CN1273508C - 丁二烯/异戊二烯共聚物的制备方法及所述共聚物 - Google Patents

丁二烯/异戊二烯共聚物的制备方法及所述共聚物 Download PDF

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Publication number
CN1273508C
CN1273508C CNB028243722A CN02824372A CN1273508C CN 1273508 C CN1273508 C CN 1273508C CN B028243722 A CNB028243722 A CN B028243722A CN 02824372 A CN02824372 A CN 02824372A CN 1273508 C CN1273508 C CN 1273508C
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CN
China
Prior art keywords
divinyl
isoprene
random copolymers
butadiene
isoprene random
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
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CNB028243722A
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English (en)
Chinese (zh)
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CN1599762A (zh
Inventor
P·洛布里
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Compagnie Generale des Etablissements Michelin SCA
Original Assignee
Michelin Recherche et Technique SA Switzerland
Societe de Technologie Michelin SAS
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Publication of CN1599762A publication Critical patent/CN1599762A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CNB028243722A 2001-12-07 2002-12-04 丁二烯/异戊二烯共聚物的制备方法及所述共聚物 Expired - Fee Related CN1273508C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0115888 2001-12-07
FR01/15888 2001-12-07

Publications (2)

Publication Number Publication Date
CN1599762A CN1599762A (zh) 2005-03-23
CN1273508C true CN1273508C (zh) 2006-09-06

Family

ID=8870258

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB028243722A Expired - Fee Related CN1273508C (zh) 2001-12-07 2002-12-04 丁二烯/异戊二烯共聚物的制备方法及所述共聚物

Country Status (12)

Country Link
US (2) US7115693B2 (https=)
EP (1) EP1456260B1 (https=)
JP (2) JP4741185B2 (https=)
KR (2) KR100939651B1 (https=)
CN (1) CN1273508C (https=)
AT (1) ATE393176T1 (https=)
AU (1) AU2002361972A1 (https=)
BR (1) BR0214685B1 (https=)
DE (1) DE60226270T2 (https=)
ES (1) ES2305339T3 (https=)
RU (1) RU2301236C2 (https=)
WO (1) WO2003048221A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107207654A (zh) * 2014-11-17 2017-09-26 株式会社普利司通 具有预成形催化剂的聚异戊二烯的本体聚合

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JP5111101B2 (ja) * 2004-03-02 2012-12-26 株式会社ブリヂストン バルク重合プロセス
DE102004022676A1 (de) * 2004-05-07 2005-12-15 Bayer Ag Hydrierte Copolymerisate aus nicht substituierten und substituierten konjugierten Dienen
FR2886937B1 (fr) * 2005-06-14 2007-08-10 Michelin Soc Tech Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene
US20080090852A1 (en) * 2006-10-13 2008-04-17 Colin Andrew Leach Bicyclic Heteroaromatic Compounds
US7705005B2 (en) * 2006-10-13 2010-04-27 Glaxo Group Limited Bicyclic heteroaromatic compounds
US20080090851A1 (en) * 2006-10-13 2008-04-17 Colin Andrew Leach Bicyclic Heteroaromatic Compounds
DE102007050119A1 (de) * 2007-10-19 2009-04-23 Robert Bosch Gmbh Speichervorrichtung, Sensorelement und Verfahren zur qualitativen und/oder quantitativen Bestimmung mindestens einer Gaskomponente, insbesondere von Stickoxiden, in einem Gas
US7820580B2 (en) 2007-11-15 2010-10-26 Bridgestone Corporation Nickel-based catalysts for preparing high cis 1,4-polydienes
RU2515980C2 (ru) * 2007-12-31 2014-05-20 Бриджстоун Корпорейшн Способ получения полидиенов полимеризацией в объеме
US8394901B2 (en) 2008-04-29 2013-03-12 Changchun Institute Of Applied Chemistry Chinese Academy Of Sciences Bi-component catalyst system for isoprene or butadiene cis 1, 4-polymerization and polymerization process
EP2291415B1 (en) 2008-06-20 2016-07-20 Bridgestone Corporation Catalysts for preparing cis 1,4-polydienes
EP2470574B1 (en) * 2009-08-24 2014-09-17 Bridgestone Corporation Process and catalyst system for polydiene production
CN102234356B (zh) * 2010-04-30 2013-03-06 青岛伊科思新材料股份有限公司 稀土戊丁橡胶的生产方法
CN101831032B (zh) * 2010-05-19 2012-05-02 中国科学院长春应用化学研究所 一种丁二烯异戊二烯共聚物的制备方法
WO2014010249A1 (ja) * 2012-07-12 2014-01-16 株式会社ブリヂストン 重合体組成物の製造方法及び重合体組成物
CN104428332B (zh) * 2012-07-12 2016-09-14 株式会社普利司通 异戊二烯共聚物及其制造方法
CN103626926B (zh) * 2012-08-21 2016-03-30 中国石油化工股份有限公司 一种聚丁二烯接枝异戊橡胶及其制备方法和硫化胶及混炼胶
CN103665197B (zh) * 2012-09-18 2015-12-02 中国石油天然气股份有限公司 一种均相稀土催化剂及其在共轭二烯烃聚合中的应用
CN104130350B (zh) * 2013-05-02 2017-08-22 中国石油化工股份有限公司 一种丁二烯‑异戊二烯共聚物橡胶及其制备方法
TWI522378B (zh) * 2013-12-13 2016-02-21 奇美實業股份有限公司 改質的高順式丁二烯－異戊二烯系共聚物、其製造方法及含有前述聚合物的輪胎
CN103980425B (zh) * 2014-06-09 2019-03-12 华宇橡胶有限责任公司 高顺式含量丁二烯-异戊二烯共聚物的制备方法
IT201800005841A1 (it) * 2018-05-30 2019-11-30 Procedimento per la preparazione di copolimeri random butadiene-isoprene ad elevato contenuto di unita’ 1,4-cis
CN112552451B (zh) * 2019-09-25 2022-08-19 中国石油化工股份有限公司 无规丁二烯-异戊二烯共聚物及其合成方法和低滚阻汽车轮胎胎面胶
EP3838932B1 (en) 2019-12-20 2022-08-10 The Goodyear Tire & Rubber Company Synthesis of isoprene-butadiene copolymer rubbers

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US3541063A (en) * 1967-12-29 1970-11-17 Goodyear Tire & Rubber Process for the polymerization of diolefins with a catalyst comprising alkylaluminum compounds,group iii-b organo metal compounds and organoaluminum fluoride compounds
JPS6023406A (ja) * 1983-07-18 1985-02-06 Asahi Chem Ind Co Ltd ポリブタジエンの製造方法
US5405815A (en) * 1993-06-17 1995-04-11 The Goodyear Tire & Rubber Company Process for preparing a catalyst system useful in the synthesis of isoprene-butadiene rubber
RU2087488C1 (ru) * 1994-03-16 1997-08-20 Акционерное общество открытого типа "Ефремовский завод синтетического каучука" Способ получения цис-1,4-полибутадиена и цис-1,4-сополимера бутадиена и изопрена
JP4067592B2 (ja) * 1996-12-04 2008-03-26 Ｊｓｒ株式会社 共役ジエン系重合体の製造方法
RU2127281C1 (ru) * 1997-03-11 1999-03-10 Акционерное общество открытого типа "Ефремовский завод синтетического каучука" Способ получения цис-1,4-полибутадиена и цис-1,4-сополимера бутадиена и изопрена
RU2127280C1 (ru) * 1997-03-11 1999-03-10 Акционерное общество открытого типа "Ефремовский завод синтетического каучука" Способ получения цис-1,4-полибутадиена и цис-1,4-сополимера бутадиена и изопрена
JP2001048940A (ja) * 1999-08-06 2001-02-20 Nippon Zeon Co Ltd ブタジエン系重合体及びその製造方法
CA2427984A1 (fr) * 2000-11-09 2002-05-16 Michelin Recherche Et Technique S.A. Systeme catalytique et procede de preparation d'elastomeres au moyen de ce systeme
US7022783B2 (en) * 2001-12-31 2006-04-04 The Goodyear Tire & Rubber Company Group III-B metal catalyst system

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107207654A (zh) * 2014-11-17 2017-09-26 株式会社普利司通 具有预成形催化剂的聚异戊二烯的本体聚合

Also Published As

Publication number Publication date
WO2003048221A1 (fr) 2003-06-12
KR100904627B1 (ko) 2009-06-25
JP4741185B2 (ja) 2011-08-03
JP2005511806A (ja) 2005-04-28
DE60226270D1 (de) 2008-06-05
KR20090058577A (ko) 2009-06-09
EP1456260A1 (fr) 2004-09-15
US20050004333A1 (en) 2005-01-06
KR20040064298A (ko) 2004-07-16
US20060270817A1 (en) 2006-11-30
BR0214685A (pt) 2004-12-07
KR100939651B1 (ko) 2010-02-03
JP2011094157A (ja) 2011-05-12
CN1599762A (zh) 2005-03-23
ATE393176T1 (de) 2008-05-15
AU2002361972A1 (en) 2003-06-17
US7169870B2 (en) 2007-01-30
ES2305339T3 (es) 2008-11-01
EP1456260B1 (fr) 2008-04-23
RU2301236C2 (ru) 2007-06-20
DE60226270T2 (de) 2009-07-16
BR0214685B1 (pt) 2012-08-21
RU2004120699A (ru) 2005-03-27
US7115693B2 (en) 2006-10-03

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GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract

Assignee: Shanghai Michelin tire Limited by Share Ltd

Assignor: Michelin Research & Technology Co., Ltd.|Michelin Co., Ltd.

Contract fulfillment period: The duration of the contract is from 2007.01.31 to 2026.12.13

Contract record no.: Contract filing No. 2007990000027

Denomination of invention: Process for the preparation of butadiene / isoprene copolymers and copolymers

Granted publication date: 20060906

License type: Common License

Record date: 20070813

LIC Patent licence contract for exploitation submitted for record

Free format text: COMMON LICENCE; TIME LIMIT OF IMPLEMENTING CONTACT: 2007.1.31 TO 2026.12.13

Name of requester: SHANGHAI MIQILIN BOOST TYRE CO., LTD.

Effective date: 20070813

ASS Succession or assignment of patent right

Owner name: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN

Free format text: FORMER OWNER: MICHELIN TECHNIQUE S.A.

Effective date: 20121123

C41 Transfer of patent application or patent right or utility model
TR01 Transfer of patent right

Effective date of registration: 20121123

Address after: French Clermont Ferrand

Patentee after: Compagnie General Des Etablissements Michelin

Patentee after: Michelin Research & Technology Co., Ltd.

Address before: French Clermont Ferrand

Patentee before: Michelin Co., Ltd.

Patentee before: Michelin Research & Technology Co., Ltd.

TR01 Transfer of patent right

Effective date of registration: 20170926

Address after: French Clermont Ferrand

Patentee after: Compagnie General Des Etablissements Michelin

Address before: French Clermont Ferrand

Co-patentee before: Michelin Research & Technology Co., Ltd.

Patentee before: Compagnie General Des Etablissements Michelin

TR01 Transfer of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20060906

Termination date: 20181204

CF01 Termination of patent right due to non-payment of annual fee