JP2008505932A5 - - Google Patents

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JP2008505932A5
JP2008505932A5 JP2007520591A JP2007520591A JP2008505932A5 JP 2008505932 A5 JP2008505932 A5 JP 2008505932A5 JP 2007520591 A JP2007520591 A JP 2007520591A JP 2007520591 A JP2007520591 A JP 2007520591A JP 2008505932 A5 JP2008505932 A5 JP 2008505932A5
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  1. 下記化学式により表される組成物であって、
    Figure 2008505932
    式中、Mは、周期律表の4族から選択される遷移金属であり、
    各Rは、水素、ヒドロカルビル、置換ヒドロカルビルおよび官能基からなる群から独立して選択され、任意の2個のR基は連結されてもよく、前記2個のR基が連結される場合、MがZrであると、前記2個のR基はブタジエン基を形成せず、
    各Rは、メチル、エチル、プロピル、ブチル、ペンチル、ヘキシルおよびこれらの異性体からなる群から独立して選択され、
    各Rは水素であり、
    各Rは、水素、メチル、エチル、プロピル、ブチル、ペンチル、ヘキシルおよびこれらの異性体からなる群から独立して選択され、
    各Rは、水素、ヒドロカルビル、置換ヒドロカルビルおよび官能基からなる群から独立して選択され、2個のR基は連結して環を形成してもよく、RとRとは連結して環を形成してもよく、RとR16とは連結して環を形成してもよく、RとR11とは連結して環を形成してもよく、
    cは0か1または2であり、
    10は−M(R16−であり、式中、MはB、Al、N、P、SiまたはGeであり、hはMの原子価が満たされるような整数1か2であり、R16は、水素、ヒドロカルビル、置換ヒドロカルビルまたは官能基であり、2個のR16基は連結して環を形成してもよく、
    dは0か1または2であり、
    11は、水素、ヒドロカルビル、置換ヒドロカルビルおよび官能基からなる群から独立して選択され、2個のR11基は結合して環を形成してもよく。R11とRとは連結して環を形成してもよく。R11とR16とは連結して環を形成してもよく、
    eは0か1または2であり、
    式中、c,dおよびeの和は1か2または3である、
    組成物。
  2. 前記組成物が、下記化学式の一つにより表され、
    Figure 2008505932
    式中、Meはメチルであり、Hfはハフニウムであり、Phはフェニルであり、Siは珪素である請求項1の組成物。
JP2007520591A 2004-07-08 2005-07-08 オレフィン重合触媒系およびその使用方法 Expired - Fee Related JP4988568B2 (ja)

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US58646504P 2004-07-08 2004-07-08
US60/586,465 2004-07-08
PCT/US2005/024708 WO2006010139A2 (en) 2004-07-08 2005-07-08 Olefin polymerization catalyst system and process for use thereof

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JP2008505932A JP2008505932A (ja) 2008-02-28
JP2008505932A5 true JP2008505932A5 (ja) 2008-08-28
JP4988568B2 JP4988568B2 (ja) 2012-08-01

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JP2007520591A Expired - Fee Related JP4988568B2 (ja) 2004-07-08 2005-07-08 オレフィン重合触媒系およびその使用方法
JP2007520528A Expired - Fee Related JP5268087B2 (ja) 2004-07-08 2005-07-08 超臨界条件におけるポリマー製造

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US (2) US7601666B2 (ja)
EP (2) EP1765841B1 (ja)
JP (2) JP4988568B2 (ja)
KR (1) KR20070039930A (ja)
CN (2) CN101010705B (ja)
BR (1) BRPI0513057A (ja)
CA (1) CA2576840A1 (ja)
DE (1) DE602005010255D1 (ja)
WO (2) WO2006010139A2 (ja)

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