JP2005506404A5 - - Google Patents
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- JP2005506404A5 JP2005506404A5 JP2003536282A JP2003536282A JP2005506404A5 JP 2005506404 A5 JP2005506404 A5 JP 2005506404A5 JP 2003536282 A JP2003536282 A JP 2003536282A JP 2003536282 A JP2003536282 A JP 2003536282A JP 2005506404 A5 JP2005506404 A5 JP 2005506404A5
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- JP
- Japan
- Prior art keywords
- group
- phn
- nph
- metal
- php
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000460 chlorine Substances 0.000 claims 125
- 229910052751 metal Inorganic materials 0.000 claims 32
- 239000002184 metal Substances 0.000 claims 32
- 229910052801 chlorine Inorganic materials 0.000 claims 28
- 150000001875 compounds Chemical class 0.000 claims 27
- 239000003054 catalyst Substances 0.000 claims 26
- 239000000203 mixture Substances 0.000 claims 21
- 125000001183 hydrocarbyl group Chemical group 0.000 claims 17
- 229910052779 Neodymium Inorganic materials 0.000 claims 12
- 150000004696 coordination complex Chemical class 0.000 claims 12
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims 10
- 239000012190 activator Substances 0.000 claims 10
- 229910052723 transition metal Inorganic materials 0.000 claims 9
- 150000003624 transition metals Chemical class 0.000 claims 9
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 7
- -1 R 29 Chemical compound 0.000 claims 6
- 150000001450 anions Chemical class 0.000 claims 5
- 125000003118 aryl group Chemical group 0.000 claims 5
- 229910052731 fluorine Inorganic materials 0.000 claims 5
- 239000000463 material Substances 0.000 claims 5
- 238000000034 method Methods 0.000 claims 5
- 239000003607 modifier Substances 0.000 claims 5
- 125000004429 atom Chemical group 0.000 claims 4
- 229910052739 hydrogen Inorganic materials 0.000 claims 4
- 239000001257 hydrogen Substances 0.000 claims 4
- 239000003446 ligand Substances 0.000 claims 4
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 claims 4
- 229910052757 nitrogen Inorganic materials 0.000 claims 4
- 230000001590 oxidative effect Effects 0.000 claims 4
- 229910052698 phosphorus Inorganic materials 0.000 claims 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical group N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims 3
- 239000002879 Lewis base Substances 0.000 claims 3
- 229910007926 ZrCl Inorganic materials 0.000 claims 3
- 229910052782 aluminium Inorganic materials 0.000 claims 3
- 229910052796 boron Inorganic materials 0.000 claims 3
- 229910052794 bromium Inorganic materials 0.000 claims 3
- 125000004432 carbon atom Chemical group C* 0.000 claims 3
- 125000002091 cationic group Chemical group 0.000 claims 3
- 238000006243 chemical reaction Methods 0.000 claims 3
- 150000004820 halides Chemical group 0.000 claims 3
- 229910052747 lanthanoid Inorganic materials 0.000 claims 3
- 150000002602 lanthanoids Chemical group 0.000 claims 3
- 150000007527 lewis bases Chemical class 0.000 claims 3
- 230000007935 neutral effect Effects 0.000 claims 3
- 239000007800 oxidant agent Substances 0.000 claims 3
- 229910052760 oxygen Inorganic materials 0.000 claims 3
- 150000003839 salts Chemical group 0.000 claims 3
- 229910052717 sulfur Inorganic materials 0.000 claims 3
- APPOKADJQUIAHP-GGWOSOGESA-N (2e,4e)-hexa-2,4-diene Chemical compound C\C=C\C=C\C APPOKADJQUIAHP-GGWOSOGESA-N 0.000 claims 2
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 claims 2
- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical compound C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 claims 2
- CJSBUWDGPXGFGA-UHFFFAOYSA-N 4-methylpenta-1,3-diene Chemical compound CC(C)=CC=C CJSBUWDGPXGFGA-UHFFFAOYSA-N 0.000 claims 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical group F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims 2
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 claims 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims 2
- 239000007983 Tris buffer Substances 0.000 claims 2
- 125000000217 alkyl group Chemical group 0.000 claims 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims 2
- 239000004927 clay Substances 0.000 claims 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims 2
- 229910002804 graphite Inorganic materials 0.000 claims 2
- 239000010439 graphite Substances 0.000 claims 2
- 150000002500 ions Chemical class 0.000 claims 2
- 230000003647 oxidation Effects 0.000 claims 2
- 238000007254 oxidation reaction Methods 0.000 claims 2
- 239000001301 oxygen Substances 0.000 claims 2
- 239000011574 phosphorus Chemical group 0.000 claims 2
- SCABQASLNUQUKD-UHFFFAOYSA-N silylium Chemical compound [SiH3+] SCABQASLNUQUKD-UHFFFAOYSA-N 0.000 claims 2
- 239000011593 sulfur Chemical group 0.000 claims 2
- RRKODOZNUZCUBN-CCAGOZQPSA-N (1z,3z)-cycloocta-1,3-diene Chemical compound C1CC\C=C/C=C\C1 RRKODOZNUZCUBN-CCAGOZQPSA-N 0.000 claims 1
- LWNGJAHMBMVCJR-UHFFFAOYSA-N (2,3,4,5,6-pentafluorophenoxy)boronic acid Chemical compound OB(O)OC1=C(F)C(F)=C(F)C(F)=C1F LWNGJAHMBMVCJR-UHFFFAOYSA-N 0.000 claims 1
- OGQVROWWFUXRST-FNORWQNLSA-N (3e)-hepta-1,3-diene Chemical compound CCC\C=C\C=C OGQVROWWFUXRST-FNORWQNLSA-N 0.000 claims 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 claims 1
- OWYDKGVEFPWBNN-UHFFFAOYSA-K 1,2-dimethoxyethane;trichloroneodymium Chemical compound Cl[Nd](Cl)Cl.COCCOC OWYDKGVEFPWBNN-UHFFFAOYSA-K 0.000 claims 1
- QTYUSOHYEPOHLV-FNORWQNLSA-N 1,3-Octadiene Chemical compound CCCC\C=C\C=C QTYUSOHYEPOHLV-FNORWQNLSA-N 0.000 claims 1
- NMXLXQGHBSPIDR-UHFFFAOYSA-N 2-(2-methylpropyl)oxaluminane Chemical compound CC(C)C[Al]1CCCCO1 NMXLXQGHBSPIDR-UHFFFAOYSA-N 0.000 claims 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- 239000007848 Bronsted acid Substances 0.000 claims 1
- KJQMOGOKAYDMOR-UHFFFAOYSA-N CC(=C)C=C.CC(=C)C=C Chemical compound CC(=C)C=C.CC(=C)C=C KJQMOGOKAYDMOR-UHFFFAOYSA-N 0.000 claims 1
- FLAKGKCBSLMHQU-UHFFFAOYSA-N CC[Mg] Chemical compound CC[Mg] FLAKGKCBSLMHQU-UHFFFAOYSA-N 0.000 claims 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 claims 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 239000002841 Lewis acid Substances 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims 1
- 229910052768 actinide Inorganic materials 0.000 claims 1
- 150000001255 actinides Chemical class 0.000 claims 1
- 239000013543 active substance Substances 0.000 claims 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 150000001639 boron compounds Chemical class 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 239000006229 carbon black Substances 0.000 claims 1
- 125000005626 carbonium group Chemical group 0.000 claims 1
- 150000007942 carboxylates Chemical class 0.000 claims 1
- 239000003610 charcoal Substances 0.000 claims 1
- BOXSCYUXSBYGRD-UHFFFAOYSA-N cyclopenta-1,3-diene;iron(3+) Chemical class [Fe+3].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 BOXSCYUXSBYGRD-UHFFFAOYSA-N 0.000 claims 1
- 150000001993 dienes Chemical class 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 150000002222 fluorine compounds Chemical group 0.000 claims 1
- XPBBUZJBQWWFFJ-UHFFFAOYSA-N fluorosilane Chemical group [SiH3]F XPBBUZJBQWWFFJ-UHFFFAOYSA-N 0.000 claims 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 claims 1
- 150000007517 lewis acids Chemical class 0.000 claims 1
- UBJFKNSINUCEAL-UHFFFAOYSA-N lithium;2-methylpropane Chemical compound [Li+].C[C-](C)C UBJFKNSINUCEAL-UHFFFAOYSA-N 0.000 claims 1
- DLPASUVGCQPFFO-UHFFFAOYSA-N magnesium;ethane Chemical compound [Mg+2].[CH2-]C.[CH2-]C DLPASUVGCQPFFO-UHFFFAOYSA-N 0.000 claims 1
- 150000002736 metal compounds Chemical class 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- DVSDBMFJEQPWNO-UHFFFAOYSA-N methyllithium Chemical compound C[Li] DVSDBMFJEQPWNO-UHFFFAOYSA-N 0.000 claims 1
- 239000000178 monomer Substances 0.000 claims 1
- DULHRAISQRWLNQ-UHFFFAOYSA-K n,n-diethylethanamine;trichloroneodymium Chemical compound Cl[Nd](Cl)Cl.CCN(CC)CC DULHRAISQRWLNQ-UHFFFAOYSA-K 0.000 claims 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 claims 1
- OSQVTPUWIIDSDY-UHFFFAOYSA-K neodymium(3+);oxolane;trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Nd+3].C1CCOC1 OSQVTPUWIIDSDY-UHFFFAOYSA-K 0.000 claims 1
- ATINCSYRHURBSP-UHFFFAOYSA-K neodymium(iii) chloride Chemical compound Cl[Nd](Cl)Cl ATINCSYRHURBSP-UHFFFAOYSA-K 0.000 claims 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims 1
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-O oxonium Chemical compound [OH3+] XLYOFNOQVPJJNP-UHFFFAOYSA-O 0.000 claims 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 claims 1
- 230000000737 periodic effect Effects 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 claims 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 claims 1
- 125000003638 stannyl group Chemical group [H][Sn]([H])([H])* 0.000 claims 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 claims 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims 1
- 125000005208 trialkylammonium group Chemical group 0.000 claims 1
- POHPFVPVRKJHCR-UHFFFAOYSA-N tris(2,3,4,5,6-pentafluorophenyl)alumane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1[Al](C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F POHPFVPVRKJHCR-UHFFFAOYSA-N 0.000 claims 1
- OBAJXDYVZBHCGT-UHFFFAOYSA-N tris(pentafluorophenyl)borane Chemical compound FC1=C(F)C(F)=C(F)C(F)=C1B(C=1C(=C(F)C(F)=C(F)C=1F)F)C1=C(F)C(F)=C(F)C(F)=C1F OBAJXDYVZBHCGT-UHFFFAOYSA-N 0.000 claims 1
- RXOKKZBVQOZILW-UHFFFAOYSA-N tris[3,5-bis(trifluoromethyl)phenyl]alumane Chemical compound FC(F)(F)C1=CC(C(F)(F)F)=CC([Al](C=2C=C(C=C(C=2)C(F)(F)F)C(F)(F)F)C=2C=C(C=C(C=2)C(F)(F)F)C(F)(F)F)=C1 RXOKKZBVQOZILW-UHFFFAOYSA-N 0.000 claims 1
- BPKXQSLAVGBZEM-UHFFFAOYSA-N tris[3,5-bis(trifluoromethyl)phenyl]borane Chemical compound FC(F)(F)C1=CC(C(F)(F)F)=CC(B(C=2C=C(C=C(C=2)C(F)(F)F)C(F)(F)F)C=2C=C(C=C(C=2)C(F)(F)F)C(F)(F)F)=C1 BPKXQSLAVGBZEM-UHFFFAOYSA-N 0.000 claims 1
- 229910052720 vanadium Chemical group 0.000 claims 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical group [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US32893701P | 2001-10-12 | 2001-10-12 | |
| US32893501P | 2001-10-12 | 2001-10-12 | |
| US40486602P | 2002-08-21 | 2002-08-21 | |
| PCT/US2002/031989 WO2003033545A2 (en) | 2001-10-12 | 2002-10-07 | Metal complex compositions and their use as catalysts to produce polydienes |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2005506404A JP2005506404A (ja) | 2005-03-03 |
| JP2005506404A5 true JP2005506404A5 (enExample) | 2005-12-22 |
Family
ID=27406641
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2003536282A Pending JP2005506404A (ja) | 2001-10-12 | 2002-10-07 | 金属錯体組成物、及び金属錯体組成物のポリジエン製造用触媒としての使用法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US20050090383A1 (enExample) |
| EP (1) | EP1436332A2 (enExample) |
| JP (1) | JP2005506404A (enExample) |
| KR (1) | KR20050034609A (enExample) |
| CN (1) | CN1568332A (enExample) |
| BR (1) | BR0213639A (enExample) |
| CA (1) | CA2462348A1 (enExample) |
| MX (1) | MXPA04003409A (enExample) |
| WO (1) | WO2003033545A2 (enExample) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101092349B1 (ko) | 2003-02-21 | 2011-12-09 | 다우 글로벌 테크놀로지스 엘엘씨 | 공액 올레핀의 단독중합법 또는 공중합법 |
| JP4207814B2 (ja) * | 2004-03-19 | 2009-01-14 | 宇部興産株式会社 | トランス−１，４−ポリブタジエンの製造方法 |
| BRPI0509641B1 (pt) | 2004-04-05 | 2016-08-16 | Bridgestone Corp | "polímero de dieno conjugado modificado terminal e seus métodos de produção, iniciador de polimerização e seu método de produção, solução iniciadora de polimerização, e composição de borracha" |
| DE102004022676A1 (de) * | 2004-05-07 | 2005-12-15 | Bayer Ag | Hydrierte Copolymerisate aus nicht substituierten und substituierten konjugierten Dienen |
| US7297653B2 (en) | 2005-07-21 | 2007-11-20 | Exxonmobil Chemical Patents Inc. | Fluorophenylborates and their use as activators in catalyst systems for olefin polymerization |
| JO3598B1 (ar) * | 2006-10-10 | 2020-07-05 | Infinity Discovery Inc | الاحماض والاسترات البورونية كمثبطات اميد هيدروليز الحامض الدهني |
| US7820580B2 (en) * | 2007-11-15 | 2010-10-26 | Bridgestone Corporation | Nickel-based catalysts for preparing high cis 1,4-polydienes |
| WO2009126691A1 (en) * | 2008-04-09 | 2009-10-15 | Infinity Pharmaceuticals, Inc | Inhibitors of fatty acid amide hydrolase |
| US8609574B2 (en) * | 2008-04-25 | 2013-12-17 | Promerus Llc | In situ olefin polymerization catalyst system |
| ES2595977T3 (es) * | 2008-06-20 | 2017-01-04 | Bridgestone Corporation | Catalizadores para preparar cis 1,4-polidienos |
| WO2010118159A1 (en) | 2009-04-07 | 2010-10-14 | Infinity Pharmaceuticals, Inc. | Inhibitors of fatty acid amide hydrolase |
| EP2416660B1 (en) | 2009-04-07 | 2014-07-02 | Infinity Pharmaceuticals, Inc. | Inhibitors of fatty acid amide hydrolase |
| FR2944800B1 (fr) | 2009-04-28 | 2012-10-26 | Michelin Soc Tech | Systemes catalytiques a base d'un complexe de terres rares pour la polymerisation stereospecifique des dienes conjugues |
| FR2946047B1 (fr) | 2009-06-02 | 2011-07-29 | Michelin Soc Tech | Nouveaux composes organometallique a base d'un metal appartenant a la 2eme colonne de la classification periodique et procede de preparation |
| FR2946048B1 (fr) | 2009-06-02 | 2012-12-28 | Michelin Soc Tech | Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu |
| AU2011213072C1 (en) | 2010-02-03 | 2016-12-15 | Infinity Pharmaceuticals, Inc. | Fatty acid amide hydrolase inhibitors |
| CN102432702B (zh) * | 2010-09-29 | 2013-11-06 | 中国石油化工股份有限公司 | 一种烯烃聚合催化剂组合物 |
| CN105732401A (zh) * | 2010-11-02 | 2016-07-06 | 宇部兴产株式会社 | (酰胺氨基烷烃)金属化合物及使用所述金属化合物制备含金属的薄膜的方法 |
| EP2641909A1 (en) | 2012-03-19 | 2013-09-25 | LANXESS Deutschland GmbH | Transition metal P-N complexes as polymerization catalysts |
| CN104245749B (zh) | 2012-04-18 | 2017-03-01 | 株式会社普利司通 | 聚合催化剂组合物的制造方法、聚合催化剂组合物、聚合物组合物的制造方法和聚合物组合物 |
| CN104379613B (zh) | 2012-05-30 | 2018-12-04 | 株式会社普利司通 | 聚合催化剂组合物、合成聚异戊二烯的制造方法和合成聚异戊二烯 |
| EP2871191B1 (en) * | 2012-07-04 | 2017-11-01 | Bridgestone Corporation | Method for producing polybutadiene, polybutadiene, rubber composition and tire |
| JP6031375B2 (ja) * | 2013-02-14 | 2016-11-24 | 株式会社ブリヂストン | 重合触媒組成物、合成ポリイソプレンの製造方法、及び合成ポリイソプレン |
| EP3245258B1 (en) | 2015-01-06 | 2019-09-11 | Scg Chemicals Co. Ltd. | Sio2-layered double hydroxide microspheres and methods of making them |
| CN105199028B (zh) * | 2015-09-12 | 2021-11-16 | 青岛科技大学 | 一种微观结构可调节的高乙烯基聚丁二烯橡胶及其制备方法 |
| DK3362462T3 (da) | 2015-10-12 | 2021-10-11 | Advanced Cell Diagnostics Inc | In situ-detektion af nukleotidvarianter i prøver med højt støjniveau, og sammensætninger og fremgangsmåder relateret dertil |
| CN106589195B (zh) * | 2015-10-19 | 2018-11-02 | 中国石油化工股份有限公司 | 一种制备聚异戊二烯的方法 |
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| CN113402637B (zh) * | 2021-05-25 | 2022-07-05 | 中国石油天然气股份有限公司 | 稀土催化剂及其制备方法、包含其的稀土催化剂组合物及应用 |
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| CN115260367B (zh) * | 2022-08-26 | 2023-10-10 | 中国科学院长春应用化学研究所 | 稀土金属配合物在乙烯和1,3-丁二烯制备乙烯/丁二烯共聚物过程中的应用 |
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2002
- 2002-10-07 JP JP2003536282A patent/JP2005506404A/ja active Pending
- 2002-10-07 BR BR0213639-2A patent/BR0213639A/pt not_active Application Discontinuation
- 2002-10-07 EP EP02782127A patent/EP1436332A2/en not_active Withdrawn
- 2002-10-07 CN CNA028201345A patent/CN1568332A/zh active Pending
- 2002-10-07 WO PCT/US2002/031989 patent/WO2003033545A2/en not_active Ceased
- 2002-10-07 CA CA002462348A patent/CA2462348A1/en not_active Abandoned
- 2002-10-07 US US10/489,370 patent/US20050090383A1/en not_active Abandoned
- 2002-10-07 KR KR1020047005411A patent/KR20050034609A/ko not_active Withdrawn
- 2002-10-07 MX MXPA04003409A patent/MXPA04003409A/es not_active Application Discontinuation
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