JP2013177639A - ガラスフレークに基づく多層顔料 - Google Patents
ガラスフレークに基づく多層顔料 Download PDFInfo
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- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/10—Interference pigments characterized by the core material
- C09C2200/102—Interference pigments characterized by the core material the core consisting of glass or silicate material like mica or clays, e.g. kaolin
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- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
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- C09C2200/301—Thickness of the core
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- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
- C09C2200/30—Interference pigments characterised by the thickness of the core or layers thereon or by the total thickness of the final pigment particle
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- C09C2200/00—Compositional and structural details of pigments exhibiting interference colours
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- C09C2220/00—Methods of preparing the interference pigments
- C09C2220/10—Wet methods, e.g. co-precipitation
- C09C2220/106—Wet methods, e.g. co-precipitation comprising only a drying or calcination step of the finally coated pigment
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
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- Y10T428/2996—Glass particles or spheres
Abstract
【解決手段】本発明に係るガラスフレークを基礎とする多層顔料は、厚み1μm未満のガラスフレークが(S1)SnO2層で被覆されており、該層(S1)が、(A)屈折率n>1.8である被覆、(B)屈折率n≦1.8である被覆、および、(C)屈折率n>1.8である被覆、の層配列の少なくとも1つで被覆されており、但し、層束(A)+(B)が層配列(A)+(B)+(C)に4回まで存在してもよく、層が金属酸化物、金属サブオキサイド、金属フッ化物、金属オキシハライド、金属カルコゲナイド、金属硫化物、金属窒化物、金属酸化窒化物、金属カーバイド、あるいはこれらの混合物からなる。
【選択図】なし
Description
(A)屈折率n>1.8である被覆、
(B)屈折率n≦1.8である被覆、および、
(C)屈折率n>1.8である被覆、
および、もし必要ならば、
(D)保護外層。
(D)保護外層。
(S1) 希望により、SnO2
(A) TiO2またはFe2O3
(B) SiO2
(B1) 希望により、SnO2
(C) TiO2
(D) 用途に関係した最終被覆
・・・優れた輝き
・・・澄んだ強い色合い
・・・際立った色変化
・・・光学遮蔽性能における比較的に高い動作
・・・かなり良い透明性(混合処方において重要である)
自動車用途に、径が3μmより大で40μm未満、より好ましくは10〜35μm、および厚みが0.2μmより大で1μm未満、好ましくは0.4〜0.8μm;
印刷用途に、径が3μmより大で20μm未満、好ましくは5〜20μm、および平均厚みが0.2μmより大で0.5μm未満。
例1
最大径40μm(平均22μm)かつ平均厚み0.5μmのガラスフレーク(屈折率1.5)100gが脱イオン水2リットルに分散される。激しい撹拌下にスラリーは75℃へ加熱され、ガラスフレークに対しSnO2で3%の量となるSnCl4水溶液を0.5時間かけて供給して被覆が開始される。pH2.0になるとすぐに32%NaOH溶液が、pHをこの値が保たれるように同時に供給される。
これは例1と同様に行なわれた。ガラスフレークの代わりに同じ粒子サイズ分布の雲母が用いられる。
最大径40μm(平均22μm)かつ平均厚み0.5μmのガラスフレーク(屈折率1.5)100gが脱イオン水2リットルに分散される。分散物は75℃へ加熱され、pHが希塩酸で1.8に調整され、まず、最初にSnCl4溶液(脱イオン水100mlにSnCl4 2.2gと濃塩酸7.5mlから)を3.3ml/分で加えることによりSnO2で被覆される。pHは32%水酸化ナトリウム溶液を用いて一定に保たれる。
第一層:約170nm
第二層:約85nm
層合計:約260nm
SiO2の中間層の厚みは約5nmである。
最大径40μm(平均22μm)かつ平均厚み0.5μmのガラスフレーク(屈折率1.5)100gが脱イオン水2リットルに分散される。分散物は75℃へ加熱され、pHが希塩酸で1.8に調整され、まず、最初にSnCl4溶液(脱イオン水100mlにSnCl4 2.2gと濃塩酸7.5mlから)を3.3ml/分で加えることによりSnO2で被覆される。pHは32%水酸化ナトリウム溶液を用いて一定に保たれる。
最大径40μm(平均22μm)かつ平均厚み0.5μmのガラスフレーク(屈折率1.5)100gが脱イオン水2リットルに分散される。分散物は75℃へ加熱され、pHが希塩酸で1.8に調整され、まず最初にSnCl4溶液(脱イオン水100mlにSnCl42.2gと濃塩酸7.5mlから)を3.3ml/分で加えることによりSnO2で被覆される。pHは32%水酸化ナトリウム溶液を用いて一定に保たれる。
使用例1:ちらちら光るおしろい
相Cの全成分を75℃ですべてのものが溶解するまで撹拌しながら加熱する。高い撹拌(Turrax)下に相Bの冷水にBlanoseおよびVeegumを別々に加える。75℃に加熱し、相Bの残りの成分を加え、混合物が滑らかで均一になるまで混合する。相Aの成分を加える。75℃で相Cを相A/Bに加え、2分間均質化する。相Dを40℃で加える。撹拌しながら室温まで冷却し、pHを6.0〜6.5に調整する(例えば、クエン酸溶液)。
(1)Merck KGaA/Rona(登録商標)
(2)Aqualon GmbH
(3)Vandebilt
(4)Cognis GmbH
(5)Croda GmbH
(6)Fragrance Resouces
(7)Schuelke & Mayr GmbH
相Aの水に顔料を分散する。Keltrol Tを撹拌しながら加え、完全に分散するまで混合する。相Bと相Cを順に相Aに撹拌しながら加え、ゲルが均一になるまでゆっくりと撹拌する。
(1)Merck KGaA/Rona(登録商標)
(2)Kelco
(3)Cognis GmbH
(4)Haarmann & Reimer GmbH
(5)BASF AG
凹版印刷用インキは下記からなる:
ポリエチレン(PE−HD)顆粒1kgが、タンブル混合機中で、粘着剤2gで均一に湿らかされる。次いで、例4に従う被覆ガラスフレーク10gとIriodin LS825(Merck KGaA社(Darmstadt Germany)製の粒子サイズ15μm未満の導電性顔料)2gが加えられ、2分間混合される。
[1]ガラスフレークが高屈折率層と低屈折率層で交互に被覆されていることおよびガラスフレークが少なくとも3層に被覆されていることを特徴とするガラスフレークを基礎とする多層顔料。
[2]顔料が下記被覆からなる層配列を少なくとも一つ有することを特徴とする[1]に記載の多層フレーク:
(A)屈折率n>1.8である被覆、
(B)屈折率n≦1.8である被覆、および、
(C)屈折率n>1.8である被覆、
および、もし必要ならば、
(D)保護外層。
但し、層束(A)+(B)が標準層集合(A)+(B)+(C)4回まで存在してもよい。
[3]ガラスフレークが厚み1μm未満であることを特徴とする[1]または[2]に記載の多層顔料。
[4]層が金属酸化物、金属サブオキサイド、金属フッ化物、金属オキシハライド、金属カルコゲナイド、金属硫化物、金属窒化物、金属酸化窒化物、金属カーバイド、あるいはこれらの混合物からなることを特徴とする[1]〜[3]のいずれかに記載の多層顔料。
[5]高屈折率層がTiO2、Fe2O3、TiFe2O5、Fe3O4、BiOCl、Cr2O3、ZrO2、ZnO、SnO2、CoO、Co3O4、VO2、V2O3、チタン酸鉄、酸化鉄水和物、チタンサブオキサイド、バナジン酸ビスマス、アルミン酸コバルト、金属硫化物、金属カルコゲナイド、金属窒化物、金属酸化窒化物、金属カーバイド、あるいはこれらの混合物からなることを特徴とする[1]〜[4]のいずれかに記載の多層顔料。
[6]低屈折率層がSiO2、Al2O3、AlO(OH)、B2O3、MgF2、あるいはこれらの混合物からなることを特徴とする[1]〜[5]のいずれかに記載の多層顔料。
[7]下記層構造を有することを特徴とする[2]に記載の多層顔料:
(D)保護外層。
[8]ガラスフレークが3層被覆されていることを特徴とする[1]〜[7]のいずれかに記載の多層顔料。
[9]湿式化学被覆法によるか化学的または物理的気相堆積法によってガラスフレークを被覆すること、および被覆されたガラスフレークを焼成することを含む多層顔料を製造する方法。
[10]プラスチック、塗装材、粉末塗装材、ペンキ、インキ、印刷インキ、ガラス、陶磁器、農業用フォイルにおいて、化粧処方において、紙およびプラスチックのレーザーマーキングのために、[1]に記載の多層顔料を使用すること。
[11][1]に記載の多層顔料を含む処方。
[12][1]に記載の多層顔料を含む非粉塵粉末、ペーストおよび顆粒。
Claims (14)
- 厚み1μm未満のガラスフレークが(S1)SnO2層で被覆されており、該層(S1)が、
(A)屈折率n>1.8である被覆、
(B)屈折率n≦1.8である被覆、および、
(C)屈折率n>1.8である被覆、
の層配列の少なくとも1つで被覆されており、
但し、層束(A)+(B)が層配列(A)+(B)+(C)に4回まで存在してもよく、
層が金属酸化物、金属サブオキサイド、金属フッ化物、金属オキシハライド、金属カルコゲナイド、金属硫化物、金属窒化物、金属酸化窒化物、金属カーバイド、あるいはこれらの混合物からなることを特徴とするガラスフレークを基礎とする多層顔料。 - 屈折率n>1.8の層がTiO2、Fe2O3、TiFe2O5、Fe3O4、BiOCl、Cr2O3、ZrO2、ZnO、SnO2、CoO、Co3O4、VO2、V2O3、チタン酸鉄、酸化鉄水和物、チタンサブオキサイド、バナジン酸ビスマス、アルミン酸コバルト、金属硫化物、金属カルコゲナイド、金属窒化物、金属酸化窒化物、金属カーバイド、あるいはこれらの混合物からなることを特徴とする請求項1に記載の多層顔料。
- 屈折率n≦1.8の層がSiO2、Al2O3、AlO(OH)、B2O3、MgF2、あるいはこれらの混合物からなることを特徴とする請求項1または2に記載の多層顔料。
- 前記層(A)が、TiO2であることを特徴とする請求項1に記載の多層顔料。
- 前記層(B)が、SiO2またはMgF2であることを特徴とする請求項5に記載の多層顔料。
- 前記層(C)が、TiO2、Fe2O3、またはTiO2/Fe2O3あることを特徴とする請求項5または6に記載の多層顔料。
- 前記層配列が、さらに、(D)保護外層を有することを特徴とする、請求項1〜7のいずれか1項に記載の多層顔料。
- ガラスフレークが3層被覆されていることを特徴とする請求項1〜8のいずれか1項に記載の多層顔料。
- 湿式化学被覆法によるか化学的または物理的気相堆積法によってガラスフレークを被覆すること、および被覆されたガラスフレークを焼成することを含む方法により製造されたものである請求項1〜9のいずれか1項に記載の多層顔料。
- 請求項1〜9のいずれか1項に記載の多層顔料を製造する方法であって、湿式化学被覆法によるか化学的または物理的気相堆積法によってガラスフレークを被覆すること、および被覆されたガラスフレークを焼成することを含む多層顔料を製造する方法。
- 請求項1〜9のいずれか1項に記載の多層顔料の、プラスチック、塗装材、粉末塗装材、ペンキ、インキ、印刷インキ、ガラス、陶磁器、農業用フォイルでの、または、化粧処方での使用、あるいは、紙およびプラスチックのレーザーマーキングのための使用。
- 請求項1〜9のいずれか1項に記載の多層顔料を含む処方。
- 請求項1〜9のいずれか1項に記載の多層顔料を含む非粉塵粉末、ペーストおよび顆粒。
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101876199B1 (ko) * | 2017-04-21 | 2018-08-03 | 씨큐브 주식회사 | 복합 백색 안료 및 그 제조 방법 |
Families Citing this family (104)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19618569A1 (de) * | 1996-05-09 | 1997-11-13 | Merck Patent Gmbh | Mehrschichtige Interferenzpigmente |
US7238424B2 (en) | 2002-05-31 | 2007-07-03 | Jds Uniphase Corporation | All-dielectric optically variable pigments |
US20060225609A1 (en) * | 2002-12-17 | 2006-10-12 | Reinhold Rueger | Silvery white interference pigments having a high luster and based on transparent substrate laminae |
WO2004061012A2 (en) | 2002-12-31 | 2004-07-22 | Engelhard Corporation | Improved effect pigment comprising a mixture of at least 2 substrate materials |
US7045007B2 (en) | 2002-12-31 | 2006-05-16 | Engelhard Corporation | Effect pigment |
US6875264B2 (en) | 2003-01-17 | 2005-04-05 | Engelhard Corporation | Multi-layer effect pigment |
US7993444B2 (en) | 2003-01-17 | 2011-08-09 | Basf Catalysts Llc | Multi-layer effect pigment |
EP1469042A3 (de) * | 2003-03-27 | 2010-07-07 | MERCK PATENT GmbH | Pigmentgemisch und dessen Verwendung in der Kosmetik und im Lebensmittel- und Pharmabereich |
JP2004323555A (ja) * | 2003-04-21 | 2004-11-18 | Nippon Paint Co Ltd | 金属コロイド光輝材およびその製造方法 |
BRPI0414602A (pt) * | 2003-09-22 | 2006-11-07 | Nippon Sheet Glass Co Ltd | pigmento preto brilhante e preparação cosmética, composição de revestimento, composição de resina e composição de tinta de escrever contendo o mesmo |
WO2005071019A1 (ja) * | 2004-01-22 | 2005-08-04 | Nippon Sheet Glass Company, Limited | 着色された光輝性顔料 |
EP1564261B1 (de) * | 2004-02-09 | 2016-05-25 | Merck Patent GmbH | Interferenzpigmente |
DE102004052544A1 (de) * | 2004-02-09 | 2005-08-25 | Merck Patent Gmbh | Interferenzpigmente |
US20060013838A1 (en) * | 2004-07-13 | 2006-01-19 | Qinyun Peng | Cosmetic powder compositions having large particle size color travel effect pigments |
CN1266229C (zh) * | 2004-08-10 | 2006-07-26 | 汕头市龙华珠光颜料有限公司 | 一种随角异色的多层变色颜料及其生产方法 |
DE102004039554A1 (de) * | 2004-08-13 | 2006-02-23 | Merck Patent Gmbh | Perlglanzpigmente |
DE602005026820D1 (de) | 2004-08-23 | 2011-04-21 | Basf Se | Verfahren zur herstellung von blättchenförmigen pi0) |
US20060051304A1 (en) | 2004-09-02 | 2006-03-09 | Qinyun Peng | Special effects with mixtures of interference pigments |
DE102004051104A1 (de) * | 2004-10-19 | 2006-04-27 | Merck Patent Gmbh | Opake Kunststoffe |
KR100843011B1 (ko) * | 2004-12-24 | 2008-07-01 | 니혼 이타가라스 가부시키가이샤 | 비늘조각형상 글래스 |
CN105295448A (zh) | 2005-02-12 | 2016-02-03 | 巴斯福催化剂公司 | 透明的视角闪色多层效果颜料 |
WO2006088761A2 (en) | 2005-02-12 | 2006-08-24 | Engelhard Corporation | Multilayer effect pigment |
US8088212B2 (en) * | 2005-04-01 | 2012-01-03 | Basf Corporation | Sparkle effect of unique particle size distribution |
JP2006316228A (ja) * | 2005-05-16 | 2006-11-24 | Nippon Sheet Glass Co Ltd | 樹脂組成物 |
JP2006328278A (ja) * | 2005-05-27 | 2006-12-07 | Nippon Sheet Glass Co Ltd | 油性インキ組成物 |
GB0512077D0 (en) * | 2005-06-14 | 2005-07-20 | Pilkington Plc | Glazing |
US20090311209A1 (en) * | 2005-06-22 | 2009-12-17 | Patrice Bujard | Interference Pigments on the Basis of Glass Flakes |
DE102005032346A1 (de) * | 2005-06-24 | 2007-01-04 | Eckart Gmbh & Co.Kg | Perlglanzpigmente mit vernetzbarer Bindemittelbeschichtung, Beschichtungszusammensetzung, Verfahren zur Herstellung der beschichteten Perlglanzpigmente und deren Verwendung |
CN101404975A (zh) * | 2006-03-20 | 2009-04-08 | 日本板硝子株式会社 | 配合有鳞片状玻璃的化妆料 |
DE102006014095A1 (de) * | 2006-03-24 | 2007-09-27 | Merck Patent Gmbh | Glasplättchen und deren Verwendung als transparenter Füllstoff |
CN101405333B (zh) * | 2006-03-24 | 2011-08-31 | 日本板硝子株式会社 | 薄片状玻璃填料及含有它的树脂组合物 |
KR20080109879A (ko) | 2006-04-21 | 2008-12-17 | 니혼 이타가라스 가부시키가이샤 | 광휘성 안료 및 그 제조 방법, 및 이 광휘성 안료를 포함하는 수성 수지 조성물 |
EP2042474B1 (en) * | 2006-06-23 | 2013-03-20 | Nippon Sheet Glass Company, Limited | Glass flake |
WO2008042802A2 (en) * | 2006-09-29 | 2008-04-10 | Sensient Pharmaceutical Technologies Inc. | Wet edible pearlescent film coatings |
US20110113984A1 (en) * | 2006-10-18 | 2011-05-19 | Basf Catalysts Llc | Transparent Goniochromatic Multilayer Effect Pigment |
EP2078057A2 (en) * | 2006-10-18 | 2009-07-15 | BASF Corporation | Multiple layered pigments exhibiting color travel |
EP2099312B1 (en) | 2006-12-14 | 2016-05-04 | Sensient Colors LLC | Pearlescent pigment compositions and methods for making and using the same |
EP2125623B1 (en) * | 2007-02-27 | 2015-10-14 | Basf Se | Method of forming a (rutile) titanium dioxide-coated platelet-like pigment |
DE102007010986A1 (de) * | 2007-03-05 | 2008-09-11 | Merck Patent Gmbh | Übergangsmetallhaltige Effektpigmente |
EP1980594B1 (en) * | 2007-04-05 | 2009-06-03 | Eckart GmbH | Effect pigments comprising a glass flake substrate |
CN101675120B (zh) | 2007-04-18 | 2012-12-05 | 日本板硝子株式会社 | 光辉性颜料以及使用了该颜料的化妆用组合物 |
EP2687563B1 (en) * | 2007-04-27 | 2018-04-04 | Nippon Sheet Glass Company, Limited | Photoluminescent pigment and photoluminescent coating composition |
US20100203093A1 (en) | 2007-07-12 | 2010-08-12 | Ciba Corporation | Interference pigments on the basis of perlite flakes |
US10690823B2 (en) | 2007-08-12 | 2020-06-23 | Toyota Motor Corporation | Omnidirectional structural color made from metal and dielectric layers |
EP2075375A1 (en) * | 2007-12-11 | 2009-07-01 | Polska Wytwornia Papierow Wartosciowych S.A. | Paper for personal document sheets and security document from this paper |
WO2009077122A2 (de) * | 2007-12-19 | 2009-06-25 | Merck Patent Gmbh | Optisch variable pigmente mit hoher elektrischer leitfähigkeit |
EP2220171B1 (de) * | 2007-12-19 | 2014-03-05 | Merck Patent GmbH | Farbstarke und/oder optisch variable pigmente mit elektrisch leitfähigem kern |
US20090185992A1 (en) * | 2008-01-18 | 2009-07-23 | Christelle Conan | Process for producing iron oxide coated pearlescent pigments |
EP2093260A1 (de) * | 2008-02-20 | 2009-08-26 | Eckart GmbH | Effektpigmente basierend auf künstlich hergestellten Substraten mit enger Grössenverteilung |
US20090291292A1 (en) * | 2008-05-22 | 2009-11-26 | 3M Innovative Properties Company | Optically active elements including multiple bead layers |
CN102076782B (zh) * | 2008-06-24 | 2014-03-26 | 巴斯夫欧洲公司 | 颜料混合物 |
KR101753916B1 (ko) * | 2008-12-11 | 2017-07-04 | 바스프 에스이 | 펄라이트 플레이크 기재의 간섭 안료 |
JP2010268857A (ja) * | 2009-05-19 | 2010-12-02 | Sri Sports Ltd | ゴルフボール |
DE102009031266A1 (de) * | 2009-06-30 | 2011-01-13 | Eckart Gmbh | Tintenstrahltinte enthaltend Perlglanzpigmente auf Basis von feinen und dünnen Substraten |
DE102009037935A1 (de) * | 2009-08-19 | 2011-02-24 | Eckart Gmbh | Hochglänzende Mehrschichtperlglanzpigmente mit silberner Interferenzfarbe und enger Größenverteilung und Verfahren zu deren Herstellung |
DE102009037933A1 (de) | 2009-08-19 | 2011-02-24 | Eckart Gmbh | Hochglänzende Mehrschichtperlglanzpigmente mit nichtsilberner Interferenzfarbe und enger Größenverteilung und Verfahren zu deren Herstellung |
DE102009037932A1 (de) | 2009-08-19 | 2011-02-24 | Eckart Gmbh | Hochglänzende Mehrschichtperlglanzpigmente mit enger Größenverteilung und Verfahren zu deren Herstellung |
DE102009037934A1 (de) | 2009-08-19 | 2011-02-24 | Eckart Gmbh | Hochglänzende Mehrschichtperlglanzpigmente mit farbiger Interferenzfarbe und enger Größenverteilung und Verfahren zu deren Herstellung |
KR101422968B1 (ko) | 2009-10-28 | 2014-07-30 | 바스프 에스이 | 개선된 스파클링 효과를 갖는 안료 |
KR101821431B1 (ko) | 2010-02-04 | 2018-01-23 | 바스프 에스이 | 개선된 스파클링 효과를 갖는 안료 조성물 |
US8784556B2 (en) * | 2010-02-24 | 2014-07-22 | Shantou Longhua Pearl Lustre Pigments Co., Ltd. | Angle-dependent interference pigments |
JP2012021089A (ja) * | 2010-07-15 | 2012-02-02 | Kansai Paint Co Ltd | 塗料組成物及び塗膜形成方法 |
CN103002993B (zh) | 2010-07-28 | 2015-06-03 | 巴斯夫欧洲公司 | 珍珠岩基效应颜料在具有古旧或绿锈外观的涂层中的用途 |
WO2012112541A2 (en) * | 2011-02-15 | 2012-08-23 | Basf Se | Pigment mixtures for cosmetics |
JP6012626B2 (ja) * | 2011-12-09 | 2016-10-25 | 日本板硝子株式会社 | 光輝性顔料、それを含有する化粧料、塗料組成物および樹脂組成物、並びに光輝性顔料の製造方法 |
EP2607432A1 (de) | 2011-12-21 | 2013-06-26 | Merck Patent GmbH | Effektpigmente basierend auf Substraten die einen Kreisformfaktor von 1,2-2 aufweisen |
CN102790217B (zh) * | 2012-07-26 | 2014-07-09 | 天津大学 | 碳包覆四氧化三铁锂离子电池负极材料及其制备方法 |
EP2881022B1 (en) * | 2012-08-01 | 2017-06-28 | Daikin Industries, Ltd. | Cooking utensil |
US10007039B2 (en) | 2012-09-26 | 2018-06-26 | 8797625 Canada Inc. | Multilayer optical interference filter |
CN103773083B (zh) * | 2012-10-18 | 2015-04-22 | 上海纳米技术及应用国家工程研究中心有限公司 | 一种光学干涉变色颜料及其制备方法和应用 |
EP2727966A1 (de) * | 2012-11-06 | 2014-05-07 | Eckart GmbH | Pigment mit photokatalytischer Aktivität, Verfahren zu dessen Herstellung und Beschichtungsmittel |
KR101978917B1 (ko) * | 2012-11-30 | 2019-05-15 | 주식회사 엘지생활건강 | 강한 간섭색을 갖는 진주 광택 안료 및 이를 함유하는 화장료 조성물 |
US9475942B2 (en) | 2012-12-07 | 2016-10-25 | Bunge Amorphic Solutions Llc | Aluminum phosphate composite materials and compositions |
US9168393B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
US9320687B2 (en) | 2013-03-13 | 2016-04-26 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
US9168394B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
US9168209B2 (en) | 2013-03-13 | 2015-10-27 | Johnson & Johnson Consumer Inc. | Pigmented skin-care compositions |
US8585818B1 (en) * | 2013-03-14 | 2013-11-19 | Basf Se | Coated perlite flakes |
CN103882781A (zh) * | 2014-02-19 | 2014-06-25 | 刘景阳 | 一种表面吸墨的金银卡纸及制作方法 |
CN106461834B (zh) | 2014-04-01 | 2021-01-15 | 丰田自动车工程及制造北美公司 | 无色移的多层结构 |
BR112016027743B1 (pt) * | 2014-05-28 | 2022-04-12 | Basf Se | Pigmento de efeito, e, método para produção de um pigmento de efeito |
DE102015112412A1 (de) * | 2014-08-15 | 2016-02-18 | Toyota Jidosha Kabushiki Kaisha | Die Farbe nicht verändernde Mehrschichtstrukturen und schützende Beschichtung hierauf |
EP2987834A1 (de) * | 2014-08-18 | 2016-02-24 | Kronos International, Inc. | Verfahren zur Oberflächenbeschichtung von anorganischen Partikeln mit Siliciumdioxid und mindestens einer weiteren anorganischen Verbindung |
JP6957350B2 (ja) | 2014-12-19 | 2021-11-02 | エッカルト ゲゼルシャフト ミット ベシュレンクテル ハフツングEckart GmbH | 高い彩度および高い輝度を有する赤色装飾的顔料、それを生産するための方法、ならびにその使用 |
SI3034563T1 (sl) | 2014-12-19 | 2019-06-28 | Eckart Gmbh | Zlato obarvani efektni pigmenti z visoko kromo in visokim sijajem, postopek za njihovo pripravo in njihova uporaba |
PL3034564T3 (pl) * | 2014-12-19 | 2018-07-31 | Eckart Gmbh | Pigmenty efektowe o wysokiej transparentności, wysokim nasyceniu i wysokiej czystości barwy, sposób ich wytwarzania i ich zastosowanie |
TR201816042T4 (tr) * | 2014-12-19 | 2018-11-21 | Eckart Gmbh | Yüksek renk koyuluğuna ve yüksek parlaklığa sahip absorbe edici etki pigmentleri, üretimlerine yönelik yöntem ve kullanımları. |
PL3034566T3 (pl) | 2014-12-19 | 2019-08-30 | Eckart Gmbh | Metaliczne pigmenty efektowe o wysokim nasyceniu barwy i wysokim połysku, sposób ich wytwarzania oraz ich zastosowanie |
WO2016187618A1 (en) * | 2015-05-21 | 2016-11-24 | Valspar Sourcing, Inc. | Antimicrobial agent for powder coating compositions |
CN105694574B (zh) * | 2016-03-16 | 2018-06-26 | 浙江凯色丽科技发展有限公司 | 片状反射隔热粉及其制备方法 |
CN106280575A (zh) * | 2016-07-21 | 2017-01-04 | 四川省川宏精细化工有限公司 | 一种油漆珠光颜料及其制备方法 |
CN106265108A (zh) * | 2016-08-11 | 2017-01-04 | 广西七色珠光材料股份有限公司 | 化妆品用金色球形颜料及其制备方法 |
KR102387100B1 (ko) | 2017-04-04 | 2022-04-15 | 바스프 컬러스앤이펙츠 게엠베하 | 무기 효과 안료 |
CN107881465B (zh) * | 2017-11-13 | 2020-04-21 | 苏州安洁科技股份有限公司 | 一种玻璃物理气相沉积颜色膜的方法 |
KR101858414B1 (ko) * | 2017-11-30 | 2018-05-16 | 씨큐브 주식회사 | 유기 또는 무기 형광체를 포함하는 보안용 진주광택 안료 |
CN108338931A (zh) * | 2018-01-23 | 2018-07-31 | 信利光电股份有限公司 | 一种光学美白活性颗粒及含有该颗粒的化妆品组合物 |
CN108690377A (zh) * | 2018-05-08 | 2018-10-23 | 江苏贝丽得新材料有限公司 | 一种具有千足金效果的珠光颜料及其制备方法 |
CN109054457B (zh) * | 2018-07-12 | 2020-08-28 | 福建坤彩材料科技股份有限公司 | 黑色珠光颜料及其制备方法和应用 |
CN108761613A (zh) * | 2018-08-01 | 2018-11-06 | 湖北五方光电股份有限公司 | 一种低红外透过率红外截止滤光片及其制备方法 |
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Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07246366A (ja) * | 1994-01-18 | 1995-09-26 | Mazda Motor Corp | 光干渉材及びそれを含有する塗料 |
WO1999020695A1 (de) * | 1997-10-17 | 1999-04-29 | Merck Patent Gmbh | Interferenzpigmente |
JP2000501774A (ja) * | 1996-09-21 | 2000-02-15 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 多層干渉顔料 |
JP2000239559A (ja) * | 1999-02-15 | 2000-09-05 | Merck Patent Gmbh | 強力な干渉顔料 |
JP2000345096A (ja) * | 1999-04-16 | 2000-12-12 | Merck Patent Gmbh | 顔料混合物 |
JP2000517374A (ja) * | 1996-05-09 | 2000-12-26 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 多層干渉性顔料 |
WO2001016235A1 (de) * | 1999-09-01 | 2001-03-08 | Merck Patent Gmbh | PIGMENTMISCHUNG ENTHALTEND BiOCl-PIGMENTE |
JP2003530457A (ja) * | 2000-04-11 | 2003-10-14 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 角度選択的透過または反射特性および/または吸収特性を有する透明媒体 |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3138475A (en) * | 1959-11-14 | 1964-06-23 | Jenaer Glaswerk Schott & Gen | Filler and meterial with an artificial pearly gloss and method of producing the same |
US3087828A (en) * | 1961-06-28 | 1963-04-30 | Du Pont | Nacreous pigment compositions |
US3331699A (en) * | 1963-10-24 | 1967-07-18 | Du Pont | Nacreous glass flake pigment compositions |
DE3617430A1 (de) * | 1986-05-23 | 1987-11-26 | Merck Patent Gmbh | Perlglanzpigmente |
CA1329867C (en) * | 1988-07-20 | 1994-05-31 | Hiroshi Ito | Pigment |
JP2985286B2 (ja) * | 1990-11-26 | 1999-11-29 | 日本板硝子株式会社 | 緻密保護被覆層を有するフレーク状ガラス及びその製造方法並びに該フレーク状ガラスを含有する塗料 |
JPH04292426A (ja) * | 1991-03-19 | 1992-10-16 | Nippon Sheet Glass Co Ltd | フレーク状ガラスの製造方法 |
DE4121352A1 (de) * | 1991-06-28 | 1993-01-07 | Merck Patent Gmbh | Oberflaechenmodifizierte plaettchenfoermige pigmente |
ES2098777T3 (es) * | 1992-03-26 | 1997-05-01 | Merck Patent Gmbh | Pigmentos de color de tipo plaquetas y proceso para su produccion. |
JP3097349B2 (ja) * | 1992-10-06 | 2000-10-10 | 日本板硝子株式会社 | 真珠光沢顔料の製造方法 |
JPH06116507A (ja) * | 1992-10-06 | 1994-04-26 | Nippon Sheet Glass Co Ltd | 真珠光沢顔料 |
JPH06116508A (ja) | 1992-10-06 | 1994-04-26 | Nippon Sheet Glass Co Ltd | チタニアまたはジルコニアで被覆されたフレーク状物体の製造方法 |
US5433779A (en) * | 1993-12-06 | 1995-07-18 | The Mearl Corporation | Rutile titanium dioxide coated micaceous pigments formed without tin |
US6045914A (en) * | 1996-06-03 | 2000-04-04 | Engelhard Corporation | Pearlescent glass pigment |
US5753371A (en) * | 1996-06-03 | 1998-05-19 | The Mearl Corporation | Pearlescent glass pigment |
US6132873A (en) * | 1996-09-21 | 2000-10-17 | Merck Patent Gesellschaft Mit Beschrankter Haftung | Multilayered interference pigments |
JPH10279828A (ja) | 1997-03-31 | 1998-10-20 | Merck Japan Kk | 高虹彩色効果を有するパール顔料、その製造方法及び用途 |
US6284032B2 (en) * | 1999-03-09 | 2001-09-04 | Merck Patent Gmbh | Multilayer interference pigments |
JP3702742B2 (ja) * | 1999-04-28 | 2005-10-05 | 日本板硝子株式会社 | 真珠光沢顔料およびその製造方法並びに真珠光沢顔料を配合した化粧料 |
US6524381B1 (en) * | 2000-03-31 | 2003-02-25 | Flex Products, Inc. | Methods for producing enhanced interference pigments |
DE19951871A1 (de) * | 1999-10-28 | 2001-05-03 | Merck Patent Gmbh | Farbstarke Interferenzpigmente |
DE10018904A1 (de) | 2000-04-14 | 2001-10-18 | Merck Patent Gmbh | Transparentes Medium mit winkelselektiven Transmissions- bzw. Reflexionseigenschaften und/oder Absorptionseigenschaften (II) |
TWI292773B (en) * | 2001-05-09 | 2008-01-21 | Merck Patent Gmbh | Effect pigments based on coated glass flakes |
US6777085B1 (en) * | 2002-04-19 | 2004-08-17 | Optical Coating Laboratory, Inc. | Article and method of preparing pigments using multiple deposition sources |
US6875264B2 (en) * | 2003-01-17 | 2005-04-05 | Engelhard Corporation | Multi-layer effect pigment |
-
2002
- 2002-07-01 CN CN2007101424720A patent/CN101104748B/zh not_active Expired - Fee Related
- 2002-07-01 RU RU2004102396/15A patent/RU2323238C2/ru not_active IP Right Cessation
- 2002-07-01 CN CNA028138473A patent/CN1622981A/zh active Pending
- 2002-07-01 EP EP02764606.6A patent/EP1474486B1/en not_active Expired - Lifetime
- 2002-07-01 US US10/483,182 patent/US7604862B2/en not_active Expired - Fee Related
- 2002-07-01 AU AU2002328827A patent/AU2002328827A1/en not_active Abandoned
- 2002-07-01 MX MXPA04000119A patent/MXPA04000119A/es unknown
- 2002-07-01 WO PCT/EP2002/007219 patent/WO2003006558A2/en active Application Filing
- 2002-07-01 JP JP2003512318A patent/JP2005502738A/ja not_active Withdrawn
-
2004
- 2004-02-09 IN IN171KO2004 patent/IN2004KO00171A/en unknown
-
2010
- 2010-04-06 JP JP2010087956A patent/JP2010174255A/ja active Pending
-
2013
- 2013-06-19 JP JP2013128442A patent/JP6166594B2/ja not_active Expired - Fee Related
-
2017
- 2017-04-18 JP JP2017082402A patent/JP2017128743A/ja active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH07246366A (ja) * | 1994-01-18 | 1995-09-26 | Mazda Motor Corp | 光干渉材及びそれを含有する塗料 |
JP2000517374A (ja) * | 1996-05-09 | 2000-12-26 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 多層干渉性顔料 |
JP2000501774A (ja) * | 1996-09-21 | 2000-02-15 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 多層干渉顔料 |
WO1999020695A1 (de) * | 1997-10-17 | 1999-04-29 | Merck Patent Gmbh | Interferenzpigmente |
JP2000239559A (ja) * | 1999-02-15 | 2000-09-05 | Merck Patent Gmbh | 強力な干渉顔料 |
JP2000345096A (ja) * | 1999-04-16 | 2000-12-12 | Merck Patent Gmbh | 顔料混合物 |
WO2001016235A1 (de) * | 1999-09-01 | 2001-03-08 | Merck Patent Gmbh | PIGMENTMISCHUNG ENTHALTEND BiOCl-PIGMENTE |
JP2003530457A (ja) * | 2000-04-11 | 2003-10-14 | メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング | 角度選択的透過または反射特性および/または吸収特性を有する透明媒体 |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101876199B1 (ko) * | 2017-04-21 | 2018-08-03 | 씨큐브 주식회사 | 복합 백색 안료 및 그 제조 방법 |
WO2018194284A1 (ko) * | 2017-04-21 | 2018-10-25 | 씨큐브 주식회사 | 복합 백색 안료 |
US11118060B2 (en) | 2017-04-21 | 2021-09-14 | Cqv Co., Ltd. | Composite white pigment |
Also Published As
Publication number | Publication date |
---|---|
WO2003006558A3 (en) | 2004-09-10 |
US7604862B2 (en) | 2009-10-20 |
IN2004KO00171A (ja) | 2006-02-17 |
US20040170838A1 (en) | 2004-09-02 |
AU2002328827A8 (en) | 2005-11-03 |
CN1622981A (zh) | 2005-06-01 |
RU2004102396A (ru) | 2005-05-10 |
AU2002328827A1 (en) | 2003-01-29 |
JP6166594B2 (ja) | 2017-07-19 |
RU2323238C2 (ru) | 2008-04-27 |
CN101104748A (zh) | 2008-01-16 |
EP1474486B1 (en) | 2019-04-03 |
CN101104748B (zh) | 2012-08-22 |
JP2017128743A (ja) | 2017-07-27 |
EP1474486A2 (en) | 2004-11-10 |
JP2010174255A (ja) | 2010-08-12 |
JP2005502738A (ja) | 2005-01-27 |
MXPA04000119A (es) | 2004-05-21 |
WO2003006558A2 (en) | 2003-01-23 |
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