JP2005530914A5 - - Google Patents
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- Publication number
- JP2005530914A5 JP2005530914A5 JP2004530897A JP2004530897A JP2005530914A5 JP 2005530914 A5 JP2005530914 A5 JP 2005530914A5 JP 2004530897 A JP2004530897 A JP 2004530897A JP 2004530897 A JP2004530897 A JP 2004530897A JP 2005530914 A5 JP2005530914 A5 JP 2005530914A5
- Authority
- JP
- Japan
- Prior art keywords
- organic
- deactivator
- series
- process according
- ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 14
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 9
- 239000003054 catalyst Substances 0.000 claims description 8
- 230000009849 deactivation Effects 0.000 claims description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 238000010791 quenching Methods 0.000 claims description 5
- 230000000171 quenching effect Effects 0.000 claims description 5
- 229920001748 polybutylene Polymers 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 239000011954 Ziegler–Natta catalyst Substances 0.000 claims description 2
- 239000012190 activator Substances 0.000 claims description 2
- -1 aluminum alkyl compound Chemical class 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 239000011949 solid catalyst Substances 0.000 claims description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 3
- 239000012429 reaction media Substances 0.000 claims 3
- 239000004711 α-olefin Substances 0.000 claims 3
- 239000007791 liquid phase Substances 0.000 claims 2
- 125000004169 (C1-C6) alkyl group Chemical group 0.000 claims 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims 1
- 230000000379 polymerizing effect Effects 0.000 claims 1
- 238000003756 stirring Methods 0.000 claims 1
- 150000003623 transition metal compounds Chemical class 0.000 claims 1
- 239000000178 monomer Substances 0.000 description 6
- 238000006116 polymerization reaction Methods 0.000 description 5
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 229920001083 polybutene Polymers 0.000 description 3
- 238000011084 recovery Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000002902 bimodal effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000008246 gaseous mixture Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 238000012667 polymer degradation Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP02077543 | 2002-06-24 | ||
| US40819602P | 2002-09-04 | 2002-09-04 | |
| PCT/EP2003/006348 WO2004000895A1 (en) | 2002-06-24 | 2003-06-17 | Liquid phase process for the polymerization of alpha-olefins |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005530914A JP2005530914A (ja) | 2005-10-13 |
| JP2005530914A5 true JP2005530914A5 (enExample) | 2009-11-12 |
| JP4498925B2 JP4498925B2 (ja) | 2010-07-07 |
Family
ID=43969229
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004530897A Expired - Fee Related JP4498925B2 (ja) | 2002-06-24 | 2003-06-17 | α−オレフィンの重合のための液相法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7160964B2 (enExample) |
| EP (1) | EP1515998B1 (enExample) |
| JP (1) | JP4498925B2 (enExample) |
| KR (1) | KR100992799B1 (enExample) |
| CN (1) | CN100360571C (enExample) |
| AT (1) | ATE509043T1 (enExample) |
| AU (1) | AU2003246444A1 (enExample) |
| WO (1) | WO2004000895A1 (enExample) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7732551B2 (en) | 2003-06-12 | 2010-06-08 | Basell Poliolefine Italia S.R.L. | Post-treatment for polymer pellets |
| US7414095B2 (en) * | 2003-12-11 | 2008-08-19 | Basell Polioefine Italia S.R.L. | Liquid phase process for polymerizing olefins |
| RU2358988C2 (ru) * | 2003-12-19 | 2009-06-20 | Базелль Полиолефине Гмбх | Способ (со)полимеризации этилена |
| JP4790627B2 (ja) | 2003-12-19 | 2011-10-12 | バーゼル・ポリオレフィン・ゲーエムベーハー | エチレン（コ）ポリマーの製造方法 |
| US8026311B2 (en) * | 2005-03-25 | 2011-09-27 | Braskem America, Inc. | Process for production of propylene copolymers |
| WO2006131450A1 (en) * | 2005-06-07 | 2006-12-14 | Basell Poliolefine Italia S.R.L. | Polyolefin nanocomposites materials |
| WO2007014842A1 (en) * | 2005-07-27 | 2007-02-08 | Basell Poliolefine Italia S.R.L. | Polymerization process for preparing polyolefins |
| US7446167B2 (en) | 2006-04-13 | 2008-11-04 | Fina Technology, Inc. | Catalyst deactivation agents and methods for use of same |
| CN101522732B (zh) * | 2006-08-08 | 2012-06-13 | 巴塞尔聚烯烃意大利有限责任公司 | 1-丁烯共聚物 |
| KR101497726B1 (ko) * | 2007-04-27 | 2015-03-02 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 부텐-１ 삼원중합체 및 이의 제조 방법 |
| US7879958B2 (en) * | 2007-08-07 | 2011-02-01 | Bridgestone Corporation | Polyhydroxy compounds as polymerization quenching agents |
| US9676920B2 (en) | 2007-11-27 | 2017-06-13 | Basell Poliolefine Italia S.R.L. | Polyolefin nanocomposites materials |
| EP2072540A1 (en) * | 2007-12-20 | 2009-06-24 | Basell Poliolefine Italia S.r.l. | Solution polymerization process for preparing polyolefins |
| EP2264003B1 (en) | 2008-03-14 | 2016-06-01 | Dia-Nitrix Co., Ltd. | Method for stabilization of aqueous acrylamide solution |
| US8748522B2 (en) | 2008-11-25 | 2014-06-10 | Basell Poliolefine Italia S.R.L. | Solution process for the olefins polymerization |
| KR101123154B1 (ko) * | 2008-12-03 | 2012-03-19 | 주식회사 엘지화학 | 전이금속 촉매의 비활성화제 및 이를 이용한 촉매의 비활성화 방법 |
| WO2013095720A1 (en) * | 2011-12-22 | 2013-06-27 | Exxonmobil Chemical Patents Inc. | Methods and apparatus for deactivating a catalyst composition |
| WO2013183600A1 (ja) * | 2012-06-04 | 2013-12-12 | 出光興産株式会社 | 粘接着剤組成物及びこれを用いた粘着テープ |
| CN105622813B (zh) * | 2016-04-06 | 2018-01-26 | 辽宁方大工程设计有限公司 | 用于聚氯乙烯种子法糊树脂的生产装置及其生产工艺 |
| US10450392B2 (en) | 2016-07-29 | 2019-10-22 | Exxonmobil Chemical Patents Inc. | Polymerization processes using high molecular weight polyhydric quenching agents |
| CN110894249A (zh) * | 2018-09-12 | 2020-03-20 | 中国石油化工股份有限公司 | 一种丁烯-1的均相聚合方法及装置 |
| KR102351986B1 (ko) * | 2019-01-18 | 2022-01-18 | 주식회사 엘지화학 | 폴리부텐의 분리방법 |
| CN114630844B (zh) * | 2019-11-18 | 2023-06-02 | 巴塞尔聚烯烃意大利有限公司 | 连续溶液聚合方法 |
| EP4263636A1 (en) | 2020-12-16 | 2023-10-25 | Basell Poliolefine Italia S.r.l. | Flexible butene-1 copolymer for pipes |
| CN114316104B (zh) * | 2022-01-07 | 2023-12-19 | 万华化学集团股份有限公司 | 一种烯烃聚合催化剂的减活化方法 |
| CN115608276B (zh) * | 2022-11-15 | 2025-11-21 | 国家能源集团宁夏煤业有限责任公司 | 连续生产聚α-烯烃的系统及方法 |
| CN116655841B (zh) * | 2023-06-06 | 2024-04-19 | 中国石油天然气股份有限公司 | 一种连续溶液聚合方法及系统 |
| CN116715788B (zh) * | 2023-08-09 | 2023-12-01 | 山东东方宏业化工有限公司 | 一种宽分子量分布的聚丁烯-1合成方法 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3356666A (en) | 1963-08-27 | 1967-12-05 | Allied Chem | Process of polymerizing butene-1 |
| GB1051679A (enExample) * | 1964-06-15 | |||
| IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
| JPS5922910A (ja) * | 1982-07-29 | 1984-02-06 | Sumitomo Chem Co Ltd | エチレン重合体またはエチレン共重合体の製造方法 |
| JPS6153307A (ja) * | 1984-08-23 | 1986-03-17 | Chisso Corp | α−オレフインの連続スラリ−重合法 |
| EP0172961B1 (en) * | 1984-08-30 | 1988-10-19 | Mitsui Petrochemical Industries, Ltd. | 1-butene polymer and its use |
| JPS61159404A (ja) * | 1985-01-07 | 1986-07-19 | Mitsui Toatsu Chem Inc | ポリオレフインの精製方法 |
| US4634744A (en) * | 1985-01-09 | 1987-01-06 | Chemplex Company | Method of catalyst deactivation |
| JPS61166802A (ja) * | 1985-01-18 | 1986-07-28 | Mitsui Toatsu Chem Inc | 希釈剤の回収方法 |
| JPS62116618A (ja) * | 1985-11-15 | 1987-05-28 | Chisso Corp | プロピレン−エチレンブロツク共重合体の連続製造法 |
| US4701489A (en) * | 1986-09-08 | 1987-10-20 | El Paso Products Company | Process for the production of stable noncorrosive amorphous polyalphaolefins |
| US5118757A (en) * | 1990-03-26 | 1992-06-02 | Shell Oil Company | Polymer production |
| JPH06128302A (ja) * | 1992-10-19 | 1994-05-10 | Idemitsu Petrochem Co Ltd | オレフィン系重合体の製造方法 |
| US5442019A (en) * | 1994-03-25 | 1995-08-15 | Exxon Chemical Company | Process for transitioning between incompatible polymerization catalysts |
| JPH1171421A (ja) * | 1997-07-03 | 1999-03-16 | Sumitomo Chem Co Ltd | オレフィン重合用固体触媒成分、オレフィン重合用触媒、及びオレフィン系重合体の製造方法 |
-
2003
- 2003-06-17 JP JP2004530897A patent/JP4498925B2/ja not_active Expired - Fee Related
- 2003-06-17 AU AU2003246444A patent/AU2003246444A1/en not_active Abandoned
- 2003-06-17 US US10/518,885 patent/US7160964B2/en not_active Expired - Fee Related
- 2003-06-17 AT AT03760626T patent/ATE509043T1/de not_active IP Right Cessation
- 2003-06-17 CN CNB038141981A patent/CN100360571C/zh not_active Expired - Fee Related
- 2003-06-17 WO PCT/EP2003/006348 patent/WO2004000895A1/en not_active Ceased
- 2003-06-17 KR KR1020047020992A patent/KR100992799B1/ko not_active Expired - Fee Related
- 2003-06-17 EP EP03760626A patent/EP1515998B1/en not_active Expired - Lifetime
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