KR100939651B1 - 부타디엔/이소프렌 공중합체의 제조방법 - Google Patents

부타디엔/이소프렌 공중합체의 제조방법 Download PDF

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Publication number
KR100939651B1
KR100939651B1 KR1020097008323A KR20097008323A KR100939651B1 KR 100939651 B1 KR100939651 B1 KR 100939651B1 KR 1020097008323 A KR1020097008323 A KR 1020097008323A KR 20097008323 A KR20097008323 A KR 20097008323A KR 100939651 B1 KR100939651 B1 KR 100939651B1
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KR
South Korea
Prior art keywords
butadiene
isoprene
rare earth
catalyst system
random copolymer
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KR1020097008323A
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English (en)
Korean (ko)
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KR20090058577A (ko
Inventor
필립 로브리
Original Assignee
소시에떼 드 테크놀로지 미쉐린
미쉐린 러쉐르슈 에 떼크니크 에스.에이.
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Publication of KR20090058577A publication Critical patent/KR20090058577A/ko
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
KR1020097008323A 2001-12-07 2002-12-04 부타디엔/이소프렌 공중합체의 제조방법 Expired - Fee Related KR100939651B1 (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0115888 2001-12-07
FR01/15888 2001-12-07

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
KR1020047008774A Division KR100904627B1 (ko) 2001-12-07 2002-12-04 부타디엔/이소프렌 공중합체의 제조방법 및 이로부터생성된 공중합체

Publications (2)

Publication Number Publication Date
KR20090058577A KR20090058577A (ko) 2009-06-09
KR100939651B1 true KR100939651B1 (ko) 2010-02-03

Family

ID=8870258

Family Applications (2)

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KR1020097008323A Expired - Fee Related KR100939651B1 (ko) 2001-12-07 2002-12-04 부타디엔/이소프렌 공중합체의 제조방법
KR1020047008774A Expired - Fee Related KR100904627B1 (ko) 2001-12-07 2002-12-04 부타디엔/이소프렌 공중합체의 제조방법 및 이로부터생성된 공중합체

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KR1020047008774A Expired - Fee Related KR100904627B1 (ko) 2001-12-07 2002-12-04 부타디엔/이소프렌 공중합체의 제조방법 및 이로부터생성된 공중합체

Country Status (12)

Country Link
US (2) US7115693B2 (https=)
EP (1) EP1456260B1 (https=)
JP (2) JP4741185B2 (https=)
KR (2) KR100939651B1 (https=)
CN (1) CN1273508C (https=)
AT (1) ATE393176T1 (https=)
AU (1) AU2002361972A1 (https=)
BR (1) BR0214685B1 (https=)
DE (1) DE60226270T2 (https=)
ES (1) ES2305339T3 (https=)
RU (1) RU2301236C2 (https=)
WO (1) WO2003048221A1 (https=)

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JP5111101B2 (ja) * 2004-03-02 2012-12-26 株式会社ブリヂストン バルク重合プロセス
DE102004022676A1 (de) * 2004-05-07 2005-12-15 Bayer Ag Hydrierte Copolymerisate aus nicht substituierten und substituierten konjugierten Dienen
FR2886937B1 (fr) * 2005-06-14 2007-08-10 Michelin Soc Tech Procede de preparation d'un elastomere dienique, tel qu'un polybutadiene
US20080090852A1 (en) * 2006-10-13 2008-04-17 Colin Andrew Leach Bicyclic Heteroaromatic Compounds
US7705005B2 (en) * 2006-10-13 2010-04-27 Glaxo Group Limited Bicyclic heteroaromatic compounds
US20080090851A1 (en) * 2006-10-13 2008-04-17 Colin Andrew Leach Bicyclic Heteroaromatic Compounds
DE102007050119A1 (de) * 2007-10-19 2009-04-23 Robert Bosch Gmbh Speichervorrichtung, Sensorelement und Verfahren zur qualitativen und/oder quantitativen Bestimmung mindestens einer Gaskomponente, insbesondere von Stickoxiden, in einem Gas
US7820580B2 (en) 2007-11-15 2010-10-26 Bridgestone Corporation Nickel-based catalysts for preparing high cis 1,4-polydienes
RU2515980C2 (ru) * 2007-12-31 2014-05-20 Бриджстоун Корпорейшн Способ получения полидиенов полимеризацией в объеме
US8394901B2 (en) 2008-04-29 2013-03-12 Changchun Institute Of Applied Chemistry Chinese Academy Of Sciences Bi-component catalyst system for isoprene or butadiene cis 1, 4-polymerization and polymerization process
EP2291415B1 (en) 2008-06-20 2016-07-20 Bridgestone Corporation Catalysts for preparing cis 1,4-polydienes
EP2470574B1 (en) * 2009-08-24 2014-09-17 Bridgestone Corporation Process and catalyst system for polydiene production
CN102234356B (zh) * 2010-04-30 2013-03-06 青岛伊科思新材料股份有限公司 稀土戊丁橡胶的生产方法
CN101831032B (zh) * 2010-05-19 2012-05-02 中国科学院长春应用化学研究所 一种丁二烯异戊二烯共聚物的制备方法
WO2014010249A1 (ja) * 2012-07-12 2014-01-16 株式会社ブリヂストン 重合体組成物の製造方法及び重合体組成物
CN104428332B (zh) * 2012-07-12 2016-09-14 株式会社普利司通 异戊二烯共聚物及其制造方法
CN103626926B (zh) * 2012-08-21 2016-03-30 中国石油化工股份有限公司 一种聚丁二烯接枝异戊橡胶及其制备方法和硫化胶及混炼胶
CN103665197B (zh) * 2012-09-18 2015-12-02 中国石油天然气股份有限公司 一种均相稀土催化剂及其在共轭二烯烃聚合中的应用
CN104130350B (zh) * 2013-05-02 2017-08-22 中国石油化工股份有限公司 一种丁二烯‑异戊二烯共聚物橡胶及其制备方法
TWI522378B (zh) * 2013-12-13 2016-02-21 奇美實業股份有限公司 改質的高順式丁二烯－異戊二烯系共聚物、其製造方法及含有前述聚合物的輪胎
CN103980425B (zh) * 2014-06-09 2019-03-12 华宇橡胶有限责任公司 高顺式含量丁二烯-异戊二烯共聚物的制备方法
US20170335032A1 (en) * 2014-11-17 2017-11-23 Bridgestone Corporation Bulk polymerization of polyisoprene with preformed catalyst
IT201800005841A1 (it) * 2018-05-30 2019-11-30 Procedimento per la preparazione di copolimeri random butadiene-isoprene ad elevato contenuto di unita’ 1,4-cis
CN112552451B (zh) * 2019-09-25 2022-08-19 中国石油化工股份有限公司 无规丁二烯-异戊二烯共聚物及其合成方法和低滚阻汽车轮胎胎面胶
EP3838932B1 (en) 2019-12-20 2022-08-10 The Goodyear Tire & Rubber Company Synthesis of isoprene-butadiene copolymer rubbers

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0846707A1 (en) * 1996-12-04 1998-06-10 Japan Synthetic Rubber Co., Ltd. Method for preparing conjugated diene polymer

Family Cites Families (9)

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US3541063A (en) * 1967-12-29 1970-11-17 Goodyear Tire & Rubber Process for the polymerization of diolefins with a catalyst comprising alkylaluminum compounds,group iii-b organo metal compounds and organoaluminum fluoride compounds
JPS6023406A (ja) * 1983-07-18 1985-02-06 Asahi Chem Ind Co Ltd ポリブタジエンの製造方法
US5405815A (en) * 1993-06-17 1995-04-11 The Goodyear Tire & Rubber Company Process for preparing a catalyst system useful in the synthesis of isoprene-butadiene rubber
RU2087488C1 (ru) * 1994-03-16 1997-08-20 Акционерное общество открытого типа "Ефремовский завод синтетического каучука" Способ получения цис-1,4-полибутадиена и цис-1,4-сополимера бутадиена и изопрена
RU2127281C1 (ru) * 1997-03-11 1999-03-10 Акционерное общество открытого типа "Ефремовский завод синтетического каучука" Способ получения цис-1,4-полибутадиена и цис-1,4-сополимера бутадиена и изопрена
RU2127280C1 (ru) * 1997-03-11 1999-03-10 Акционерное общество открытого типа "Ефремовский завод синтетического каучука" Способ получения цис-1,4-полибутадиена и цис-1,4-сополимера бутадиена и изопрена
JP2001048940A (ja) * 1999-08-06 2001-02-20 Nippon Zeon Co Ltd ブタジエン系重合体及びその製造方法
CA2427984A1 (fr) * 2000-11-09 2002-05-16 Michelin Recherche Et Technique S.A. Systeme catalytique et procede de preparation d'elastomeres au moyen de ce systeme
US7022783B2 (en) * 2001-12-31 2006-04-04 The Goodyear Tire & Rubber Company Group III-B metal catalyst system

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0846707A1 (en) * 1996-12-04 1998-06-10 Japan Synthetic Rubber Co., Ltd. Method for preparing conjugated diene polymer

Also Published As

Publication number Publication date
WO2003048221A1 (fr) 2003-06-12
KR100904627B1 (ko) 2009-06-25
JP4741185B2 (ja) 2011-08-03
JP2005511806A (ja) 2005-04-28
DE60226270D1 (de) 2008-06-05
KR20090058577A (ko) 2009-06-09
EP1456260A1 (fr) 2004-09-15
US20050004333A1 (en) 2005-01-06
KR20040064298A (ko) 2004-07-16
CN1273508C (zh) 2006-09-06
US20060270817A1 (en) 2006-11-30
BR0214685A (pt) 2004-12-07
JP2011094157A (ja) 2011-05-12
CN1599762A (zh) 2005-03-23
ATE393176T1 (de) 2008-05-15
AU2002361972A1 (en) 2003-06-17
US7169870B2 (en) 2007-01-30
ES2305339T3 (es) 2008-11-01
EP1456260B1 (fr) 2008-04-23
RU2301236C2 (ru) 2007-06-20
DE60226270T2 (de) 2009-07-16
BR0214685B1 (pt) 2012-08-21
RU2004120699A (ru) 2005-03-27
US7115693B2 (en) 2006-10-03

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