RU2400492C2 - Каталитическая система для получения сопряженных диен/моноолефиновых сополимеров и указанные сополимеры - Google Patents

Каталитическая система для получения сопряженных диен/моноолефиновых сополимеров и указанные сополимеры Download PDF

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Publication number
RU2400492C2
RU2400492C2 RU2006107530/04A RU2006107530A RU2400492C2 RU 2400492 C2 RU2400492 C2 RU 2400492C2 RU 2006107530/04 A RU2006107530/04 A RU 2006107530/04A RU 2006107530 A RU2006107530 A RU 2006107530A RU 2400492 C2 RU2400492 C2 RU 2400492C2
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Russia
Prior art keywords
copolymer
catalyst
butadiene
conjugated diene
organometallic complex
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RU2006107530/04A
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English (en)
Russian (ru)
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RU2006107530A (ru
Inventor
Кристоф БУАССОН (FR)
Кристоф Буассон
Винсен МОНТЕЛЬ (FR)
Винсен МОНТЕЛЬ
Роже СПИТЦ (FR)
Роже СПИТЦ
Original Assignee
Сосьете Де Текноложи Мишлен
Мишлен Решерш Э Текник С.А.
Тотал Петрокемикалс Резеч Фелюи
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/58—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with silicon, germanium, tin, lead, antimony, bismuth or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/14—Monomers containing five or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Polymerization Catalysts (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
RU2006107530/04A 2003-08-13 2004-07-26 Каталитическая система для получения сопряженных диен/моноолефиновых сополимеров и указанные сополимеры RU2400492C2 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0309930 2003-08-13
FR0309930A FR2858817B1 (fr) 2003-08-13 2003-08-13 Systeme catalytique pour l'obtention de copolymeres diene(s) conjugue(s)/ mono-olefine(s) et ces copolymeres

Publications (2)

Publication Number Publication Date
RU2006107530A RU2006107530A (ru) 2006-06-27
RU2400492C2 true RU2400492C2 (ru) 2010-09-27

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RU2006107530/04A RU2400492C2 (ru) 2003-08-13 2004-07-26 Каталитическая система для получения сопряженных диен/моноолефиновых сополимеров и указанные сополимеры

Country Status (10)

Country Link
US (2) US7547654B2 (https=)
EP (1) EP1656400B1 (https=)
JP (1) JP5329040B2 (https=)
KR (2) KR101263815B1 (https=)
CN (1) CN100567343C (https=)
BR (1) BRPI0413457B1 (https=)
FR (1) FR2858817B1 (https=)
MX (1) MXPA06001656A (https=)
RU (1) RU2400492C2 (https=)
WO (1) WO2005028526A1 (https=)

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FR2893029B1 (fr) * 2005-11-09 2009-01-16 Michelin Soc Tech Complexe metallocene borohydrure d'un lanthanide, systeme catalytique l'incorporant, procede de polymerisation l'utilisant et copolymere ethylene/butadiene obtenu par ce procede
US8048961B2 (en) * 2006-08-25 2011-11-01 Dow Global Technologies Llc Production of metathesis products by amorphous polymer segment interchange
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JP5557710B2 (ja) * 2010-11-30 2014-07-23 株式会社ブリヂストン 共重合体
JP5731216B2 (ja) * 2011-02-04 2015-06-10 株式会社ブリヂストン 共役ジエン化合物と非共役オレフィンとの共重合体、ゴム組成物、架橋ゴム組成物、及びタイヤ
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JP5917886B2 (ja) * 2011-11-04 2016-05-18 株式会社ブリヂストン 共役ジエン系重合体
JP5898975B2 (ja) * 2012-01-27 2016-04-06 株式会社ブリヂストン 共重合体における単量体単位の含有割合の制御方法
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FR3044007B1 (fr) 2015-11-19 2017-12-08 Michelin & Cie Bande de roulement pour pneumatique d'avion
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FR3044664B1 (fr) 2015-12-08 2017-12-29 Michelin & Cie Copolymere monofonctionnel ou telechelique de 1,3-diene et d'ethylene ou d'alpha-monoolefine.
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FR3045633B1 (fr) 2015-12-22 2017-12-15 Michelin & Cie Pneumatique comprenant une composition de caoutchouc comprenant un elastomere dienique substitue
FR3060007A1 (fr) * 2016-12-09 2018-06-15 Compagnie Generale Des Etablissements Michelin Terpolymeres d'ethylene, de 1,3-butadiene ou d'isoprene, et d'une alpha-monoolefine aromatique
FR3060592A1 (fr) 2016-12-15 2018-06-22 Compagnie Generale Des Etablissements Michelin Pneumatique comportant une composition de caoutchouc comprenant un polymere porteur d'un groupement diene conjugue reticule par un dienophile
FR3060576A1 (fr) 2016-12-15 2018-06-22 Compagnie Generale Des Etablissements Michelin Elastomere dienique portant des groupes pendants anthracenyles
FR3060570A1 (fr) 2016-12-19 2018-06-22 Compagnie Generale Des Etablissements Michelin Procede de preparation d'un elastomere dienique modifie par un compose 1,3-dipolaire par extrusion reactive
FR3060571A1 (fr) 2016-12-19 2018-06-22 Compagnie Generale Des Etablissements Michelin Procede de preparation d'un elastomere dienique modifie par un compose 1,3-dipolaire
FR3063731A1 (fr) 2017-03-08 2018-09-14 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un acrylate de zinc
FR3063732A1 (fr) 2017-03-08 2018-09-14 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate polyfonctionnel
WO2019002756A1 (fr) 2017-06-28 2019-01-03 Compagnie Generale Des Etablissements Michelin Elastomère diénique portant des groupes imidazole
FR3068698A1 (fr) 2017-07-04 2019-01-11 Compagnie Generale Des Etablissements Michelin Polymere portant des groupes pendants fonctionnels particuliers imidazolidinone
FR3068703A1 (fr) 2017-07-04 2019-01-11 Compagnie Generale Des Etablissements Michelin Composition a base d'au moins un compose polyaromatique particulier
FR3069550A1 (fr) 2017-07-28 2019-02-01 Compagnie Generale Des Etablissements Michelin Elastomere etendu a la resine
WO2019102132A1 (fr) 2017-11-21 2019-05-31 Compagnie Generale Des Etablissements Michelin Composition de caoutchouc
EP3713924B1 (fr) 2017-11-21 2023-01-04 Compagnie Générale des Etablissements Michelin Composé 1,3-dipolaire comportant un groupe époxyde
WO2019102126A1 (fr) 2017-11-21 2019-05-31 Compagnie Generale Des Etablissements Michelin Polymère diénique modifié par un groupe époxyde
EP3713774B1 (fr) 2017-11-21 2022-03-09 Compagnie Générale des Etablissements Michelin Composition de caoutchouc
JP7002310B2 (ja) * 2017-12-05 2022-02-04 株式会社ブリヂストン 多元共重合体の製造方法
JP2019099719A (ja) 2017-12-05 2019-06-24 株式会社ブリヂストン 共重合体、ゴム組成物、樹脂組成物、タイヤ及び樹脂製品
JP6983048B2 (ja) * 2017-12-05 2021-12-17 株式会社ブリヂストン 共重合体、ゴム組成物、樹脂組成物、タイヤ及び樹脂製品
EP3720700A1 (fr) 2017-12-06 2020-10-14 Compagnie Générale des Etablissements Michelin Stratifié élastomère
WO2019110926A1 (fr) 2017-12-06 2019-06-13 Compagnie Generale Des Etablissements Michelin Stratifie elastomere
FR3085166B1 (fr) 2018-08-23 2020-07-17 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
FR3085165B1 (fr) 2018-08-23 2020-07-17 Compagnie Generale Des Etablissements Michelin Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
FR3085167B1 (fr) 2018-08-23 2020-07-31 Michelin & Cie Pneumatique muni d'une composition comprenant un elastomere riche en ethylene, un peroxyde et un derive d'acrylate specifique
FR3088328B3 (fr) 2018-11-09 2020-12-04 Michelin & Cie Elastomere dienique fonctionnel et composition de caoutchouc
FR3104584B1 (fr) 2019-12-17 2021-12-03 Michelin & Cie Composé diorganomagnésien asymétrique
FR3104586B1 (fr) * 2019-12-17 2021-12-03 Michelin & Cie Composé diorganomagnésien asymétrique pour système catalytique
FR3116276B1 (fr) 2020-11-19 2023-11-10 Michelin & Cie Diorganomagnésien ayant une chaîne diénique ou oléfinique et fonctionnelle amine
FR3116277A1 (fr) 2020-11-19 2022-05-20 Compagnie Generale Des Etablissements Michelin Copolymères fonctionnels amine à blocs éthyléniques et diéniques
FR3116538B1 (fr) 2020-11-24 2022-11-25 Michelin & Cie Co-catalyseur comprenant plusieurs liaisons carbone magnésium
CN120981495A (zh) 2023-02-08 2025-11-18 埃克森美孚技术与工程公司 用于共聚的催化剂
KR20260015988A (ko) 2023-06-06 2026-02-03 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 용액 촉매계 및 이의 용도

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Publication number Publication date
MXPA06001656A (es) 2006-08-11
RU2006107530A (ru) 2006-06-27
KR20120082478A (ko) 2012-07-23
KR20060088100A (ko) 2006-08-03
CN1835978A (zh) 2006-09-20
JP2007501881A (ja) 2007-02-01
JP5329040B2 (ja) 2013-10-30
FR2858817B1 (fr) 2006-02-03
US20060160969A1 (en) 2006-07-20
BRPI0413457B1 (pt) 2014-09-09
FR2858817A1 (fr) 2005-02-18
BRPI0413457A (pt) 2006-10-17
EP1656400A1 (fr) 2006-05-17
KR101196236B1 (ko) 2012-11-05
CN100567343C (zh) 2009-12-09
EP1656400B1 (fr) 2019-05-29
US8039565B2 (en) 2011-10-18
KR101263815B1 (ko) 2013-05-13
US7547654B2 (en) 2009-06-16
US20090270578A1 (en) 2009-10-29
WO2005028526A1 (fr) 2005-03-31

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