MXPA04003409A - Composiciones de complejo metalico y su uso como catalizadores para producir polidienos. - Google Patents

Composiciones de complejo metalico y su uso como catalizadores para producir polidienos.

Info

Publication number
MXPA04003409A
MXPA04003409A MXPA04003409A MXPA04003409A MXPA04003409A MX PA04003409 A MXPA04003409 A MX PA04003409A MX PA04003409 A MXPA04003409 A MX PA04003409A MX PA04003409 A MXPA04003409 A MX PA04003409A MX PA04003409 A MXPA04003409 A MX PA04003409A
Authority
MX
Mexico
Prior art keywords
optionally
metal complex
catalysts
complex compositions
transition metal
Prior art date
Application number
MXPA04003409A
Other languages
English (en)
Inventor
Stoye Hartmut
Original Assignee
Dow Global Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dow Global Technologies Inc filed Critical Dow Global Technologies Inc
Publication of MXPA04003409A publication Critical patent/MXPA04003409A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated

Abstract

La presente invencion se refiere a composiciones de complejo metalico, su preparacion y su uso como catalizadores para producir polimeros de dienos conjugados a traves de la polimerizacion de monomeros de dieno conjugado. Las composiciones de complejo metalico utilizadas son compuestos de metal de transicion en combinacion con un compuesto activador, opcionalmente con un compuesto de haluro de metal de transicion y opcionalmente un modificador catalitico y opcionalmente un material de soporte inorganico u organico. Los complejos metalicos comprenden metales del grupo 3 a 10 del Sistema Periodico de los Elementos en combinacion con activadores, y opcionalmente compuestos de haluro de metal de transicion de los grupos 3 a 10 de la Tabla periodica de los Elementos que incluye metales lantanidos y metales actinidos y opcionalmente, modificadores cataliticos, especialmente acidos de Lewis y opcionalmente un materia de soporte inorganico u organico. Mas en particular, la invencion se refiere a composiciones de complejo metalico, su preparacion y su uso como catalizadores para producir homopolimeros de dienos conjugados, de preferencia, pero no limitados a, a traves de la polimerizacion de 1,3-butadieno o isopreno.
MXPA04003409A 2001-10-12 2002-10-07 Composiciones de complejo metalico y su uso como catalizadores para producir polidienos. MXPA04003409A (es)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US32893701P 2001-10-12 2001-10-12
US32893501P 2001-10-12 2001-10-12
US40486602P 2002-08-21 2002-08-21
PCT/US2002/031989 WO2003033545A2 (en) 2001-10-12 2002-10-07 Metal complex compositions and their use as catalysts to produce polydienes

Publications (1)

Publication Number Publication Date
MXPA04003409A true MXPA04003409A (es) 2004-07-30

Family

ID=27406641

Family Applications (1)

Application Number Title Priority Date Filing Date
MXPA04003409A MXPA04003409A (es) 2001-10-12 2002-10-07 Composiciones de complejo metalico y su uso como catalizadores para producir polidienos.

Country Status (9)

Country Link
US (1) US20050090383A1 (es)
EP (1) EP1436332A2 (es)
JP (1) JP2005506404A (es)
KR (1) KR20050034609A (es)
CN (1) CN1568332A (es)
BR (1) BR0213639A (es)
CA (1) CA2462348A1 (es)
MX (1) MXPA04003409A (es)
WO (1) WO2003033545A2 (es)

Families Citing this family (42)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2267046B1 (en) * 2003-02-21 2013-08-07 Styron Europe GmbH Process for homo- or copolymerization of conjugated olefines
JP4207814B2 (ja) * 2004-03-19 2009-01-14 宇部興産株式会社 トランス−１，４−ポリブタジエンの製造方法
CN1961011B (zh) * 2004-04-05 2013-09-11 株式会社普利司通 改性共轭二烯类聚合物、聚合引发剂及其制备方法和橡胶组合物
DE102004022676A1 (de) * 2004-05-07 2005-12-15 Bayer Ag Hydrierte Copolymerisate aus nicht substituierten und substituierten konjugierten Dienen
US7297653B2 (en) 2005-07-21 2007-11-20 Exxonmobil Chemical Patents Inc. Fluorophenylborates and their use as activators in catalyst systems for olefin polymerization
JO3598B1 (ar) 2006-10-10 2020-07-05 Infinity Discovery Inc الاحماض والاسترات البورونية كمثبطات اميد هيدروليز الحامض الدهني
US7820580B2 (en) * 2007-11-15 2010-10-26 Bridgestone Corporation Nickel-based catalysts for preparing high cis 1,4-polydienes
CA2721060A1 (en) * 2008-04-09 2009-10-15 Infinity Pharmaceuticals, Inc. Inhibitors of fatty acid amide hydrolase
US8609574B2 (en) * 2008-04-25 2013-12-17 Promerus Llc In situ olefin polymerization catalyst system
EP2291415B1 (en) * 2008-06-20 2016-07-20 Bridgestone Corporation Catalysts for preparing cis 1,4-polydienes
JP2012523425A (ja) 2009-04-07 2012-10-04 インフイニトイ プハルマセウトイカルス インコーポレイテッド 脂肪酸アミドヒドロラーゼの阻害薬
EP2416660B1 (en) 2009-04-07 2014-07-02 Infinity Pharmaceuticals, Inc. Inhibitors of fatty acid amide hydrolase
FR2944800B1 (fr) 2009-04-28 2012-10-26 Michelin Soc Tech Systemes catalytiques a base d'un complexe de terres rares pour la polymerisation stereospecifique des dienes conjugues
FR2946047B1 (fr) * 2009-06-02 2011-07-29 Michelin Soc Tech Nouveaux composes organometallique a base d'un metal appartenant a la 2eme colonne de la classification periodique et procede de preparation
FR2946048B1 (fr) 2009-06-02 2012-12-28 Michelin Soc Tech Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu
MX361011B (es) * 2010-02-03 2018-11-26 Infinity Pharmaceuticals Inc Inhibidores de amida hidrolasa de ácido graso.
CN102432702B (zh) * 2010-09-29 2013-11-06 中国石油化工股份有限公司 一种烯烃聚合催化剂组合物
CN105732401A (zh) * 2010-11-02 2016-07-06 宇部兴产株式会社 (酰胺氨基烷烃)金属化合物及使用所述金属化合物制备含金属的薄膜的方法
EP2641909A1 (en) 2012-03-19 2013-09-25 LANXESS Deutschland GmbH Transition metal P-N complexes as polymerization catalysts
EP2840095B1 (en) * 2012-04-18 2020-06-17 Bridgestone Corporation Method for producing polymerization catalyst composition, polymerization catalyst composition, method for producing polymer composition, and polymer composition
RU2590155C2 (ru) * 2012-05-30 2016-07-10 Бриджстоун Корпорейшн Композиция катализатора полимеризации, способ получения синтетического полиизопрена и синтетический полиизопрен
SG11201408828TA (en) 2012-07-04 2015-02-27 Bridgestone Corp Method for producing polybutadiene, polybutadiene, rubber composition and tire
JP6031375B2 (ja) * 2013-02-14 2016-11-24 株式会社ブリヂストン 重合触媒組成物、合成ポリイソプレンの製造方法、及び合成ポリイソプレン
SG11201705078TA (en) 2015-01-06 2017-07-28 Scg Chemicals Co Ltd SIO<sb>2</sb>-LAYERED DOUBLE HYDROXIDE MICROSPHERES AND METHODS OF MAKING THEM
CN105199028B (zh) * 2015-09-12 2021-11-16 青岛科技大学 一种微观结构可调节的高乙烯基聚丁二烯橡胶及其制备方法
ES2893100T3 (es) 2015-10-12 2022-02-08 Advanced Cell Diagnostics Inc Detección in situ de variantes de nucleótidos en muestras con un elevado nivel de ruido, y composiciones y métodos relacionados con ésta
CN106589239B (zh) * 2015-10-19 2019-04-19 中国石油化工股份有限公司 一种制备丁二烯/异戊二烯共聚物的方法
CN106589195B (zh) * 2015-10-19 2018-11-02 中国石油化工股份有限公司 一种制备聚异戊二烯的方法
CN106588962A (zh) * 2015-10-19 2017-04-26 中国石油化工股份有限公司 稀土金属有机化合物和稀土催化剂组合物及其制备方法和应用
EP3159346B1 (en) 2015-10-21 2018-07-04 Trinseo Europe GmbH Aminosilane-functionalized dienes for use in functionalization of elastomeric polymers
JP2017082137A (ja) * 2015-10-29 2017-05-18 株式会社ブリヂストン 変性共役ジエン重合体の製造方法、変性共役ジエン重合体、ゴム組成物、及びタイヤ
GB201607989D0 (en) * 2016-05-06 2016-06-22 Scg Chemicals Co Ltd Catalytic support and the uses thereof
GB201608384D0 (en) 2016-05-12 2016-06-29 Scg Chemicals Co Ltd Unsymmetrical metallocene catalysts and uses thereof
CN108164646B (zh) * 2016-12-08 2020-09-15 中国石油化工股份有限公司 一种由蒸汽裂化c5石脑油馏分制备聚异戊二烯的方法
KR102363032B1 (ko) 2018-03-21 2022-02-16 주식회사 엘지화학 전이금속 복합체의 제조 방법
CN112642428B (zh) * 2019-10-12 2023-05-02 中国石油化工股份有限公司 催化剂及其制备方法和应用以及废气的处理方法
CN110628010B (zh) * 2019-10-18 2022-09-27 辽宁奥克医药辅料股份有限公司 一种催化剂组合物及其应用于制备中等分子量聚乙二醇的方法
CN113735686B (zh) * 2020-05-29 2023-10-10 中国石油化工股份有限公司 一种环烷烃的催化氧化方法
CN113402637B (zh) * 2021-05-25 2022-07-05 中国石油天然气股份有限公司 稀土催化剂及其制备方法、包含其的稀土催化剂组合物及应用
KR102569201B1 (ko) * 2021-06-04 2023-08-23 주식회사 한솔케미칼 유기 금속 화합물 제조방법 및 이를 이용하여 박막을 형성하는 방법
FR3123917B1 (fr) * 2021-06-10 2024-04-19 Cie Generale Des Etablissements Michelin Système catalytique pour la polymérisation stéréospécifique de diènes et leur utilisation en procédé de synthèse de polymères diéniques
CN115260367B (zh) * 2022-08-26 2023-10-10 中国科学院长春应用化学研究所 稀土金属配合物在乙烯和1,3-丁二烯制备乙烯/丁二烯共聚物过程中的应用

Family Cites Families (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1068433B (it) * 1976-10-28 1985-03-21 Snam Progetti Procedimento per l'lachilazione di ammine secondarie alifatiche
CA1212932A (en) * 1982-04-01 1986-10-21 Derek K. Jenkins Polymerisation of conjugated dienes
FR2567135B1 (fr) * 1984-07-03 1989-01-13 Asahi Chemical Ind Polymere ou copolymere de butadiene et procede de preparation
US4575538A (en) * 1984-12-20 1986-03-11 Phillips Petroleum Company Olefin polymerization
US5153157A (en) * 1987-01-30 1992-10-06 Exxon Chemical Patents Inc. Catalyst system of enhanced productivity
US5064802A (en) * 1989-09-14 1991-11-12 The Dow Chemical Company Metal complex compounds
JP2545006B2 (ja) * 1990-07-03 1996-10-16 ザ ダウ ケミカル カンパニー 付加重合触媒
US5721185A (en) * 1991-06-24 1998-02-24 The Dow Chemical Company Homogeneous olefin polymerization catalyst by abstraction with lewis acids
US5296433A (en) * 1992-04-14 1994-03-22 Minnesota Mining And Manufacturing Company Tris(pentafluorophenyl)borane complexes and catalysts derived therefrom
US5350723A (en) * 1992-05-15 1994-09-27 The Dow Chemical Company Process for preparation of monocyclopentadienyl metal complex compounds and method of use
ZA94612B (en) * 1993-01-29 1995-07-28 Dow Chemical Co Ethylene interpolymerization
US5625087A (en) * 1994-09-12 1997-04-29 The Dow Chemical Company Silylium cationic polymerization activators for metallocene complexes
DE4436059A1 (de) * 1994-10-10 1996-04-11 Bayer Ag Verfahren zur Herstellung von mittels Nd-Katalysatoren polymerisierten Dienkautschuken mit niedrigem cold-flow und geringem Eigengeruch
HUP9801224A3 (en) * 1995-03-10 1998-11-30 Dow Chemical Co Supported catalyst component, supported catalyst, preparation process, polymerization process, complex compounds, and their preparation
DE19512116A1 (de) * 1995-04-04 1996-10-10 Bayer Ag Gasphasenpolymerisation von konjugierten Dienen in Gegenwart von Allylverbindungen der seltenen Erden
US5914377A (en) * 1995-04-04 1999-06-22 Bayer Ag Method for the production of diene rubbers in the gas phase
US5610115A (en) * 1995-07-20 1997-03-11 Samsung General Chemicals Co., Ltd. Organic carrier supported metallocene catalyst for olefin polymerization
FI102476B (fi) * 1996-05-31 1998-12-15 Borealis As Uudet siirtymämetallikompleksit ja menetelmä niiden valmistamiseksi
DE69722902T2 (de) * 1996-12-09 2004-05-19 Mitsubishi Chemical Corp. Katalysator für Alpha-Olefinpolymerisation
DE19720171A1 (de) * 1997-05-14 1998-11-19 Bayer Ag Verbindungen der Seltenen Erden und ihre Verwendung als Polymerisationskatalysatoren für ungesättigte Verbindungen
US6001478A (en) * 1997-08-08 1999-12-14 Union Carbide Chemicals & Plastics Technology Corporation Resin particle produced by diene polymerization with rare earth and transition metal catalysts
US5879805A (en) * 1997-09-09 1999-03-09 Union Carbide Chemicals & Plastics Technology Corporation Gas phase polymerization of vinylpolybutadiene
US6018007A (en) * 1997-09-22 2000-01-25 Bridgestone Corporation Synthesis of 1,4-trans-polybutadiene using a lanthanide organic acid salt catalyst
DE19746266A1 (de) * 1997-10-20 1999-04-22 Bayer Ag Katalysator auf Basis von Verbindungen der seltenen Erdmetalle für die Polymerisation von ungesättigten organischen Verbindungen
US6197713B1 (en) * 1997-12-19 2001-03-06 Bridgestone Corporation Use of Lewis acids for the breakdown of gelatinous rare earth compounds in hydrocarbon solutions
US20030134999A1 (en) * 1998-07-18 2003-07-17 Heike Windisch Method for polymerizing conjugated diolefins (dienes) with rare earth catalysts in the presence of vinylaromatic solvents
US6403773B1 (en) * 1998-09-30 2002-06-11 Exxon Mobil Chemical Patents Inc. Cationic group 3 catalyst system
KR100365581B1 (ko) * 1999-02-25 2003-01-15 금호석유화학 주식회사 높은 1,4-시스 함량을 갖는 폴리부타디엔의 제조방법
EP1086957A4 (en) * 1999-03-04 2005-08-31 Riken CATALYST COMPOSITION
US6825297B1 (en) * 1999-05-14 2004-11-30 The Dow Chemical Company Transition metal complexes and olefin polymerization process
US6887824B1 (en) * 1999-09-21 2005-05-03 The Regents Of The University Of California Divalent lanthanide reduction catalysts
JP2004532320A (ja) * 2001-05-04 2004-10-21 ダウ グローバル テクノロジーズ インコーポレイティド 金属錯体触媒の使用により製造されたランダムまたはブロック共重合体または三元重合体
DE10140202A1 (de) * 2001-08-16 2003-03-06 Bayer Ag Vanadium-Imido-Phosphoraniminato für die Olefinpolymerisation
AU2003277808A1 (en) * 2002-06-21 2004-01-06 Exxonmobil Chemical Patents Inc. Yttrium-based ethylene polymerization catalysts with bulky amidinate ancillary ligands

Also Published As

Publication number Publication date
CN1568332A (zh) 2005-01-19
CA2462348A1 (en) 2003-04-24
JP2005506404A (ja) 2005-03-03
WO2003033545A2 (en) 2003-04-24
KR20050034609A (ko) 2005-04-14
WO2003033545A3 (en) 2003-11-27
BR0213639A (pt) 2004-09-14
US20050090383A1 (en) 2005-04-28
EP1436332A2 (en) 2004-07-14

Similar Documents

Publication Publication Date Title
MXPA04003409A (es) Composiciones de complejo metalico y su uso como catalizadores para producir polidienos.
Ricci et al. Polymerization of 1, 3-dienes with iron complexes based catalysts: influence of the ligand on catalyst activity and stereospecificity
DE69528781T2 (de) Biscyclopentadienyl-Dien Komplexe, ihre Herstellung und diese enthaltende Katalysatorzusammensetzungen
DE60035769D1 (de) Neodymium-Carboxylatederivate und ihre Verwendung für die Polymerisation von konjugierten Dienen
TW200514795A (en) A catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
BR0014332A (pt) Composições de catalisadores organometálicos
NO20050092L (no) Gruppe 4 metallkomplekser inneholdende 4-aryl-substituerte trisykliske indenyl derivater
AU2002360982A1 (en) Support-fixed bleaching catalyst complex compounds suitable as catalysts for peroxide compounds
ES2139906T3 (es) Complejos dienicos de metal del grupo 4 y catalizadores de polimerizacion por adicion procedentes de los mismos.
MXPA02005907A (es) Metodo de polimerizacion.
TW200617043A (en) Technique for selecting polymerization modifiers
CA2250001A1 (en) Compositions containing inorganic, organic and organometallic palladium hydrogen scavengers
ATE301144T1 (de) Verfahren zur herstellung von amorphen polyalphaolefinen mit ultrahohem molekulargewicht zur strömungbeschleunigung
HUP9903962A2 (hu) A 13. csoport vegyületét tartalmazó olefin polimerizációs katalizátorkészítmények
ES2182494T3 (es) Procedimiento integrado para la preparacion de complejos de dienos.
MXPA03010095A (es) Copolimeros o terpolimeros aleatorios o de bloques, producidos usando catalizadores de complejo metalico.
TW200604228A (en) A catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
TW200613345A (en) A catalytic composition and its preparation and use for preparing polymers from ethylenically unsaturated monomers
ATE285429T1 (de) Beschleuniger für die kationische polymerisation katalysiert durch katalysatoren auf eisenbasis
BG103994A (en) Activation composition of metallocene complexes in the catalysis of co-polymerization of olefins
MXPA03009868A (es) Composiciones de recubrimiento que comprenden productos de carbon de area-t alta.
ATE471331T1 (de) Neue übergangsmetall-komplexe und deren einsatz in übergangsmetall-katalysierten reaktionen
BR0004767B1 (pt) catalisador sàlido suportado, utilizÁvel para a polimerizaÇço de dienos conjugados e processos de preparaÇço do mesmo e de polimerizaÇço de dienos conjugados.
AU2728999A (en) Novel dendrimer compounds, method for the production thereof, use thereof as catalysts
CA2425588A1 (en) A method for preparing a catalyst system and its use in a polymerization process

Legal Events

Date Code Title Description
FA Abandonment or withdrawal