FI68408B - Foerfarande foer framstaellning av en vattenemulsion eller -dispersion av ett delvis vattenloesligt material och eventuellt vidare omvandling av den framstaellda dispersionen eller emulsionen till en polymerdispersion dao det delvis vattenloesliga materialet aer en polymeriserbar monomer samt anvaendning av sao framstaellda monodispersa polymerpartiklar som toing i xerografi - Google Patents
Foerfarande foer framstaellning av en vattenemulsion eller -dispersion av ett delvis vattenloesligt material och eventuellt vidare omvandling av den framstaellda dispersionen eller emulsionen till en polymerdispersion dao det delvis vattenloesliga materialet aer en polymeriserbar monomer samt anvaendning av sao framstaellda monodispersa polymerpartiklar som toing i xerografi Download PDFInfo
- Publication number
- FI68408B FI68408B FI790563A FI790563A FI68408B FI 68408 B FI68408 B FI 68408B FI 790563 A FI790563 A FI 790563A FI 790563 A FI790563 A FI 790563A FI 68408 B FI68408 B FI 68408B
- Authority
- FI
- Finland
- Prior art keywords
- substance
- water
- particles
- dispersion
- added
- Prior art date
Links
- 239000000178 monomer Substances 0.000 title claims description 75
- 239000006185 dispersion Substances 0.000 title claims description 42
- 239000004815 dispersion polymer Substances 0.000 title claims description 4
- 239000000463 material Substances 0.000 title description 3
- 101100148710 Clarkia breweri SAMT gene Proteins 0.000 title 1
- 239000002245 particle Substances 0.000 claims description 214
- 239000000126 substance Substances 0.000 claims description 139
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 90
- 229920000642 polymer Polymers 0.000 claims description 77
- 238000003756 stirring Methods 0.000 claims description 71
- 239000000839 emulsion Substances 0.000 claims description 58
- 238000000034 method Methods 0.000 claims description 54
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 54
- GRTOGORTSDXSFK-XJTZBENFSA-N ajmalicine Chemical compound C1=CC=C2C(CCN3C[C@@H]4[C@H](C)OC=C([C@H]4C[C@H]33)C(=O)OC)=C3NC2=C1 GRTOGORTSDXSFK-XJTZBENFSA-N 0.000 claims description 52
- 239000003999 initiator Substances 0.000 claims description 38
- 238000006116 polymerization reaction Methods 0.000 claims description 32
- 230000008569 process Effects 0.000 claims description 29
- 238000001704 evaporation Methods 0.000 claims description 28
- 230000008020 evaporation Effects 0.000 claims description 28
- 239000008346 aqueous phase Substances 0.000 claims description 24
- 239000003995 emulsifying agent Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 18
- 239000002904 solvent Substances 0.000 claims description 13
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 12
- 229920002554 vinyl polymer Polymers 0.000 claims description 12
- 238000006243 chemical reaction Methods 0.000 claims description 8
- SRSFOMHQIATOFV-UHFFFAOYSA-N octanoyl octaneperoxoate Chemical compound CCCCCCCC(=O)OOC(=O)CCCCCCC SRSFOMHQIATOFV-UHFFFAOYSA-N 0.000 claims description 8
- 239000012071 phase Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 2
- 239000000693 micelle Substances 0.000 claims description 2
- 239000011368 organic material Substances 0.000 claims 2
- 238000010790 dilution Methods 0.000 claims 1
- 239000012895 dilution Substances 0.000 claims 1
- 150000002894 organic compounds Chemical class 0.000 claims 1
- 229920000126 latex Polymers 0.000 description 58
- 239000004816 latex Substances 0.000 description 57
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 38
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 26
- 239000002054 inoculum Substances 0.000 description 25
- 239000004793 Polystyrene Substances 0.000 description 16
- YAYNEUUHHLGGAH-UHFFFAOYSA-N 1-chlorododecane Chemical compound CCCCCCCCCCCCCl YAYNEUUHHLGGAH-UHFFFAOYSA-N 0.000 description 15
- 238000007792 addition Methods 0.000 description 15
- 229920002223 polystyrene Polymers 0.000 description 15
- 230000008961 swelling Effects 0.000 description 14
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 12
- 230000003287 optical effect Effects 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 12
- 238000001493 electron microscopy Methods 0.000 description 10
- 238000010521 absorption reaction Methods 0.000 description 9
- 238000007720 emulsion polymerization reaction Methods 0.000 description 9
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 8
- 230000015572 biosynthetic process Effects 0.000 description 8
- 238000009826 distribution Methods 0.000 description 8
- 238000000265 homogenisation Methods 0.000 description 8
- 238000013508 migration Methods 0.000 description 7
- 230000005012 migration Effects 0.000 description 7
- 229940043264 dodecyl sulfate Drugs 0.000 description 6
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 5
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 5
- 238000009792 diffusion process Methods 0.000 description 5
- 230000009477 glass transition Effects 0.000 description 5
- 238000011081 inoculation Methods 0.000 description 5
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 4
- IEORSVTYLWZQJQ-UHFFFAOYSA-N 2-(2-nonylphenoxy)ethanol Chemical compound CCCCCCCCCC1=CC=CC=C1OCCO IEORSVTYLWZQJQ-UHFFFAOYSA-N 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 4
- 239000012986 chain transfer agent Substances 0.000 description 4
- ZBJVLWIYKOAYQH-UHFFFAOYSA-N naphthalen-2-yl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=C(C=CC=C2)C2=C1 ZBJVLWIYKOAYQH-UHFFFAOYSA-N 0.000 description 4
- 229920000847 nonoxynol Polymers 0.000 description 4
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 239000004800 polyvinyl chloride Substances 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 238000010899 nucleation Methods 0.000 description 3
- 150000003384 small molecules Chemical class 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- ZFMQKOWCDKKBIF-UHFFFAOYSA-N bis(3,5-difluorophenyl)phosphane Chemical compound FC1=CC(F)=CC(PC=2C=C(F)C=C(F)C=2)=C1 ZFMQKOWCDKKBIF-UHFFFAOYSA-N 0.000 description 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- HMZGPNHSPWNGEP-UHFFFAOYSA-N octadecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)C(C)=C HMZGPNHSPWNGEP-UHFFFAOYSA-N 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- QJJDJWUCRAPCOL-UHFFFAOYSA-N 1-ethenoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOC=C QJJDJWUCRAPCOL-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 241000404883 Pisa Species 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 239000000427 antigen Substances 0.000 description 1
- 102000036639 antigens Human genes 0.000 description 1
- 108091007433 antigens Proteins 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 239000013060 biological fluid Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- HRYZWHHZPQKTII-UHFFFAOYSA-N chloroethane Chemical compound CCCl HRYZWHHZPQKTII-UHFFFAOYSA-N 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 229960003750 ethyl chloride Drugs 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 238000004255 ion exchange chromatography Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- -1 mercaptan compound Chemical class 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 239000004005 microsphere Substances 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 239000003021 water soluble solvent Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Claims (19)
1. Förfarande för framställning av en vattenemulsion eller -dispersion av ett delvis.vattenlösligt, organiskt material och eventuellt vidare omvandling av den framställda dispersionen eller emulsionen tili en polymerdispersion da det delvis vattenlösliga, organiska materialet är en polymer iserbar nqnaner, kännetecknat av att i ett första steg framställes en dispersion av polymerpartiklar, som innehäller ett eller flere mycket knappt i vatten lösliga organiska äinnen, för vilka används benämningen ämne I, vars -2 -4 vattenlöslighet är < 10 , normalt < 10 och företrädesvis < 10 ^ g/1 ί^Ο och vars molekylvikt är < 5000, varefter i ett andra steg tillföres ett delvis i vatten lösligt organiskt ämne, vars vattenlöslighet är ätminstone 10 ganger större än hos ämnet I och för vilket används benämningen ämne II, vilket ämne II diffun-deras in i de ämnet I innehällande partiklarna i förhällanden, som förhindrar eller försvärar transport av ämnet I genom vatten-fasen, varefter eventuellt utföres en polymerisation, om ämnet II är en polymeriserbar monomer.
2. Förfarande enligt patentkravet 1, kännetecknat av att den i det första steget framställda dispersionen av polymerpartiklar innehäller ämnet I i en mängd, som normalt är 0,5-10, i synnerhet 1-4, ganger mängden av polymer i partiklarna, beräknat enligt volymen.
3. Förfarande enligt patentkravet 1 eller 2, kännetecknat av att i det första steget tillföres nägot ämne I, vars molekylvikt är < 5000 och företrädesvis < 500, i polymerpartik-larnas vattendispersion, i förhällanden, som leder tili en kraftig ökning av transporthastigheten för ämnet I genom vattenfasen in i partiklarna, vilka härvld sväller av ämnet vid omröring, vilka polymerpartiklar är framställda pä i och för sig känt sätt, varefter i ett andra steg tillföres ämne II efter det, att för-hällandena ändrats sä, att ämnets I transport genom vattenfasen är förhindrad, varvid ämne II vid omröring diffunderas in i polymerpartiklarna, som svällt av ämnet I. 30 68408
4. Förfarande enligt patentkravet 3, kännetecknat av att ämne I tillföres i form av en vattendispersion.
5. Förfarande enligt patentkraven 3 och 4, kännetecknat av att det för ökning av ämnets I transport genom vatten-fasen i det första steget användes sä mycket emulgatorämne, att emulgatorkoncentrationen ligger over den kritiska micellkoncent-rationen, sä att ämnet I helt eller delvis löser sig micellärt, och att denna verkan avlägsnas före tillförseln av ämnet II i det andra steget, genom utspädning med vatten.
6. Förfarande enligt patentkraven 3 och 4, kännetecknat av att det första steget utföres i närvaro av ett lösnings-medel, som är helt eller delvis vattenlösligt och är ett lösnings-medel för ämne I.
7. Förfarande enligt patentkravet 6, kännetecknat av att säsom lösningsmedel användes aceton eller nägon annan lägre alkanol.
8. Förfarande enligt patentkravet 6, kännetecknat av att säsom lösningsmedel användes en relativt vattenlöslig monomer.
9. Förfarande enligt patentkraven 6-8, kännetecknat av att lösningsmedlet användes i en mängd som utgör 1-100 % av den i det första steget använda vattenmängden, enligt volymen.
10. Förfarande enligt patentkraven 6, 7 och 9, kännetecknat av att lösningsmedlet avlägsnas efter det första steget, exempelvis genom avdunstning.
11. Förfarande enligt patentkraven 1-10, kännetecknat av att i det andra steget ökas vattenmängden i dispersionen av polymerpartiklar som bringats att svälla av ämne I, att ett emulgatorämne eventuellt tillsättes och att det önskade ämnet II tillsättes, företrädesvis under omröring, i en mängd som är upp tili 1000, normalt upp tili 800, företrädesvis 20-300, ganger sä 68408 stor som polymermängden i de fran det första steget erhällna partiklarna, enligt volymen.
12. Förfarande enligt patentkraven 1-11, kännetecknat av att sasom ämne II tillföres helt eller delvis en monomer som efter att ha diffunderat in i de svällda polymerpartiklarna poly-meriseras.
13. Förfarande enligt patentkravet 12, kännetecknat av att efter tillförandet av monomeren i det andra steget tillföres nägon vattenlöslig eller delvis vattenlöslig initiator, eventuellt lost i ett lämpligt lösningsmedel.
14. Förfarande enligt patentkravet 12,kännetecknat av att det i första steget tillföres en knappt i vatten löslig initiator som är löst i ämnet I.
15. Förfarande enligt patentkravet 12, kännetecknat av att säsom ämne I användes en initiator i vätskeform, som utöver det, att den fungerar som ämne I, även fungerar som initiator vid polymerisationen av den i det andra steget tillförda monomeren.
16. Förfarande enligt patentkravet 13, kännetecknat av att det som initiator i vätskeform användes dioktanoylperoxid.
17. Förfarande enligt patentkraven 1 och 2, kännetecknat av att dispersionen i det första steget framställes genom homogenisering av en blandning, som innehäller nägon monomer, ämne I och eventuellt nägon oljelöslig initiator, tillsammans med vatten och emulgatorämnet, sä att man erhäller en emulsion av denna blandning, att det därefter eventuellt tillföres en helt eller delvis vattenlöslig initiator och att polymerisationen utföres sä, att man erhäller en dispersion av polymer-partiklar som innehäller 5-90 volym-% av ämnet I, varefter det andra steget utföres pä dispersionen enligt patentkravet 1.
18. Förfarande enligt patentkravet 17, kännetecknat av att det som ämne II, som tillföres i det andra steget, användes nägon vinylmonomer, som polymeriseras efter att den diffunderat in i de i det första steget framställda partiklarna.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO780596 | 1978-02-21 | ||
| NO780596A NO142082C (no) | 1978-02-21 | 1978-02-21 | Frgm for fr.st. av en vandig emulsjon eller dispersjon av et delv. vannloeselig materiale, og event. videre omdannelse av den fremst. disper. eller emul. til en polymerdisper. naar det delv. vannloes. materiale er en polymeriser monomer |
| NO782920A NO143403C (no) | 1978-08-28 | 1978-08-28 | Fremgangsmaate for fremstilling av en vandig emulsjon eller dispersjon av et delvis vannloeselig materiale, og eventuelt videre omdannelse av den fremstilte dispersjon eller emulsjon til en polymerdispersjon naar det delvis vannloeselelige |
| NO782920 | 1978-08-28 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| FI790563A FI790563A (fi) | 1979-08-22 |
| FI68408B true FI68408B (fi) | 1985-05-31 |
| FI68408C FI68408C (fi) | 1985-09-10 |
Family
ID=26647655
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| FI790563A FI68408C (fi) | 1978-02-21 | 1979-02-20 | Foerfarande foer framstaellning av en vattenemulsion eller -dispersion av ett delvis vattenloesligt material och eventuellt vidare omvandling av den framstaellda dispersionen eller emulsionen till en polymerdispersion dao det delvis vattenloesliga materialet aer en polymeriserbar monomer samt anvaendning av sao framstaellda monodispersa polymerpartiklar som toing i xerografi |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US4336173A (sv) |
| EP (1) | EP0003905B2 (sv) |
| JP (1) | JPS54126288A (sv) |
| AT (1) | AT368169B (sv) |
| AU (1) | AU530410B2 (sv) |
| BR (1) | BR7901146A (sv) |
| CA (1) | CA1166779A (sv) |
| DE (1) | DE2966965D1 (sv) |
| DK (1) | DK160318C (sv) |
| FI (1) | FI68408C (sv) |
| PT (1) | PT69217A (sv) |
Families Citing this family (215)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE430896B (sv) * | 1979-12-06 | 1983-12-19 | Kema Nord Ab | Forfarande for polymerisation av vinylklorid i nervaro av en stabiliserande polymerlatex |
| JPS5728106A (en) * | 1980-07-25 | 1982-02-15 | Nippon Oil & Fats Co Ltd | Organic peroxide emulsified in water |
| NO149108C (no) * | 1981-10-21 | 1984-02-15 | Sintef | Fremgangsmaate for fremstilling av vandige dispersjoner av organisk materiale og eventuelt videre omdannelse til en polymerdispersjon naar det organiske materiale er en polymeriserbar monomer |
| BR8207120A (pt) * | 1981-12-10 | 1983-10-11 | Kema Nord Ab | Pigmentador para processos eletrofotograficos e um processo para a preparacao do pigmentador |
| US4601968A (en) * | 1982-10-04 | 1986-07-22 | Canon Kabushiki Kaisha | Process for producing toner for development of electrostatic images by stepwise suspension polymerizations |
| DE3313922A1 (de) * | 1983-04-16 | 1984-10-25 | Hoechst Ag, 6230 Frankfurt | Emulgator- und schutzkolloidfreie emulsionspolymerisate, verfahren zu ihrer herstellung und ihre verwendung |
| US4524199A (en) * | 1983-11-09 | 1985-06-18 | Xerox Corporation | Stable polymeric dispersion and methods for making |
| US4609689A (en) * | 1984-04-27 | 1986-09-02 | Becton, Dickinson And Company | Method of preparing fluorescently labeled microbeads |
| US4699826A (en) * | 1984-04-27 | 1987-10-13 | Becton, Dickinson And Company | Fluorescently labeled microbeads |
| US4699828A (en) * | 1984-04-27 | 1987-10-13 | Becton, Dickinson And Company | Fluorescently labeled microbeads |
| US4698262A (en) * | 1984-04-27 | 1987-10-06 | Becton, Dickinson And Company | Fluorescently labeled microbeads |
| GB8412423D0 (en) * | 1984-05-16 | 1984-06-20 | Allied Colloids Ltd | Polymeric compositions |
| JPS6182835A (ja) * | 1984-09-29 | 1986-04-26 | Ricoh Co Ltd | 微粒子体を含有するミクロゲル分散液 |
| US5106903A (en) * | 1984-12-17 | 1992-04-21 | Lehigh University | Preparation of large particle size monodisperse latexes |
| US4791162A (en) * | 1984-12-17 | 1988-12-13 | Lehigh University | Preparation of large particle size monodisperse latexes |
| CA1284695C (en) * | 1984-12-20 | 1991-06-04 | Rohm And Haas Company | Modified latex polymer compositions |
| US4767206A (en) * | 1984-12-24 | 1988-08-30 | Flow Cytometry Standards Corporation | Calibration method for flow cytometry using fluorescent microbeads and synthesis thereof |
| US4828984A (en) * | 1986-04-11 | 1989-05-09 | Flow Cytometry Standards Corporation | Composition, synthesis and use of simulated cells |
| JPH0674285B2 (ja) * | 1985-01-30 | 1994-09-21 | 日本合成ゴム株式会社 | 重合体粒子の製造方法 |
| NO860171L (no) * | 1985-01-30 | 1986-07-31 | Japan Synthetic Rubber Co Ltd | Fremgangsmaate for fremstilling av store polymerpartikler. |
| JPS61225208A (ja) * | 1985-03-30 | 1986-10-07 | Nitto Electric Ind Co Ltd | 耐溶剤型均一粒径微粒子の製造方法 |
| US4687594A (en) * | 1985-05-10 | 1987-08-18 | Stepan Company | Emulsifiers useful in the manufacture of high solids emulsion polymers |
| US4644041A (en) * | 1985-07-08 | 1987-02-17 | The University Of Toronto Innovations Foundation | Preparation of poly(methylmethacrylate) polymer particles |
| US5169884A (en) * | 1985-07-10 | 1992-12-08 | Sequa Chemicals, Inc. | Coating compositions |
| US5177128A (en) * | 1985-07-10 | 1993-01-05 | Sequa Chemicals, Inc. | Paper coating composition |
| US5190997A (en) * | 1985-07-10 | 1993-03-02 | Sequa Chemicals, Inc. | Adhesive composition |
| US4686260A (en) * | 1985-07-10 | 1987-08-11 | Sun Chemical Corporation | Printing ink composition |
| US5154749A (en) * | 1985-11-04 | 1992-10-13 | Dowelanco | Herbicidal latex dispersion for controlled delivery and release of herbicides and their preparation |
| US5260259A (en) * | 1985-11-04 | 1993-11-09 | Dowelanco | Herbicidal latex dispersion for controlled delivery and release of herbicides and their preparation |
| US4767205A (en) * | 1986-01-28 | 1988-08-30 | Flow Cytometry Standards Corporation | Composition and method for hidden identification |
| US4818536A (en) * | 1986-06-05 | 1989-04-04 | The Dow Chemical Company | Emulsfiable polymer concentrate controlled delivery and release system |
| DE3621685A1 (de) * | 1986-06-27 | 1988-01-14 | Basf Ag | Lichtempfindliches aufzeichnungsmaterial |
| US5292814A (en) * | 1987-04-29 | 1994-03-08 | Ernst Bayer | Process for the preparation of monodispersed polymer beads |
| JP2508083B2 (ja) * | 1987-05-19 | 1996-06-19 | 大日本インキ化学工業株式会社 | 乳化重合体の製造方法 |
| JPH0721011B2 (ja) * | 1987-06-25 | 1995-03-08 | 日本ゼオン株式会社 | 中空重合体粒子の製造方法 |
| US5225278A (en) * | 1987-08-26 | 1993-07-06 | Rohm And Haas Company | Process for microencapsulation |
| JPS6481810A (en) * | 1987-09-22 | 1989-03-28 | Kao Corp | Production of fine polymer particle having uniform particle diameter |
| EP0320833B1 (de) * | 1987-12-14 | 1993-09-15 | Klüber Chemie Kg | Wässriges Trennmittel zur Herstellung von Polyurethan-Formkörpern |
| JP2762507B2 (ja) * | 1988-01-29 | 1998-06-04 | ミノルタ株式会社 | 静電潜像現像用トナーおよびその製造方法 |
| US4981625A (en) * | 1988-03-14 | 1991-01-01 | California Institute Of Technology | Monodisperse, polymeric microspheres produced by irradiation of slowly thawing frozen drops |
| US4952651A (en) * | 1988-03-30 | 1990-08-28 | Japan Synthetic Rubber Co., Ltd. | Highly crosslinked polymer particles and process for producing the same |
| DE68913555T2 (de) * | 1988-11-21 | 1994-07-07 | Dynal As | Sonden aus nukleinsäuren. |
| US5079125A (en) * | 1989-04-28 | 1992-01-07 | Minolta Camera Kabushiki Kaisha | Three layered toner for electrophotography |
| US5204205A (en) * | 1989-04-28 | 1993-04-20 | Minolta Camera Kabushiki Kaisha | Three layered toner for electrophotography |
| US5147937A (en) * | 1990-03-22 | 1992-09-15 | Rohm And Haas Company | Process for making controlled, uniform-sized particles in the 1 to 50 micrometer range |
| US5061586A (en) * | 1990-04-05 | 1991-10-29 | Eastman Kodak Company | Glass composite magnetic carrier particles |
| GB9019650D0 (en) | 1990-09-07 | 1990-10-24 | Nycomed As | Chemical compounds |
| GB9115372D0 (en) * | 1991-07-16 | 1991-08-28 | Sinvent As | Polymerisation process |
| US5190841A (en) * | 1991-12-19 | 1993-03-02 | Eastman Kodak Company | Two-phase ferroelectric-ferromagnetic composite and carrier therefrom |
| US5190842A (en) * | 1991-12-19 | 1993-03-02 | Eastman Kodak Company | Two phase ferroelectric-ferromagnetic composite carrier |
| JPH0558902U (ja) * | 1992-01-27 | 1993-08-03 | 東京焼結金属株式会社 | サージ圧吸収ダンパを具える電磁開閉弁装置 |
| US5268249A (en) * | 1992-10-29 | 1993-12-07 | Eastman Kodak Company | Magnetic carrier particles |
| US5306592A (en) * | 1992-10-29 | 1994-04-26 | Eastman Kodak Company | Method of preparing electrographic magnetic carrier particles |
| US5326808A (en) * | 1993-02-18 | 1994-07-05 | The Glidden Company | Odor free, air dry, aqueous emulsion paints |
| US5367018A (en) * | 1993-02-18 | 1994-11-22 | The Glidden Company | Odor free, air dry, decorative latex paints |
| GB9304979D0 (en) * | 1993-03-11 | 1993-04-28 | Sinvent As | Imobilisation and separation of cells and other particles |
| US5306593A (en) * | 1993-04-02 | 1994-04-26 | Xerox Corporation | Suspension polymerized toner treated by starved feed monomer addition process |
| US5344867A (en) * | 1993-06-14 | 1994-09-06 | The Bfgoodrich Company | Vinylidene chloride emulsion interpolymer composition |
| US5686518A (en) * | 1993-10-12 | 1997-11-11 | Georgia Tech | Miniemulsion polymerization process using polymeric co-surfactant |
| GB9323305D0 (en) * | 1993-11-11 | 1994-01-05 | Medinnova Sf | Isoaltion of nucleic acid |
| US5492960A (en) * | 1994-10-28 | 1996-02-20 | Eastman Kodak Company | Method of making polymeric particles |
| GB9425138D0 (en) * | 1994-12-12 | 1995-02-08 | Dynal As | Isolation of nucleic acid |
| EP0755946A3 (en) * | 1995-07-24 | 1997-10-01 | Basf Corp | Method for the preparation of hydrophobic emulsion polymers, the polymers thus obtained and the aqueous coating compositions containing these polymers |
| US5835174A (en) * | 1995-10-12 | 1998-11-10 | Rohm And Haas Company | Droplets and particles containing liquid crystal and films and apparatus containing the same |
| US6037058A (en) * | 1995-10-12 | 2000-03-14 | Rohms And Haas Company | Particles and droplets containing liquid domains and method for forming in an acueous medium |
| JP3875754B2 (ja) * | 1995-11-17 | 2007-01-31 | シスメックス株式会社 | フローサイトメータ用標準液 |
| US5777036A (en) * | 1996-02-01 | 1998-07-07 | Basf Aktiengesellschaft | Particulate graft copolymers and thermoplastic molding materials containing them and having improved colorability |
| EP0907889B1 (en) | 1996-04-25 | 2007-07-04 | BioArray Solutions Ltd. | Light-controlled electrokinetic assembly of particles near surfaces |
| NO302370B1 (no) * | 1996-07-18 | 1998-02-23 | Nyfotek As | Fremgangsmåte for fremstilling av en vandig emulsjon med snever dråpestörrelsesfordeling, og anvendelse av en slik emulsjon for fremstilling av en polymerdispersjon |
| US5846657A (en) * | 1996-07-25 | 1998-12-08 | Rohm And Haas Company | Liquid crystal displays containing spacers and methods for producing the spacer |
| JPH10186372A (ja) * | 1996-12-20 | 1998-07-14 | Kao Corp | 液晶表示装置用スペーサ及びこれを用いる液晶表示装置 |
| US5972363A (en) * | 1997-04-11 | 1999-10-26 | Rohm And Haas Company | Use of an encapsulated bioactive composition |
| GB9721603D0 (en) * | 1997-10-10 | 1997-12-10 | Dyno Ind Asa | Method |
| US20020197469A1 (en) | 1998-10-26 | 2002-12-26 | Richard Roy Clikeman | Particles and a process for preparing the same |
| US6337215B1 (en) | 1997-12-01 | 2002-01-08 | International Business Machines Corporation | Magnetic particles having two antiparallel ferromagnetic layers and attached affinity recognition molecules |
| DE69934536T2 (de) * | 1998-04-09 | 2007-10-04 | Nippon Shokubai Co. Ltd. | Vernetzes Polymerteilchen und Verfahren zu seiner Herstellung und Verwendung |
| GB2339573A (en) * | 1998-07-15 | 2000-02-02 | Amersham Pharm Biotech Ab | Support media e.g. for chromatography |
| GB9822822D0 (en) | 1998-10-19 | 1998-12-16 | Dyno Particles As | Particles |
| DE19848897A1 (de) | 1998-10-23 | 2000-04-27 | Agfa Gevaert Ag | Herstellung monodisperser kugelförmiger Polymerisate |
| CA2369293C (en) | 1999-04-09 | 2010-06-08 | Dynal Particles As | Process for the preparation of monodisperse polymer particles |
| EP1171494B1 (en) * | 1999-04-09 | 2006-01-11 | Microbeads AS | Preparation of polymer particles |
| GB9908163D0 (en) * | 1999-04-09 | 1999-06-02 | Dyno Ind Asa | Process |
| US6855761B2 (en) | 1999-04-23 | 2005-02-15 | Tosoh Corporation | Monodisperse particles, process for producing the same, and uses thereof |
| GB0001450D0 (en) | 2000-01-21 | 2000-03-08 | Genpoint As | Cell isolation method |
| GB0003782D0 (en) * | 2000-02-17 | 2000-04-05 | Dumex Ltd As | Process |
| US6984702B2 (en) | 2000-03-22 | 2006-01-10 | Dynal Biotech Asa | Process for the preparation of functionalized polymer particles |
| US20040009614A1 (en) * | 2000-05-12 | 2004-01-15 | Ahn Chong H | Magnetic bead-based arrays |
| US6228549B1 (en) | 2000-05-17 | 2001-05-08 | Heidelberg Digital L.L.C. | Magnetic carrier particles |
| EP1156373A1 (en) | 2000-05-17 | 2001-11-21 | Heidelberger Druckmaschinen Aktiengesellschaft | Electrographic developer compositions and method for development of an electrostatic image |
| US6232026B1 (en) | 2000-05-17 | 2001-05-15 | Heidelberg Digital L.L.C. | Magnetic carrier particles |
| US6723481B2 (en) | 2000-05-17 | 2004-04-20 | Heidelberger Druckmaschinen Ag | Method for using hard magnetic carriers in an electrographic process |
| GB0013658D0 (en) * | 2000-06-05 | 2000-07-26 | Dynal Asa | Nucleic acid isolation |
| US9709559B2 (en) | 2000-06-21 | 2017-07-18 | Bioarray Solutions, Ltd. | Multianalyte molecular analysis using application-specific random particle arrays |
| ES2259666T3 (es) | 2000-06-21 | 2006-10-16 | Bioarray Solutions Ltd | Analisis molecular de multiples analitos usando series de particulas aleatorias con especificidad de aplicacion. |
| GB0024688D0 (en) * | 2000-10-09 | 2000-11-22 | Dyno Specialty Polymers As | Process |
| GB0028264D0 (en) | 2000-11-20 | 2001-01-03 | Norske Stats Oljeselskap | Well treatment |
| US6610451B2 (en) | 2000-12-26 | 2003-08-26 | Heidelberger Druckmaschinen Ag | Development systems for magnetic toners having reduced magnetic loadings |
| CA2440773A1 (en) | 2001-03-14 | 2002-09-19 | Dakocytomation Denmark A/S | Novel mhc molecule constructs, and methods of employing these constructs for diagnosis and therapy, and uses of mhc molecules |
| US6797448B2 (en) | 2001-05-14 | 2004-09-28 | Eastman Kodak Company | Electrophotographic toner and development process with improved image and fusing quality |
| US6692880B2 (en) | 2001-05-14 | 2004-02-17 | Heidelberger Druckmaschinen Ag | Electrophotographic toner with stable triboelectric properties |
| US7262063B2 (en) | 2001-06-21 | 2007-08-28 | Bio Array Solutions, Ltd. | Directed assembly of functional heterostructures |
| ES2248460T3 (es) | 2001-09-05 | 2006-03-16 | Eastman Kodak Company | Toneres electrofotograficos que contienen ceras de polialquileno de alta cristalinidad. |
| EP2722395B1 (en) | 2001-10-15 | 2018-12-19 | Bioarray Solutions Ltd | Multiplexed analysis of polymorphic loci by concurrent interrogation and enzyme-mediated detection |
| EP1487969A4 (en) * | 2001-12-07 | 2008-07-09 | Dyax Corp | METHOD AND DEVICE FOR WASHING MAGNETICALLY RESPONSIVE PARTICLES |
| AU2003202026A1 (en) | 2002-01-16 | 2003-09-02 | Dynal Biotech Asa | Method for isolating nucleic acids and protein from a single sample |
| US6792019B2 (en) * | 2002-02-28 | 2004-09-14 | Texas Instruments Incorporated | Driver with tail currents in discrete subranges |
| US7214427B2 (en) * | 2002-03-21 | 2007-05-08 | Aviva Biosciences Corporation | Composite beads comprising magnetizable substance and electro-conductive substance |
| JP2004163879A (ja) | 2002-06-13 | 2004-06-10 | Heidelberger Druckmas Ag | ワックスが均一に分散したエレクトロフォトグラフトナー |
| EP1376250A3 (en) | 2002-06-24 | 2009-04-08 | Eastman Kodak Company | Electrophotographic toner and development process using chemically prepared toner |
| US8557743B2 (en) | 2002-09-05 | 2013-10-15 | Dyax Corp. | Display library process |
| US7526114B2 (en) | 2002-11-15 | 2009-04-28 | Bioarray Solutions Ltd. | Analysis, secure access to, and transmission of array images |
| CN1230531C (zh) * | 2002-12-09 | 2005-12-07 | 清华大学 | 从样品中分离细胞粒子的方法 |
| CN1223680C (zh) | 2002-12-10 | 2005-10-19 | 清华大学 | 扩增靶细胞或病毒的核酸的方法 |
| DE10258989A1 (de) * | 2002-12-13 | 2004-07-01 | Carl Zeiss Jena Gmbh | Testpräparat für Mikroskope |
| US6964747B2 (en) * | 2003-01-21 | 2005-11-15 | Bioarray Solutions, Ltd. | Production of dyed polymer microparticles |
| US7255895B2 (en) * | 2003-01-21 | 2007-08-14 | Bioarray Solutions, Ltd. | Method for controlling solute loading of polymer microparticles |
| CN100439515C (zh) * | 2003-03-03 | 2008-12-03 | 清华大学 | 一种核酸分析芯片实验室系统与应用 |
| CN1280428C (zh) * | 2003-05-19 | 2006-10-18 | 清华大学 | 一种基于微小颗粒的生物芯片系统及其应用 |
| CN100494399C (zh) * | 2003-06-30 | 2009-06-03 | 清华大学 | 一种基于dna芯片的基因分型方法及其应用 |
| KR20060052889A (ko) * | 2003-07-30 | 2006-05-19 | 코닌클리케 필립스 일렉트로닉스 엔.브이. | 생체 활성 분자 사이의 결합을 결정하기 위한 자기 입자의사용 |
| WO2005026225A1 (en) * | 2003-09-15 | 2005-03-24 | Hans-Joachim Metz | Process of making monodisperse, spherical, controlled-size micrometer polymer particles |
| WO2005029705A2 (en) | 2003-09-18 | 2005-03-31 | Bioarray Solutions, Ltd. | Number coding for identification of subtypes of coded types of solid phase carriers |
| WO2005031305A2 (en) | 2003-09-22 | 2005-04-07 | Bioarray Solutions, Ltd. | Surface immobilized polyelectrolyte with multiple functional groups capable of covalently bonding to biomolecules |
| JP2007521017A (ja) | 2003-10-28 | 2007-08-02 | バイオアレイ ソリューションズ リミテッド | 固定化捕捉プローブを用いる遺伝子発現分析法の最適化 |
| EP1694859B1 (en) | 2003-10-29 | 2015-01-07 | Bioarray Solutions Ltd | Multiplexed nucleic acid analysis by fragmentation of double-stranded dna |
| US20050271961A1 (en) * | 2004-03-05 | 2005-12-08 | Jadwin Thomas A | Substrate and near infrared absorbing toner |
| BRPI0512142B1 (pt) | 2004-06-17 | 2018-01-23 | Statoil Petroleum As | Método para o tratamento de uma formação subterrânea, uso de um material, e, composição de tratamento de poço de hidrocarboneto |
| EA200802357A1 (ru) | 2004-06-17 | 2010-02-26 | Статойлгидро Аса | Обработка скважин |
| US7848889B2 (en) | 2004-08-02 | 2010-12-07 | Bioarray Solutions, Ltd. | Automated analysis of multiplexed probe-target interaction patterns: pattern matching and allele identification |
| EP1859038B1 (en) * | 2005-02-11 | 2010-08-04 | Invitrogen Dynal AS | Method for isolating nucleic acids comprising the use of ethylene glycol multimers |
| JP4811565B2 (ja) * | 2005-03-31 | 2011-11-09 | Ｊｓｒ株式会社 | 多孔質表面を有する磁性粒子およびその製造方法、生化学用担体、ならびにビオチン類結合用粒子 |
| CA2604220A1 (en) | 2005-04-26 | 2006-11-02 | Rune Godoey | Method of well treatment and construction |
| US20060266707A1 (en) * | 2005-05-26 | 2006-11-30 | Fisher Jon R | Drying method for macroporous polymers, and method of preparation and use of macroporous polymers made using the method |
| US8486629B2 (en) | 2005-06-01 | 2013-07-16 | Bioarray Solutions, Ltd. | Creation of functionalized microparticle libraries by oligonucleotide ligation or elongation |
| EP2295472B1 (en) * | 2005-09-16 | 2017-06-28 | Rohm and Haas Company | Swellable particles |
| DE602006010956D1 (de) * | 2005-11-01 | 2010-01-21 | Jsr Corp | Magnetische Partikel für die Diagnostik |
| WO2007085266A1 (en) * | 2006-01-30 | 2007-08-02 | Dako Denmark A/S | High-speed quantification of antigen specific t-cells in whole blood by flow cytometry |
| GB0603081D0 (en) * | 2006-02-15 | 2006-03-29 | Dynal Biotech Asa Oslo | Method |
| GB0605584D0 (en) * | 2006-03-20 | 2006-04-26 | Olink Ab | Method for analyte detection using proximity probes |
| JP2009536348A (ja) | 2006-05-10 | 2009-10-08 | コーニンクレッカ フィリップス エレクトロニクス エヌ ヴィ | 高速磁気バイオセンサ |
| WO2007129284A1 (en) * | 2006-05-10 | 2007-11-15 | Koninklijke Philips Electronics N.V. | System and methods for actuation on magnetoresistive sensors |
| JP4840580B2 (ja) * | 2006-07-26 | 2011-12-21 | Ｊｓｒ株式会社 | 磁性粒子およびその製造方法、ならびにプローブ結合粒子 |
| JP5003868B2 (ja) * | 2006-09-28 | 2012-08-15 | Ｊｓｒ株式会社 | 有機ポリマー粒子およびその製造方法 |
| WO2008140573A2 (en) * | 2006-11-15 | 2008-11-20 | Invitrogen Dynal As | Methods for reversibly binding a biotin compound to a support |
| CN100478388C (zh) * | 2006-11-21 | 2009-04-15 | 南京大学 | 聚苯乙烯/聚苯胺导电高分子复合粒子的制备方法 |
| JP4947288B2 (ja) * | 2006-12-28 | 2012-06-06 | Ｊｓｒ株式会社 | 磁性粒子およびその製造方法、ならびに生化学用担体 |
| EP2361930A3 (en) | 2007-03-26 | 2011-10-26 | Dako Denmark A/S | Multimers of MHC-peptide complexes and uses thereof in Borrelia infectious diseases |
| GB2450502B (en) | 2007-06-26 | 2012-03-07 | Statoil Asa | Microbial enhanced oil recovery |
| EP2167536A1 (en) * | 2007-07-03 | 2010-03-31 | Dako Denmark A/S | Mhc multimers, methods for their generation, labeling and use |
| US10611818B2 (en) | 2007-09-27 | 2020-04-07 | Agilent Technologies, Inc. | MHC multimers in tuberculosis diagnostics, vaccine and therapeutics |
| EP2257371A1 (en) | 2008-02-28 | 2010-12-08 | Aker Clean Carbon AS | Co2 absorbent and method for co2 capture |
| US10968269B1 (en) | 2008-02-28 | 2021-04-06 | Agilent Technologies, Inc. | MHC multimers in borrelia diagnostics and disease |
| US8435712B2 (en) | 2008-05-21 | 2013-05-07 | Eastman Kodak Company | Developer for selective printing of raised information by electrography |
| US8574669B2 (en) | 2008-05-21 | 2013-11-05 | Toray Industries, Inc. | Method for producing polymer fine particle comprising contacting an emulsion with a poor solvent |
| EP2128617A1 (en) * | 2008-05-27 | 2009-12-02 | Koninklijke Philips Electronics N.V. | Device and methods for detecting analytes in saliva |
| EP2130844A1 (en) * | 2008-06-06 | 2009-12-09 | Université de Liège | Multifunctional coatings |
| EP2133695A1 (en) | 2008-06-12 | 2009-12-16 | Koninklijke Philips Electronics N.V. | Parathyroid hormone assay |
| US10722562B2 (en) * | 2008-07-23 | 2020-07-28 | Immudex Aps | Combinatorial analysis and repair |
| GB0817244D0 (en) * | 2008-09-20 | 2008-10-29 | Univ Cardiff | Use of a protein kinase inhibitor to detect immune cells, such as T cells |
| EP2342346B1 (en) | 2008-09-24 | 2013-08-14 | Hyperthermics Holding AS | Thermotoga for treatment of biomass |
| EP2339339A4 (en) | 2008-09-25 | 2016-10-12 | Jsr Corp | CHARGE FOR AFFINITY CHROMATOGRAPHY |
| US11992518B2 (en) | 2008-10-02 | 2024-05-28 | Agilent Technologies, Inc. | Molecular vaccines for infectious disease |
| US10369204B2 (en) | 2008-10-02 | 2019-08-06 | Dako Denmark A/S | Molecular vaccines for infectious disease |
| WO2010054385A2 (en) | 2008-11-10 | 2010-05-14 | Luminex Corporation | Method and system for manufacture and use of macroporous beads in a multiplex assay |
| US8221947B2 (en) | 2008-12-18 | 2012-07-17 | Eastman Kodak Company | Toner surface treatment |
| RU2530716C2 (ru) | 2008-12-22 | 2014-10-10 | Конинклейке Филипс Электроникс Н.В. | Анализ тропонина i с применением магнитных меток |
| WO2010086772A1 (en) | 2009-01-29 | 2010-08-05 | Koninklijke Philips Electronics N.V. | System and method for assay |
| GB0907372D0 (en) * | 2009-04-29 | 2009-06-10 | Invitrogen Dynal As | Particles |
| US8574835B2 (en) * | 2009-05-29 | 2013-11-05 | Life Technologies Corporation | Scaffolded nucleic acid polymer particles and methods of making and using |
| GB0912909D0 (en) | 2009-07-23 | 2009-08-26 | Olink Genomics Ab | Probes for specific analysis of nucleic acids |
| GB0921264D0 (en) | 2009-12-03 | 2010-01-20 | Olink Genomics Ab | Method for amplification of target nucleic acid |
| JP5474745B2 (ja) * | 2009-12-30 | 2014-04-16 | ローム アンド ハース カンパニー | 均一なオリゴマー液滴を製造する方法 |
| GB201004292D0 (en) * | 2010-03-15 | 2010-04-28 | Olink Ab | Assay for localised detection of analytes |
| US20110262954A1 (en) | 2010-03-18 | 2011-10-27 | Universitat Regensburg | Shuttle vector based transformation system for pyrococcus furiosus |
| JP5354094B2 (ja) | 2010-03-31 | 2013-11-27 | Ｊｓｒ株式会社 | アフィニティークロマトグラフィー用充填剤 |
| GB201007209D0 (en) | 2010-04-29 | 2010-06-16 | King S College London | Compound |
| GB201011971D0 (en) | 2010-07-15 | 2010-09-01 | Olink Ab | Methods and product |
| WO2012049316A1 (en) | 2010-10-15 | 2012-04-19 | Olink Ab | Dynamic range methods |
| GB201018380D0 (en) | 2010-10-29 | 2010-12-15 | Conpart As | Process |
| GB201018379D0 (en) | 2010-10-29 | 2010-12-15 | Conpart As | Conductive rf particles |
| EP2466310A1 (en) | 2010-12-17 | 2012-06-20 | Helmholtz Zentrum München Deutsches Forschungszentrum für Gesundheit und Umwelt GmbH | Means and methods for detecting double-strand breaks |
| GB201101621D0 (en) | 2011-01-31 | 2011-03-16 | Olink Ab | Method and product |
| US8404424B2 (en) | 2011-02-08 | 2013-03-26 | Eastman Kodak Company | Security enhanced printed products and methods |
| US20120202022A1 (en) | 2011-02-08 | 2012-08-09 | Detlef Schulze-Hagenest | Printed product with authentication bi-fluorescence feature |
| GB201107863D0 (en) | 2011-05-11 | 2011-06-22 | Olink Ab | Method and product |
| EP2546199A1 (en) | 2011-07-14 | 2013-01-16 | Université Catholique De Louvain | Solid iron oxide support for isolation of microorganisms |
| GB201201547D0 (en) | 2012-01-30 | 2012-03-14 | Olink Ab | Method and product |
| GB201212489D0 (en) | 2012-07-13 | 2012-08-29 | Conpart As | Improvements in conductive adhesives |
| ES2776029T3 (es) | 2012-10-08 | 2020-07-28 | St Jude Childrens Res Hospital | Terapias basadas en el control de la estabilidad y función de las células T reguladoras por medio de un eje neuropilina-1:semaforina |
| EP2920320B1 (en) | 2012-11-14 | 2016-12-28 | Olink Bioscience AB | Rca reporter probes and their use in detecting nucleic acid molecules |
| EP2920324B1 (en) | 2012-11-14 | 2017-12-27 | Olink Bioscience AB | Localised rca-based amplification method |
| WO2014134144A1 (en) | 2013-02-28 | 2014-09-04 | The General Hospital Corporation | Mirna profiling compositions and methods of use |
| GB201320145D0 (en) | 2013-11-14 | 2014-01-01 | Olink Ab | Localised RCA-based amplification method using a padlock-probe |
| US10139401B2 (en) | 2014-02-10 | 2018-11-27 | Jsr Corporation | Method for capturing target substance, solid-phase carrier for capturing target substance, and method for producing solid-phase carrier |
| WO2016051274A2 (en) | 2014-10-01 | 2016-04-07 | Surf Technology As | Ultrasound transducer matching layers and method of manufacturing |
| WO2016065218A1 (en) | 2014-10-23 | 2016-04-28 | Corning Incorporated | Polymer-encapsulated magnetic nanoparticles |
| GB201509782D0 (en) | 2015-06-05 | 2015-07-22 | Isis Innovation | Methods and products for fusion protein synthesis |
| GB201518655D0 (en) | 2015-10-21 | 2015-12-02 | Olink Ab | Method for generating proximity probes |
| GB201621514D0 (en) | 2016-12-16 | 2017-02-01 | Q-Linea Ab | Padlock probe detection method |
| JP6218916B1 (ja) | 2016-12-28 | 2017-10-25 | Jsr株式会社 | 磁性粒子分散液 |
| GB201700983D0 (en) | 2017-01-20 | 2017-03-08 | Life Tech As | Polymeric particles |
| CN106883345A (zh) * | 2017-02-22 | 2017-06-23 | 李峰 | 一种脲醛树脂改性聚丙烯酰胺有机‑无机复合微球及其制备方法 |
| JP6289705B1 (ja) | 2017-03-31 | 2018-03-07 | Jsr株式会社 | プローブ結合担体の製造方法、プローブ結合担体および標的物質を検出または分離する方法 |
| CA3078158A1 (en) | 2017-10-06 | 2019-04-11 | Cartana Ab | Rna templated ligation |
| WO2019238944A1 (en) | 2018-06-15 | 2019-12-19 | Olink Proteomics Ab | Biomarker panel for ovarian cancer |
| US20200041518A1 (en) | 2018-08-03 | 2020-02-06 | CellMax Life, Inc. | Lipid vesicle-coated magnetic beads and uses of the same |
| GB201819850D0 (en) | 2018-12-05 | 2019-01-23 | Univ Oxford Innovation Ltd | Polypeptide and its use in affinity purification |
| EP3898666A2 (en) | 2018-12-17 | 2021-10-27 | Immudex ApS | Panel comprising borrelia mhc multimers |
| GB201903479D0 (en) | 2019-03-14 | 2019-05-01 | Univ Oxford Innovation Ltd | Polypeptide with enchanced rate of spontaneous isopeptide bond formation with it's peptide tag partner and uses thereof |
| GB201904081D0 (en) | 2019-03-25 | 2019-05-08 | Feyrer Hannes | Method and products for producing RNA molecules |
| EP4025351A1 (en) | 2019-09-10 | 2022-07-13 | Surf Technology AS | Ultrasound transducer and method of manufacturing |
| GB202009730D0 (en) | 2020-06-25 | 2020-08-12 | Univ Oslo | Uses, methods and products relating to oligomeric lipopolysaccharide binding proteins |
| CN112851866B (zh) * | 2021-01-13 | 2022-04-12 | 杭州博岳生物技术有限公司 | 一种接枝制备官能团化表面包覆聚苯乙烯微球的方法 |
| GB202104999D0 (en) | 2021-04-08 | 2021-05-26 | Univ Oxford Innovation Ltd | Polypeptides that interact with peptide tags at loops or termini and uses thereof |
| GB202117283D0 (en) | 2021-11-30 | 2022-01-12 | Univ Oxford Innovation Ltd | Switchable polypeptide and its use for gentle affinity purification |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2467352A (en) * | 1944-04-22 | 1949-04-12 | Du Pont | Vinyl halide polymer compositions |
| US2538273A (en) * | 1947-11-14 | 1951-01-16 | Us Rubber Co | Method of increasing the particle size of synthetic resin latices |
| US3282874A (en) * | 1963-12-30 | 1966-11-01 | Dow Chemical Co | Method for dissolving watersoluble polymers |
| US3875130A (en) * | 1969-05-19 | 1975-04-01 | Pechiney Saint Gobain | Preparation with seeding of polymers insoluble in their monomeric compositions |
| US3669728A (en) * | 1970-06-22 | 1972-06-13 | Ppg Industries Inc | Method for providing opaque,microcellular,film coatings on substrates and the resultant product |
| US3669729A (en) * | 1970-06-22 | 1972-06-13 | Ppg Industries Inc | Method for producing articles having pigmented coatings with improved hiding ability and the resultant product |
| US4152496A (en) * | 1971-08-05 | 1979-05-01 | Rohm And Haas Company | Hybrid copolymers |
| US4094841A (en) * | 1974-06-17 | 1978-06-13 | The Dow Chemical Company | Highly monodisperse latexes of non-film forming polymers |
| US4011388A (en) * | 1974-07-02 | 1977-03-08 | E. I. Du Pont De Nemours And Company | Process for preparing emulsions by polymerization of aqueous monomer-polymer dispersions |
| NO139410C (no) * | 1976-02-19 | 1979-03-07 | Sintef | Fremgangsmaate for fremstilling av lateks |
| NO141367C (no) * | 1976-11-22 | 1980-02-27 | Sintef | Framgangsmaate for framstilling av findelte emulsjoner av et litt vannloeselig materiale |
| NO140932C (no) * | 1977-08-10 | 1979-12-12 | Sintef | Fremgangsmaate for fremstilling av lateks |
| US4247434A (en) * | 1978-12-29 | 1981-01-27 | Lovelace Alan M Administrator | Process for preparation of large-particle-size monodisperse |
-
1979
- 1979-02-12 AU AU44152/79A patent/AU530410B2/en not_active Expired
- 1979-02-13 PT PT7969217A patent/PT69217A/pt unknown
- 1979-02-19 CA CA000321791A patent/CA1166779A/en not_active Expired
- 1979-02-20 AT AT0130879A patent/AT368169B/de not_active IP Right Cessation
- 1979-02-20 FI FI790563A patent/FI68408C/fi not_active IP Right Cessation
- 1979-02-20 JP JP1899179A patent/JPS54126288A/ja active Granted
- 1979-02-20 DK DK074579A patent/DK160318C/da not_active IP Right Cessation
- 1979-02-21 BR BR7901146A patent/BR7901146A/pt unknown
- 1979-02-21 EP EP79300274A patent/EP0003905B2/en not_active Expired - Lifetime
- 1979-02-21 DE DE7979300274T patent/DE2966965D1/de not_active Expired
-
1980
- 1980-09-10 US US06/186,008 patent/US4336173A/en not_active Expired - Lifetime
-
1982
- 1982-03-30 US US06/363,497 patent/US4459378A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| AU4415279A (en) | 1979-08-30 |
| PT69217A (en) | 1979-03-01 |
| DK160318C (da) | 1991-08-05 |
| JPS5724369B2 (sv) | 1982-05-24 |
| EP0003905B1 (en) | 1984-05-09 |
| ATA130879A (de) | 1982-01-15 |
| CA1166779A (en) | 1984-05-01 |
| EP0003905A1 (en) | 1979-09-05 |
| DE2966965D1 (en) | 1984-06-14 |
| EP0003905B2 (en) | 1996-10-16 |
| AU530410B2 (en) | 1983-07-14 |
| US4336173A (en) | 1982-06-22 |
| DK74579A (da) | 1979-08-22 |
| DK160318B (da) | 1991-02-25 |
| US4459378A (en) | 1984-07-10 |
| BR7901146A (pt) | 1979-09-11 |
| AT368169B (de) | 1982-09-27 |
| FI790563A (fi) | 1979-08-22 |
| FI68408C (fi) | 1985-09-10 |
| JPS54126288A (en) | 1979-10-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| FI68408B (fi) | Foerfarande foer framstaellning av en vattenemulsion eller -dispersion av ett delvis vattenloesligt material och eventuellt vidare omvandling av den framstaellda dispersionen eller emulsionen till en polymerdispersion dao det delvis vattenloesliga materialet aer en polymeriserbar monomer samt anvaendning av sao framstaellda monodispersa polymerpartiklar som toing i xerografi | |
| EP0091453B1 (en) | Process for the preparation of polymer particles | |
| FI68845B (fi) | Foerfarande foer framstaellning av polymerlatex | |
| Lei et al. | High internal phase emulsion with double emulsion morphology and their templated porous polymer systems | |
| KR930011757B1 (ko) | 용매 코어 순차적 중합체 분산을 제조하는 마이크로 서스펜션법 | |
| Ma et al. | Microencapsulation of oil with poly (styrene-N, N-dimethylaminoethyl methacrylate) by SPG emulsification technique: Effects of conversion and composition of oil phase | |
| DE69314136T2 (de) | Nanopartikeln von funktionalisierten polymeren, deren verfahren zur herstellung und deren verwendung | |
| US20020143088A1 (en) | Process for obtaining a photochromic latex | |
| SE442871B (sv) | Forfarande for framstellning av finfordelade emulsioner av ett foga vattenlosligt organiskt material | |
| CN102580570B (zh) | 一种固载Ag+促进传递膜及其制备方法和应用 | |
| CN100512945C (zh) | 以小分子烃为模板制备温敏性纳米微胶囊的方法 | |
| SE442997B (sv) | Forfarande utgorande av forfarandet enligt krav 1 i se,b, 432 770 varvid till den homogeniserade blandningen en oljeloslig polymerisationsinitiator tillsettes, vilken har en vattenloslighet som medger att den kan diffun | |
| CN100354039C (zh) | 以有机小分子烃为模板的制备有机－无机杂化纳米微胶囊的方法 | |
| DE60026076D1 (de) | Herstellungsverfahren von einem latex mit hohem feststoffgehalt, mit einer niedrigen viskosität und eine einer bimodalen verteilung | |
| DE10031859B4 (de) | Verbesserte Mikrogele und Filme | |
| Hu et al. | Optical detection of the morphology of hollow polymer particles prepared from seeded emulsions in the presence of n-octanol | |
| CN111072845A (zh) | 乳液及其制备方法 | |
| Narongthong et al. | One-pot synthesis of organic-inorganic hybrid hollow latex particles via Pickering and seeded emulsion polymerizations | |
| KR20180119499A (ko) | 유화 입자 클러스터를 포함하는 수중유형 유화 조성물 및 그 제조방법 | |
| CN110183686B (zh) | 一种类型可调控乳液及其制备方法 | |
| Tawonsree et al. | Control of various morphological changes of poly (meth) acrylate microspheres and their swelling degrees by SPG emulsification | |
| CN113105650A (zh) | 一种以毛刷状微球为稳定乳化剂的皮克林乳液及其制备方法 | |
| EP0105057B1 (de) | Verfahren zur Herstellung von reaktiven hydrophilen, mit Farbstoffen oder fluoreszierenden Verbindungen markierten Latexpartikeln | |
| FI62845B (fi) | Foerfarande foer framstaellning av vinylpolymerlatex | |
| JPS6372713A (ja) | 耐溶剤型均一粒径微粒子の製造方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MA | Patent expired | ||
| MA | Patent expired |
Owner name: SINTEF |