ES2530217T3 - Procedimiento para la preparación de acil-glicinatos - Google Patents
Procedimiento para la preparación de acil-glicinatos Download PDFInfo
- Publication number
- ES2530217T3 ES2530217T3 ES08852108.3T ES08852108T ES2530217T3 ES 2530217 T3 ES2530217 T3 ES 2530217T3 ES 08852108 T ES08852108 T ES 08852108T ES 2530217 T3 ES2530217 T3 ES 2530217T3
- Authority
- ES
- Spain
- Prior art keywords
- chloride
- fatty acid
- cocoyl
- acyl
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000000034 method Methods 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 125000002252 acyl group Chemical group 0.000 title claims description 32
- 239000000194 fatty acid Substances 0.000 claims abstract description 44
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 43
- 229930195729 fatty acid Natural products 0.000 claims abstract description 43
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 claims abstract description 34
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims abstract description 32
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000004471 Glycine Substances 0.000 claims abstract description 17
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 17
- 150000001339 alkali metal compounds Chemical class 0.000 claims abstract description 13
- 150000001768 cations Chemical class 0.000 claims abstract description 13
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 12
- 125000003892 C18 acyl group Chemical group 0.000 claims abstract description 9
- 239000003960 organic solvent Substances 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims description 47
- -1 alkali metal cations Chemical class 0.000 claims description 45
- 150000004679 hydroxides Chemical class 0.000 claims description 5
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 3
- 150000001340 alkali metals Chemical class 0.000 abstract description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 38
- 239000011734 sodium Substances 0.000 description 26
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 19
- 238000006243 chemical reaction Methods 0.000 description 19
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 16
- 238000003756 stirring Methods 0.000 description 15
- 239000007844 bleaching agent Substances 0.000 description 14
- 235000011121 sodium hydroxide Nutrition 0.000 description 13
- 238000004128 high performance liquid chromatography Methods 0.000 description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 239000011780 sodium chloride Substances 0.000 description 8
- 229940065859 sodium cocoyl glycinate Drugs 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 7
- 150000001413 amino acids Chemical class 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 7
- 239000007788 liquid Substances 0.000 description 7
- 238000004448 titration Methods 0.000 description 7
- 238000001816 cooling Methods 0.000 description 6
- 239000002537 cosmetic Substances 0.000 description 6
- 150000002333 glycines Chemical class 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- IKGKWKGYFJBGQJ-UHFFFAOYSA-M sodium;2-(dodecanoylamino)acetate Chemical compound [Na+].CCCCCCCCCCCC(=O)NCC([O-])=O IKGKWKGYFJBGQJ-UHFFFAOYSA-M 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 150000001298 alcohols Chemical class 0.000 description 4
- 230000007935 neutral effect Effects 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 3
- 150000001805 chlorine compounds Chemical class 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000011541 reaction mixture Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000011022 opal Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 229940079988 potassium cocoyl glycinate Drugs 0.000 description 2
- KIDBBTHHMJOMAU-UHFFFAOYSA-N propan-1-ol;hydrate Chemical compound O.CCCO KIDBBTHHMJOMAU-UHFFFAOYSA-N 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- NGNBDVOYPDDBFK-UHFFFAOYSA-N 2-[2,4-di(pentan-2-yl)phenoxy]acetyl chloride Chemical compound CCCC(C)C1=CC=C(OCC(Cl)=O)C(C(C)CCC)=C1 NGNBDVOYPDDBFK-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical group [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- 238000003436 Schotten-Baumann reaction Methods 0.000 description 1
- 125000004442 acylamino group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Chemical group BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000004247 glycine and its sodium salt Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 239000011630 iodine Chemical group 0.000 description 1
- 229910052740 iodine Chemical group 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 239000012074 organic phase Substances 0.000 description 1
- 238000006053 organic reaction Methods 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- FSYKKLYZXJSNPZ-UHFFFAOYSA-N sarcosine Chemical class C[NH2+]CC([O-])=O FSYKKLYZXJSNPZ-UHFFFAOYSA-N 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 150000003333 secondary alcohols Chemical class 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229940029258 sodium glycinate Drugs 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 150000003509 tertiary alcohols Chemical class 0.000 description 1
- 125000005207 tetraalkylammonium group Chemical group 0.000 description 1
- 125000005208 trialkylammonium group Chemical group 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C231/00—Preparation of carboxylic acid amides
- C07C231/02—Preparation of carboxylic acid amides from carboxylic acids or from esters, anhydrides, or halides thereof by reaction with ammonia or amines
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Epidemiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Birds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102007055265 | 2007-11-20 | ||
| DE102007055265A DE102007055265A1 (de) | 2007-11-20 | 2007-11-20 | Verfahren zur Herstellung von Acylglycinaten |
| PCT/EP2008/009646 WO2009065530A2 (de) | 2007-11-20 | 2008-11-14 | Verfahren zur herstellung von acylglycinaten |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2530217T3 true ES2530217T3 (es) | 2015-02-27 |
Family
ID=40394359
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES08852108.3T Active ES2530217T3 (es) | 2007-11-20 | 2008-11-14 | Procedimiento para la preparación de acil-glicinatos |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8338483B2 (enExample) |
| EP (2) | EP2248512A3 (enExample) |
| JP (1) | JP5496905B2 (enExample) |
| CN (1) | CN101903336B (enExample) |
| BR (1) | BRPI0819337A2 (enExample) |
| DE (1) | DE102007055265A1 (enExample) |
| ES (1) | ES2530217T3 (enExample) |
| WO (1) | WO2009065530A2 (enExample) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006038853A1 (de) * | 2006-08-18 | 2008-02-21 | Clariant International Limited | Verfahren zur Herstellung von Acylglycinaten mittels Direktoxidation |
| DE102008003825A1 (de) * | 2008-01-10 | 2009-07-16 | Clariant International Ltd. | Verfahren zur Herstellung von Acylglycinaten mittels Direktoxidation |
| DE102011107503A1 (de) * | 2011-07-15 | 2012-03-01 | Clariant International Ltd. | Verfahren zur Herstellung von Acylglycinaten und Zusammensetzungen enthaltend derartige Verbindungen |
| US8822711B2 (en) * | 2011-07-28 | 2014-09-02 | Conopco, Inc. | Method for preparing fatty acyl amido carboxylic acid based surfactants |
| US8658589B2 (en) | 2011-07-28 | 2014-02-25 | Conopco, Inc. | Fatty acyl amido based surfactant concentrates |
| EP2870136B1 (en) | 2012-07-03 | 2018-10-24 | Stepan Company | Process for preparing n-acyl amino acid salts |
| RU2624026C2 (ru) * | 2012-08-23 | 2017-06-30 | Гэлакси Сёфэктентс Лтд. | Способ получения основанных на n-ациламинокислоте поверхностно-активных веществ с применением основанных на n-ациламинокислоте поверхностно-активных веществ или соответствующих ангидридов в качестве катализаторов |
| CN102863352A (zh) * | 2012-09-05 | 2013-01-09 | 长沙普济生物科技有限公司 | 一种椰油酰基氨基酸钠的合成方法 |
| WO2015000931A2 (en) | 2013-07-05 | 2015-01-08 | Akzo Nobel Chemicals International B.V. | The synthesis of new anionic surfactants and their use as collectors in froth flotation of non-sulphidic ores |
| JP6595472B2 (ja) | 2013-08-19 | 2019-10-23 | ステパン カンパニー | Ｎ−アシルアミノ酸塩を調製するためのプロセス |
| CN105683151B (zh) | 2013-10-31 | 2020-11-03 | 味之素株式会社 | 包含n-长链酰基酸性氨基酸和/或其盐的水溶液及其制造方法 |
| CN104649927B (zh) * | 2013-11-25 | 2017-10-31 | 江苏四新界面剂科技有限公司 | 一种正十一烷二酰基二谷氨酸三乙醇胺盐及其制备方法 |
| EP3080086B1 (en) | 2013-12-09 | 2017-07-05 | Unilever PLC, a company registered in England and Wales under company no. 41424 of | Process of making adamantanamides |
| CN103965072B (zh) * | 2014-04-02 | 2016-08-17 | 烟台恒迪克能源科技有限公司 | 一种癸二酰基谷氨酸的合成方法 |
| CN103951581B (zh) * | 2014-04-05 | 2016-04-27 | 烟台恒迪克能源科技有限公司 | 一种正十一碳二酰基二天门冬氨酸-双-二甘醇胺盐的合成 |
| DE102015014929A1 (de) * | 2015-11-13 | 2017-05-18 | Bernd Kunze | Verfahren zur Herstellung von N-Acylderivaten, die Fettsäure-Reste enthalten |
| EP3708643A4 (en) | 2017-11-06 | 2021-08-18 | Ajinomoto Co., Inc. | DETERGENT COMPOSITION |
| US12123004B2 (en) | 2018-07-18 | 2024-10-22 | Modular Genetics, Inc. | Generation of acyl amino acids |
| EP3647303B1 (en) * | 2018-10-31 | 2022-08-31 | Clariant International Ltd | Process for preparing fatty acid chlorides and n-acyl amino acid salts |
| CN111187174A (zh) * | 2020-01-16 | 2020-05-22 | 广东丽臣奥威实业有限公司 | 一种脂肪酰甘氨酸盐或脂肪衍生物酰甘氨酸盐的生产及纯化方法 |
| CN114369036B (zh) * | 2021-12-30 | 2024-04-19 | 广州花语精细化工有限公司 | 一种降低甘氨酸类表面活性剂中胺类副产物的方法 |
| CN115160169B (zh) * | 2022-07-25 | 2024-04-16 | 湖州欧利生物科技有限公司 | 椰油酰甘氨酸盐表面活性剂的生产工艺 |
| CN117003661A (zh) * | 2023-07-07 | 2023-11-07 | 广东聚石科技研究院有限公司 | 一种n-酰基氨基酸的制备方法 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT490450A (enExample) | 1951-07-19 | |||
| LU86587A1 (fr) * | 1986-09-15 | 1988-04-05 | Oreal | Dentifrice contenant un tensio-actif non ionique poly(hydroxypropylether)et un sel d'un derive specifique d'un produit de degradation des proteines |
| FR2676922B1 (fr) * | 1991-06-03 | 1995-01-20 | Givaudan Lavirotte | Applications en cosmetique de derives n-acyles de melanges d'acides amines issus d'hydrolysats de proteines vegetales. |
| JP2969397B2 (ja) * | 1991-09-10 | 1999-11-02 | 花王株式会社 | Ｎ−長鎖アシル−β−アラニンの製造方法 |
| DE69422366T2 (de) * | 1993-03-30 | 2000-08-24 | Ajinomoto Co., Inc. | Waschmittelzusammensetzung |
| JP3362468B2 (ja) | 1993-08-25 | 2003-01-07 | 味の素株式会社 | Ｎ−混合飽和脂肪酸アシル中性アミノ酸の製造法 |
| DE4415312A1 (de) * | 1994-05-02 | 1995-11-09 | Hoechst Ag | Verfahren zur Herstellung von N-Acylglycinderivaten |
| JP3304646B2 (ja) | 1994-06-07 | 2002-07-22 | 味の素株式会社 | 洗浄剤組成物 |
| US5710295A (en) | 1995-06-06 | 1998-01-20 | Hampshire Chemical Corp. | Preparation of alkali metal acyl amino acids |
| JPH1081656A (ja) * | 1996-09-06 | 1998-03-31 | Ajinomoto Co Inc | Ｎ−長鎖アシル酸性アミノ酸またはその塩の製造法 |
| FR2765109B1 (fr) * | 1997-06-25 | 2001-02-09 | Seppic Sa | Composition comprenant un lipoaminoacide et les constituants d'un extrait de plantes riches en tanins et utilisation en cosmetique |
| JP4407846B2 (ja) | 1998-02-27 | 2010-02-03 | 花王株式会社 | １級アルコールの酸化方法 |
| JP4392884B2 (ja) * | 1998-12-28 | 2010-01-06 | 旭化成ケミカルズ株式会社 | Ｎ−長鎖アシル酸性アミノ酸塩、およびその製造方法 |
| JP2001278778A (ja) * | 2000-03-31 | 2001-10-10 | Shiseido Co Ltd | 皮膚洗浄料 |
| US6828452B2 (en) * | 2001-01-18 | 2004-12-07 | Cognis Deutschland Gmbh & Co. Kg | Method for producing acyl amino acids |
| US6703517B2 (en) | 2001-11-26 | 2004-03-09 | Ajinomoto Co., Inc. | Method for preparing N-long chain acyl neutral amino acid |
| EP1672055B1 (en) | 2003-10-03 | 2008-10-01 | Ajinomoto Co., Inc. | Detergent compositions and processes for the production thereof |
| DE102004048324A1 (de) | 2003-10-08 | 2005-05-12 | Ajinomoto Kk | Kristalle von N-langkettigen Acyglycin-Salzen, Verfahren zu ihrer Herstellung und diese Kristalle enthaltende Reinigungsmittel-Zusammensetzungen |
| JP2007269662A (ja) * | 2006-03-30 | 2007-10-18 | Ajinomoto Co Inc | クリーム状皮膚洗浄剤組成物 |
| US20070299269A1 (en) | 2006-06-27 | 2007-12-27 | Conopco, Inc., D/B/A Unilever | Process for converting primary amidoalcohols to amidocarboxylic acids in high yield |
| US7307187B1 (en) | 2006-06-27 | 2007-12-11 | Conopco, Inc. | Process for converting primary amidoalcohols to amidocarboxylic acids in high yield |
| DE102006038853A1 (de) | 2006-08-18 | 2008-02-21 | Clariant International Limited | Verfahren zur Herstellung von Acylglycinaten mittels Direktoxidation |
| DE102008003825A1 (de) | 2008-01-10 | 2009-07-16 | Clariant International Ltd. | Verfahren zur Herstellung von Acylglycinaten mittels Direktoxidation |
-
2007
- 2007-11-20 DE DE102007055265A patent/DE102007055265A1/de not_active Withdrawn
-
2008
- 2008-11-14 WO PCT/EP2008/009646 patent/WO2009065530A2/de not_active Ceased
- 2008-11-14 CN CN200880121606.3A patent/CN101903336B/zh active Active
- 2008-11-14 JP JP2010534399A patent/JP5496905B2/ja active Active
- 2008-11-14 EP EP20100008258 patent/EP2248512A3/de not_active Ceased
- 2008-11-14 US US12/743,458 patent/US8338483B2/en not_active Expired - Fee Related
- 2008-11-14 ES ES08852108.3T patent/ES2530217T3/es active Active
- 2008-11-14 BR BRPI0819337 patent/BRPI0819337A2/pt not_active IP Right Cessation
- 2008-11-14 EP EP08852108.3A patent/EP2212278B1/de active Active
Also Published As
| Publication number | Publication date |
|---|---|
| US20100273879A1 (en) | 2010-10-28 |
| BRPI0819337A2 (pt) | 2015-05-12 |
| WO2009065530A2 (de) | 2009-05-28 |
| CN101903336B (zh) | 2014-06-25 |
| DE102007055265A1 (de) | 2009-05-28 |
| US8338483B2 (en) | 2012-12-25 |
| EP2212278A2 (de) | 2010-08-04 |
| EP2248512A3 (de) | 2012-01-25 |
| JP5496905B2 (ja) | 2014-05-21 |
| CN101903336A (zh) | 2010-12-01 |
| JP2011503218A (ja) | 2011-01-27 |
| EP2248512A2 (de) | 2010-11-10 |
| WO2009065530A3 (de) | 2009-09-03 |
| EP2212278B1 (de) | 2015-01-07 |
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