FR2946048B1 - Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu - Google Patents
Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenuInfo
- Publication number
- FR2946048B1 FR2946048B1 FR0902650A FR0902650A FR2946048B1 FR 2946048 B1 FR2946048 B1 FR 2946048B1 FR 0902650 A FR0902650 A FR 0902650A FR 0902650 A FR0902650 A FR 0902650A FR 2946048 B1 FR2946048 B1 FR 2946048B1
- Authority
- FR
- France
- Prior art keywords
- polymerization
- polymer obtained
- functional polymer
- conjugated dienes
- catalytic system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 230000003197 catalytic effect Effects 0.000 title 1
- 150000001993 dienes Chemical class 0.000 title 1
- 229920001002 functional polymer Polymers 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 238000006116 polymerization reaction Methods 0.000 title 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F36/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
- C08F4/463—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from sodium or potassium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
- C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/08—Isoprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/21—Rubbery or elastomeric properties
Priority Applications (8)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0902650A FR2946048B1 (fr) | 2009-06-02 | 2009-06-02 | Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu |
PCT/EP2010/003306 WO2010139449A1 (fr) | 2009-06-02 | 2010-06-01 | Systeme catalytique pour la polymerisation de dienes conjugues, procede de polymerisation et polymere fonctionnel obtenu |
JP2012513505A JP5623514B2 (ja) | 2009-06-02 | 2010-06-01 | 共役ジエン重合用の触媒系、重合方法および得られる官能化ポリマー |
KR1020117031572A KR101706925B1 (ko) | 2009-06-02 | 2010-06-01 | 공액 디엔 중합용 촉매계, 중합방법 및 수득된 관능성 중합체 |
EP10722954A EP2438095A1 (fr) | 2009-06-02 | 2010-06-01 | Systeme catalytique pour la polymerisation de dienes conjugues, procede de polymerisation et polymere fonctionnel obtenu |
BRPI1011131A BRPI1011131A8 (pt) | 2009-06-02 | 2010-06-01 | Sistema catalítico, processo de preparação de um sistema catalítico, elastômero diênico funcionalizado, e, composição de borracha |
CN201080023918.8A CN102449002B (zh) | 2009-06-02 | 2010-06-01 | 用于共轭二烯聚合的催化体系、聚合方法和所得到的官能聚合物 |
US13/709,446 US9315590B2 (en) | 2009-06-02 | 2012-12-10 | Catalytic system for conjugated diene polymerisation, polymerisation method and functional polymer obtained |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0902650A FR2946048B1 (fr) | 2009-06-02 | 2009-06-02 | Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu |
Publications (2)
Publication Number | Publication Date |
---|---|
FR2946048A1 FR2946048A1 (fr) | 2010-12-03 |
FR2946048B1 true FR2946048B1 (fr) | 2012-12-28 |
Family
ID=41651169
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
FR0902650A Expired - Fee Related FR2946048B1 (fr) | 2009-06-02 | 2009-06-02 | Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu |
Country Status (8)
Country | Link |
---|---|
US (1) | US9315590B2 (fr) |
EP (1) | EP2438095A1 (fr) |
JP (1) | JP5623514B2 (fr) |
KR (1) | KR101706925B1 (fr) |
CN (1) | CN102449002B (fr) |
BR (1) | BRPI1011131A8 (fr) |
FR (1) | FR2946048B1 (fr) |
WO (1) | WO2010139449A1 (fr) |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2946047B1 (fr) * | 2009-06-02 | 2011-07-29 | Michelin Soc Tech | Nouveaux composes organometallique a base d'un metal appartenant a la 2eme colonne de la classification periodique et procede de preparation |
FR2946048B1 (fr) * | 2009-06-02 | 2012-12-28 | Michelin Soc Tech | Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu |
JP5965169B2 (ja) * | 2012-03-16 | 2016-08-03 | 株式会社ブリヂストン | 重合触媒組成物、及び重合体組成物の製造方法 |
WO2016080764A1 (fr) * | 2014-11-20 | 2016-05-26 | 주식회사 엘지화학 | Composition catalytique pour la polymérisation d'un diène conjugué |
FR3029920B1 (fr) | 2014-12-12 | 2016-12-09 | Univ Claude Bernard Lyon | Polyolefine fonctionnelle ou telechelique, ses derives, et son procede de preparation |
FR3029918B1 (fr) | 2014-12-12 | 2018-01-26 | Universite Claude Bernard Lyon 1 | Agent de transfert pour la preparation d'une polyolefine fonctionnelle ou telechelique |
KR20170000757A (ko) | 2015-06-24 | 2017-01-03 | 주식회사 엘지화학 | 공액 디엔계 중합체 제조용 촉매 조성물 및 이를 이용하여 제조된 공액 디엔계 중합체 |
FR3044664B1 (fr) | 2015-12-08 | 2017-12-29 | Michelin & Cie | Copolymere monofonctionnel ou telechelique de 1,3-diene et d'ethylene ou d'alpha-monoolefine. |
FR3044663B1 (fr) * | 2015-12-08 | 2017-12-29 | Michelin & Cie | Copolymere monofonctionnel ou telechelique de 1,3-butadiene et d'ethylene. |
FR3061181B1 (fr) | 2016-12-22 | 2019-07-05 | Universite Claude Bernard Lyon 1 | Copolymere d'ethylene et de derive styrenique, sa preparation et son utilisation |
FR3068973B1 (fr) * | 2017-07-11 | 2020-08-28 | Centre Nat Rech Scient | Procede de fonctionnalisation d'un polydiene stereo-regulier |
KR102193437B1 (ko) | 2017-10-30 | 2020-12-21 | 주식회사 엘지화학 | 공액디엔 중합용 촉매의 제조방법, 촉매 및 이를 이용한 공액디엔계 중합체의 제조방법 |
EP3720889A1 (fr) | 2017-12-05 | 2020-10-14 | Compagnie Générale des Etablissements Michelin | Procede continu de preparation d'un elastomere dienique |
Family Cites Families (28)
Publication number | Priority date | Publication date | Assignee | Title |
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US506621A (en) | 1893-10-10 | Jewel setting | ||
US4057565A (en) * | 1975-07-22 | 1977-11-08 | E. I. Du Pont De Nemours And Company | 2-Dialkylaminobenzyl and 2-dialkylaminomethylphenyl derivatives of selected transition metals |
JPS58189203A (ja) | 1982-04-30 | 1983-11-04 | Nippon Zeon Co Ltd | ゴム組成物 |
JPH0713158B1 (fr) | 1987-01-14 | 1995-02-15 | Bridgestone Corp | |
US5274106A (en) * | 1991-12-30 | 1993-12-28 | Bridgestone Corporation | Amino-substituted aryllithium compounds as anionic polymerization initiators |
US5519086A (en) * | 1991-12-30 | 1996-05-21 | Bridgestone Corporation | Low-hysteresis elastomer compositions using amino-substituted aryllithium polymerization initiators |
US5238893A (en) * | 1991-12-30 | 1993-08-24 | Bridgestone Corporation | Method of preparing an anionic polymerization initiator |
ES2088188T3 (es) * | 1992-05-22 | 1996-08-01 | Bridgestone Corp | Neumaticos que tienen resistencia reducida a la rodadura. |
JP3769294B2 (ja) * | 1993-07-30 | 2006-04-19 | 日本ゼオン株式会社 | 変性共役ジエン系重合体およびその製造方法ならびにその組成物 |
FR2722505B1 (fr) | 1994-07-15 | 1996-09-27 | Michelin & Cie | Compositions elastomeres chargees a la silice utilisables pour des enveloppes de pneumatiques |
FR2722503A1 (fr) | 1994-07-15 | 1996-01-19 | Michelin & Cie | Polymeres dieniques fonctionnels, leur procede de preparation et leur utilisation dans des compositions elastomeres chargees a la silice utilisables pour des enveloppes de pneumatiques |
US5527753A (en) * | 1994-12-13 | 1996-06-18 | Fmc Corporation | Functionalized amine initiators for anionic polymerization |
US5521309A (en) * | 1994-12-23 | 1996-05-28 | Bridgestone Corporation | Tertiary-amino allyl-or xylyl-lithium initiators and method of preparing same |
US5496940A (en) * | 1995-02-01 | 1996-03-05 | Bridgestone Corporation | Alkyllithium compounds containing cyclic amines and their use in polymerization |
FR2740778A1 (fr) | 1995-11-07 | 1997-05-09 | Michelin & Cie | Composition de caoutchouc a base de silice et de polymere dienique fonctionalise ayant une fonction silanol terminale |
US5700888A (en) * | 1996-11-07 | 1997-12-23 | Bridgestone Corporation | Synthesis of macrocyclic polymers having low hysteresis compounded properties |
US5935893A (en) * | 1997-08-01 | 1999-08-10 | Bridgestone Corporation | Aliphatic solutions of aminoalkyllithium compounds |
US6610859B1 (en) * | 1999-02-24 | 2003-08-26 | Fmc Corporation | Protected aminofunctionalized polymerization initiators and methods of making and using same |
FR2795976B1 (fr) * | 1999-07-05 | 2001-10-05 | Rhodia Terres Rares | Systeme catalytique a base de terre rare et de magnesium, nouvel alcoolate de neodyme, utilisation pour la polymerisation de composes insatures |
BR0115238B1 (pt) | 2000-11-09 | 2011-09-20 | sistema catalìtico utilizável para preparar por polimerização elastÈmeros diênicos e processos de preparação do mesmo e de elastÈmeros diênicos. | |
US6943250B2 (en) * | 2001-03-06 | 2005-09-13 | Fmc Corporation | Protected aminofunctionalized polymerization initiators and methods of making and using same |
US20050090383A1 (en) * | 2001-10-12 | 2005-04-28 | Thiele Sven K. | Metal complex compositions and their use as catalysts to produce polydienes |
KR101010865B1 (ko) | 2002-05-16 | 2011-01-26 | 미쉐린 러쉐르슈 에 떼크니크 에스.에이. | 폴리부타디엔 제조용 촉매 시스템 및 폴리부타디엔의제조방법 |
DE10259243A1 (de) * | 2002-12-17 | 2004-07-01 | Merck Patent Gmbh | Verfahren zur Herstellung von Co- und Terpolymeren aus Olefinen |
WO2004074333A2 (fr) * | 2003-02-18 | 2004-09-02 | Dow Global Technologies Inc. | Procede d'homo- ou copolymerisation d'olefines conjuguees |
ES2530797T3 (es) * | 2008-03-15 | 2015-03-05 | Bridgestone Corp | Polímeros funcionalizados e iniciadores para su fabricación |
FR2946048B1 (fr) * | 2009-06-02 | 2012-12-28 | Michelin Soc Tech | Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu |
FR2946047B1 (fr) * | 2009-06-02 | 2011-07-29 | Michelin Soc Tech | Nouveaux composes organometallique a base d'un metal appartenant a la 2eme colonne de la classification periodique et procede de preparation |
-
2009
- 2009-06-02 FR FR0902650A patent/FR2946048B1/fr not_active Expired - Fee Related
-
2010
- 2010-06-01 KR KR1020117031572A patent/KR101706925B1/ko active IP Right Grant
- 2010-06-01 CN CN201080023918.8A patent/CN102449002B/zh active Active
- 2010-06-01 EP EP10722954A patent/EP2438095A1/fr not_active Ceased
- 2010-06-01 BR BRPI1011131A patent/BRPI1011131A8/pt not_active Application Discontinuation
- 2010-06-01 WO PCT/EP2010/003306 patent/WO2010139449A1/fr active Application Filing
- 2010-06-01 JP JP2012513505A patent/JP5623514B2/ja active Active
-
2012
- 2012-12-10 US US13/709,446 patent/US9315590B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
EP2438095A1 (fr) | 2012-04-11 |
WO2010139449A1 (fr) | 2010-12-09 |
KR20120031186A (ko) | 2012-03-30 |
CN102449002A (zh) | 2012-05-09 |
BRPI1011131A8 (pt) | 2018-04-03 |
JP5623514B2 (ja) | 2014-11-12 |
KR101706925B1 (ko) | 2017-02-15 |
JP2012528906A (ja) | 2012-11-15 |
CN102449002B (zh) | 2014-09-24 |
US20130274407A1 (en) | 2013-10-17 |
BRPI1011131A2 (pt) | 2018-02-06 |
FR2946048A1 (fr) | 2010-12-03 |
US9315590B2 (en) | 2016-04-19 |
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