CN102449002A - 用于共轭二烯聚合的催化体系、聚合方法和所得到的官能聚合物 - Google Patents
用于共轭二烯聚合的催化体系、聚合方法和所得到的官能聚合物 Download PDFInfo
- Publication number
- CN102449002A CN102449002A CN2010800239188A CN201080023918A CN102449002A CN 102449002 A CN102449002 A CN 102449002A CN 2010800239188 A CN2010800239188 A CN 2010800239188A CN 201080023918 A CN201080023918 A CN 201080023918A CN 102449002 A CN102449002 A CN 102449002A
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- China
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- catalystsystem
- formula
- rare earth
- functionalized
- diene elastomer
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- 0 Cc1c(C)c(*)c(*)c(*)c1* Chemical compound Cc1c(C)c(*)c(*)c(*)c1* 0.000 description 2
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F36/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/46—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals
- C08F4/463—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from alkali metals selected from sodium or potassium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/52—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides selected from boron, aluminium, gallium, indium, thallium or rare earths
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/54—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
- C08F4/545—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/08—Isoprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/21—Rubbery or elastomeric properties
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerization Catalysts (AREA)
Abstract
Description
Claims (21)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR0902650A FR2946048B1 (fr) | 2009-06-02 | 2009-06-02 | Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu |
FR0902650 | 2009-06-02 | ||
PCT/EP2010/003306 WO2010139449A1 (fr) | 2009-06-02 | 2010-06-01 | Systeme catalytique pour la polymerisation de dienes conjugues, procede de polymerisation et polymere fonctionnel obtenu |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102449002A true CN102449002A (zh) | 2012-05-09 |
CN102449002B CN102449002B (zh) | 2014-09-24 |
Family
ID=41651169
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201080023918.8A Active CN102449002B (zh) | 2009-06-02 | 2010-06-01 | 用于共轭二烯聚合的催化体系、聚合方法和所得到的官能聚合物 |
Country Status (8)
Country | Link |
---|---|
US (1) | US9315590B2 (zh) |
EP (1) | EP2438095A1 (zh) |
JP (1) | JP5623514B2 (zh) |
KR (1) | KR101706925B1 (zh) |
CN (1) | CN102449002B (zh) |
BR (1) | BRPI1011131A8 (zh) |
FR (1) | FR2946048B1 (zh) |
WO (1) | WO2010139449A1 (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107531853A (zh) * | 2015-06-24 | 2018-01-02 | Lg化学株式会社 | 用于制备基于共轭二烯的聚合物的催化剂组合物和使用其制备的基于共轭二烯的聚合物 |
CN108699187A (zh) * | 2015-12-08 | 2018-10-23 | 米其林集团总公司 | 1,3-丁二烯和乙烯的单官能或遥爪共聚物 |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2946047B1 (fr) * | 2009-06-02 | 2011-07-29 | Michelin Soc Tech | Nouveaux composes organometallique a base d'un metal appartenant a la 2eme colonne de la classification periodique et procede de preparation |
FR2946048B1 (fr) * | 2009-06-02 | 2012-12-28 | Michelin Soc Tech | Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu |
JP5965169B2 (ja) * | 2012-03-16 | 2016-08-03 | 株式会社ブリヂストン | 重合触媒組成物、及び重合体組成物の製造方法 |
WO2016080764A1 (ko) * | 2014-11-20 | 2016-05-26 | 주식회사 엘지화학 | 공액 디엔의 중합용 촉매 조성물 |
FR3029918B1 (fr) | 2014-12-12 | 2018-01-26 | Universite Claude Bernard Lyon 1 | Agent de transfert pour la preparation d'une polyolefine fonctionnelle ou telechelique |
FR3029920B1 (fr) | 2014-12-12 | 2016-12-09 | Univ Claude Bernard Lyon | Polyolefine fonctionnelle ou telechelique, ses derives, et son procede de preparation |
FR3044664B1 (fr) | 2015-12-08 | 2017-12-29 | Michelin & Cie | Copolymere monofonctionnel ou telechelique de 1,3-diene et d'ethylene ou d'alpha-monoolefine. |
FR3061181B1 (fr) | 2016-12-22 | 2019-07-05 | Universite Claude Bernard Lyon 1 | Copolymere d'ethylene et de derive styrenique, sa preparation et son utilisation |
FR3068973B1 (fr) | 2017-07-11 | 2020-08-28 | Centre Nat Rech Scient | Procede de fonctionnalisation d'un polydiene stereo-regulier |
KR102193437B1 (ko) | 2017-10-30 | 2020-12-21 | 주식회사 엘지화학 | 공액디엔 중합용 촉매의 제조방법, 촉매 및 이를 이용한 공액디엔계 중합체의 제조방법 |
WO2019110915A1 (fr) | 2017-12-05 | 2019-06-13 | Compagnie Generale Des Etablissements Michelin | Procede continu de preparation d'un elastomere dienique |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5238893A (en) * | 1991-12-30 | 1993-08-24 | Bridgestone Corporation | Method of preparing an anionic polymerization initiator |
WO2004074333A2 (en) * | 2003-02-18 | 2004-09-02 | Dow Global Technologies Inc. | Process for homo- or copolymerizationof conjugated olefines |
CN1568332A (zh) * | 2001-10-12 | 2005-01-19 | 陶氏环球技术公司 | 金属配位组合物和它们作为生产聚二烯烃的催化剂的用途 |
US20060149006A1 (en) * | 2002-12-17 | 2006-07-06 | Katrin Koehler | Method for producing copolymers and terpolymers from olefins |
Family Cites Families (24)
Publication number | Priority date | Publication date | Assignee | Title |
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US506621A (en) | 1893-10-10 | Jewel setting | ||
US4057565A (en) * | 1975-07-22 | 1977-11-08 | E. I. Du Pont De Nemours And Company | 2-Dialkylaminobenzyl and 2-dialkylaminomethylphenyl derivatives of selected transition metals |
JPS58189203A (ja) | 1982-04-30 | 1983-11-04 | Nippon Zeon Co Ltd | ゴム組成物 |
EP0299074B1 (en) | 1987-01-14 | 1992-01-29 | Bridgestone Corporation | Tire |
US5519086A (en) * | 1991-12-30 | 1996-05-21 | Bridgestone Corporation | Low-hysteresis elastomer compositions using amino-substituted aryllithium polymerization initiators |
US5274106A (en) * | 1991-12-30 | 1993-12-28 | Bridgestone Corporation | Amino-substituted aryllithium compounds as anionic polymerization initiators |
EP0570715B1 (en) * | 1992-05-22 | 1996-06-12 | Bridgestone Corporation | Pneumatic tires having reduced rolling resistance |
EP0713885B1 (en) * | 1993-07-30 | 1998-05-20 | Nippon Zeon Co., Ltd. | Modified conjugated diene copolymer, process for producing the same, and composition thereof |
FR2722503A1 (fr) | 1994-07-15 | 1996-01-19 | Michelin & Cie | Polymeres dieniques fonctionnels, leur procede de preparation et leur utilisation dans des compositions elastomeres chargees a la silice utilisables pour des enveloppes de pneumatiques |
FR2722505B1 (fr) | 1994-07-15 | 1996-09-27 | Michelin & Cie | Compositions elastomeres chargees a la silice utilisables pour des enveloppes de pneumatiques |
US5527753A (en) * | 1994-12-13 | 1996-06-18 | Fmc Corporation | Functionalized amine initiators for anionic polymerization |
US5521309A (en) * | 1994-12-23 | 1996-05-28 | Bridgestone Corporation | Tertiary-amino allyl-or xylyl-lithium initiators and method of preparing same |
US5496940A (en) * | 1995-02-01 | 1996-03-05 | Bridgestone Corporation | Alkyllithium compounds containing cyclic amines and their use in polymerization |
FR2740778A1 (fr) | 1995-11-07 | 1997-05-09 | Michelin & Cie | Composition de caoutchouc a base de silice et de polymere dienique fonctionalise ayant une fonction silanol terminale |
US5700888A (en) * | 1996-11-07 | 1997-12-23 | Bridgestone Corporation | Synthesis of macrocyclic polymers having low hysteresis compounded properties |
US5935893A (en) * | 1997-08-01 | 1999-08-10 | Bridgestone Corporation | Aliphatic solutions of aminoalkyllithium compounds |
US6610859B1 (en) * | 1999-02-24 | 2003-08-26 | Fmc Corporation | Protected aminofunctionalized polymerization initiators and methods of making and using same |
FR2795976B1 (fr) * | 1999-07-05 | 2001-10-05 | Rhodia Terres Rares | Systeme catalytique a base de terre rare et de magnesium, nouvel alcoolate de neodyme, utilisation pour la polymerisation de composes insatures |
CA2427984A1 (fr) | 2000-11-09 | 2002-05-16 | Michelin Recherche Et Technique S.A. | Systeme catalytique et procede de preparation d'elastomeres au moyen de ce systeme |
US6943250B2 (en) * | 2001-03-06 | 2005-09-13 | Fmc Corporation | Protected aminofunctionalized polymerization initiators and methods of making and using same |
ES2254934T3 (es) | 2002-05-16 | 2006-06-16 | Societe De Technologie Michelin | Sistema catalitico para preparar polibutadienos y procedimiento de preparacion. |
ES2530797T3 (es) * | 2008-03-15 | 2015-03-05 | Bridgestone Corp | Polímeros funcionalizados e iniciadores para su fabricación |
FR2946048B1 (fr) * | 2009-06-02 | 2012-12-28 | Michelin Soc Tech | Systeme catalytique pour la polymerisation de dienes conjugues,procede de polymerisation et polymere fonctionnel obtenu |
FR2946047B1 (fr) * | 2009-06-02 | 2011-07-29 | Michelin Soc Tech | Nouveaux composes organometallique a base d'un metal appartenant a la 2eme colonne de la classification periodique et procede de preparation |
-
2009
- 2009-06-02 FR FR0902650A patent/FR2946048B1/fr not_active Expired - Fee Related
-
2010
- 2010-06-01 WO PCT/EP2010/003306 patent/WO2010139449A1/fr active Application Filing
- 2010-06-01 KR KR1020117031572A patent/KR101706925B1/ko active IP Right Grant
- 2010-06-01 CN CN201080023918.8A patent/CN102449002B/zh active Active
- 2010-06-01 JP JP2012513505A patent/JP5623514B2/ja active Active
- 2010-06-01 EP EP10722954A patent/EP2438095A1/fr not_active Ceased
- 2010-06-01 BR BRPI1011131A patent/BRPI1011131A8/pt not_active Application Discontinuation
-
2012
- 2012-12-10 US US13/709,446 patent/US9315590B2/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5238893A (en) * | 1991-12-30 | 1993-08-24 | Bridgestone Corporation | Method of preparing an anionic polymerization initiator |
CN1568332A (zh) * | 2001-10-12 | 2005-01-19 | 陶氏环球技术公司 | 金属配位组合物和它们作为生产聚二烯烃的催化剂的用途 |
US20060149006A1 (en) * | 2002-12-17 | 2006-07-06 | Katrin Koehler | Method for producing copolymers and terpolymers from olefins |
WO2004074333A2 (en) * | 2003-02-18 | 2004-09-02 | Dow Global Technologies Inc. | Process for homo- or copolymerizationof conjugated olefines |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107531853A (zh) * | 2015-06-24 | 2018-01-02 | Lg化学株式会社 | 用于制备基于共轭二烯的聚合物的催化剂组合物和使用其制备的基于共轭二烯的聚合物 |
US10538608B2 (en) | 2015-06-24 | 2020-01-21 | Lg Chem, Ltd. | Catalyst composition for preparing conjugated diene-based polymer and conjugated diene-based polymer prepared using the same |
US10538607B2 (en) | 2015-06-24 | 2020-01-21 | Lg Chem, Ltd. | Catalyst composition for preparing conjugated diene-based polymer and conjugated diene-based polymer prepared using the same |
US10556976B2 (en) | 2015-06-24 | 2020-02-11 | Lg Chem, Ltd. | Catalyst composition for preparing conjugated diene-based polymer and conjugated diene-based polymer preparing using the same |
US10836850B2 (en) | 2015-06-24 | 2020-11-17 | Lg Chem, Ltd. | Catalyst composition for preparing conjugated diene-based polymer and conjugated diene-based polymer preparing using the same |
US10995165B2 (en) | 2015-06-24 | 2021-05-04 | Lg Chem, Ltd. | Catalyst composition for preparing conjugated diene-based polymer and conjugated diene-based polymer prepared using the same |
CN108699187A (zh) * | 2015-12-08 | 2018-10-23 | 米其林集团总公司 | 1,3-丁二烯和乙烯的单官能或遥爪共聚物 |
CN108699187B (zh) * | 2015-12-08 | 2020-12-22 | 米其林集团总公司 | 1,3-丁二烯和乙烯的单官能或遥爪共聚物 |
Also Published As
Publication number | Publication date |
---|---|
FR2946048A1 (fr) | 2010-12-03 |
CN102449002B (zh) | 2014-09-24 |
US20130274407A1 (en) | 2013-10-17 |
WO2010139449A1 (fr) | 2010-12-09 |
BRPI1011131A2 (pt) | 2018-02-06 |
FR2946048B1 (fr) | 2012-12-28 |
JP5623514B2 (ja) | 2014-11-12 |
BRPI1011131A8 (pt) | 2018-04-03 |
US9315590B2 (en) | 2016-04-19 |
JP2012528906A (ja) | 2012-11-15 |
KR101706925B1 (ko) | 2017-02-15 |
EP2438095A1 (fr) | 2012-04-11 |
KR20120031186A (ko) | 2012-03-30 |
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