) * | 2013-04-15 | 2015-07-08 | 广西有色金属集团汇元锰业有限公司 | 电解二氧化锰的生产方法 |
| CN103560240B (zh) * | 2013-11-07 | 2015-11-25 | 广西桂柳化工有限责任公司 | 无汞碱性电池专用电解二氧化锰制备方法 |
| CN103643252B (zh) * | 2013-12-05 | 2016-05-18 | 中信大锰矿业有限责任公司大新锰矿分公司 | 一种二氧化锰电解悬浮剂 |
| CN103710541B (zh) * | 2013-12-24 | 2015-12-30 | 柳州豪祥特科技有限公司 | 湿法生产电解二氧化锰的方法 |
| KR101528507B1 (ko) | 2015-01-13 | 2015-06-12 | 한국지질자원연구원 | 리튬계 전지로부터 코발트 및 망간의 동시 회수 방법 |
| CN104928709B (zh) * | 2015-06-24 | 2017-04-12 | 广西有色金属集团汇元锰业有限公司 | 二氧化锰的电解系统及其生产方法 |
| CN106480471B (zh) * | 2016-11-04 | 2018-05-22 | 柳州高新区欧亚自动化设备有限责任公司 | EMD连续浸出工艺化合槽pH值控制装置及其控制方法 |
| CN110143615A (zh) * | 2019-06-19 | 2019-08-20 | 贵州红星发展大龙锰业有限责任公司 | 电解二氧化锰及电解二氧化锰深度除钾的方法 |
| CN110127766A (zh) * | 2019-07-02 | 2019-08-16 | 贵州中伟资源循环产业发展有限公司 | 一种电池级硫酸锰溶液的制备工艺 |
| CN110747329B (zh) * | 2019-11-26 | 2022-02-22 | 广西汇元锰业有限责任公司 | 基于蔗渣造纸白泥的电解二氧化锰生产方法 |
| CN111620355A (zh) * | 2020-06-03 | 2020-09-04 | 四川兴晟锂业有限责任公司 | 一种去除氢氧化钾溶液中钾离子的方法 |
| CN112708753B (zh) * | 2020-12-29 | 2023-05-12 | 武钢资源集团大冶铁矿有限公司 | 一种铁精矿深度脱硫处理方法及系统 |
| CN113215387A (zh) * | 2021-02-25 | 2021-08-06 | 宁夏天元锰材料研究院(有限公司) | 一种碳酸锰低温分解活化的方法及系统 |
| CN114481165B (zh) * | 2021-12-31 | 2023-11-28 | 广西大新汇元新能源科技有限责任公司 | 基于半氧化锰矿生产电解二氧化锰的方法 |
| CN114477521B (zh) * | 2021-12-31 | 2024-05-28 | 广西大新汇元新能源科技有限责任公司 | 一种电解二氧化锰废水处理及锰的回收利用方法 |
| CN114715945A (zh) * | 2022-05-31 | 2022-07-08 | 广西下田锰矿有限责任公司 | 一种高效率纯化硫酸锰溶液的方法 |
| CN115074753A (zh) * | 2022-07-14 | 2022-09-20 | 广西桂柳新材料股份有限公司 | 碱锰电池用电解二氧化锰后处理除杂方法 |
| CN115094441A (zh) * | 2022-07-14 | 2022-09-23 | 广西桂柳新材料股份有限公司 | 锂电池用电解二氧化锰的生产方法 |
| CN115724470B (zh) * | 2022-09-26 | 2024-05-07 | 广西科技师范学院 | 一种硫酸锰溶液的净化方法 |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1874827A (en) * | 1931-05-12 | 1932-08-30 | Burgess Battery Co | Production of manganese dioxide |
| US2424958A (en) * | 1943-08-31 | 1947-08-05 | Dorr Co | Process of electrodepositing a manganese dioxide compound |
| US3348912A (en) * | 1963-09-23 | 1967-10-24 | Utah Construction & Mining Co | Method of preparing manganese sulfate from pyrite reduced manganese dioxide ores |
| JPS5121959B1 (fi) * | 1969-06-16 | 1976-07-06 | ||
| JPS49197A (fi) * | 1972-04-21 | 1974-01-05 | ||
| JPS5216880B2 (fi) * | 1973-09-20 | 1977-05-12 | ||
| DE2949791A1 (de) * | 1979-12-11 | 1981-06-19 | Krupp Polysius Ag, 4720 Beckum | Vorrats- und mischsilo fuer schuettgut |
| JPS5988324A (ja) * | 1982-11-12 | 1984-05-22 | Japan Metals & Chem Co Ltd | 電解二酸化マンガン用硫酸マンガン溶液の精製法 |
| JPS60103192A (ja) * | 1983-11-09 | 1985-06-07 | Japan Metals & Chem Co Ltd | 電解槽内蓄積物の処理法 |
| JPS60236458A (ja) * | 1984-05-10 | 1985-11-25 | Toshiba Battery Co Ltd | 水銀無添加電池 |
| US4549943A (en) * | 1984-11-01 | 1985-10-29 | Union Carbide Corporation | Suspension bath and process for production of electrolytic manganese dioxide |
| JPS6244586A (ja) * | 1985-08-20 | 1987-02-26 | Toshiba Battery Co Ltd | 電池用電解二酸化マンガンの製造方法 |
| CN87102046A (zh) * | 1987-06-23 | 1987-12-09 | 桂阳县电解锰厂 | 用二氧化锰矿制取硫酸锰溶液的方法 |
| CN1027294C (zh) * | 1991-06-04 | 1995-01-04 | 上海钢铁研究所 | 电解二氧化锰用的钛合金阳极 |
| JP3493835B2 (ja) * | 1995-10-16 | 2004-02-03 | 松下電器産業株式会社 | 二酸化マンガンの製造法及びそれを用いたアルカリ乾電池 |
| US6589693B1 (en) * | 1999-08-05 | 2003-07-08 | Eveready Battery Company, Inc. | High discharge electrolytic manganese dioxide and an electrode and alkaline cell incorporating the same |
| JP4730488B2 (ja) * | 2000-04-04 | 2011-07-20 | 東ソー株式会社 | マンガン鉱石処理物の製造方法 |
| US6630065B2 (en) * | 2000-09-01 | 2003-10-07 | Tosoh Corporation | Powder of electrolytic manganese dioxide and process for producing the same |
| JP3553541B2 (ja) * | 2001-11-26 | 2004-08-11 | 三井金属鉱業株式会社 | 電池用正極活物質及び電解二酸化マンガンの製造方法並びに電池 |
| US6896817B2 (en) * | 2002-04-15 | 2005-05-24 | Gregory S. Bowers | Essentially insoluble heavy metal sulfide slurry for wastewater treatment |
| CN1861815A (zh) * | 2005-05-14 | 2006-11-15 | 广西汇元锰业有限公司 | 连续浸出氧化锰矿的方法 |
| CN1907866A (zh) * | 2005-08-01 | 2007-02-07 | 李忠红 | 锰矿石直接制备四氧化三锰的方法 |
| CN101456594A (zh) * | 2007-12-14 | 2009-06-17 | 杜祖德 | 利用低品位锰矿渣制取硫酸锰的方法 |
| WO2009120384A2 (en) * | 2008-03-28 | 2009-10-01 | Siemens Water Technologies Corp. | Hybrid aerobic and anaerobic wastewater and sludge treatment systems and methods |
| CN101684562A (zh) * | 2008-09-28 | 2010-03-31 | 熊一言 | 氧化锰矿的制液工艺 |
| CN101550556A (zh) * | 2009-04-01 | 2009-10-07 | 广西靖西县一洲锰业有限公司 | 碱性锌锰电池用电解二氧化锰的制备方法 |
| CN101892384B (zh) * | 2010-07-15 | 2011-09-21 | 广西有色金属集团汇元锰业有限公司 | 无汞碱锰型电解二氧化锰的生产方法 |
-
2010
- 2010-07-15 CN CN2010102279887A patent/CN101892384B/zh active Active
-
2011
- 2011-07-09 US US13/521,952 patent/US20130037416A1/en not_active Abandoned
- 2011-07-09 JP JP2013518940A patent/JP5764207B2/ja active Active
- 2011-07-09 WO PCT/CN2011/077011 patent/WO2012006935A1/zh active Application Filing
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