JP4741185B2 - ブタジエン／イソプレンコポリマーの製造方法および該コポリマー - Google Patents

ブタジエン／イソプレンコポリマーの製造方法および該コポリマー Download PDF

Info

Publication number
JP4741185B2
JP4741185B2 JP2003549406A JP2003549406A JP4741185B2 JP 4741185 B2 JP4741185 B2 JP 4741185B2 JP 2003549406 A JP2003549406 A JP 2003549406A JP 2003549406 A JP2003549406 A JP 2003549406A JP 4741185 B2 JP4741185 B2 JP 4741185B2
Authority
JP
Japan
Prior art keywords
butadiene
isoprene
catalyst system
random copolymer
salt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
JP2003549406A
Other languages
English (en)
Japanese (ja)
Other versions
JP2005511806A (ja
JP2005511806A5 (https=
Inventor
フィリップ ローブリー
Original Assignee
ソシエテ ド テクノロジー ミシュラン
ミシュラン ルシェルシュ エ テクニーク ソシエテ アノニム
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ソシエテ ド テクノロジー ミシュラン, ミシュラン ルシェルシュ エ テクニーク ソシエテ アノニム filed Critical ソシエテ ド テクノロジー ミシュラン
Publication of JP2005511806A publication Critical patent/JP2005511806A/ja
Publication of JP2005511806A5 publication Critical patent/JP2005511806A5/ja
Application granted granted Critical
Publication of JP4741185B2 publication Critical patent/JP4741185B2/ja
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2003549406A 2001-12-07 2002-12-04 ブタジエン／イソプレンコポリマーの製造方法および該コポリマー Expired - Fee Related JP4741185B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0115888 2001-12-07
FR01/15888 2001-12-07
PCT/EP2002/013709 WO2003048221A1 (fr) 2001-12-07 2002-12-04 Procede de preparation de copolymeres butadiene/isoprene et ces copolymeres

Related Child Applications (1)

Application Number Title Priority Date Filing Date
JP2011028442A Division JP2011094157A (ja) 2001-12-07 2011-02-14 ブタジエン／イソプレンコポリマーの製造方法および該コポリマー

Publications (3)

Publication Number Publication Date
JP2005511806A JP2005511806A (ja) 2005-04-28
JP2005511806A5 JP2005511806A5 (https=) 2006-01-26
JP4741185B2 true JP4741185B2 (ja) 2011-08-03

Family

ID=8870258

Family Applications (2)

Application Number Title Priority Date Filing Date
JP2003549406A Expired - Fee Related JP4741185B2 (ja) 2001-12-07 2002-12-04 ブタジエン／イソプレンコポリマーの製造方法および該コポリマー
JP2011028442A Pending JP2011094157A (ja) 2001-12-07 2011-02-14 ブタジエン／イソプレンコポリマーの製造方法および該コポリマー

Family Applications After (1)

Application Number Title Priority Date Filing Date
JP2011028442A Pending JP2011094157A (ja) 2001-12-07 2011-02-14 ブタジエン／イソプレンコポリマーの製造方法および該コポリマー

Country Status (12)

Country Link
US (2) US7115693B2 (https=)
EP (1) EP1456260B1 (https=)
JP (2) JP4741185B2 (https=)
KR (2) KR100939651B1 (https=)
CN (1) CN1273508C (https=)
AT (1) ATE393176T1 (https=)
AU (1) AU2002361972A1 (https=)
BR (1) BR0214685B1 (https=)
DE (1) DE60226270T2 (https=)
ES (1) ES2305339T3 (https=)
RU (1) RU2301236C2 (https=)
WO (1) WO2003048221A1 (https=)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5111101B2 (ja) * 2004-03-02 2012-12-26 株式会社ブリヂストン バルク重合プロセス
DE102004022676A1 (de) * 2004-05-07 2005-12-15 Bayer Ag Hydrierte Copolymerisate aus nicht substituierten und substituierten konjugierten Dienen
FR2886937B1 (fr) * 2005-06-14 2007-08-10 Michelin Soc Tech Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene
US20080090852A1 (en) * 2006-10-13 2008-04-17 Colin Andrew Leach Bicyclic Heteroaromatic Compounds
US7705005B2 (en) * 2006-10-13 2010-04-27 Glaxo Group Limited Bicyclic heteroaromatic compounds
US20080090851A1 (en) * 2006-10-13 2008-04-17 Colin Andrew Leach Bicyclic Heteroaromatic Compounds
DE102007050119A1 (de) * 2007-10-19 2009-04-23 Robert Bosch Gmbh Speichervorrichtung, Sensorelement und Verfahren zur qualitativen und/oder quantitativen Bestimmung mindestens einer Gaskomponente, insbesondere von Stickoxiden, in einem Gas
US7820580B2 (en) 2007-11-15 2010-10-26 Bridgestone Corporation Nickel-based catalysts for preparing high cis 1,4-polydienes
RU2515980C2 (ru) * 2007-12-31 2014-05-20 Бриджстоун Корпорейшн Способ получения полидиенов полимеризацией в объеме
US8394901B2 (en) 2008-04-29 2013-03-12 Changchun Institute Of Applied Chemistry Chinese Academy Of Sciences Bi-component catalyst system for isoprene or butadiene cis 1, 4-polymerization and polymerization process
EP2291415B1 (en) 2008-06-20 2016-07-20 Bridgestone Corporation Catalysts for preparing cis 1,4-polydienes
EP2470574B1 (en) * 2009-08-24 2014-09-17 Bridgestone Corporation Process and catalyst system for polydiene production
CN102234356B (zh) * 2010-04-30 2013-03-06 青岛伊科思新材料股份有限公司 稀土戊丁橡胶的生产方法
CN101831032B (zh) * 2010-05-19 2012-05-02 中国科学院长春应用化学研究所 一种丁二烯异戊二烯共聚物的制备方法
WO2014010249A1 (ja) * 2012-07-12 2014-01-16 株式会社ブリヂストン 重合体組成物の製造方法及び重合体組成物
CN104428332B (zh) * 2012-07-12 2016-09-14 株式会社普利司通 异戊二烯共聚物及其制造方法
CN103626926B (zh) * 2012-08-21 2016-03-30 中国石油化工股份有限公司 一种聚丁二烯接枝异戊橡胶及其制备方法和硫化胶及混炼胶
CN103665197B (zh) * 2012-09-18 2015-12-02 中国石油天然气股份有限公司 一种均相稀土催化剂及其在共轭二烯烃聚合中的应用
CN104130350B (zh) * 2013-05-02 2017-08-22 中国石油化工股份有限公司 一种丁二烯‑异戊二烯共聚物橡胶及其制备方法
TWI522378B (zh) * 2013-12-13 2016-02-21 奇美實業股份有限公司 改質的高順式丁二烯－異戊二烯系共聚物、其製造方法及含有前述聚合物的輪胎
CN103980425B (zh) * 2014-06-09 2019-03-12 华宇橡胶有限责任公司 高顺式含量丁二烯-异戊二烯共聚物的制备方法
US20170335032A1 (en) * 2014-11-17 2017-11-23 Bridgestone Corporation Bulk polymerization of polyisoprene with preformed catalyst
IT201800005841A1 (it) * 2018-05-30 2019-11-30 Procedimento per la preparazione di copolimeri random butadiene-isoprene ad elevato contenuto di unita’ 1,4-cis
CN112552451B (zh) * 2019-09-25 2022-08-19 中国石油化工股份有限公司 无规丁二烯-异戊二烯共聚物及其合成方法和低滚阻汽车轮胎胎面胶
EP3838932B1 (en) 2019-12-20 2022-08-10 The Goodyear Tire & Rubber Company Synthesis of isoprene-butadiene copolymer rubbers

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3541063A (en) * 1967-12-29 1970-11-17 Goodyear Tire & Rubber Process for the polymerization of diolefins with a catalyst comprising alkylaluminum compounds,group iii-b organo metal compounds and organoaluminum fluoride compounds
JPS6023406A (ja) * 1983-07-18 1985-02-06 Asahi Chem Ind Co Ltd ポリブタジエンの製造方法
US5405815A (en) * 1993-06-17 1995-04-11 The Goodyear Tire & Rubber Company Process for preparing a catalyst system useful in the synthesis of isoprene-butadiene rubber
RU2087488C1 (ru) * 1994-03-16 1997-08-20 Акционерное общество открытого типа "Ефремовский завод синтетического каучука" Способ получения цис-1,4-полибутадиена и цис-1,4-сополимера бутадиена и изопрена
JP4067592B2 (ja) * 1996-12-04 2008-03-26 Ｊｓｒ株式会社 共役ジエン系重合体の製造方法
RU2127281C1 (ru) * 1997-03-11 1999-03-10 Акционерное общество открытого типа "Ефремовский завод синтетического каучука" Способ получения цис-1,4-полибутадиена и цис-1,4-сополимера бутадиена и изопрена
RU2127280C1 (ru) * 1997-03-11 1999-03-10 Акционерное общество открытого типа "Ефремовский завод синтетического каучука" Способ получения цис-1,4-полибутадиена и цис-1,4-сополимера бутадиена и изопрена
JP2001048940A (ja) * 1999-08-06 2001-02-20 Nippon Zeon Co Ltd ブタジエン系重合体及びその製造方法
CA2427984A1 (fr) * 2000-11-09 2002-05-16 Michelin Recherche Et Technique S.A. Systeme catalytique et procede de preparation d'elastomeres au moyen de ce systeme
US7022783B2 (en) * 2001-12-31 2006-04-04 The Goodyear Tire & Rubber Company Group III-B metal catalyst system

Also Published As

Publication number Publication date
WO2003048221A1 (fr) 2003-06-12
KR100904627B1 (ko) 2009-06-25
JP2005511806A (ja) 2005-04-28
DE60226270D1 (de) 2008-06-05
KR20090058577A (ko) 2009-06-09
EP1456260A1 (fr) 2004-09-15
US20050004333A1 (en) 2005-01-06
KR20040064298A (ko) 2004-07-16
CN1273508C (zh) 2006-09-06
US20060270817A1 (en) 2006-11-30
BR0214685A (pt) 2004-12-07
KR100939651B1 (ko) 2010-02-03
JP2011094157A (ja) 2011-05-12
CN1599762A (zh) 2005-03-23
ATE393176T1 (de) 2008-05-15
AU2002361972A1 (en) 2003-06-17
US7169870B2 (en) 2007-01-30
ES2305339T3 (es) 2008-11-01
EP1456260B1 (fr) 2008-04-23
RU2301236C2 (ru) 2007-06-20
DE60226270T2 (de) 2009-07-16
BR0214685B1 (pt) 2012-08-21
RU2004120699A (ru) 2005-03-27
US7115693B2 (en) 2006-10-03

Similar Documents

Publication Publication Date Title
JP4741185B2 (ja) ブタジエン／イソプレンコポリマーの製造方法および該コポリマー
CN100386352C (zh) 制备聚丁二烯的催化体系及其制备方法
JP4820529B2 (ja) 触媒系及びこの系を用いたエラストマーの製造方法
US6992157B2 (en) Synthetic polyisoprenes and a process for their preparation
JP4939726B2 (ja) 高シス−１，４結合含有量を有するポリイソプレンを得る方法
JP5097918B2 (ja) 合成分枝ポリイソプレン及びそれらの製造方法
KR101075811B1 (ko) 탄소원자를 4개 갖는 모노올레핀(들)의 존재하에서의부타디엔 단독중합체의 제조방법

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20051205

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20051205

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20080714

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20080728

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20081022

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20081029

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20090128

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20100315

A601 Written request for extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A601

Effective date: 20100615

A602 Written permission of extension of time

Free format text: JAPANESE INTERMEDIATE CODE: A602

Effective date: 20100622

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20100914

A02 Decision of refusal

Free format text: JAPANESE INTERMEDIATE CODE: A02

Effective date: 20101012

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110214

A911 Transfer to examiner for re-examination before appeal (zenchi)

Free format text: JAPANESE INTERMEDIATE CODE: A911

Effective date: 20110221

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20110404

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20110506

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140513

Year of fee payment: 3

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees