JP2005520923A5 - - Google Patents
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- Publication number
- JP2005520923A5 JP2005520923A5 JP2003579294A JP2003579294A JP2005520923A5 JP 2005520923 A5 JP2005520923 A5 JP 2005520923A5 JP 2003579294 A JP2003579294 A JP 2003579294A JP 2003579294 A JP2003579294 A JP 2003579294A JP 2005520923 A5 JP2005520923 A5 JP 2005520923A5
- Authority
- JP
- Japan
- Prior art keywords
- degree
- carbon atoms
- alkyl group
- aqueous dispersion
- hydrolysis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000006185 dispersion Substances 0.000 claims 6
- 125000000217 alkyl group Chemical group 0.000 claims 5
- 125000004432 carbon atoms Chemical group C* 0.000 claims 5
- 239000004372 Polyvinyl alcohol Substances 0.000 claims 4
- 239000000654 additive Substances 0.000 claims 4
- 238000006460 hydrolysis reaction Methods 0.000 claims 4
- 238000006116 polymerization reaction Methods 0.000 claims 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims 3
- 150000001875 compounds Chemical class 0.000 claims 2
- 125000004435 hydrogen atoms Chemical group [H]* 0.000 claims 2
- 239000008346 aqueous phase Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 claims 1
Claims (4)
- ａ）式
Ｒ1及びＲ2の一方は、互いに独立して、水素原子又は炭素原子数１ないし４のアルキル基を表わし、他方は炭素原子数３ないし４のアルキル基を表わし；
ｘは０（直接結合）、又は１ないし３の数を表わし；及び
Ｒ3は炭素原子数８ないし２２のアルキル基を表わすか；又は部分式
Ｒ1’及びＲ2’の一方は、互いに独立して、水素原子又は炭素原子数１ないし４のアルキル基を表わし、他方は炭素原子数３ないし４のアルキル基を表わし；
ｘは０（直接結合）、又は１ないし３の数を表わし；及び
ｙは２ないし６の数を表わす。）で表わされる基を表わす。］で表わされる化合物；
ｂ）約５００ないし２５００の重合度、及び約７０．０ないし９９．９％の加水分解度を有するポリビニルアルコール；及び、所望により、更なる添加剤；及び、
ｃ）水
からなる水性分散液。 - ａ）１．０ないし８０．０（重量）％の前記式（Ｉ）で表わされる化合物；
ｂ）０．１ないし１０．０％の、約５００ないし２５００の重合度及び約７０．０ないし９９．９％の加水分解度を有するポリビニルアルコール；及び、所望により、更なる添加剤；及び、
ｃ）１００．０重量％とするための残部としての水
からなる請求項１記載の水性分散液。 - ａ）オクタデシル−３−（３，５−ジ−第三ブチル−４−ヒドロキシフェニル）−プロピオネート；
ｂ）約５００ないし２５００の重合度及び約７９．０ないし９４．０％の加水分解度を有するポリビニルアルコール；及び、所望により、更なる添加剤；及び、
ｃ）１００．０重量％とするための残部としての水
からなる請求項１記載の水性分散液。 - 前記化合物（Ｉ）の溶融相を、約５００ないし２５００の重合度及び約７０．０ないし９９．９％の加水分解度を有するポリビニルアルコール；及び、所望により、更なる添加剤が存在する水相中に分散させることを特徴とする、請求項１記載の水性分散液の製造方法。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02405218 | 2002-03-21 | ||
| PCT/EP2003/002619 WO2003081690A2 (en) | 2002-03-21 | 2003-03-13 | Aqueous dispersions for antioxidants |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005520923A JP2005520923A (ja) | 2005-07-14 |
| JP2005520923A5 true JP2005520923A5 (ja) | 2006-03-30 |
| JP4399776B2 JP4399776B2 (ja) | 2010-01-20 |
Family
ID=28051877
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003579294A Expired - Lifetime JP4399776B2 (ja) | 2002-03-21 | 2003-03-13 | 抗酸化剤のための水性分散液 |
Country Status (14)
| Country | Link |
|---|---|
| US (2) | US7205350B2 (ja) |
| EP (1) | EP1485441B2 (ja) |
| JP (1) | JP4399776B2 (ja) |
| KR (1) | KR101057745B1 (ja) |
| CN (1) | CN1290910C (ja) |
| AT (1) | ATE316996T1 (ja) |
| AU (1) | AU2003218751A1 (ja) |
| DE (1) | DE60303438T3 (ja) |
| DK (1) | DK1485441T4 (ja) |
| ES (1) | ES2256724T5 (ja) |
| MX (1) | MXPA04009118A (ja) |
| SI (1) | SI1485441T2 (ja) |
| TW (1) | TWI288775B (ja) |
| WO (1) | WO2003081690A2 (ja) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2500122C (en) * | 2002-10-04 | 2012-12-11 | Ciba Specialty Chemicals Holding Inc. | Aqueous polymer dispersion, preparation and use thereof |
| US20060041087A1 (en) * | 2004-07-23 | 2006-02-23 | Cholli Ashok L | Anti-oxidant macromonomers and polymers and methods of making and using the same |
| WO2006010718A1 (en) * | 2004-07-27 | 2006-02-02 | Ciba Specialty Chemicals Holding Inc. | Process for preparing solid particles of phenolic antioxidants |
| CA2589883A1 (en) * | 2004-12-03 | 2006-06-08 | Polnox Corporation | Synthesis of aniline and phenol-based antioxidant macromonomers and corresponding polymers |
| CA2598703A1 (en) | 2005-02-22 | 2006-08-31 | Polnox Corporation | Nitrogen and hindered phenol containing dual functional macromolecular antioxidants: synthesis , performances and applications |
| EP1866279A2 (en) * | 2005-03-25 | 2007-12-19 | Polnox Corporation | Alkylated and polymeric macromolecular antioxidants and methods of making and using the same |
| WO2007050991A1 (en) * | 2005-10-27 | 2007-05-03 | Polnox Corporation | Stabilized polyolefin compositions |
| US20070106059A1 (en) * | 2005-10-27 | 2007-05-10 | Cholli Ashok L | Macromolecular antioxidants and polymeric macromolecular antioxidants |
| US7705176B2 (en) * | 2005-10-27 | 2010-04-27 | Polnox Corporation | Macromolecular antioxidants based on sterically hindered phenols and phosphites |
| WO2007064843A1 (en) | 2005-12-02 | 2007-06-07 | Polnox Corporation | Lubricant oil compositions |
| US20090038701A1 (en) | 2006-01-17 | 2009-02-12 | Baxter International Inc. | Device, system and method for mixing |
| WO2008005358A2 (en) * | 2006-07-06 | 2008-01-10 | Polnox Corporation | Novel macromolecular antioxidants comprising differing antioxidant moieties: structures, methods of making and using the same |
| US7767853B2 (en) | 2006-10-20 | 2010-08-03 | Polnox Corporation | Antioxidants and methods of making and using the same |
| JP2010534754A (ja) * | 2007-08-01 | 2010-11-11 | ビーエーエスエフ ソシエタス・ヨーロピア | 液状酸化防止剤混合物 |
| JP2011527358A (ja) * | 2008-07-11 | 2011-10-27 | ビーエーエスエフ ソシエタス・ヨーロピア | 安定剤としての貯蔵安定性水性エマルジョンおよび低粘度の液体ブレンド |
| BRPI1015256B1 (pt) * | 2009-04-22 | 2021-02-23 | Franwell, Inc | Sistema rfid usável por usuário acionado por sensor de movimento emídias legíveis por computador |
| EP2464739B1 (en) | 2009-08-14 | 2016-01-13 | Basf Se | Methods in cell cultures, and related inventions, employing certain additives |
| CN101805458B (zh) * | 2010-04-07 | 2012-02-08 | 天津力生化工有限公司 | 乳液型复合抗氧剂的制备方法 |
| CN102344581B (zh) * | 2011-06-14 | 2013-01-16 | 江苏飞亚化学工业有限责任公司 | 一种乳液型低粒径高效抗氧剂的制备方法 |
| US10294423B2 (en) | 2013-11-22 | 2019-05-21 | Polnox Corporation | Macromolecular antioxidants based on dual type moiety per molecule: structures, methods of making and using the same |
| TWI639638B (zh) * | 2014-02-03 | 2018-11-01 | 德商朗盛德意志有限公司 | 安定化橡膠 |
| JP6510178B2 (ja) * | 2014-04-03 | 2019-05-08 | 株式会社クラレ | ポリビニルアルコールフィルムの製造方法 |
| JP2018534415A (ja) | 2015-11-19 | 2018-11-22 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | スチレン−マレイン酸樹脂のアンモニア系イミド含有樹脂カット |
| CN106589456A (zh) * | 2016-12-17 | 2017-04-26 | 大连大学 | 一种高温稳定抗氧化剂乳化液及其制备方法 |
| WO2018160879A2 (en) | 2017-03-01 | 2018-09-07 | Polnox Corporation | Macromolecular corrosion (mcin) inhibitors: structures, methods of making and using the same |
| EP3666835A1 (en) * | 2018-12-14 | 2020-06-17 | Henkel AG & Co. KGaA | Water based dispersion to make coatings with increased mvtr barrier properties out of it |
| CN114478841B (zh) * | 2021-12-29 | 2023-07-14 | 广东希必达新材料科技有限公司 | 一种乳液型悬浮终止液的制备方法及其应用 |
| WO2023202971A1 (en) * | 2022-04-20 | 2023-10-26 | Basf Se | An aqueous antioxidant suspoemulsion and a process for preparing the same |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1366702A (en) | 1971-05-22 | 1974-09-11 | Reynolds R J W | Stabilisation of polymeric materials |
| JPH0788401B2 (ja) † | 1987-03-06 | 1995-09-27 | 信越化学工業株式会社 | 塩化ビニル系重合体の製造方法 |
| US5032632A (en) | 1990-05-15 | 1991-07-16 | E. I. Du Pont De Nemours And Company | Oxidation-resistant ethylene vinyl alcohol polymer compositions |
| SE508224C2 (sv) | 1996-01-18 | 1998-09-14 | Akzo Nobel Ind Coatings Ab | Vattenburen hybridbindemedelskomposition samt användning därav |
| EP0884352B1 (en) * | 1997-06-11 | 2001-09-05 | Kuraray Co., Ltd. | Water-soluble film |
| JPH11349940A (ja) † | 1998-06-11 | 1999-12-21 | Yoshitomi Fine Chemical Kk | 酸化防止剤分散液 |
| JP2000290308A (ja) † | 1999-04-09 | 2000-10-17 | Shin Etsu Chem Co Ltd | 塩化ビニル系重合体の製造方法 |
| EP1085069B1 (en) * | 1999-09-14 | 2004-12-08 | Ricoh Company, Ltd. | Heat activatable adhesive composition and adhesive sheet having adhesive layer thereof |
| EP1127567B1 (de) * | 2000-02-17 | 2010-09-01 | Basf Se | Wässrige Dispersion wasserunlöslicher organischer UV-Filtersubstanzen |
| GB0004436D0 (en) * | 2000-02-25 | 2000-04-12 | Clariant Int Ltd | Synergistic stabilizer compositions for thermoplastic polymers in prolonged contact with water |
| JP2002308917A (ja) * | 2001-04-17 | 2002-10-23 | Shin Etsu Chem Co Ltd | ビニル系重合体の製造方法 |
-
2003
- 2003-03-13 MX MXPA04009118A patent/MXPA04009118A/es active IP Right Grant
- 2003-03-13 DE DE60303438T patent/DE60303438T3/de not_active Expired - Lifetime
- 2003-03-13 AT AT03712000T patent/ATE316996T1/de active
- 2003-03-13 EP EP03712000A patent/EP1485441B2/en not_active Expired - Lifetime
- 2003-03-13 DK DK03712000T patent/DK1485441T4/da active
- 2003-03-13 AU AU2003218751A patent/AU2003218751A1/en not_active Abandoned
- 2003-03-13 WO PCT/EP2003/002619 patent/WO2003081690A2/en active IP Right Grant
- 2003-03-13 CN CNB038065517A patent/CN1290910C/zh not_active Expired - Lifetime
- 2003-03-13 KR KR1020047014804A patent/KR101057745B1/ko active IP Right Grant
- 2003-03-13 SI SI200330188T patent/SI1485441T2/sl unknown
- 2003-03-13 ES ES03712000T patent/ES2256724T5/es not_active Expired - Lifetime
- 2003-03-13 US US10/508,443 patent/US7205350B2/en not_active Expired - Lifetime
- 2003-03-13 JP JP2003579294A patent/JP4399776B2/ja not_active Expired - Lifetime
- 2003-03-19 TW TW092106011A patent/TWI288775B/zh not_active IP Right Cessation
-
2006
- 2006-03-23 US US11/387,358 patent/US7323505B2/en not_active Expired - Lifetime