FR2795976B1 - Systeme catalytique a base de terre rare et de magnesium, nouvel alcoolate de neodyme, utilisation pour la polymerisation de composes insatures - Google Patents

Systeme catalytique a base de terre rare et de magnesium, nouvel alcoolate de neodyme, utilisation pour la polymerisation de composes insatures

Info

Publication number
FR2795976B1
FR2795976B1 FR9908648A FR9908648A FR2795976B1 FR 2795976 B1 FR2795976 B1 FR 2795976B1 FR 9908648 A FR9908648 A FR 9908648A FR 9908648 A FR9908648 A FR 9908648A FR 2795976 B1 FR2795976 B1 FR 2795976B1
Authority
FR
France
Prior art keywords
neodyme
alcoolate
polymerization
magnesium
novel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR9908648A
Other languages
English (en)
Other versions
FR2795976A1 (fr
Inventor
Jean Francois Carpentier
Thomas Chenal
Jerome Gromada
Andre Mortreux
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Terres Rares SA
Original Assignee
Rhodia Terres Rares SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR9908648A priority Critical patent/FR2795976B1/fr
Application filed by Rhodia Terres Rares SA filed Critical Rhodia Terres Rares SA
Priority to BR0012165-7A priority patent/BR0012165A/pt
Priority to KR1020027000118A priority patent/KR20020037328A/ko
Priority to CA002378450A priority patent/CA2378450A1/fr
Priority to JP2001508233A priority patent/JP2003504429A/ja
Priority to EP00949599A priority patent/EP1200490A1/fr
Priority to MXPA02000038A priority patent/MXPA02000038A/es
Priority to PCT/FR2000/001863 priority patent/WO2001002446A1/fr
Priority to TW089113221A priority patent/TW567190B/zh
Publication of FR2795976A1 publication Critical patent/FR2795976A1/fr
Application granted granted Critical
Publication of FR2795976B1 publication Critical patent/FR2795976B1/fr
Priority to ZA200200012A priority patent/ZA200200012B/en
Priority to NO20020040A priority patent/NO20020040L/no
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201Oxygen-containing compounds
    • B01J31/0211Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212Alkoxylates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/10Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122Metal aryl or alkyl compounds
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/28Metal alcoholates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/52Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02Ethene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Polymerization Catalysts (AREA)
  • Catalysts (AREA)
FR9908648A 1999-07-05 1999-07-05 Systeme catalytique a base de terre rare et de magnesium, nouvel alcoolate de neodyme, utilisation pour la polymerisation de composes insatures Expired - Fee Related FR2795976B1 (fr)

Priority Applications (11)

Application Number Priority Date Filing Date Title
FR9908648A FR2795976B1 (fr) 1999-07-05 1999-07-05 Systeme catalytique a base de terre rare et de magnesium, nouvel alcoolate de neodyme, utilisation pour la polymerisation de composes insatures
PCT/FR2000/001863 WO2001002446A1 (fr) 1999-07-05 2000-06-30 Systeme catalytique a base de terre rare et de magnesium, nouvel alcoolate de neodyme, utilisation pour la polymerisation de composes insatures
CA002378450A CA2378450A1 (fr) 1999-07-05 2000-06-30 Systeme catalytique a base de terre rare et de magnesium, nouvel alcoolate de neodyme, utilisation pour la polymerisation de composes insatures
JP2001508233A JP2003504429A (ja) 1999-07-05 2000-06-30 希土類元素とマグネシウムを基材とした触媒系、新規なネオジムアルコラート及び不飽和化合物の重合への使用
EP00949599A EP1200490A1 (fr) 1999-07-05 2000-06-30 Systeme catalytique a base de terre rare et de magnesium, nouvel alcoolate de neodyme, utilisation pour la polymerisation de composes insatures
MXPA02000038A MXPA02000038A (es) 1999-07-05 2000-06-30 Sistema catalitico basado en una tierra rara y el magnesio, novedoso alcoholato de neodimio, y su empleo en la polimerizacion de compuestos insaturados.
BR0012165-7A BR0012165A (pt) 1999-07-05 2000-06-30 Sistema catalìtico, alcoolato de neodìmio, e, processo de polimerização ou de copolimerização de, um composto insaturado
KR1020027000118A KR20020037328A (ko) 1999-07-05 2000-06-30 희토류 및 마그네슘 기재의 촉매 시스템, 신규 네오디뮴알코올레이트, 불포화 화합물의 중합에 있어서의 이들의용도
TW089113221A TW567190B (en) 1999-07-05 2000-07-04 Catalytic system based on a rare earth and magnesium, novel neodymium alcoholate, use in polymerising unsaturated compounds
ZA200200012A ZA200200012B (en) 1999-07-05 2002-01-02 Catalytic system based on rare earth and magnesium, novel neodymium alcoholate, fuse for polymerising unsaturated compounds.
NO20020040A NO20020040L (no) 1999-07-05 2002-01-04 Katalytisk system basert på sjeldent jordmetall, et nytt neodymalkoholat og anvendelse for polymerisering av umettedeforbindelser

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9908648A FR2795976B1 (fr) 1999-07-05 1999-07-05 Systeme catalytique a base de terre rare et de magnesium, nouvel alcoolate de neodyme, utilisation pour la polymerisation de composes insatures

Publications (2)

Publication Number Publication Date
FR2795976A1 FR2795976A1 (fr) 2001-01-12
FR2795976B1 true FR2795976B1 (fr) 2001-10-05

Family

ID=9547715

Family Applications (1)

Application Number Title Priority Date Filing Date
FR9908648A Expired - Fee Related FR2795976B1 (fr) 1999-07-05 1999-07-05 Systeme catalytique a base de terre rare et de magnesium, nouvel alcoolate de neodyme, utilisation pour la polymerisation de composes insatures

Country Status (11)

Country Link
EP (1) EP1200490A1 (fr)
JP (1) JP2003504429A (fr)
KR (1) KR20020037328A (fr)
BR (1) BR0012165A (fr)
CA (1) CA2378450A1 (fr)
FR (1) FR2795976B1 (fr)
MX (1) MXPA02000038A (fr)
NO (1) NO20020040L (fr)
TW (1) TW567190B (fr)
WO (1) WO2001002446A1 (fr)
ZA (1) ZA200200012B (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2819199A1 (fr) * 2001-01-09 2002-07-12 Rhodia Elect & Catalysis Espece catatytique a base d'une terre rare et de magnesium, son utilisation dans la polymerisation d'une olefine ou d'une lactone et copolymeres diblocs ethylene-co-esters (meth) acryliques obtenus
FR2824834B1 (fr) * 2001-05-18 2005-05-13 Rhodia Elect & Catalysis Procede de preparation de copolymeres blocs, copolymeres blocs ainsi obtenus et utilisation comme agents compatibilisants
EP2341055B1 (fr) 2002-06-25 2016-03-02 Solvay USA Inc. Polymérisation par greffage de guar au moyen d'un faisceau d'électrons
FR2946048B1 (fr) * 2009-06-02 2012-12-28 Michelin Soc Tech Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu
CN105218451A (zh) * 2015-10-20 2016-01-06 复旦大学 一种稀土催化环眯化反应合成咪唑啉衍生物的方法
CN105237481B (zh) * 2015-10-20 2018-07-13 复旦大学 一种稀土催化合成1,4,5,6-四氢嘧啶衍生物的方法
FR3122428B1 (fr) * 2021-04-29 2024-03-29 Michelin & Cie copolymère fonctionnel d’un 1,3-diène et d’éthylène ou d’un 1,3-diène, d’éthylène et d’une alphamonooléfine.

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8314382D0 (en) * 1983-05-24 1983-06-29 Enoxy Chemicals Ltd Polymerisation of conjugated dienes
EP0304088B1 (fr) * 1987-08-19 1993-01-27 Asahi Kasei Kogyo Kabushiki Kaisha Procédé de prépolymérisation pour préparer une solution d'un composé d'un diène conjugué
IT1273753B (it) * 1994-02-11 1997-07-10 Eniriceche Spa Sistema catalitico e processo per la produzione di polidiolefine

Also Published As

Publication number Publication date
NO20020040D0 (no) 2002-01-04
JP2003504429A (ja) 2003-02-04
KR20020037328A (ko) 2002-05-18
EP1200490A1 (fr) 2002-05-02
ZA200200012B (en) 2003-02-03
WO2001002446A1 (fr) 2001-01-11
CA2378450A1 (fr) 2001-01-11
FR2795976A1 (fr) 2001-01-12
NO20020040L (no) 2002-03-05
BR0012165A (pt) 2002-06-18
TW567190B (en) 2003-12-21
MXPA02000038A (es) 2004-08-12

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Effective date: 20080331