JP2012532885A5 - - Google Patents
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- Publication number
- JP2012532885A5 JP2012532885A5 JP2012519754A JP2012519754A JP2012532885A5 JP 2012532885 A5 JP2012532885 A5 JP 2012532885A5 JP 2012519754 A JP2012519754 A JP 2012519754A JP 2012519754 A JP2012519754 A JP 2012519754A JP 2012532885 A5 JP2012532885 A5 JP 2012532885A5
- Authority
- JP
- Japan
- Prior art keywords
- group
- alkyl
- unsaturated
- complex
- substituted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims description 16
- 125000005842 heteroatom Chemical group 0.000 claims description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 11
- -1 polyethylene Polymers 0.000 claims description 11
- 229920002554 vinyl polymer Polymers 0.000 claims description 10
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 claims description 9
- 125000003118 aryl group Chemical group 0.000 claims description 9
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 9
- 125000003107 substituted aryl group Chemical group 0.000 claims description 9
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 9
- 229920000570 polyether Polymers 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- 125000004122 cyclic group Chemical group 0.000 claims description 6
- 125000000524 functional group Chemical group 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- 229920006395 saturated elastomer Polymers 0.000 claims description 5
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 4
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 125000003367 polycyclic group Polymers 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 125000006657 (C1-C10) hydrocarbyl group Chemical group 0.000 claims description 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims description 2
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims description 2
- 150000001345 alkine derivatives Chemical class 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 2
- 150000008378 aryl ethers Chemical class 0.000 claims description 2
- 150000001924 cycloalkanes Chemical class 0.000 claims description 2
- 150000004795 grignard reagents Chemical class 0.000 claims description 2
- 229910052753 mercury Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 229910052716 thallium Inorganic materials 0.000 claims description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 4
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 4
- 150000002431 hydrogen Chemical class 0.000 claims 4
- 229910052799 carbon Inorganic materials 0.000 claims 3
- 125000001033 ether group Chemical group 0.000 claims 3
- 125000005843 halogen group Chemical group 0.000 claims 3
- 238000006459 hydrosilylation reaction Methods 0.000 claims 3
- UWRZIZXBOLBCON-UHFFFAOYSA-N 2-phenylethenamine Chemical compound NC=CC1=CC=CC=C1 UWRZIZXBOLBCON-UHFFFAOYSA-N 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- 239000004698 Polyethylene Substances 0.000 claims 2
- 239000004743 Polypropylene Substances 0.000 claims 2
- 239000004793 Polystyrene Substances 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 239000000412 dendrimer Substances 0.000 claims 2
- 229920000736 dendritic polymer Polymers 0.000 claims 2
- 229910052760 oxygen Inorganic materials 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- 229920000573 polyethylene Polymers 0.000 claims 2
- 229920001155 polypropylene Polymers 0.000 claims 2
- 229920002223 polystyrene Polymers 0.000 claims 2
- 239000000377 silicon dioxide Substances 0.000 claims 2
- VTLYFUHAOXGGBS-UHFFFAOYSA-N Fe3+ Chemical compound [Fe+3] VTLYFUHAOXGGBS-UHFFFAOYSA-N 0.000 claims 1
- 229910004298 SiO 2 Inorganic materials 0.000 claims 1
- 229910004283 SiO 4 Inorganic materials 0.000 claims 1
- 239000002168 alkylating agent Substances 0.000 claims 1
- 229940100198 alkylating agent Drugs 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 150000001721 carbon Chemical group 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- 238000006317 isomerization reaction Methods 0.000 claims 1
- 238000007885 magnetic separation Methods 0.000 claims 1
- 125000000962 organic group Chemical group 0.000 claims 1
- 229910000077 silane Inorganic materials 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 239000007818 Grignard reagent Substances 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005805 hydroxylation reaction Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US22460909P | 2009-07-10 | 2009-07-10 | |
| US61/224,609 | 2009-07-10 | ||
| US12/832,533 | 2010-07-08 | ||
| US12/832,533 US8415443B2 (en) | 2009-07-10 | 2010-07-08 | Hydrosilylation catalysts |
| PCT/US2010/041499 WO2011006049A1 (en) | 2009-07-10 | 2010-07-09 | Hydrosilylation catalysts |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012532885A JP2012532885A (ja) | 2012-12-20 |
| JP2012532885A5 true JP2012532885A5 (enExample) | 2016-06-02 |
| JP5969387B2 JP5969387B2 (ja) | 2016-08-17 |
Family
ID=43427965
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012519754A Expired - Fee Related JP5969387B2 (ja) | 2009-07-10 | 2010-07-09 | ヒドロシリル化触媒 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8415443B2 (enExample) |
| EP (1) | EP2451818A1 (enExample) |
| JP (1) | JP5969387B2 (enExample) |
| KR (1) | KR101450080B1 (enExample) |
| CN (1) | CN102471354B (enExample) |
| BR (1) | BR112012000167A2 (enExample) |
| TW (1) | TWI511785B (enExample) |
| WO (1) | WO2011006049A1 (enExample) |
Families Citing this family (42)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BR112013012733A2 (pt) | 2010-11-24 | 2016-09-13 | Univ Cornell | ativação in situ de complexos de metal contendo ligantes de nitrogênio terdentado usados como catalisadores de hydrosililação |
| EP2643335B1 (en) | 2010-11-24 | 2015-03-11 | Momentive Performance Materials Inc. | Hydrosilylation catalyst |
| EP2643330B1 (en) | 2010-11-24 | 2017-01-04 | Momentive Performance Materials Inc. | Metal-catalyzed mono-hydrosilylation of polyunsaturated compounds |
| US20140228570A1 (en) * | 2011-09-20 | 2014-08-14 | Dow Corning Corporation | Hydrosilylation Catalysts Made With Terdentate Nitrogen Ligands And Compositions Containing The Catalysts |
| US9139699B2 (en) | 2012-10-04 | 2015-09-22 | Dow Corning Corporation | Metal containing condensation reaction catalysts, methods for preparing the catalysts, and compositions containing the catalysts |
| US9782763B2 (en) * | 2011-12-14 | 2017-10-10 | Momentive Performance Materials Inc. | Non-precious metal-based hyrdosilylation catalysts exhibiting improved selectivity |
| WO2013120057A1 (en) | 2012-02-10 | 2013-08-15 | The Regents Of The University Of California | First row metal-based catalysts for hydosilylation |
| BR102013016146A2 (pt) * | 2012-08-16 | 2016-09-13 | Momentive Performance Mat Inc | processo para produzir um produto sililado, por desidrogenação, composição, composto e processo para produzir um material reticulado |
| US9447125B2 (en) * | 2012-08-16 | 2016-09-20 | Momentive Performance Materials Inc. | Reusable homogeneous cobalt pyridine diimine catalysts for dehydrogenative silylation and tandem dehydrogenative-silylation-hydrogenation |
| JP6125222B2 (ja) * | 2012-08-16 | 2017-05-10 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | コバルト触媒を用いる脱水素シリル化および架橋 |
| US9371340B2 (en) | 2012-08-16 | 2016-06-21 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts |
| US9371339B2 (en) | 2013-05-06 | 2016-06-21 | Momentive Performance Materials Inc. | Saturated and unsaturated silahydrocarbons via iron and cobalt pyridine diimine catalyzed olefin silylation |
| WO2014182670A2 (en) | 2013-05-06 | 2014-11-13 | Momentive Performance Materials Inc. | Selective 1,2-hydrosilylation of terminally unsaturated 1,3-dienes using iron catalysts |
| JP2016520083A (ja) | 2013-05-15 | 2016-07-11 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | シリルヒドリドによる金属塩の活性化およびヒドロシリル化反応におけるその使用 |
| US9708355B2 (en) | 2013-06-12 | 2017-07-18 | Arizona Board Of Regents On Behalf Of Arizona State University | First-row transition metal hydrogenation and hydrosilylation catalysts |
| WO2015077306A1 (en) * | 2013-11-19 | 2015-05-28 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| TW201524603A (zh) * | 2013-11-19 | 2015-07-01 | Momentive Performance Mat Inc | 鈷觸媒及其於矽氫化與脫氫甲矽烷化之用途 |
| EP3071583B1 (en) * | 2013-11-19 | 2018-05-09 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using cobalt catalysts |
| US9387468B2 (en) | 2013-11-19 | 2016-07-12 | Momentive Performance Materials Inc. | Cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| JP6308547B2 (ja) * | 2014-02-20 | 2018-04-11 | 公立大学法人大阪市立大学 | 有機ケイ素化合物の製造方法 |
| WO2015171881A1 (en) * | 2014-05-08 | 2015-11-12 | Momentive Performance Materials Inc. | Dialkyl cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| WO2016024611A1 (ja) * | 2014-08-12 | 2016-02-18 | 国立大学法人九州大学 | ヒドロシリル化反応触媒 |
| WO2016024607A1 (ja) | 2014-08-12 | 2016-02-18 | 国立大学法人九州大学 | ヒドロシリル化反応触媒 |
| JP6761997B2 (ja) | 2014-08-19 | 2020-09-30 | 国立大学法人九州大学 | ヒドロシリル化鉄触媒 |
| JP6373125B2 (ja) * | 2014-08-22 | 2018-08-15 | 国立大学法人山形大学 | トランジスタ型重金属イオンセンサ |
| EP3240823A4 (en) * | 2014-12-30 | 2018-08-01 | Momentive Performance Materials Inc. | Siloxane coordination polymers |
| CN107847921B (zh) | 2015-07-14 | 2022-01-14 | 国立大学法人九州大学 | 氢化硅烷化反应催化剂 |
| US10717752B2 (en) * | 2015-07-24 | 2020-07-21 | Momentive Performance Materials Inc. | Dehydrogenative silylation, hydrosilylation and crosslinking using pyridinediimine cobalt carboxylate catalysts |
| JP6536262B2 (ja) * | 2015-07-31 | 2019-07-03 | 株式会社豊田中央研究所 | 固体触媒 |
| US11091573B2 (en) | 2015-11-25 | 2021-08-17 | General Cable Technologies Corporation | Hydrosilylation crosslinking of polyolefin cable components |
| EP3406616B1 (en) | 2016-01-22 | 2022-06-29 | Shin-Etsu Chemical Co., Ltd. | Novel isocyanide compound and hydrosilylation reaction catalyst |
| JP6933835B2 (ja) * | 2017-01-25 | 2021-09-08 | 公立大学法人大阪 | 鉄錯体触媒を用いたカルボニル化合物のヒドロシリル化反応によるアルコキシシランの製造方法 |
| CN110366449B (zh) | 2017-02-28 | 2022-10-21 | 国立大学法人九州大学 | 氢化硅烷化反应、氢化反应和氢硅烷还原反应用催化剂 |
| US10946368B2 (en) * | 2017-07-17 | 2021-03-16 | Dow Silicones Corporation | Catalyst and related methods involving hydrosilylation and dehydrogenative silylation |
| JP2019064950A (ja) | 2017-09-29 | 2019-04-25 | 国立大学法人九州大学 | コバルト錯体、その製造方法およびヒドロシリル化反応用触媒 |
| US11273432B2 (en) | 2018-05-31 | 2022-03-15 | Arizona Board Of Regents On Behalf Of Arizona State University | Beta-diketiminate manganese catalysts for hydrosilylation, hydroboration, and dehydrogenative pnictogen-silicon and pnictogen-boron bond formation |
| KR102807413B1 (ko) | 2018-09-13 | 2025-05-13 | 모멘티브 퍼포먼스 머티리얼즈 게엠베하 | 기능성 폴리실록산 |
| JP6806299B2 (ja) * | 2019-02-15 | 2021-01-06 | 国立大学法人九州大学 | ヒドロシリル化鉄触媒の調製方法 |
| JP7351460B2 (ja) * | 2019-06-19 | 2023-09-27 | 公立大学法人大阪 | イミノビピリジンコバルト錯体、及びイミノビピリジンコバルト錯体を利用したヒドロシリル化反応による有機ケイ素化合物の製造方法 |
| CN110465330B (zh) * | 2019-08-09 | 2022-06-10 | 杭州师范大学 | 一种利用钴催化剂的硅氢加成反应的方法 |
| JP2021042177A (ja) * | 2019-09-13 | 2021-03-18 | 国立大学法人九州大学 | 新規イソシアニド化合物、ホルムアミド化合物及びイソシアニド化合物を用いた有機ケイ素化合物の製造方法 |
| EP3915995B1 (en) | 2020-05-29 | 2025-11-26 | Momentive Performance Materials Inc. | Process for the stepwise synthesis of silahydrocarbons |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3220972A (en) | 1962-07-02 | 1965-11-30 | Gen Electric | Organosilicon process using a chloroplatinic acid reaction product as the catalyst |
| US3159601A (en) | 1962-07-02 | 1964-12-01 | Gen Electric | Platinum-olefin complex catalyzed addition of hydrogen- and alkenyl-substituted siloxanes |
| US3775452A (en) | 1971-04-28 | 1973-11-27 | Gen Electric | Platinum complexes of unsaturated siloxanes and platinum containing organopolysiloxanes |
| IL129929A0 (en) | 1996-12-17 | 2000-02-29 | Du Pont | Polymerization of ethylene with specific iron or cobalt complexes novel pyridinebis (imines) and novel complexes of pyridinebis(imines) with iron and cobalt |
| DE69921304T2 (de) | 1998-03-12 | 2005-02-24 | Bp Chemicals Ltd. | Polymerisationskatalysatoren |
| GB9819847D0 (en) * | 1998-09-12 | 1998-11-04 | Bp Chem Int Ltd | Novel compounds |
| DE60211884T2 (de) | 2001-04-30 | 2006-11-23 | Ciba Speciality Chemicals Holding Inc. | Verwendung von metallkomplexverbindungen als oxidationskatalysatoren |
| WO2004007657A1 (en) * | 2002-07-11 | 2004-01-22 | Ciba Specialty Chemicals Holding Inc. | Use of metal complex compounds as oxidation catalysts |
| EP1542797B1 (en) | 2002-09-25 | 2006-05-31 | Shell Internationale Researchmaatschappij B.V. | Catalyst systems for ethylene oligomerisation to linear alpha olefins |
| US7442819B2 (en) | 2004-07-09 | 2008-10-28 | E. I. Du Pont De Nemours And Company | Catalysts for olefin polymerization or oligomerization |
| CN100378111C (zh) * | 2005-07-01 | 2008-04-02 | 中国科学院上海有机化学研究所 | 含碳氧醚键有机硅化合物、合成方法及其应用 |
| JP5572798B2 (ja) | 2008-08-05 | 2014-08-20 | 公立大学法人大阪市立大学 | ヒドロシリル化反応用触媒、及び同触媒を用いた有機ケイ素化合物の製造方法 |
-
2010
- 2010-07-08 US US12/832,533 patent/US8415443B2/en not_active Expired - Fee Related
- 2010-07-09 KR KR1020117031653A patent/KR101450080B1/ko not_active Expired - Fee Related
- 2010-07-09 EP EP10731908A patent/EP2451818A1/en not_active Withdrawn
- 2010-07-09 WO PCT/US2010/041499 patent/WO2011006049A1/en not_active Ceased
- 2010-07-09 JP JP2012519754A patent/JP5969387B2/ja not_active Expired - Fee Related
- 2010-07-09 CN CN201080030965.5A patent/CN102471354B/zh not_active Expired - Fee Related
- 2010-07-09 BR BR112012000167A patent/BR112012000167A2/pt not_active Application Discontinuation
- 2010-07-12 TW TW099122883A patent/TWI511785B/zh not_active IP Right Cessation
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