JPS57140788A - Preparation of vinylsilane having perfluoro group - Google Patents
Preparation of vinylsilane having perfluoro groupInfo
- Publication number
- JPS57140788A JPS57140788A JP56025540A JP2554081A JPS57140788A JP S57140788 A JPS57140788 A JP S57140788A JP 56025540 A JP56025540 A JP 56025540A JP 2554081 A JP2554081 A JP 2554081A JP S57140788 A JPS57140788 A JP S57140788A
- Authority
- JP
- Japan
- Prior art keywords
- complex
- vinylsilane
- perfluoro group
- preparation
- hydrosilane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- -1 perfluoro group Chemical group 0.000 title abstract 2
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical compound [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 title abstract 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 abstract 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 3
- 150000001336 alkenes Chemical class 0.000 abstract 2
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 abstract 1
- 125000003545 alkoxy group Chemical group 0.000 abstract 1
- 125000000217 alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- NQZFAUXPNWSLBI-UHFFFAOYSA-N carbon monoxide;ruthenium Chemical compound [Ru].[Ru].[Ru].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-].[O+]#[C-] NQZFAUXPNWSLBI-UHFFFAOYSA-N 0.000 abstract 1
- 239000003814 drug Substances 0.000 abstract 1
- 229910052731 fluorine Inorganic materials 0.000 abstract 1
- 239000011737 fluorine Substances 0.000 abstract 1
- 229910052736 halogen Inorganic materials 0.000 abstract 1
- 150000002367 halogens Chemical group 0.000 abstract 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 239000002904 solvent Substances 0.000 abstract 1
Abstract
PURPOSE: To prepare the titled compound useful as a synthetic intermediate of pharmaceuticals, pesticides, etc., from easily available raw materials, in high yield, by reacting an olefin having perfluoro group with hydrosilane in the presence of an Ru complex or an Rh complex.
CONSTITUTION: The olefin of formulaI(Rf is 1W20C perfluoroalkyl or perfluoroaryl) is made to react with the hydrosilane of formula II (R is alkyl, aryl, halogen or alkoxy) to obtain the vinylsilane of formula III. The reaction is carried out in the presence of an Ru complex or an Rh complex, e.g. Ru3(CO)12, Ru(PPh3)3Cl2, Rh(PPh3)3Cl, etc., preferably in a solvent such as benzene at 50W150°C. The compound of formula III is useful as a synthetic intermediate of various fluorine-containing compounds.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56025540A JPS57140788A (en) | 1981-02-25 | 1981-02-25 | Preparation of vinylsilane having perfluoro group |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP56025540A JPS57140788A (en) | 1981-02-25 | 1981-02-25 | Preparation of vinylsilane having perfluoro group |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57140788A true JPS57140788A (en) | 1982-08-31 |
| JPS6344160B2 JPS6344160B2 (en) | 1988-09-02 |
Family
ID=12168825
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP56025540A Granted JPS57140788A (en) | 1981-02-25 | 1981-02-25 | Preparation of vinylsilane having perfluoro group |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57140788A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0228095A2 (en) * | 1985-12-31 | 1987-07-08 | Union Carbide Corporation | Process for the preparation of olefinic silanes and siloxanes |
| WO2018159641A1 (en) * | 2017-03-02 | 2018-09-07 | Ａｇｃ株式会社 | Production method for fluorine-containing silane compound, and fluorine-containing silane compound |
| WO2019178876A1 (en) * | 2018-03-23 | 2019-09-26 | 南通纺织丝绸产业技术研究院 | Pressure-sensitive organosilicon adhesive and preparation method thereof |
| WO2019178875A1 (en) * | 2018-03-23 | 2019-09-26 | 南通纺织丝绸产业技术研究院 | High-temperature resistant and pressure-sensitive adhesive precursor and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3296291A (en) * | 1962-07-02 | 1967-01-03 | Gen Electric | Reaction of silanes with unsaturated olefinic compounds |
| JPS4839441A (en) * | 1971-09-22 | 1973-06-09 | ||
| DD103903A1 (en) * | 1972-09-15 | 1974-02-12 | ||
| JPS5543051A (en) * | 1978-09-22 | 1980-03-26 | Chisso Corp | Preparation of dialkyldichlorosilane |
-
1981
- 1981-02-25 JP JP56025540A patent/JPS57140788A/en active Granted
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3296291A (en) * | 1962-07-02 | 1967-01-03 | Gen Electric | Reaction of silanes with unsaturated olefinic compounds |
| JPS4839441A (en) * | 1971-09-22 | 1973-06-09 | ||
| DD103903A1 (en) * | 1972-09-15 | 1974-02-12 | ||
| JPS5543051A (en) * | 1978-09-22 | 1980-03-26 | Chisso Corp | Preparation of dialkyldichlorosilane |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0228095A2 (en) * | 1985-12-31 | 1987-07-08 | Union Carbide Corporation | Process for the preparation of olefinic silanes and siloxanes |
| JPS62164688A (en) * | 1985-12-31 | 1987-07-21 | ユニオン・カ−バイド・コ−ポレ−シヨン | Production of olefinic silane and siloxane |
| JPH0353317B2 (en) * | 1985-12-31 | 1991-08-14 | Yunion Kaabaido Chem Ando Purasuchitsukusu Co Inc | |
| WO2018159641A1 (en) * | 2017-03-02 | 2018-09-07 | Ａｇｃ株式会社 | Production method for fluorine-containing silane compound, and fluorine-containing silane compound |
| JPWO2018159641A1 (en) * | 2017-03-02 | 2019-12-19 | Ａｇｃ株式会社 | Method for producing fluorine-containing silane compound and fluorine-containing silane compound |
| JP2022116175A (en) * | 2017-03-02 | 2022-08-09 | Ａｇｃ株式会社 | Fluorine-containing silane compound |
| WO2019178876A1 (en) * | 2018-03-23 | 2019-09-26 | 南通纺织丝绸产业技术研究院 | Pressure-sensitive organosilicon adhesive and preparation method thereof |
| WO2019178875A1 (en) * | 2018-03-23 | 2019-09-26 | 南通纺织丝绸产业技术研究院 | High-temperature resistant and pressure-sensitive adhesive precursor and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6344160B2 (en) | 1988-09-02 |
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