JP2010501656A - 撥油性、撥水性及び撥汚物性メタクリル酸ペルフルオロアルキルエチルコポリマー - Google Patents
撥油性、撥水性及び撥汚物性メタクリル酸ペルフルオロアルキルエチルコポリマー Download PDFInfo
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Abstract
【選択図】なし
Description
11〜17重量%の6個のフッ化炭素原子を有するモノマー
48〜52重量%の8個のフッ化炭素原子を有するモノマー
18〜22重量%の10個のフッ化炭素原子を有するモノマー
1〜15重量%の12個以上のフッ化炭素原子を有するモノマー
である。
25〜70重量%の6個以下のフッ化炭素原子を有するモノマー
20〜40重量%の8個のフッ化炭素原子を有するモノマー
5〜25重量%の10個のフッ化炭素原子を有するモノマー
0〜15重量%の12個以上のフッ化炭素原子を有するモノマー
RFCH2CH2OCOC(CH3)=CH2 (II)
(式中、RF=4及び6)のメタクリル酸ペルフルオロアルキルエチルの混合物が、特に環境適合性であって、フッ化炭素原子8個の直鎖ペルフルオロアルキル鎖の存在を全く必要とせずに、低温の後処理をしてから高い性能及び耐久性も有する撥油性、撥水性及び撥汚物性被膜になることが、今や分かっている。
a)40〜97重量%、好ましくは45〜90重量%のメタクリル酸ペルフルオロアルキルエチル混合物、
b)1〜50重量%、好ましくは5〜30重量%の(メタ)アクリル酸C12‐C22アルキル、並びに
c)0.5〜10重量%、好ましくは1〜5重量%の単数又は複数の熱架橋性若しくはイソシアネート反応性モノマー、並びに
d)1.5〜50重量%、好ましくは4〜30重量%の塩化ビニル及び/又は塩化ビニリデン
を含むコポリマーを提供する。
1〜70重量%の4個のフッ化炭素原子を有する式IIのモノマー
30〜99重量%の6個のフッ化炭素原子を有する式IIのモノマー
1〜10重量%の4個のフッ化炭素原子を有する式IIのモノマー
90〜99重量%の6個のフッ化炭素原子を有する式IIのモノマー
30〜70重量%の4個のフッ化炭素原子を有する式IIのモノマー
30〜70重量%の6個のフッ化炭素原子を有する式IIのモノマー
FMA‐6:95重量%のメタクリル酸ペルフルオロヘキシルエチル及び5重量%のメタクリル酸ペルフルオロブチルエチルの混合物
FA‐6a:95重量%のアクリル酸ペルフルオロヘキシルエチル及び5重量%のアクリル酸ペルフルオロブチルエチルの混合物
FA‐6b:アクリル酸ペルフルオロヘキシルエチル
FA‐8:14重量%のアクリル酸ペルフルオロヘキシルエチル
50重量%のアクリル酸ペルフルオロオクチルエチル
20重量%のアクリル酸ペルフルオロデシルエチル
15重量%のアクリル酸ペルフルオロドデシルエチル
を含む混合物
FMA‐46:33重量%のメタクリル酸ペルフルオロヘキシルエチル及び66重量%のメタクリル酸ペルフルオロブチルエチルの混合物
VC:塩化ビニル
VDC:塩化ビニリデン
SA:アクリル酸ステアリル
CA:アクリル酸セチル
N‐MAM:N‐メトキシメチルアクリルアミド
HEMA:メタクリル酸2‐ヒドロキシエチル
HEA:アクリル酸2‐ヒドロキシエチル
PEPM:ポリエチレングリコール‐ポリプロピレングリコールモノメタクリレート
攪拌子、還流冷却器、コンデンサー及び内部温度計を備えたオートクレーブ中で、不活性ガス雰囲気下の次の組成物を激しく攪拌することにより分散液を調製した。
60.0gのメタクリル酸2‐ペルフルオロヘキシルエチル
22.5gのアクリル酸ステアリル
15.5gの塩化ビニリデン
1.0gのN‐メトキシメチルアクリルアミド
1.0gのメタクリル酸ヒドロキシエチル
30.0gのジプロピレングリコール
0.5gのドデカンチオール
4.0gのラウリルアルコール/16個のエチレンオキシド付加物
3.5gの酢酸N,N‐ジメチルドデシルアンモニウム
200.0gの水
テキスタイル仕上げ用分散液を実施例1と同様に調製した。モノマー量を表3に示す。
比較例Dは、米国特許第6716944号明細書の実施例4の処方に従っている。しかしながら、この処方はその特許文献で開示された撥水値及び撥油値を示さなかった。モノマー量を表3に示す。
Claims (7)
- コポリマーの全重量を基準として、
a)40〜97重量%、好ましくは45〜90重量%のメタクリル酸ペルフルオロアルキルエチル混合物、
b)1〜50重量%、好ましくは5〜30重量%の(メタ)アクリル酸C12‐C22アルキル、並びに
c)0.5〜10重量%、好ましくは1〜5重量%の単数又は複数の熱架橋性若しくはイソシアネート反応性モノマー、並びに
d)1.5〜50重量%、好ましくは4〜30重量%の塩化ビニル及び/又は塩化ビニリデンを含むコポリマーであって、
下記式
RFCH2CH2OCOC(CH3)=CH2
のメタクリル酸ペルフルオロアルキルエチルが
1〜70重量%の4個以下のフッ化炭素原子及び
30〜99重量%の6個のフッ化炭素原子
を含むことを特徴とするコポリマー。 - メタクリル酸ペルフルオロアルキルエチルのペルフルオロアルキル基が、
30〜70重量%の4個以下のフッ化炭素原子及び
30〜70重量%の6個のフッ化炭素原子
を含むことを特徴とする請求項1に記載の化合物。 - メタクリル酸ペルフルオロアルキルエチルのペルフルオロアルキル基が、
1〜10重量%の4個以下のフッ化炭素原子及び
90〜99重量%の6個のフッ化炭素原子
を含むことを特徴とする請求項1に記載の化合物。 - (メタ)アクリル酸C12‐C22アルキルがアクリル酸セチル、アクリル酸ステアリル及び/又はアクリル酸ベヘニルから構成されることを特徴とする請求項1に記載の化合物。
- 請求項1〜4のいずれか1項に記載のコポリマーの、繊維状基材の撥水、撥油及び撥汚物仕上げのための使用。
- 請求項1〜4のいずれか1項に記載のコポリマーと保護基の付いたイソシアネートの混合物との水性混合物。
- 請求項6に記載の水性混合物の、繊維状基材の撥水、撥油及び撥汚物仕上げのための使用。
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DE102006039914 | 2006-08-25 | ||
DE102006039914.5 | 2006-08-25 | ||
PCT/EP2007/058620 WO2008022985A1 (en) | 2006-08-25 | 2007-08-20 | Oil-, water- and soil-repellent perfluoroalkylethyl methacrylate copolymers |
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JP5351023B2 JP5351023B2 (ja) | 2013-11-27 |
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US (1) | US7976583B2 (ja) |
EP (1) | EP2057201B1 (ja) |
JP (1) | JP5351023B2 (ja) |
KR (1) | KR101359258B1 (ja) |
CN (1) | CN101506257B (ja) |
DE (1) | DE602007003995D1 (ja) |
ES (1) | ES2336722T3 (ja) |
RU (1) | RU2444534C2 (ja) |
TW (1) | TWI441837B (ja) |
WO (1) | WO2008022985A1 (ja) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012020735A1 (ja) * | 2010-08-11 | 2012-02-16 | 旭硝子株式会社 | 撥水剤組成物、その製造方法、疎水性基材処理剤組成物および物品 |
JP2013519758A (ja) * | 2010-02-12 | 2013-05-30 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 部分フッ素化メタクリルポリマーを含む非水性組成物 |
JP2013151625A (ja) * | 2012-01-26 | 2013-08-08 | Teijin Frontier Co Ltd | 撥水加工剤および加工方法および加工製品 |
WO2014030648A1 (ja) * | 2012-08-21 | 2014-02-27 | 旭硝子株式会社 | 含フッ素共重合体およびその製造方法、撥水剤組成物、物品 |
WO2014034053A1 (ja) * | 2012-08-27 | 2014-03-06 | 日東電工株式会社 | 撥油性が付与された通気フィルタ |
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JP2014210882A (ja) * | 2013-04-19 | 2014-11-13 | 旭化成ケミカルズ株式会社 | ブロックポリイソシアネート組成物、水分散体、繊維処理剤組成物及び布帛 |
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EP2057201B1 (en) | 2009-12-23 |
ES2336722T3 (es) | 2010-04-15 |
US20090325849A1 (en) | 2009-12-31 |
JP5351023B2 (ja) | 2013-11-27 |
KR20090076898A (ko) | 2009-07-13 |
RU2009110774A (ru) | 2010-09-27 |
EP2057201A1 (en) | 2009-05-13 |
KR101359258B1 (ko) | 2014-02-06 |
CN101506257B (zh) | 2012-08-08 |
US7976583B2 (en) | 2011-07-12 |
TW200825110A (en) | 2008-06-16 |
TWI441837B (zh) | 2014-06-21 |
DE602007003995D1 (de) | 2010-02-04 |
RU2444534C2 (ru) | 2012-03-10 |
WO2008022985A1 (en) | 2008-02-28 |
CN101506257A (zh) | 2009-08-12 |
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