JP2014037398A5 - - Google Patents
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- JP2014037398A5 JP2014037398A5 JP2012278847A JP2012278847A JP2014037398A5 JP 2014037398 A5 JP2014037398 A5 JP 2014037398A5 JP 2012278847 A JP2012278847 A JP 2012278847A JP 2012278847 A JP2012278847 A JP 2012278847A JP 2014037398 A5 JP2014037398 A5 JP 2014037398A5
- Authority
- JP
- Japan
- Prior art keywords
- alkyl
- substituted
- aryl
- group
- unsaturated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 238000000034 method Methods 0.000 claims description 42
- 125000003118 aryl group Chemical group 0.000 claims description 26
- 125000000547 substituted alkyl group Chemical group 0.000 claims description 26
- 125000003107 substituted aryl group Chemical group 0.000 claims description 26
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 claims description 22
- 125000005842 heteroatom Chemical group 0.000 claims description 20
- 229910052739 hydrogen Inorganic materials 0.000 claims description 18
- 239000001257 hydrogen Substances 0.000 claims description 18
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 16
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 13
- 125000000524 functional group Chemical group 0.000 claims description 10
- 150000002431 hydrogen Chemical class 0.000 claims description 10
- 150000001875 compounds Chemical class 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 9
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 229920006395 saturated elastomer Polymers 0.000 claims description 7
- 239000012190 activator Substances 0.000 claims description 6
- 239000012018 catalyst precursor Substances 0.000 claims description 6
- 239000003638 chemical reducing agent Substances 0.000 claims description 5
- 239000002168 alkylating agent Substances 0.000 claims description 3
- 229940100198 alkylating agent Drugs 0.000 claims description 3
- 125000002947 alkylene group Chemical group 0.000 claims description 3
- 238000011065 in-situ storage Methods 0.000 claims description 3
- YNESATAKKCNGOF-UHFFFAOYSA-N lithium bis(trimethylsilyl)amide Chemical compound [Li+].C[Si](C)(C)[N-][Si](C)(C)C YNESATAKKCNGOF-UHFFFAOYSA-N 0.000 claims description 3
- -1 chloro, bromo, iodo Chemical group 0.000 claims 13
- 229920002554 vinyl polymer Polymers 0.000 claims 12
- 150000002170 ethers Chemical class 0.000 claims 11
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 10
- 150000001336 alkenes Chemical class 0.000 claims 8
- 125000001153 fluoro group Chemical group F* 0.000 claims 7
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 7
- 238000006884 silylation reaction Methods 0.000 claims 7
- 239000004721 Polyphenylene oxide Substances 0.000 claims 6
- 238000006243 chemical reaction Methods 0.000 claims 6
- 229920000570 polyether Polymers 0.000 claims 6
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims 4
- 125000000217 alkyl group Chemical group 0.000 claims 4
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 claims 4
- 239000000203 mixture Substances 0.000 claims 4
- 150000001412 amines Chemical class 0.000 claims 3
- 150000008282 halocarbons Chemical class 0.000 claims 3
- 229930195733 hydrocarbon Natural products 0.000 claims 3
- 150000002430 hydrocarbons Chemical class 0.000 claims 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims 3
- 229920000642 polymer Polymers 0.000 claims 3
- 229920000098 polyolefin Polymers 0.000 claims 3
- 125000006657 (C1-C10) hydrocarbyl group Chemical group 0.000 claims 2
- UWRZIZXBOLBCON-UHFFFAOYSA-N 2-phenylethenamine Chemical compound NC=CC1=CC=CC=C1 UWRZIZXBOLBCON-UHFFFAOYSA-N 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 2
- 239000004698 Polyethylene Substances 0.000 claims 2
- 239000004743 Polypropylene Substances 0.000 claims 2
- 239000004793 Polystyrene Substances 0.000 claims 2
- 229910004298 SiO 2 Inorganic materials 0.000 claims 2
- 229910004283 SiO 4 Inorganic materials 0.000 claims 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims 2
- 150000001345 alkine derivatives Chemical class 0.000 claims 2
- 125000005336 allyloxy group Chemical group 0.000 claims 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 2
- 150000008378 aryl ethers Chemical class 0.000 claims 2
- 229910052799 carbon Inorganic materials 0.000 claims 2
- 239000011243 crosslinked material Substances 0.000 claims 2
- 150000001925 cycloalkenes Chemical class 0.000 claims 2
- 238000006356 dehydrogenation reaction Methods 0.000 claims 2
- 239000000412 dendrimer Substances 0.000 claims 2
- 229920000736 dendritic polymer Polymers 0.000 claims 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 claims 2
- 150000002148 esters Chemical class 0.000 claims 2
- 239000003446 ligand Substances 0.000 claims 2
- 239000012705 liquid precursor Substances 0.000 claims 2
- 125000005394 methallyl group Chemical group 0.000 claims 2
- GBCKRQRXNXQQPW-UHFFFAOYSA-N n,n-dimethylprop-2-en-1-amine Chemical group CN(C)CC=C GBCKRQRXNXQQPW-UHFFFAOYSA-N 0.000 claims 2
- UUEVFMOUBSLVJW-UHFFFAOYSA-N oxo-[[1-[2-[2-[2-[4-(oxoazaniumylmethylidene)pyridin-1-yl]ethoxy]ethoxy]ethyl]pyridin-4-ylidene]methyl]azanium;dibromide Chemical compound [Br-].[Br-].C1=CC(=C[NH+]=O)C=CN1CCOCCOCCN1C=CC(=C[NH+]=O)C=C1 UUEVFMOUBSLVJW-UHFFFAOYSA-N 0.000 claims 2
- 229920001467 poly(styrenesulfonates) Polymers 0.000 claims 2
- 229920000573 polyethylene Polymers 0.000 claims 2
- 229920001155 polypropylene Polymers 0.000 claims 2
- 229920001296 polysiloxane Polymers 0.000 claims 2
- 229920002223 polystyrene Polymers 0.000 claims 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims 2
- 229910000077 silane Inorganic materials 0.000 claims 2
- 150000004756 silanes Chemical class 0.000 claims 2
- 239000000377 silicon dioxide Substances 0.000 claims 2
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 claims 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 claims 2
- 239000004711 α-olefin Substances 0.000 claims 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 1
- 101100242814 Caenorhabditis elegans parg-1 gene Proteins 0.000 claims 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims 1
- 239000005977 Ethylene Substances 0.000 claims 1
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical group O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 150000001450 anions Chemical class 0.000 claims 1
- 150000001642 boronic acid derivatives Chemical class 0.000 claims 1
- 229910001873 dinitrogen Inorganic materials 0.000 claims 1
- 230000007935 neutral effect Effects 0.000 claims 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims 1
- 150000003003 phosphines Chemical class 0.000 claims 1
- 150000003839 salts Chemical group 0.000 claims 1
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261683882P | 2012-08-16 | 2012-08-16 | |
| US61/683,882 | 2012-08-16 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017075009A Division JP6389297B2 (ja) | 2012-08-16 | 2017-04-05 | コバルト触媒を用いる脱水素シリル化および架橋 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2014037398A JP2014037398A (ja) | 2014-02-27 |
| JP2014037398A5 true JP2014037398A5 (enExample) | 2017-01-12 |
| JP6125222B2 JP6125222B2 (ja) | 2017-05-10 |
Family
ID=50285833
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012278847A Active JP6125222B2 (ja) | 2012-08-16 | 2012-12-21 | コバルト触媒を用いる脱水素シリル化および架橋 |
| JP2017075009A Active JP6389297B2 (ja) | 2012-08-16 | 2017-04-05 | コバルト触媒を用いる脱水素シリル化および架橋 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2017075009A Active JP6389297B2 (ja) | 2012-08-16 | 2017-04-05 | コバルト触媒を用いる脱水素シリル化および架橋 |
Country Status (2)
| Country | Link |
|---|---|
| JP (2) | JP6125222B2 (enExample) |
| TW (1) | TWI583690B (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20170190722A1 (en) * | 2014-05-08 | 2017-07-06 | Momentive Performance Materials Inc. | Dialkyl cobalt catalysts and their use for hydrosilylation and dehydrogenative silylation |
| JP6473392B2 (ja) * | 2015-07-10 | 2019-02-20 | 信越化学工業株式会社 | 化粧料 |
| CN108026126B (zh) * | 2015-07-24 | 2021-04-20 | 莫门蒂夫性能材料股份有限公司 | 使用吡啶二亚胺羧酸钴催化剂的脱氢硅烷化、氢化硅烷化和交联 |
| WO2025225552A1 (ja) * | 2024-04-26 | 2025-10-30 | モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社 | 紫外線活性型シリコーン組成物及びそれを用いた接着部材の製造方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57109795A (en) * | 1980-12-26 | 1982-07-08 | Mitsubishi Chem Ind Ltd | Preparation of vinylsilane |
| US4668812A (en) * | 1985-12-31 | 1987-05-26 | Union Carbide Corporation | Process for the preparation of olefinic silanes and siloxanes |
| CN101010351B (zh) * | 2004-07-09 | 2011-06-22 | 纳幕尔杜邦公司 | 用于烯烃聚合或低聚的催化剂 |
| US8236915B2 (en) * | 2009-07-10 | 2012-08-07 | Momentive Performance Materials Inc. | Hydrosilylation catalysts |
| US8415443B2 (en) * | 2009-07-10 | 2013-04-09 | Momentive Performance Materials Inc. | Hydrosilylation catalysts |
| JP5991981B2 (ja) * | 2010-11-24 | 2016-09-14 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | ヒドロシリル化触媒として使用される三座窒素配位子を有する金属錯体のｉｎ−ｓｉｔｕ活性化 |
-
2012
- 2012-12-21 JP JP2012278847A patent/JP6125222B2/ja active Active
- 2012-12-24 TW TW101149620A patent/TWI583690B/zh active
-
2017
- 2017-04-05 JP JP2017075009A patent/JP6389297B2/ja active Active
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