CN100360571C - α-烯烃聚合的液相法 - Google Patents

α-烯烃聚合的液相法 Download PDF

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Publication number
CN100360571C
CN100360571C CNB038141981A CN03814198A CN100360571C CN 100360571 C CN100360571 C CN 100360571C CN B038141981 A CNB038141981 A CN B038141981A CN 03814198 A CN03814198 A CN 03814198A CN 100360571 C CN100360571 C CN 100360571C
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CN
China
Prior art keywords
butene
deactivator
polymerization
polybutene
solution
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CNB038141981A
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English (en)
Chinese (zh)
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CN1662565A (zh
Inventor
D·比加维
G·梅
N·阿里奇德菲内蒂
G·彭佐
G·维塔尔
M·科维兹
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Basell Technology Co BV
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Basell Technology Co BV
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/42—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using short-stopping agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/903—Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CNB038141981A 2002-06-24 2003-06-17 α-烯烃聚合的液相法 Expired - Fee Related CN100360571C (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP02077543.3 2002-06-24
EP02077543 2002-06-24
US40819602P 2002-09-04 2002-09-04
US60/408,196 2002-09-04
PCT/EP2003/006348 WO2004000895A1 (en) 2002-06-24 2003-06-17 Liquid phase process for the polymerization of alpha-olefins

Publications (2)

Publication Number Publication Date
CN1662565A CN1662565A (zh) 2005-08-31
CN100360571C true CN100360571C (zh) 2008-01-09

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Family Applications (1)

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CNB038141981A Expired - Fee Related CN100360571C (zh) 2002-06-24 2003-06-17 α-烯烃聚合的液相法

Country Status (8)

Country Link
US (1) US7160964B2 (enExample)
EP (1) EP1515998B1 (enExample)
JP (1) JP4498925B2 (enExample)
KR (1) KR100992799B1 (enExample)
CN (1) CN100360571C (enExample)
AT (1) ATE509043T1 (enExample)
AU (1) AU2003246444A1 (enExample)
WO (1) WO2004000895A1 (enExample)

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CN100410297C (zh) 2003-06-12 2008-08-13 巴塞尔聚烯烃意大利有限责任公司 聚合物颗粒的后处理
US7414095B2 (en) * 2003-12-11 2008-08-19 Basell Polioefine Italia S.R.L. Liquid phase process for polymerizing olefins
RU2358988C2 (ru) * 2003-12-19 2009-06-20 Базелль Полиолефине Гмбх Способ (со)полимеризации этилена
KR101359287B1 (ko) * 2003-12-19 2014-02-10 바젤 폴리올레핀 게엠베하 에틸렌의 (공)중합 방법
US8026311B2 (en) * 2005-03-25 2011-09-27 Braskem America, Inc. Process for production of propylene copolymers
JP2008542511A (ja) * 2005-06-07 2008-11-27 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ ポリオレフィンナノコンポジット材料
CA2616681A1 (en) * 2005-07-27 2007-02-08 Basell Poliolefine Italia S.R.L. Polymerization process for preparing polyolefins
US7446167B2 (en) 2006-04-13 2008-11-04 Fina Technology, Inc. Catalyst deactivation agents and methods for use of same
CN101522732B (zh) * 2006-08-08 2012-06-13 巴塞尔聚烯烃意大利有限责任公司 1-丁烯共聚物
ATE482982T1 (de) * 2007-04-27 2010-10-15 Basell Poliolefine Srl Buten-1-terpolymere und herstellungsverfahren dafür
US7879958B2 (en) * 2007-08-07 2011-02-01 Bridgestone Corporation Polyhydroxy compounds as polymerization quenching agents
CN101878256A (zh) 2007-11-27 2010-11-03 巴塞尔聚烯烃意大利有限责任公司 聚烯烃纳米复合材料
EP2072540A1 (en) * 2007-12-20 2009-06-24 Basell Poliolefine Italia S.r.l. Solution polymerization process for preparing polyolefins
JP5659489B2 (ja) 2008-03-14 2015-01-28 三菱レイヨン株式会社 アクリルアミド水溶液の安定化方法
WO2010060799A1 (en) * 2008-11-25 2010-06-03 Basell Poliolefine Italia S.R.L. Solution process for the olefins polymerization
KR101123154B1 (ko) * 2008-12-03 2012-03-19 주식회사 엘지화학 전이금속 촉매의 비활성화제 및 이를 이용한 촉매의 비활성화 방법
WO2013095720A1 (en) * 2011-12-22 2013-06-27 Exxonmobil Chemical Patents Inc. Methods and apparatus for deactivating a catalyst composition
WO2013183600A1 (ja) * 2012-06-04 2013-12-12 出光興産株式会社 粘接着剤組成物及びこれを用いた粘着テープ
CN105622813B (zh) * 2016-04-06 2018-01-26 辽宁方大工程设计有限公司 用于聚氯乙烯种子法糊树脂的生产装置及其生产工艺
US10450392B2 (en) 2016-07-29 2019-10-22 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
CN110894249A (zh) * 2018-09-12 2020-03-20 中国石油化工股份有限公司 一种丁烯-1的均相聚合方法及装置
KR102351986B1 (ko) * 2019-01-18 2022-01-18 주식회사 엘지화학 폴리부텐의 분리방법
US12312425B2 (en) 2019-11-18 2025-05-27 Basell Poliolefine Italia S.R.L. Continuous solution polymerization process
JP7700241B2 (ja) 2020-12-16 2025-06-30 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ パイプ用軟質ブテン－１コポリマー
CN114316104B (zh) * 2022-01-07 2023-12-19 万华化学集团股份有限公司 一种烯烃聚合催化剂的减活化方法
CN115608276B (zh) * 2022-11-15 2025-11-21 国家能源集团宁夏煤业有限责任公司 连续生产聚α-烯烃的系统及方法
CN116655841B (zh) * 2023-06-06 2024-04-19 中国石油天然气股份有限公司 一种连续溶液聚合方法及系统
CN116715788B (zh) * 2023-08-09 2023-12-01 山东东方宏业化工有限公司 一种宽分子量分布的聚丁烯-1合成方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1645282A1 (de) * 1964-06-15 1970-07-16 Mobil Oil Corp Verfahren zum Abtrennen eines Polymerisats eines 1-Olefins mit 4 bis 10 Kohlenstoffatomen aus einer Loesung in seinem fluessigen 1-Olefinmonomer
EP0172961A1 (en) * 1984-08-30 1986-03-05 Mitsui Petrochemical Industries, Ltd. 1-Butene polymer and its use
EP0225099A2 (en) * 1985-11-15 1987-06-10 Chisso Corporation Process for continuously producing a propylene-ethylene block copolymer
CN87106011A (zh) * 1986-09-08 1988-07-06 埃尔·帕索产品公司 生产稳定无腐蚀性的无定形聚α-烯烃的工艺方法
CN1157000A (zh) * 1994-03-25 1997-08-13 埃克森化学专利公司 不相容的聚合催化剂之间的转换方法

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US3356666A (en) 1963-08-27 1967-12-05 Allied Chem Process of polymerizing butene-1
IT1098272B (it) * 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
JPS5922910A (ja) * 1982-07-29 1984-02-06 Sumitomo Chem Co Ltd エチレン重合体またはエチレン共重合体の製造方法
JPS6153307A (ja) * 1984-08-23 1986-03-17 Chisso Corp α−オレフインの連続スラリ−重合法
JPS61159404A (ja) * 1985-01-07 1986-07-19 Mitsui Toatsu Chem Inc ポリオレフインの精製方法
US4634744A (en) * 1985-01-09 1987-01-06 Chemplex Company Method of catalyst deactivation
JPS61166802A (ja) * 1985-01-18 1986-07-28 Mitsui Toatsu Chem Inc 希釈剤の回収方法
US5118757A (en) * 1990-03-26 1992-06-02 Shell Oil Company Polymer production
JPH06128302A (ja) * 1992-10-19 1994-05-10 Idemitsu Petrochem Co Ltd オレフィン系重合体の製造方法
JPH1171421A (ja) * 1997-07-03 1999-03-16 Sumitomo Chem Co Ltd オレフィン重合用固体触媒成分、オレフィン重合用触媒、及びオレフィン系重合体の製造方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1645282A1 (de) * 1964-06-15 1970-07-16 Mobil Oil Corp Verfahren zum Abtrennen eines Polymerisats eines 1-Olefins mit 4 bis 10 Kohlenstoffatomen aus einer Loesung in seinem fluessigen 1-Olefinmonomer
EP0172961A1 (en) * 1984-08-30 1986-03-05 Mitsui Petrochemical Industries, Ltd. 1-Butene polymer and its use
EP0225099A2 (en) * 1985-11-15 1987-06-10 Chisso Corporation Process for continuously producing a propylene-ethylene block copolymer
CN87106011A (zh) * 1986-09-08 1988-07-06 埃尔·帕索产品公司 生产稳定无腐蚀性的无定形聚α-烯烃的工艺方法
CN1157000A (zh) * 1994-03-25 1997-08-13 埃克森化学专利公司 不相容的聚合催化剂之间的转换方法

Also Published As

Publication number Publication date
JP4498925B2 (ja) 2010-07-07
AU2003246444A1 (en) 2004-01-06
KR100992799B1 (ko) 2010-11-08
EP1515998A1 (en) 2005-03-23
EP1515998B1 (en) 2011-05-11
JP2005530914A (ja) 2005-10-13
ATE509043T1 (de) 2011-05-15
WO2004000895A1 (en) 2003-12-31
US20050250917A1 (en) 2005-11-10
KR20050016627A (ko) 2005-02-21
CN1662565A (zh) 2005-08-31
US7160964B2 (en) 2007-01-09

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Termination date: 20130617