JP2007501881A5 - - Google Patents
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- Publication number
- JP2007501881A5 JP2007501881A5 JP2006522929A JP2006522929A JP2007501881A5 JP 2007501881 A5 JP2007501881 A5 JP 2007501881A5 JP 2006522929 A JP2006522929 A JP 2006522929A JP 2006522929 A JP2006522929 A JP 2006522929A JP 2007501881 A5 JP2007501881 A5 JP 2007501881A5
- Authority
- JP
- Japan
- Prior art keywords
- copolymer
- catalyst system
- conjugated diene
- producing
- olefin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001577 copolymer Polymers 0.000 claims description 46
- 150000001993 dienes Chemical class 0.000 claims description 22
- 239000004711 α-olefin Substances 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 5
- 239000005977 Ethylene Substances 0.000 claims description 5
- 229920001897 terpolymer Polymers 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 claims 29
- 238000004519 manufacturing process Methods 0.000 claims 15
- 125000002524 organometallic group Chemical group 0.000 claims 13
- 230000000536 complexating effect Effects 0.000 claims 8
- 239000002904 solvent Substances 0.000 claims 8
- 150000005673 monoalkenes Chemical class 0.000 claims 5
- 150000002602 lanthanoids Chemical group 0.000 claims 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims 3
- 125000005234 alkyl aluminium group Chemical group 0.000 claims 3
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims 3
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims 3
- 229910052747 lanthanoid Inorganic materials 0.000 claims 3
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 claims 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims 2
- 229910052779 Neodymium Inorganic materials 0.000 claims 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 2
- -1 alkyl lithium Chemical compound 0.000 claims 2
- 239000003426 co-catalyst Substances 0.000 claims 2
- 125000005843 halogen group Chemical group 0.000 claims 2
- 239000003446 ligand Substances 0.000 claims 2
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims 2
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 claims 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- 239000007818 Grignard reagent Substances 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 229910052801 chlorine Inorganic materials 0.000 claims 1
- 239000000460 chlorine Substances 0.000 claims 1
- 125000004122 cyclic group Chemical group 0.000 claims 1
- 125000000753 cycloalkyl group Chemical group 0.000 claims 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims 1
- 238000001704 evaporation Methods 0.000 claims 1
- 230000001747 exhibiting effect Effects 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 150000004795 grignard reagents Chemical class 0.000 claims 1
- 229930195733 hydrocarbon Natural products 0.000 claims 1
- 150000002430 hydrocarbons Chemical class 0.000 claims 1
- 229910052740 iodine Inorganic materials 0.000 claims 1
- 229910052744 lithium Inorganic materials 0.000 claims 1
- 229910003002 lithium salt Inorganic materials 0.000 claims 1
- 159000000002 lithium salts Chemical class 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 150000003839 salts Chemical class 0.000 claims 1
- 125000001424 substituent group Chemical group 0.000 claims 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 8
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- 238000005481 NMR spectroscopy Methods 0.000 description 4
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 2
- 238000010183 spectrum analysis Methods 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 238000001460 carbon-13 nuclear magnetic resonance spectrum Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000011002 quantification Methods 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0309930 | 2003-08-13 | ||
| FR0309930A FR2858817B1 (fr) | 2003-08-13 | 2003-08-13 | Systeme catalytique pour l'obtention de copolymeres diene(s) conjugue(s)/ mono-olefine(s) et ces copolymeres |
| PCT/EP2004/008336 WO2005028526A1 (fr) | 2003-08-13 | 2004-07-26 | Système catalytique pour l'obtention de copolymères diène(s) conjugué(s) / mono-oléfine(s) et ces copolymères |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2007501881A JP2007501881A (ja) | 2007-02-01 |
| JP2007501881A5 true JP2007501881A5 (https=) | 2007-08-23 |
| JP5329040B2 JP5329040B2 (ja) | 2013-10-30 |
Family
ID=34112767
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006522929A Expired - Fee Related JP5329040B2 (ja) | 2003-08-13 | 2004-07-26 | 共役ジエン／モノオレフィンコポリマーを得るための触媒およびこれらのコポリマー |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US7547654B2 (https=) |
| EP (1) | EP1656400B1 (https=) |
| JP (1) | JP5329040B2 (https=) |
| KR (2) | KR101263815B1 (https=) |
| CN (1) | CN100567343C (https=) |
| BR (1) | BRPI0413457B1 (https=) |
| FR (1) | FR2858817B1 (https=) |
| MX (1) | MXPA06001656A (https=) |
| RU (1) | RU2400492C2 (https=) |
| WO (1) | WO2005028526A1 (https=) |
Families Citing this family (59)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2886937B1 (fr) * | 2005-06-14 | 2007-08-10 | Michelin Soc Tech | Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene |
| EP1777240A1 (en) * | 2005-10-24 | 2007-04-25 | Total Petrochemicals Research Feluy | Preparation of styrene-isoprene and of styrene isoprene ethylene copolymers |
| FR2893029B1 (fr) * | 2005-11-09 | 2009-01-16 | Michelin Soc Tech | Complexe metallocene borohydrure d'un lanthanide, systeme catalytique l'incorporant, procede de polymerisation l'utilisant et copolymere ethylene/butadiene obtenu par ce procede |
| US8048961B2 (en) * | 2006-08-25 | 2011-11-01 | Dow Global Technologies Llc | Production of metathesis products by amorphous polymer segment interchange |
| US8530579B2 (en) * | 2006-08-25 | 2013-09-10 | Dow Global Technologies Llc | Production of metathesis products by high melting polymer segment interchange |
| DE102007043626A1 (de) | 2007-09-13 | 2009-03-19 | Rolls-Royce Deutschland Ltd & Co Kg | Gasturbinenmagerbrenner mit Kraftstoffdüse mit kontrollierter Kraftstoffinhomogenität |
| JP5917809B2 (ja) * | 2010-11-30 | 2016-05-18 | 株式会社ブリヂストン | 共重合体及びその製造方法、並びに、ゴム組成物、架橋ゴム組成物、及びタイヤ |
| JP5557710B2 (ja) * | 2010-11-30 | 2014-07-23 | 株式会社ブリヂストン | 共重合体 |
| JP5731216B2 (ja) * | 2011-02-04 | 2015-06-10 | 株式会社ブリヂストン | 共役ジエン化合物と非共役オレフィンとの共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ |
| BR112013019814B1 (pt) | 2011-02-05 | 2022-07-12 | Bridgestone Corporation | Catalisador de complexo de lantanídeo e método de polimerização empregando o mesmo |
| JP5917886B2 (ja) * | 2011-11-04 | 2016-05-18 | 株式会社ブリヂストン | 共役ジエン系重合体 |
| JP5898975B2 (ja) * | 2012-01-27 | 2016-04-06 | 株式会社ブリヂストン | 共重合体における単量体単位の含有割合の制御方法 |
| WO2014052957A1 (en) | 2012-09-30 | 2014-04-03 | Bridgestone Corporation | Organometallic catalyst complex and polymerization method employing same |
| WO2014055868A1 (en) | 2012-10-04 | 2014-04-10 | Bridgestone Corporation | Organometallic complex catalyst and polymerization method employing same |
| FR3001223B1 (fr) | 2013-01-22 | 2015-03-06 | Michelin & Cie | Composition de caoutchouc comprenant un elastomere dienique fortement sature |
| EP3148937B1 (en) | 2014-05-30 | 2019-09-18 | Bridgestone Corporation | Metallic complex catalyst and polymerization methods employing same |
| EP3738927A1 (en) | 2014-05-31 | 2020-11-18 | Bridgestone Corporation | Metallic complex catalyst, polymerization methods employing same and polymer products thereof |
| WO2016139996A1 (ja) | 2015-03-04 | 2016-09-09 | Jsr株式会社 | 共重合体、重合体組成物及び架橋重合体 |
| FR3037588B1 (fr) | 2015-06-19 | 2017-05-19 | Michelin & Cie | Copolymere elastomere thermoplastique a base d'elastomere dienique et de polypropylene, compositions le comprenant et procede de preparation |
| CN108137731B (zh) | 2015-08-31 | 2020-08-25 | 株式会社普利司通 | 多烯和烯烃的共聚 |
| WO2017065300A1 (ja) * | 2015-10-16 | 2017-04-20 | 株式会社ブリヂストン | 多元共重合体、樹脂組成物、架橋樹脂組成物、及び製品 |
| EP3363824B1 (en) * | 2015-10-16 | 2024-05-01 | Bridgestone Corporation | Multicomponent copolymer, rubber composition, cross-linked rubber composition, rubber product, and tire |
| FR3044010A1 (fr) | 2015-11-19 | 2017-05-26 | Michelin & Cie | Bande de roulement pour pneumatique d'avion |
| FR3044007B1 (fr) | 2015-11-19 | 2017-12-08 | Michelin & Cie | Bande de roulement pour pneumatique d'avion |
| FR3044663B1 (fr) * | 2015-12-08 | 2017-12-29 | Michelin & Cie | Copolymere monofonctionnel ou telechelique de 1,3-butadiene et d'ethylene. |
| FR3044664B1 (fr) | 2015-12-08 | 2017-12-29 | Michelin & Cie | Copolymere monofonctionnel ou telechelique de 1,3-diene et d'ethylene ou d'alpha-monoolefine. |
| FR3045613B1 (fr) | 2015-12-17 | 2017-12-15 | Michelin & Cie | Copolymere d'ethylene et de butadiene de microstructure homogene |
| FR3045633B1 (fr) | 2015-12-22 | 2017-12-15 | Michelin & Cie | Pneumatique comprenant une composition de caoutchouc comprenant un elastomere dienique substitue |
| FR3060007A1 (fr) * | 2016-12-09 | 2018-06-15 | Compagnie Generale Des Etablissements Michelin | Terpolymeres d'ethylene, de 1,3-butadiene ou d'isoprene, et d'une alpha-monoolefine aromatique |
| FR3060592A1 (fr) | 2016-12-15 | 2018-06-22 | Compagnie Generale Des Etablissements Michelin | Pneumatique comportant une composition de caoutchouc comprenant un polymere porteur d'un groupement diene conjugue reticule par un dienophile |
| FR3060576A1 (fr) | 2016-12-15 | 2018-06-22 | Compagnie Generale Des Etablissements Michelin | Elastomere dienique portant des groupes pendants anthracenyles |
| FR3060570A1 (fr) | 2016-12-19 | 2018-06-22 | Compagnie Generale Des Etablissements Michelin | Procede de preparation d'un elastomere dienique modifie par un compose 1,3-dipolaire par extrusion reactive |
| FR3060571A1 (fr) | 2016-12-19 | 2018-06-22 | Compagnie Generale Des Etablissements Michelin | Procede de preparation d'un elastomere dienique modifie par un compose 1,3-dipolaire |
| FR3063731A1 (fr) | 2017-03-08 | 2018-09-14 | Compagnie Generale Des Etablissements Michelin | Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un acrylate de zinc |
| FR3063732A1 (fr) | 2017-03-08 | 2018-09-14 | Compagnie Generale Des Etablissements Michelin | Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate polyfonctionnel |
| WO2019002756A1 (fr) | 2017-06-28 | 2019-01-03 | Compagnie Generale Des Etablissements Michelin | Elastomère diénique portant des groupes imidazole |
| FR3068698A1 (fr) | 2017-07-04 | 2019-01-11 | Compagnie Generale Des Etablissements Michelin | Polymere portant des groupes pendants fonctionnels particuliers imidazolidinone |
| FR3068703A1 (fr) | 2017-07-04 | 2019-01-11 | Compagnie Generale Des Etablissements Michelin | Composition a base d'au moins un compose polyaromatique particulier |
| FR3069550A1 (fr) | 2017-07-28 | 2019-02-01 | Compagnie Generale Des Etablissements Michelin | Elastomere etendu a la resine |
| WO2019102132A1 (fr) | 2017-11-21 | 2019-05-31 | Compagnie Generale Des Etablissements Michelin | Composition de caoutchouc |
| EP3713924B1 (fr) | 2017-11-21 | 2023-01-04 | Compagnie Générale des Etablissements Michelin | Composé 1,3-dipolaire comportant un groupe époxyde |
| WO2019102126A1 (fr) | 2017-11-21 | 2019-05-31 | Compagnie Generale Des Etablissements Michelin | Polymère diénique modifié par un groupe époxyde |
| EP3713774B1 (fr) | 2017-11-21 | 2022-03-09 | Compagnie Générale des Etablissements Michelin | Composition de caoutchouc |
| JP7002310B2 (ja) * | 2017-12-05 | 2022-02-04 | 株式会社ブリヂストン | 多元共重合体の製造方法 |
| JP2019099719A (ja) | 2017-12-05 | 2019-06-24 | 株式会社ブリヂストン | 共重合体、ゴム組成物、樹脂組成物、タイヤ及び樹脂製品 |
| JP6983048B2 (ja) * | 2017-12-05 | 2021-12-17 | 株式会社ブリヂストン | 共重合体、ゴム組成物、樹脂組成物、タイヤ及び樹脂製品 |
| EP3720700A1 (fr) | 2017-12-06 | 2020-10-14 | Compagnie Générale des Etablissements Michelin | Stratifié élastomère |
| WO2019110926A1 (fr) | 2017-12-06 | 2019-06-13 | Compagnie Generale Des Etablissements Michelin | Stratifie elastomere |
| FR3085166B1 (fr) | 2018-08-23 | 2020-07-17 | Compagnie Generale Des Etablissements Michelin | Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique |
| FR3085165B1 (fr) | 2018-08-23 | 2020-07-17 | Compagnie Generale Des Etablissements Michelin | Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique |
| FR3085167B1 (fr) | 2018-08-23 | 2020-07-31 | Michelin & Cie | Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique |
| FR3088328B3 (fr) | 2018-11-09 | 2020-12-04 | Michelin & Cie | Elastomere dienique fonctionnel et composition de caoutchouc |
| FR3104584B1 (fr) | 2019-12-17 | 2021-12-03 | Michelin & Cie | Composé diorganomagnésien asymétrique |
| FR3104586B1 (fr) * | 2019-12-17 | 2021-12-03 | Michelin & Cie | Composé diorganomagnésien asymétrique pour système catalytique |
| FR3116276B1 (fr) | 2020-11-19 | 2023-11-10 | Michelin & Cie | Diorganomagnésien ayant une chaîne diénique ou oléfinique et fonctionnelle amine |
| FR3116277A1 (fr) | 2020-11-19 | 2022-05-20 | Compagnie Generale Des Etablissements Michelin | Copolymères fonctionnels amine à blocs éthyléniques et diéniques |
| FR3116538B1 (fr) | 2020-11-24 | 2022-11-25 | Michelin & Cie | Co-catalyseur comprenant plusieurs liaisons carbone magnésium |
| CN120981495A (zh) | 2023-02-08 | 2025-11-18 | 埃克森美孚技术与工程公司 | 用于共聚的催化剂 |
| KR20260015988A (ko) | 2023-06-06 | 2026-02-03 | 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 | 용액 촉매계 및 이의 용도 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3898207A (en) * | 1974-03-25 | 1975-08-05 | Firestone Tire & Rubber Co | Process for polymerizing conjugated dienes |
| US5278272A (en) * | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| IT1256259B (it) * | 1992-12-30 | 1995-11-29 | Montecatini Tecnologie Srl | Composti mettallocenici aventi leganti di tipo fluorenilico |
| IT1273753B (it) * | 1994-02-11 | 1997-07-10 | Eniriceche Spa | Sistema catalitico e processo per la produzione di polidiolefine |
| JPH07258319A (ja) * | 1994-03-23 | 1995-10-09 | Mitsubishi Rayon Co Ltd | 有機金属触媒及びそれを用いたビニル系重合体の製造方法 |
| JPH1180269A (ja) * | 1997-07-18 | 1999-03-26 | Mitsui Chem Inc | 不飽和性共重合体、その製造方法および該共重合体系組成物 |
| EP0891993B1 (en) * | 1997-07-18 | 2003-05-02 | Mitsui Chemicals, Inc. | Unsaturated copolymers, processes for preparing the same, and compositions containing the same |
| CN1240796A (zh) * | 1998-06-11 | 2000-01-12 | 意大利燃料添加剂股份公司 | 含α－烯烃的乙烯聚合物 |
| FR2799468B1 (fr) * | 1999-10-12 | 2006-04-28 | Michelin Soc Tech | Systeme catalytique utilisable pour la copolymerisation de l'ethylene et d'un diene conjugue, procede de preparation de ce systeme catalytique et d'un copolymere d'ethylene et d'un diene conjugue |
-
2003
- 2003-08-13 FR FR0309930A patent/FR2858817B1/fr not_active Expired - Fee Related
-
2004
- 2004-07-26 CN CNB2004800230775A patent/CN100567343C/zh not_active Expired - Fee Related
- 2004-07-26 KR KR1020127017251A patent/KR101263815B1/ko not_active Expired - Fee Related
- 2004-07-26 RU RU2006107530/04A patent/RU2400492C2/ru not_active IP Right Cessation
- 2004-07-26 WO PCT/EP2004/008336 patent/WO2005028526A1/fr not_active Ceased
- 2004-07-26 MX MXPA06001656A patent/MXPA06001656A/es unknown
- 2004-07-26 KR KR1020067002964A patent/KR101196236B1/ko not_active Expired - Fee Related
- 2004-07-26 EP EP04763491.0A patent/EP1656400B1/fr not_active Expired - Lifetime
- 2004-07-26 JP JP2006522929A patent/JP5329040B2/ja not_active Expired - Fee Related
- 2004-07-26 BR BRPI0413457-5A patent/BRPI0413457B1/pt not_active IP Right Cessation
-
2006
- 2006-02-10 US US11/350,754 patent/US7547654B2/en not_active Expired - Fee Related
-
2009
- 2009-05-07 US US12/453,333 patent/US8039565B2/en not_active Expired - Lifetime
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