JPS57109795A - Preparation of vinylsilane - Google Patents
Preparation of vinylsilaneInfo
- Publication number
- JPS57109795A JPS57109795A JP18901380A JP18901380A JPS57109795A JP S57109795 A JPS57109795 A JP S57109795A JP 18901380 A JP18901380 A JP 18901380A JP 18901380 A JP18901380 A JP 18901380A JP S57109795 A JPS57109795 A JP S57109795A
- Authority
- JP
- Japan
- Prior art keywords
- alkoxysilane
- formula
- ruthenium
- olefin
- alkyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Catalysts (AREA)
Abstract
PURPOSE: To obtain the titled compound useful as an organic synthetic reagent, high polymer modifier, etc. in high selectivity, by dehydrogenating an alkoxysilane with olefin in the presence of metallic ruthenium or a ruthenium carbonyl complex catalyst.
CONSTITUTION: (A) An alkoxysilane of the formula HSi(OR1)3 (R1 is alkyl), e.g. triethoxysilane, is dehydrogenated with (B) an olefin of the formula R2 -CH=CH2 [R2 is H or (substituted) alkyl] in the presence of metallic ruthenium or ruthenium carbonyl complex catalyst, e.g. Ru3(CO)12 at a molar ratio between the catalyst (B) and the alkoxysilane (A) of preferably 0.001W0.01 at 50W150°C for 2W50hr to give the aimed vinylsilane of the formula.
EFFECT: Expensive and difficultly handled organic solvents need not be used, a high yield is obtd.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18901380A JPS57109795A (en) | 1980-12-26 | 1980-12-26 | Preparation of vinylsilane |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP18901380A JPS57109795A (en) | 1980-12-26 | 1980-12-26 | Preparation of vinylsilane |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS57109795A true JPS57109795A (en) | 1982-07-08 |
JPH0253437B2 JPH0253437B2 (en) | 1990-11-16 |
Family
ID=16233834
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP18901380A Granted JPS57109795A (en) | 1980-12-26 | 1980-12-26 | Preparation of vinylsilane |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57109795A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62164688A (en) * | 1985-12-31 | 1987-07-21 | ユニオン・カ−バイド・コ−ポレ−シヨン | Production of olefinic silane and siloxane |
JP2017171661A (en) * | 2012-08-16 | 2017-09-28 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | Dehydrogenative silylation and crosslinking using cobalt catalyst |
JP2020516623A (en) * | 2017-04-11 | 2020-06-11 | ダウ シリコーンズ コーポレーション | Method for preparing arylalkoxysilanes by dehydrogenative silylation |
-
1980
- 1980-12-26 JP JP18901380A patent/JPS57109795A/en active Granted
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62164688A (en) * | 1985-12-31 | 1987-07-21 | ユニオン・カ−バイド・コ−ポレ−シヨン | Production of olefinic silane and siloxane |
JPH0353317B2 (en) * | 1985-12-31 | 1991-08-14 | Yunion Kaabaido Chem Ando Purasuchitsukusu Co Inc | |
JP2017171661A (en) * | 2012-08-16 | 2017-09-28 | モメンティブ パフォーマンス マテリアルズ インコーポレイテッド | Dehydrogenative silylation and crosslinking using cobalt catalyst |
JP2020516623A (en) * | 2017-04-11 | 2020-06-11 | ダウ シリコーンズ コーポレーション | Method for preparing arylalkoxysilanes by dehydrogenative silylation |
Also Published As
Publication number | Publication date |
---|---|
JPH0253437B2 (en) | 1990-11-16 |
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