JP2006332190A - カルコパイライト型太陽電池 - Google Patents
カルコパイライト型太陽電池 Download PDFInfo
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- JP2006332190A JP2006332190A JP2005151152A JP2005151152A JP2006332190A JP 2006332190 A JP2006332190 A JP 2006332190A JP 2005151152 A JP2005151152 A JP 2005151152A JP 2005151152 A JP2005151152 A JP 2005151152A JP 2006332190 A JP2006332190 A JP 2006332190A
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- 229910052951 chalcopyrite Inorganic materials 0.000 title claims abstract description 47
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 239000000758 substrate Substances 0.000 claims abstract description 68
- 239000010445 mica Substances 0.000 claims abstract description 56
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 56
- 230000031700 light absorption Effects 0.000 claims description 32
- 239000011230 binding agent Substances 0.000 claims description 15
- 150000004767 nitrides Chemical class 0.000 claims description 6
- -1 chalcopyrite compound Chemical class 0.000 claims description 4
- 230000000149 penetrating effect Effects 0.000 abstract description 3
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 157
- 239000010408 film Substances 0.000 description 16
- 238000000034 method Methods 0.000 description 16
- 230000008569 process Effects 0.000 description 14
- 239000011521 glass Substances 0.000 description 13
- 239000002243 precursor Substances 0.000 description 10
- 238000004544 sputter deposition Methods 0.000 description 9
- 230000015572 biosynthetic process Effects 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 238000005452 bending Methods 0.000 description 7
- 239000000919 ceramic Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 230000002093 peripheral effect Effects 0.000 description 7
- 239000011669 selenium Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000009499 grossing Methods 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- 238000000137 annealing Methods 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 238000000224 chemical solution deposition Methods 0.000 description 3
- 238000003475 lamination Methods 0.000 description 3
- 239000005361 soda-lime glass Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 229910052733 gallium Inorganic materials 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- 229920006254 polymer film Polymers 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 239000011241 protective layer Substances 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910001868 water Inorganic materials 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910015475 FeF 2 Inorganic materials 0.000 description 1
- 240000002329 Inga feuillei Species 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012212 insulator Substances 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000010297 mechanical methods and process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052711 selenium Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/0445—PV modules or arrays of single PV cells including thin film solar cells, e.g. single thin film a-Si, CIS or CdTe solar cells
- H01L31/046—PV modules composed of a plurality of thin film solar cells deposited on the same substrate
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/0248—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies
- H01L31/036—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes
- H01L31/0392—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes including thin films deposited on metallic or insulating substrates ; characterised by specific substrate materials or substrate features or by the presence of intermediate layers, e.g. barrier layers, on the substrate
- H01L31/03926—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes including thin films deposited on metallic or insulating substrates ; characterised by specific substrate materials or substrate features or by the presence of intermediate layers, e.g. barrier layers, on the substrate comprising a flexible substrate
- H01L31/03928—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by their semiconductor bodies characterised by their crystalline structure or particular orientation of the crystalline planes including thin films deposited on metallic or insulating substrates ; characterised by specific substrate materials or substrate features or by the presence of intermediate layers, e.g. barrier layers, on the substrate comprising a flexible substrate including AIBIIICVI compound, e.g. CIS, CIGS deposited on metal or polymer foils
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/042—PV modules or arrays of single PV cells
- H01L31/0445—PV modules or arrays of single PV cells including thin film solar cells, e.g. single thin film a-Si, CIS or CdTe solar cells
- H01L31/046—PV modules composed of a plurality of thin film solar cells deposited on the same substrate
- H01L31/0465—PV modules composed of a plurality of thin film solar cells deposited on the same substrate comprising particular structures for the electrical interconnection of adjacent PV cells in the module
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/04—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices
- H01L31/06—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers
- H01L31/072—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers the potential barriers being only of the PN heterojunction type
- H01L31/0749—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof adapted as photovoltaic [PV] conversion devices characterised by potential barriers the potential barriers being only of the PN heterojunction type including a AIBIIICVI compound, e.g. CdS/CulnSe2 [CIS] heterojunction solar cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
- Y02E10/541—CuInSe2 material PV cells
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
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- Crystallography & Structural Chemistry (AREA)
- Photovoltaic Devices (AREA)
Abstract
【解決手段】マイカ基板54上に第1電極層14を成膜した後、第1スクライブ部64を設ける。次に、第1電極層14上に光吸収層16、バッファ層18を設け、バッファ層18の上端面からマイカ基板54の下端面まで貫通するスルーホール(第2スクライブ部66)を点状に形成する。次に、バッファ層18上に第2電極層20を設ける。この際、第2電極層20の下端面が第2スクライブ部66の内周壁に沿って第1電極層14まで到達する。さらに、第2電極層20をスクライブして第3スクライブ部70を設ける。
【選択図】図2
Description
前記第1電極層を線状に分割する第1スクライブ部と、前記絶縁基板から前記第2電極層の直下に位置する層までを貫通するスルーホールからなる第2スクライブ部と、前記第2電極層を分割する第3スクライブ部とが設けられることによって単位セルに分割され、
前記第2電極層の下端面に、前記第2スクライブ部の内壁に沿って第1電極層に到達するまで延在する部位が存在することにより、互いに隣接する単位セルの第1電極層と第2電極層とが電気的に接続されたことを特徴とする。
14…第1電極層 16…光吸収層
18…バッファ層 20…第2電極層
30…レーザ照射 31…パンチ
32…金属針 52…単位セル
54…マイカ基板 56…バインダ層
64…第1スクライブ部 66…第2スクライブ部
68…垂下部 70…第3スクライブ部
72…直線部 74…湾曲部
Claims (2)
- マイカを含む絶縁基板上に、少なくとも、窒化物を含むバインダ層と、第1電極層と、カルコパイライト化合物からなるP型光吸収層と、バッファ層と、透明且つn型である第2電極層とが積層され、
前記第1電極層を線状に分割する第1スクライブ部と、前記絶縁基板から前記第2電極層の直下に位置する層までを貫通するスルーホールからなる第2スクライブ部と、前記第2電極層を分割する第3スクライブ部とが設けられることによって単位セルに分割され、
前記第2電極層の下端面に、前記第2スクライブ部の内壁に沿って第1電極層に到達するまで延在する部位が存在することにより、互いに隣接する単位セルの第1電極層と第2電極層とが電気的に接続されたことを特徴とするカルコパイライト型太陽電池。 - 請求項1記載のカルコパイライト型太陽電池において、前記第3スクライブ部が直線部と湾曲部とを有し、前記直線部が前記第1スクライブ部に平行して設けられ、且つ前記湾曲部が前記第1スクライブ部とともに前記第2スクライブ部を囲繞する位置に設けられたことを特徴とするカルコパイライト型太陽電池。
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005151152A JP4681352B2 (ja) | 2005-05-24 | 2005-05-24 | カルコパイライト型太陽電池 |
PCT/JP2006/310361 WO2006126590A1 (ja) | 2005-05-24 | 2006-05-24 | カルコパイライト型太陽電池 |
US11/718,434 US7964791B2 (en) | 2005-05-24 | 2006-05-24 | Chalcopyrite type solar cell |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2005151152A JP4681352B2 (ja) | 2005-05-24 | 2005-05-24 | カルコパイライト型太陽電池 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2006332190A true JP2006332190A (ja) | 2006-12-07 |
JP4681352B2 JP4681352B2 (ja) | 2011-05-11 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2005151152A Expired - Fee Related JP4681352B2 (ja) | 2005-05-24 | 2005-05-24 | カルコパイライト型太陽電池 |
Country Status (3)
Country | Link |
---|---|
US (1) | US7964791B2 (ja) |
JP (1) | JP4681352B2 (ja) |
WO (1) | WO2006126590A1 (ja) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2009110093A1 (ja) * | 2008-03-07 | 2009-09-11 | 昭和シェル石油株式会社 | Cis系太陽電池の集積構造 |
WO2011149008A1 (ja) * | 2010-05-27 | 2011-12-01 | 京セラ株式会社 | 光電変換装置および光電変換装置の製造方法 |
KR101295547B1 (ko) | 2009-10-07 | 2013-08-12 | 엘지전자 주식회사 | 박막 태양 전지 모듈 및 그 제조 방법 |
US8703525B2 (en) | 2009-09-24 | 2014-04-22 | Samsung Sdi Co., Ltd. | Solar cell and manufacturing method thereof |
JP2014530498A (ja) * | 2011-09-19 | 2014-11-17 | サン−ゴバングラス フランスSaint−Gobain Glass France | 直列接続部を含む薄膜ソーラーモジュール、及び、複数の薄膜ソーラーセルを直列接続する方法 |
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JP4969785B2 (ja) * | 2005-02-16 | 2012-07-04 | 本田技研工業株式会社 | カルコパイライト型太陽電池及びその製造方法 |
JP4620105B2 (ja) * | 2007-11-30 | 2011-01-26 | 昭和シェル石油株式会社 | Cis系薄膜太陽電池の光吸収層の製造方法 |
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TWI504002B (zh) * | 2009-06-05 | 2015-10-11 | Semiconductor Energy Lab | 光電轉換裝置 |
US20120006389A1 (en) * | 2009-06-29 | 2012-01-12 | Kyocera Corporation | Method of Manufacturing Photoelectric Conversion Device, Apparatus for Manufacturing Photoelectric Conversion Device, and Photoelectric Conversion Device |
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US8580389B2 (en) | 2010-07-21 | 2013-11-12 | E. I. Dupont De Nemours And Company | Articles comprising phyllosilicate composites containing mica |
KR101173401B1 (ko) * | 2011-01-24 | 2012-08-10 | 엘지이노텍 주식회사 | 태양전지 및 그의 제조방법 |
FR2979752B1 (fr) * | 2011-09-02 | 2016-03-11 | Commissariat Energie Atomique | Dispositif photovoltaique non plan |
KR101332297B1 (ko) * | 2011-11-24 | 2013-11-22 | 인텔렉추얼디스커버리 주식회사 | 탄뎀형 집적 광기전력 모듈 및 이의 제조방법 |
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Also Published As
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US7964791B2 (en) | 2011-06-21 |
WO2006126590A1 (ja) | 2006-11-30 |
JP4681352B2 (ja) | 2011-05-11 |
US20090065060A1 (en) | 2009-03-12 |
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