JP2006506494A5 - - Google Patents
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- Publication number
- JP2006506494A5 JP2006506494A5 JP2004552628A JP2004552628A JP2006506494A5 JP 2006506494 A5 JP2006506494 A5 JP 2006506494A5 JP 2004552628 A JP2004552628 A JP 2004552628A JP 2004552628 A JP2004552628 A JP 2004552628A JP 2006506494 A5 JP2006506494 A5 JP 2006506494A5
- Authority
- JP
- Japan
- Prior art keywords
- butadiene
- catalyst system
- monoolefin
- rare earth
- earth salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 claims 19
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 18
- 239000003054 catalyst Substances 0.000 claims 8
- 150000005673 monoalkenes Chemical class 0.000 claims 7
- -1 alicyclic hydrocarbon Chemical class 0.000 claims 6
- 229910052761 rare earth metal Inorganic materials 0.000 claims 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 3
- 229940100198 alkylating agent Drugs 0.000 claims 3
- 239000002168 alkylating agent Substances 0.000 claims 3
- 150000001993 dienes Chemical class 0.000 claims 3
- 229910052736 halogen Inorganic materials 0.000 claims 3
- 150000002367 halogens Chemical class 0.000 claims 3
- 239000000178 monomer Substances 0.000 claims 3
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 claims 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims 2
- 239000007983 Tris buffer Substances 0.000 claims 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N but-2-ene Chemical compound CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 claims 2
- SEGLCEQVOFDUPX-UHFFFAOYSA-N di-(2-ethylhexyl)phosphoric acid Chemical compound CCCCC(CC)COP(O)(=O)OCC(CC)CCCC SEGLCEQVOFDUPX-UHFFFAOYSA-N 0.000 claims 2
- 150000002910 rare earth metals Chemical class 0.000 claims 2
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- 229910052779 Neodymium Inorganic materials 0.000 claims 1
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 125000005234 alkyl aluminium group Chemical group 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 238000004458 analytical method Methods 0.000 claims 1
- SIPUZPBQZHNSDW-UHFFFAOYSA-N bis(2-methylpropyl)aluminum Chemical group CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 claims 1
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical group CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 claims 1
- XNMQEEKYCVKGBD-UHFFFAOYSA-N dimethylacetylene Natural products CC#CC XNMQEEKYCVKGBD-UHFFFAOYSA-N 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims 1
- 238000001542 size-exclusion chromatography Methods 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0214482 | 2002-11-18 | ||
| FR0214482 | 2002-11-18 | ||
| PCT/EP2003/012845 WO2004046213A1 (fr) | 2002-11-18 | 2003-11-17 | Procede d’obtention d’un homopolymere du butadiene en presence de mono-olefine(s) a 4 atomes de carbone |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2006506494A JP2006506494A (ja) | 2006-02-23 |
| JP2006506494A5 true JP2006506494A5 (https=) | 2007-01-11 |
| JP5318316B2 JP5318316B2 (ja) | 2013-10-16 |
Family
ID=32319951
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2004552628A Expired - Fee Related JP5318316B2 (ja) | 2002-11-18 | 2003-11-17 | 炭素原子４個を有するモノオレフィンの存在下でのブタジエンホモポリマーの製造方法 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7485765B2 (https=) |
| EP (1) | EP1565501A1 (https=) |
| JP (1) | JP5318316B2 (https=) |
| KR (1) | KR101075811B1 (https=) |
| AU (1) | AU2003292037A1 (https=) |
| BR (1) | BR0316317B1 (https=) |
| CA (1) | CA2506181C (https=) |
| WO (1) | WO2004046213A1 (https=) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5227490B2 (ja) * | 2004-08-25 | 2013-07-03 | Ｊｘ日鉱日石エネルギー株式会社 | オレフィン重合体の製造方法 |
| FR2886937B1 (fr) * | 2005-06-14 | 2007-08-10 | Michelin Soc Tech | Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene |
| JP6105830B2 (ja) * | 2010-11-02 | 2017-03-29 | 株式会社ブリヂストン | ポリブタジエンの製造方法、並びに、分離方法 |
| JP6268119B2 (ja) * | 2015-04-09 | 2018-01-24 | 株式会社ブリヂストン | ポリブタジエン及びその製造方法、並びにゴム組成物及びタイヤ |
| CN106905458A (zh) * | 2015-12-22 | 2017-06-30 | 中国石油天然气股份有限公司 | 含混合配体的稀土催化剂及其制备方法和应用 |
| KR102193437B1 (ko) | 2017-10-30 | 2020-12-21 | 주식회사 엘지화학 | 공액디엔 중합용 촉매의 제조방법, 촉매 및 이를 이용한 공액디엔계 중합체의 제조방법 |
| CN110294823B (zh) * | 2018-03-21 | 2022-01-04 | 中国石油化工股份有限公司 | 丁二烯-异戊二烯共聚物及其制备方法 |
| CN110294822B (zh) * | 2018-03-21 | 2021-12-31 | 中国石油化工股份有限公司 | 丁二烯-异戊二烯共聚物及其制备方法 |
| CN116023533B (zh) * | 2021-10-25 | 2025-02-28 | 中国石油化工股份有限公司 | 膦酸酯钕溶液及其制备方法和应用 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS58154705A (ja) * | 1982-03-10 | 1983-09-14 | Asahi Chem Ind Co Ltd | 新しいジエン類の重合方法およびその重合触媒 |
| JPS6023406A (ja) * | 1983-07-18 | 1985-02-06 | Asahi Chem Ind Co Ltd | ポリブタジエンの製造方法 |
| US5397851A (en) * | 1993-11-09 | 1995-03-14 | Polysar Rubber Corporation | Process for cis-1,4-polybutadiene production with reduced gel formation |
| DE19919870A1 (de) * | 1999-04-30 | 2000-11-02 | Bayer Ag | Verfahren zur Suspensions-Polymerisation von konjugierten Dienen |
| ATE465211T1 (de) * | 1999-05-19 | 2010-05-15 | Bridgestone Corp | Niedermolekulares polybutadien mit hohem cis gehalt |
| CA2427984A1 (fr) * | 2000-11-09 | 2002-05-16 | Michelin Recherche Et Technique S.A. | Systeme catalytique et procede de preparation d'elastomeres au moyen de ce systeme |
| AU2003233065A1 (en) * | 2002-05-16 | 2003-12-02 | Michelin Recherche Et Technique S.A. | Catalytic system for preparing polybutadienes and preparation method |
-
2003
- 2003-11-17 WO PCT/EP2003/012845 patent/WO2004046213A1/fr not_active Ceased
- 2003-11-17 AU AU2003292037A patent/AU2003292037A1/en not_active Abandoned
- 2003-11-17 EP EP03767562A patent/EP1565501A1/fr not_active Ceased
- 2003-11-17 JP JP2004552628A patent/JP5318316B2/ja not_active Expired - Fee Related
- 2003-11-17 CA CA2506181A patent/CA2506181C/fr not_active Expired - Fee Related
- 2003-11-17 BR BRPI0316317-2A patent/BR0316317B1/pt not_active IP Right Cessation
- 2003-11-17 KR KR1020057008848A patent/KR101075811B1/ko not_active Expired - Fee Related
-
2005
- 2005-05-16 US US11/129,401 patent/US7485765B2/en not_active Expired - Lifetime
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