JP5329040B2 - 共役ジエン／モノオレフィンコポリマーを得るための触媒およびこれらのコポリマー - Google Patents

共役ジエン／モノオレフィンコポリマーを得るための触媒およびこれらのコポリマー Download PDF

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Publication number
JP5329040B2
JP5329040B2 JP2006522929A JP2006522929A JP5329040B2 JP 5329040 B2 JP5329040 B2 JP 5329040B2 JP 2006522929 A JP2006522929 A JP 2006522929A JP 2006522929 A JP2006522929 A JP 2006522929A JP 5329040 B2 JP5329040 B2 JP 5329040B2
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JP
Japan
Prior art keywords
copolymer
catalyst system
butadiene
conjugated diene
olefin
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Expired - Fee Related
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JP2006522929A
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English (en)
Japanese (ja)
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JP2007501881A5 (https=
JP2007501881A (ja
Inventor
クリストフ ボワソン
ヴァンサン モンテイュ
ロジェ スピッツ
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Compagnie Generale des Etablissements Michelin SCA
Michelin Recherche et Technique SA France
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Compagnie Generale des Etablissements Michelin SCA
Michelin Recherche et Technique SA France
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Publication of JP2007501881A5 publication Critical patent/JP2007501881A5/ja
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/58—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with silicon, germanium, tin, lead, antimony, bismuth or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2006522929A 2003-08-13 2004-07-26 共役ジエン／モノオレフィンコポリマーを得るための触媒およびこれらのコポリマー Expired - Fee Related JP5329040B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0309930 2003-08-13
FR0309930A FR2858817B1 (fr) 2003-08-13 2003-08-13 Systeme catalytique pour l'obtention de copolymeres diene(s) conjugue(s)/ mono-olefine(s) et ces copolymeres
PCT/EP2004/008336 WO2005028526A1 (fr) 2003-08-13 2004-07-26 Système catalytique pour l'obtention de copolymères diène(s) conjugué(s) / mono-oléfine(s) et ces copolymères

Publications (3)

Publication Number Publication Date
JP2007501881A JP2007501881A (ja) 2007-02-01
JP2007501881A5 JP2007501881A5 (https=) 2007-08-23
JP5329040B2 true JP5329040B2 (ja) 2013-10-30

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JP2006522929A Expired - Fee Related JP5329040B2 (ja) 2003-08-13 2004-07-26 共役ジエン／モノオレフィンコポリマーを得るための触媒およびこれらのコポリマー

Country Status (10)

Country Link
US (2) US7547654B2 (https=)
EP (1) EP1656400B1 (https=)
JP (1) JP5329040B2 (https=)
KR (2) KR101263815B1 (https=)
CN (1) CN100567343C (https=)
BR (1) BRPI0413457B1 (https=)
FR (1) FR2858817B1 (https=)
MX (1) MXPA06001656A (https=)
RU (1) RU2400492C2 (https=)
WO (1) WO2005028526A1 (https=)

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US8048961B2 (en) * 2006-08-25 2011-11-01 Dow Global Technologies Llc Production of metathesis products by amorphous polymer segment interchange
US8530579B2 (en) * 2006-08-25 2013-09-10 Dow Global Technologies Llc Production of metathesis products by high melting polymer segment interchange
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JP5917809B2 (ja) * 2010-11-30 2016-05-18 株式会社ブリヂストン 共重合体及びその製造方法、並びに、ゴム組成物、架橋ゴム組成物、及びタイヤ
JP5557710B2 (ja) * 2010-11-30 2014-07-23 株式会社ブリヂストン 共重合体
JP5731216B2 (ja) * 2011-02-04 2015-06-10 株式会社ブリヂストン 共役ジエン化合物と非共役オレフィンとの共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ
BR112013019814B1 (pt) 2011-02-05 2022-07-12 Bridgestone Corporation Catalisador de complexo de lantanídeo e método de polimerização empregando o mesmo
JP5917886B2 (ja) * 2011-11-04 2016-05-18 株式会社ブリヂストン 共役ジエン系重合体
JP5898975B2 (ja) * 2012-01-27 2016-04-06 株式会社ブリヂストン 共重合体における単量体単位の含有割合の制御方法
WO2014052957A1 (en) 2012-09-30 2014-04-03 Bridgestone Corporation Organometallic catalyst complex and polymerization method employing same
WO2014055868A1 (en) 2012-10-04 2014-04-10 Bridgestone Corporation Organometallic complex catalyst and polymerization method employing same
FR3001223B1 (fr) 2013-01-22 2015-03-06 Michelin & Cie Composition de caoutchouc comprenant un elastomere dienique fortement sature
EP3148937B1 (en) 2014-05-30 2019-09-18 Bridgestone Corporation Metallic complex catalyst and polymerization methods employing same
EP3738927A1 (en) 2014-05-31 2020-11-18 Bridgestone Corporation Metallic complex catalyst, polymerization methods employing same and polymer products thereof
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FR3037588B1 (fr) 2015-06-19 2017-05-19 Michelin & Cie Copolymere elastomere thermoplastique a base d'elastomere dienique et de polypropylene, compositions le comprenant et procede de preparation
CN108137731B (zh) 2015-08-31 2020-08-25 株式会社普利司通 多烯和烯烃的共聚
WO2017065300A1 (ja) * 2015-10-16 2017-04-20 株式会社ブリヂストン 多元共重合体、樹脂組成物、架橋樹脂組成物、及び製品
EP3363824B1 (en) * 2015-10-16 2024-05-01 Bridgestone Corporation Multicomponent copolymer, rubber composition, cross-linked rubber composition, rubber product, and tire
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FR3044007B1 (fr) 2015-11-19 2017-12-08 Michelin & Cie Bande de roulement pour pneumatique d'avion
FR3044663B1 (fr) * 2015-12-08 2017-12-29 Michelin & Cie Copolymere monofonctionnel ou telechelique de 1,3-butadiene et d'ethylene.
FR3044664B1 (fr) 2015-12-08 2017-12-29 Michelin & Cie Copolymere monofonctionnel ou telechelique de 1,3-diene et d'ethylene ou d'alpha-monoolefine.
FR3045613B1 (fr) 2015-12-17 2017-12-15 Michelin & Cie Copolymere d'ethylene et de butadiene de microstructure homogene
FR3045633B1 (fr) 2015-12-22 2017-12-15 Michelin & Cie Pneumatique comprenant une composition de caoutchouc comprenant un elastomere dienique substitue
FR3060007A1 (fr) * 2016-12-09 2018-06-15 Compagnie Generale Des Etablissements Michelin Terpolymeres d'ethylene, de 1,3-butadiene ou d'isoprene, et d'une alpha-monoolefine aromatique
FR3060592A1 (fr) 2016-12-15 2018-06-22 Compagnie Generale Des Etablissements Michelin Pneumatique comportant une composition de caoutchouc comprenant un polymere porteur d'un groupement diene conjugue reticule par un dienophile
FR3060576A1 (fr) 2016-12-15 2018-06-22 Compagnie Generale Des Etablissements Michelin Elastomere dienique portant des groupes pendants anthracenyles
FR3060570A1 (fr) 2016-12-19 2018-06-22 Compagnie Generale Des Etablissements Michelin Procede de preparation d'un elastomere dienique modifie par un compose 1,3-dipolaire par extrusion reactive
FR3060571A1 (fr) 2016-12-19 2018-06-22 Compagnie Generale Des Etablissements Michelin Procede de preparation d'un elastomere dienique modifie par un compose 1,3-dipolaire
FR3063731A1 (fr) 2017-03-08 2018-09-14 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un acrylate de zinc
FR3063732A1 (fr) 2017-03-08 2018-09-14 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate polyfonctionnel
WO2019002756A1 (fr) 2017-06-28 2019-01-03 Compagnie Generale Des Etablissements Michelin Elastomère diénique portant des groupes imidazole
FR3068698A1 (fr) 2017-07-04 2019-01-11 Compagnie Generale Des Etablissements Michelin Polymere portant des groupes pendants fonctionnels particuliers imidazolidinone
FR3068703A1 (fr) 2017-07-04 2019-01-11 Compagnie Generale Des Etablissements Michelin Composition a base d'au moins un compose polyaromatique particulier
FR3069550A1 (fr) 2017-07-28 2019-02-01 Compagnie Generale Des Etablissements Michelin Elastomere etendu a la resine
WO2019102132A1 (fr) 2017-11-21 2019-05-31 Compagnie Generale Des Etablissements Michelin Composition de caoutchouc
EP3713924B1 (fr) 2017-11-21 2023-01-04 Compagnie Générale des Etablissements Michelin Composé 1,3-dipolaire comportant un groupe époxyde
WO2019102126A1 (fr) 2017-11-21 2019-05-31 Compagnie Generale Des Etablissements Michelin Polymère diénique modifié par un groupe époxyde
EP3713774B1 (fr) 2017-11-21 2022-03-09 Compagnie Générale des Etablissements Michelin Composition de caoutchouc
JP7002310B2 (ja) * 2017-12-05 2022-02-04 株式会社ブリヂストン 多元共重合体の製造方法
JP2019099719A (ja) 2017-12-05 2019-06-24 株式会社ブリヂストン 共重合体、ゴム組成物、樹脂組成物、タイヤ及び樹脂製品
JP6983048B2 (ja) * 2017-12-05 2021-12-17 株式会社ブリヂストン 共重合体、ゴム組成物、樹脂組成物、タイヤ及び樹脂製品
EP3720700A1 (fr) 2017-12-06 2020-10-14 Compagnie Générale des Etablissements Michelin Stratifié élastomère
WO2019110926A1 (fr) 2017-12-06 2019-06-13 Compagnie Generale Des Etablissements Michelin Stratifie elastomere
FR3085166B1 (fr) 2018-08-23 2020-07-17 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
FR3085165B1 (fr) 2018-08-23 2020-07-17 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
FR3085167B1 (fr) 2018-08-23 2020-07-31 Michelin & Cie Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
FR3088328B3 (fr) 2018-11-09 2020-12-04 Michelin & Cie Elastomere dienique fonctionnel et composition de caoutchouc
FR3104584B1 (fr) 2019-12-17 2021-12-03 Michelin & Cie Composé diorganomagnésien asymétrique
FR3104586B1 (fr) * 2019-12-17 2021-12-03 Michelin & Cie Composé diorganomagnésien asymétrique pour système catalytique
FR3116276B1 (fr) 2020-11-19 2023-11-10 Michelin & Cie Diorganomagnésien ayant une chaîne diénique ou oléfinique et fonctionnelle amine
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Also Published As

Publication number Publication date
MXPA06001656A (es) 2006-08-11
RU2006107530A (ru) 2006-06-27
KR20120082478A (ko) 2012-07-23
KR20060088100A (ko) 2006-08-03
CN1835978A (zh) 2006-09-20
JP2007501881A (ja) 2007-02-01
FR2858817B1 (fr) 2006-02-03
US20060160969A1 (en) 2006-07-20
BRPI0413457B1 (pt) 2014-09-09
FR2858817A1 (fr) 2005-02-18
BRPI0413457A (pt) 2006-10-17
EP1656400A1 (fr) 2006-05-17
KR101196236B1 (ko) 2012-11-05
CN100567343C (zh) 2009-12-09
EP1656400B1 (fr) 2019-05-29
US8039565B2 (en) 2011-10-18
KR101263815B1 (ko) 2013-05-13
US7547654B2 (en) 2009-06-16
US20090270578A1 (en) 2009-10-29
WO2005028526A1 (fr) 2005-03-31
RU2400492C2 (ru) 2010-09-27

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