JP2004074041A - フッ素の回収方法 - Google Patents
フッ素の回収方法 Download PDFInfo
- Publication number
- JP2004074041A JP2004074041A JP2002239217A JP2002239217A JP2004074041A JP 2004074041 A JP2004074041 A JP 2004074041A JP 2002239217 A JP2002239217 A JP 2002239217A JP 2002239217 A JP2002239217 A JP 2002239217A JP 2004074041 A JP2004074041 A JP 2004074041A
- Authority
- JP
- Japan
- Prior art keywords
- calcium
- fluorine
- wastewater
- particle size
- fluoride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011737 fluorine Substances 0.000 title claims abstract description 66
- 229910052731 fluorine Inorganic materials 0.000 title claims abstract description 66
- 238000000034 method Methods 0.000 title claims abstract description 22
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 title 1
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims abstract description 71
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 66
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims abstract description 64
- 239000002245 particle Substances 0.000 claims abstract description 55
- 229910001634 calcium fluoride Inorganic materials 0.000 claims abstract description 45
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 claims abstract description 44
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 33
- 239000007864 aqueous solution Substances 0.000 claims abstract description 9
- 239000011575 calcium Substances 0.000 claims description 36
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 11
- 229910052791 calcium Inorganic materials 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 9
- 239000002351 wastewater Substances 0.000 abstract description 46
- 239000012528 membrane Substances 0.000 abstract description 20
- 239000000243 solution Substances 0.000 abstract description 2
- 229940095672 calcium sulfate Drugs 0.000 description 30
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 17
- 150000003839 salts Chemical class 0.000 description 16
- 238000001914 filtration Methods 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 10
- 229910052715 tantalum Inorganic materials 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 9
- 230000001186 cumulative effect Effects 0.000 description 8
- 238000006722 reduction reaction Methods 0.000 description 8
- 238000004140 cleaning Methods 0.000 description 7
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 6
- 239000003638 chemical reducing agent Substances 0.000 description 6
- 239000000706 filtrate Substances 0.000 description 6
- 238000011084 recovery Methods 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical class [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 5
- 239000011698 potassium fluoride Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- -1 K 2 TaF 7 Chemical class 0.000 description 4
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 4
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 4
- 229910001424 calcium ion Inorganic materials 0.000 description 4
- 238000007865 diluting Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910017604 nitric acid Inorganic materials 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 239000006227 byproduct Substances 0.000 description 3
- 229940043430 calcium compound Drugs 0.000 description 3
- 150000001674 calcium compounds Chemical class 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 238000005755 formation reaction Methods 0.000 description 3
- 239000001103 potassium chloride Substances 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 239000003990 capacitor Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 229910004261 CaF 2 Inorganic materials 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229940095564 anhydrous calcium sulfate Drugs 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- GJYLKIZKRHDRER-UHFFFAOYSA-N calcium;sulfuric acid Chemical compound [Ca].OS(O)(=O)=O GJYLKIZKRHDRER-UHFFFAOYSA-N 0.000 description 1
- HWVBCNFHNCFLTO-UHFFFAOYSA-L calcium;sulfuric acid;carbonate Chemical compound [Ca+2].OC(O)=O.[O-]S([O-])(=O)=O HWVBCNFHNCFLTO-UHFFFAOYSA-L 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005345 coagulation Methods 0.000 description 1
- 230000015271 coagulation Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 239000012510 hollow fiber Substances 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000010812 mixed waste Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- 229910000484 niobium oxide Inorganic materials 0.000 description 1
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229910001936 tantalum oxide Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
- C02F1/5245—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents using basic salts, e.g. of aluminium and iron
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/12—Halogens or halogen-containing compounds
- C02F2101/14—Fluorine or fluorine-containing compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Removal Of Specific Substances (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002239217A JP2004074041A (ja) | 2002-08-20 | 2002-08-20 | フッ素の回収方法 |
| PCT/JP2003/010450 WO2004018369A1 (ja) | 2002-08-20 | 2003-08-19 | フッ素の回収方法 |
| AU2003262247A AU2003262247A1 (en) | 2002-08-20 | 2003-08-19 | Method of recovering fluorine |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002239217A JP2004074041A (ja) | 2002-08-20 | 2002-08-20 | フッ素の回収方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2004074041A true JP2004074041A (ja) | 2004-03-11 |
| JP2004074041A5 JP2004074041A5 (enExample) | 2005-10-13 |
Family
ID=31943857
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2002239217A Pending JP2004074041A (ja) | 2002-08-20 | 2002-08-20 | フッ素の回収方法 |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP2004074041A (enExample) |
| AU (1) | AU2003262247A1 (enExample) |
| WO (1) | WO2004018369A1 (enExample) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006206359A (ja) * | 2005-01-27 | 2006-08-10 | Nikon Corp | フッ化カルシウム微粒子,フッ化カルシウム乾燥体,フッ化カルシウム焼結体,フッ化カルシウム透明焼結体及びそれらの製造方法 |
| JP2006290703A (ja) * | 2005-04-14 | 2006-10-26 | Cabot Supermetal Kk | フッ素の回収方法 |
| JP2008173527A (ja) * | 2007-01-16 | 2008-07-31 | Matsushita Electric Ind Co Ltd | フッ素含有水の処理方法および処理装置 |
| WO2011049052A1 (ja) * | 2009-10-22 | 2011-04-28 | 栗田工業株式会社 | フッ素含有水の処理方法および処理装置 |
| WO2013136385A1 (ja) * | 2012-03-13 | 2013-09-19 | 株式会社 東芝 | フッ素回収装置、フッ素回収システム及びフッ素回収方法 |
| WO2013145373A1 (ja) * | 2012-03-30 | 2013-10-03 | 株式会社 東芝 | 水処理方法 |
| JP2014097501A (ja) * | 2014-01-31 | 2014-05-29 | Toshiba Corp | 水処理方法 |
| JP2014133188A (ja) * | 2013-01-08 | 2014-07-24 | Toshiba Corp | 水処理方法及び水処理装置 |
| JP2014162794A (ja) * | 2013-02-21 | 2014-09-08 | Pfizer Inc | 選択的cdk4/6阻害剤の固体形態 |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4368249B2 (ja) * | 2004-06-01 | 2009-11-18 | 三洋電機株式会社 | 処理装置およびそれを用いた被処理水の処理方法 |
| JP2013220955A (ja) * | 2012-04-13 | 2013-10-28 | Central Glass Co Ltd | フッ化カルシウムの製造方法及び装置 |
| JP2013220956A (ja) * | 2012-04-13 | 2013-10-28 | Central Glass Co Ltd | フッ化カルシウムの製造方法及び装置 |
| US10136709B2 (en) | 2013-09-06 | 2018-11-27 | Oliver Joen-An Ma | Cantilever umbrella |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49122880A (enExample) * | 1973-03-28 | 1974-11-25 | ||
| US5362461A (en) * | 1991-10-03 | 1994-11-08 | Kurita Water Industries, Ltd. | Method for recovering calcium fluoride from fluoroetchant |
| JP2001137864A (ja) * | 1999-11-10 | 2001-05-22 | Daikin Ind Ltd | フッ酸を含有する廃水の処理方法 |
-
2002
- 2002-08-20 JP JP2002239217A patent/JP2004074041A/ja active Pending
-
2003
- 2003-08-19 AU AU2003262247A patent/AU2003262247A1/en not_active Abandoned
- 2003-08-19 WO PCT/JP2003/010450 patent/WO2004018369A1/ja not_active Ceased
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006206359A (ja) * | 2005-01-27 | 2006-08-10 | Nikon Corp | フッ化カルシウム微粒子,フッ化カルシウム乾燥体,フッ化カルシウム焼結体,フッ化カルシウム透明焼結体及びそれらの製造方法 |
| JP2006290703A (ja) * | 2005-04-14 | 2006-10-26 | Cabot Supermetal Kk | フッ素の回収方法 |
| JP2008173527A (ja) * | 2007-01-16 | 2008-07-31 | Matsushita Electric Ind Co Ltd | フッ素含有水の処理方法および処理装置 |
| KR101775888B1 (ko) * | 2009-10-22 | 2017-09-07 | 쿠리타 고교 가부시키가이샤 | 불소 함유수의 처리 방법 및 처리 장치 |
| WO2011049052A1 (ja) * | 2009-10-22 | 2011-04-28 | 栗田工業株式会社 | フッ素含有水の処理方法および処理装置 |
| JP2011088071A (ja) * | 2009-10-22 | 2011-05-06 | Kurita Water Ind Ltd | フッ素含有水の処理方法および処理装置 |
| CN102574712A (zh) * | 2009-10-22 | 2012-07-11 | 栗田工业株式会社 | 含有氟的水的处理方法及处理装置 |
| WO2013136385A1 (ja) * | 2012-03-13 | 2013-09-19 | 株式会社 東芝 | フッ素回収装置、フッ素回収システム及びフッ素回収方法 |
| JP2013188673A (ja) * | 2012-03-13 | 2013-09-26 | Toshiba Corp | フッ素回収装置、フッ素回収システム及びフッ素回収方法 |
| WO2013145373A1 (ja) * | 2012-03-30 | 2013-10-03 | 株式会社 東芝 | 水処理方法 |
| JP2013208543A (ja) * | 2012-03-30 | 2013-10-10 | Toshiba Corp | 水処理方法 |
| JP2014133188A (ja) * | 2013-01-08 | 2014-07-24 | Toshiba Corp | 水処理方法及び水処理装置 |
| JP2014162794A (ja) * | 2013-02-21 | 2014-09-08 | Pfizer Inc | 選択的cdk4/6阻害剤の固体形態 |
| JP2014097501A (ja) * | 2014-01-31 | 2014-05-29 | Toshiba Corp | 水処理方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2004018369A1 (ja) | 2004-03-04 |
| AU2003262247A1 (en) | 2004-03-11 |
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