JP2005511806A5 - - Google Patents
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- Publication number
- JP2005511806A5 JP2005511806A5 JP2003549406A JP2003549406A JP2005511806A5 JP 2005511806 A5 JP2005511806 A5 JP 2005511806A5 JP 2003549406 A JP2003549406 A JP 2003549406A JP 2003549406 A JP2003549406 A JP 2003549406A JP 2005511806 A5 JP2005511806 A5 JP 2005511806A5
- Authority
- JP
- Japan
- Prior art keywords
- butadiene
- isoprene
- random copolymer
- copolymer
- catalyst system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 53
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims 51
- 238000000034 method Methods 0.000 claims 20
- 229920005604 random copolymer Polymers 0.000 claims 17
- 239000003054 catalyst Substances 0.000 claims 13
- 229920001577 copolymer Polymers 0.000 claims 8
- 229910052761 rare earth metal Inorganic materials 0.000 claims 7
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 6
- 238000004458 analytical method Methods 0.000 claims 6
- -1 alkyl aluminum halide Chemical class 0.000 claims 5
- 239000000178 monomer Substances 0.000 claims 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 4
- 229940100198 alkylating agent Drugs 0.000 claims 4
- 239000002168 alkylating agent Substances 0.000 claims 4
- 230000009477 glass transition Effects 0.000 claims 4
- 238000004519 manufacturing process Methods 0.000 claims 4
- OKTJSMMVPCPJKN-OUBTZVSYSA-N Carbon-13 Chemical compound [13C] OKTJSMMVPCPJKN-OUBTZVSYSA-N 0.000 claims 3
- 238000005481 NMR spectroscopy Methods 0.000 claims 3
- 239000005062 Polybutadiene Substances 0.000 claims 3
- 238000007334 copolymerization reaction Methods 0.000 claims 3
- 150000001993 dienes Chemical class 0.000 claims 3
- 229910052736 halogen Inorganic materials 0.000 claims 3
- 150000002367 halogens Chemical class 0.000 claims 3
- 150000002910 rare earth metals Chemical class 0.000 claims 3
- 150000003839 salts Chemical class 0.000 claims 3
- 239000002904 solvent Substances 0.000 claims 3
- 239000004215 Carbon black (E152) Substances 0.000 claims 2
- 239000007983 Tris buffer Substances 0.000 claims 2
- SEGLCEQVOFDUPX-UHFFFAOYSA-N di-(2-ethylhexyl)phosphoric acid Chemical compound CCCCC(CC)COP(O)(=O)OCC(CC)CCCC SEGLCEQVOFDUPX-UHFFFAOYSA-N 0.000 claims 2
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- 150000002430 hydrocarbons Chemical class 0.000 claims 2
- 102100027755 Histone-lysine N-methyltransferase 2C Human genes 0.000 claims 1
- 101001008892 Homo sapiens Histone-lysine N-methyltransferase 2C Proteins 0.000 claims 1
- 229910052779 Neodymium Inorganic materials 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 125000005234 alkyl aluminium group Chemical group 0.000 claims 1
- SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical group CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 claims 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical group CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical group [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims 1
- 229920002857 polybutadiene Polymers 0.000 claims 1
- 229920001195 polyisoprene Polymers 0.000 claims 1
- 238000006116 polymerization reaction Methods 0.000 claims 1
- 239000000725 suspension Substances 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0115888 | 2001-12-07 | ||
| FR01/15888 | 2001-12-07 | ||
| PCT/EP2002/013709 WO2003048221A1 (fr) | 2001-12-07 | 2002-12-04 | Procede de preparation de copolymeres butadiene/isoprene et ces copolymeres |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011028442A Division JP2011094157A (ja) | 2001-12-07 | 2011-02-14 | ブタジエン／イソプレンコポリマーの製造方法および該コポリマー |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2005511806A JP2005511806A (ja) | 2005-04-28 |
| JP2005511806A5 true JP2005511806A5 (https=) | 2006-01-26 |
| JP4741185B2 JP4741185B2 (ja) | 2011-08-03 |
Family
ID=8870258
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003549406A Expired - Fee Related JP4741185B2 (ja) | 2001-12-07 | 2002-12-04 | ブタジエン／イソプレンコポリマーの製造方法および該コポリマー |
| JP2011028442A Pending JP2011094157A (ja) | 2001-12-07 | 2011-02-14 | ブタジエン／イソプレンコポリマーの製造方法および該コポリマー |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011028442A Pending JP2011094157A (ja) | 2001-12-07 | 2011-02-14 | ブタジエン／イソプレンコポリマーの製造方法および該コポリマー |
Country Status (12)
| Country | Link |
|---|---|
| US (2) | US7115693B2 (https=) |
| EP (1) | EP1456260B1 (https=) |
| JP (2) | JP4741185B2 (https=) |
| KR (2) | KR100939651B1 (https=) |
| CN (1) | CN1273508C (https=) |
| AT (1) | ATE393176T1 (https=) |
| AU (1) | AU2002361972A1 (https=) |
| BR (1) | BR0214685B1 (https=) |
| DE (1) | DE60226270T2 (https=) |
| ES (1) | ES2305339T3 (https=) |
| RU (1) | RU2301236C2 (https=) |
| WO (1) | WO2003048221A1 (https=) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5111101B2 (ja) * | 2004-03-02 | 2012-12-26 | 株式会社ブリヂストン | バルク重合プロセス |
| DE102004022676A1 (de) * | 2004-05-07 | 2005-12-15 | Bayer Ag | Hydrierte Copolymerisate aus nicht substituierten und substituierten konjugierten Dienen |
| FR2886937B1 (fr) * | 2005-06-14 | 2007-08-10 | Michelin Soc Tech | Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene |
| US20080090852A1 (en) * | 2006-10-13 | 2008-04-17 | Colin Andrew Leach | Bicyclic Heteroaromatic Compounds |
| US7705005B2 (en) * | 2006-10-13 | 2010-04-27 | Glaxo Group Limited | Bicyclic heteroaromatic compounds |
| US20080090851A1 (en) * | 2006-10-13 | 2008-04-17 | Colin Andrew Leach | Bicyclic Heteroaromatic Compounds |
| DE102007050119A1 (de) * | 2007-10-19 | 2009-04-23 | Robert Bosch Gmbh | Speichervorrichtung, Sensorelement und Verfahren zur qualitativen und/oder quantitativen Bestimmung mindestens einer Gaskomponente, insbesondere von Stickoxiden, in einem Gas |
| US7820580B2 (en) | 2007-11-15 | 2010-10-26 | Bridgestone Corporation | Nickel-based catalysts for preparing high cis 1,4-polydienes |
| RU2515980C2 (ru) * | 2007-12-31 | 2014-05-20 | Бриджстоун Корпорейшн | Способ получения полидиенов полимеризацией в объеме |
| US8394901B2 (en) | 2008-04-29 | 2013-03-12 | Changchun Institute Of Applied Chemistry Chinese Academy Of Sciences | Bi-component catalyst system for isoprene or butadiene cis 1, 4-polymerization and polymerization process |
| EP2291415B1 (en) | 2008-06-20 | 2016-07-20 | Bridgestone Corporation | Catalysts for preparing cis 1,4-polydienes |
| EP2470574B1 (en) * | 2009-08-24 | 2014-09-17 | Bridgestone Corporation | Process and catalyst system for polydiene production |
| CN102234356B (zh) * | 2010-04-30 | 2013-03-06 | 青岛伊科思新材料股份有限公司 | 稀土戊丁橡胶的生产方法 |
| CN101831032B (zh) * | 2010-05-19 | 2012-05-02 | 中国科学院长春应用化学研究所 | 一种丁二烯异戊二烯共聚物的制备方法 |
| WO2014010249A1 (ja) * | 2012-07-12 | 2014-01-16 | 株式会社ブリヂストン | 重合体組成物の製造方法及び重合体組成物 |
| CN104428332B (zh) * | 2012-07-12 | 2016-09-14 | 株式会社普利司通 | 异戊二烯共聚物及其制造方法 |
| CN103626926B (zh) * | 2012-08-21 | 2016-03-30 | 中国石油化工股份有限公司 | 一种聚丁二烯接枝异戊橡胶及其制备方法和硫化胶及混炼胶 |
| CN103665197B (zh) * | 2012-09-18 | 2015-12-02 | 中国石油天然气股份有限公司 | 一种均相稀土催化剂及其在共轭二烯烃聚合中的应用 |
| CN104130350B (zh) * | 2013-05-02 | 2017-08-22 | 中国石油化工股份有限公司 | 一种丁二烯‑异戊二烯共聚物橡胶及其制备方法 |
| TWI522378B (zh) * | 2013-12-13 | 2016-02-21 | 奇美實業股份有限公司 | 改質的高順式丁二烯－異戊二烯系共聚物、其製造方法及含有前述聚合物的輪胎 |
| CN103980425B (zh) * | 2014-06-09 | 2019-03-12 | 华宇橡胶有限责任公司 | 高顺式含量丁二烯-异戊二烯共聚物的制备方法 |
| US20170335032A1 (en) * | 2014-11-17 | 2017-11-23 | Bridgestone Corporation | Bulk polymerization of polyisoprene with preformed catalyst |
| IT201800005841A1 (it) * | 2018-05-30 | 2019-11-30 | Procedimento per la preparazione di copolimeri random butadiene-isoprene ad elevato contenuto di unita’ 1,4-cis | |
| CN112552451B (zh) * | 2019-09-25 | 2022-08-19 | 中国石油化工股份有限公司 | 无规丁二烯-异戊二烯共聚物及其合成方法和低滚阻汽车轮胎胎面胶 |
| EP3838932B1 (en) | 2019-12-20 | 2022-08-10 | The Goodyear Tire & Rubber Company | Synthesis of isoprene-butadiene copolymer rubbers |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3541063A (en) * | 1967-12-29 | 1970-11-17 | Goodyear Tire & Rubber | Process for the polymerization of diolefins with a catalyst comprising alkylaluminum compounds,group iii-b organo metal compounds and organoaluminum fluoride compounds |
| JPS6023406A (ja) * | 1983-07-18 | 1985-02-06 | Asahi Chem Ind Co Ltd | ポリブタジエンの製造方法 |
| US5405815A (en) * | 1993-06-17 | 1995-04-11 | The Goodyear Tire & Rubber Company | Process for preparing a catalyst system useful in the synthesis of isoprene-butadiene rubber |
| RU2087488C1 (ru) * | 1994-03-16 | 1997-08-20 | Акционерное общество открытого типа "Ефремовский завод синтетического каучука" | Способ получения цис-1,4-полибутадиена и цис-1,4-сополимера бутадиена и изопрена |
| JP4067592B2 (ja) * | 1996-12-04 | 2008-03-26 | Ｊｓｒ株式会社 | 共役ジエン系重合体の製造方法 |
| RU2127281C1 (ru) * | 1997-03-11 | 1999-03-10 | Акционерное общество открытого типа "Ефремовский завод синтетического каучука" | Способ получения цис-1,4-полибутадиена и цис-1,4-сополимера бутадиена и изопрена |
| RU2127280C1 (ru) * | 1997-03-11 | 1999-03-10 | Акционерное общество открытого типа "Ефремовский завод синтетического каучука" | Способ получения цис-1,4-полибутадиена и цис-1,4-сополимера бутадиена и изопрена |
| JP2001048940A (ja) * | 1999-08-06 | 2001-02-20 | Nippon Zeon Co Ltd | ブタジエン系重合体及びその製造方法 |
| CA2427984A1 (fr) * | 2000-11-09 | 2002-05-16 | Michelin Recherche Et Technique S.A. | Systeme catalytique et procede de preparation d'elastomeres au moyen de ce systeme |
| US7022783B2 (en) * | 2001-12-31 | 2006-04-04 | The Goodyear Tire & Rubber Company | Group III-B metal catalyst system |
-
2002
- 2002-12-04 KR KR1020097008323A patent/KR100939651B1/ko not_active Expired - Fee Related
- 2002-12-04 EP EP02796566A patent/EP1456260B1/fr not_active Expired - Lifetime
- 2002-12-04 KR KR1020047008774A patent/KR100904627B1/ko not_active Expired - Fee Related
- 2002-12-04 DE DE60226270T patent/DE60226270T2/de not_active Expired - Lifetime
- 2002-12-04 RU RU2004120699/04A patent/RU2301236C2/ru not_active IP Right Cessation
- 2002-12-04 AU AU2002361972A patent/AU2002361972A1/en not_active Abandoned
- 2002-12-04 CN CNB028243722A patent/CN1273508C/zh not_active Expired - Fee Related
- 2002-12-04 BR BRPI0214685-1A patent/BR0214685B1/pt not_active IP Right Cessation
- 2002-12-04 ES ES02796566T patent/ES2305339T3/es not_active Expired - Lifetime
- 2002-12-04 WO PCT/EP2002/013709 patent/WO2003048221A1/fr not_active Ceased
- 2002-12-04 JP JP2003549406A patent/JP4741185B2/ja not_active Expired - Fee Related
- 2002-12-04 AT AT02796566T patent/ATE393176T1/de not_active IP Right Cessation
-
2004
- 2004-05-28 US US10/855,354 patent/US7115693B2/en not_active Expired - Lifetime
-
2006
- 2006-05-03 US US11/416,188 patent/US7169870B2/en not_active Expired - Lifetime
-
2011
- 2011-02-14 JP JP2011028442A patent/JP2011094157A/ja active Pending
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