ES2519715T3 - Material compuesto y procedimiento para la preparación del mismo - Google Patents

Material compuesto y procedimiento para la preparación del mismo Download PDF

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Publication number
ES2519715T3
ES2519715T3 ES09015803.1T ES09015803T ES2519715T3 ES 2519715 T3 ES2519715 T3 ES 2519715T3 ES 09015803 T ES09015803 T ES 09015803T ES 2519715 T3 ES2519715 T3 ES 2519715T3
Authority
ES
Spain
Prior art keywords
combination
orbital
vulcanized rubber
resin
rubber
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES09015803.1T
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English (en)
Inventor
Toru Ikuta
Mitsuteru Mutsuda
Hajime Komada
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daicel Evonik Ltd
Original Assignee
Daicel Evonik Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
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Application filed by Daicel Evonik Ltd filed Critical Daicel Evonik Ltd
Application granted granted Critical
Publication of ES2519715T3 publication Critical patent/ES2519715T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B32B27/20—Layered products comprising a layer of synthetic resin characterised by the use of special additives using fillers, pigments, thixotroping agents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00—Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08—Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
    • B32B27/285—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polyethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
    • C08J5/121—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives by heating
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00—Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2375/00—Polyureas; Polyurethanes
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    • Y10T428/31859—Next to an aldehyde or ketone condensation product
    • Y10T428/31862—Melamine-aldehyde
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31859—Next to an aldehyde or ketone condensation product
    • Y10T428/3187—Amide-aldehyde
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31931—Polyene monomer-containing
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31935—Ester, halide or nitrile of addition polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31855—Of addition polymer from unsaturated monomers
    • Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon

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  • Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

Material compuesto que comprende una pieza de caucho vulcanizado formada mediante una vulcanización de un caucho no vulcanizado que no es de la serie de silicone, y una pieza de resina que comprende una resina termoplástica y este directamente unida a la pieza de caucho, mediante lo cual dicho material compuesto comprende una combinación de una pieza de caucho vulcanizado con un agente de generación de radicales y una pieza de resina que comprende una resina termoplastica que tiene al menos 2 atomos, en promedio, seleccionados de un atomo de hidrogeno y un atomo de azufre por molecula, y cada atomo tiene un coeficiente de energia de interacción de orbitales S de no menos de 0,006, en el que el coeficiente de energia de interacción de orbitales S este representado por la siguiente formula (1): S [eVi] >= (CHOM0A2 IEC EHOMO,n1 (CLUMO,n)2 Ec ELUMO,n1 (1) en la que cada uno de Ec, CHomo, EHomo,n, CLumo,n, y ELumo,n representa un valor calculado mediante un metodo de orbitales moleculares semiempirico MOPACPM3, representando Ec una energia de orbital (eV) de un radical del agente de generación de radicales, representando CHomo,n un coeficiente de orbital molecular del orbital molecular ocupado mas alto (HOMO) de un atomo de hidrógeno o azufre de orden n que constituye una unidad constitutiva de la resina termoplastica, representando EHomo,n una energia de orbital (eV) del HOMO, representando Clumo,n un coeficiente de orbital molecular del orbital molecular ocupado mas bajo (LUMO) del atomo de hidrógeno o azufre de orden n que constituye la unidad constitutiva de la resina termoplastica, y representando ELumo,n una energia de orbital (eV) del LUMO; mediante lo cual dicha unidad constitutive significa una estructura molecular de modelado que comprende un extremo terminal de polimero y de 1 a 3 unidades de repeticion siempre que dicha combinacion excluya las siguientes combinaciones (1) a (3); (1) una combinación de una resina de la serie de poliamida alifatica que tiene un grupo amino y un caucho no vulcanizado que tiene un grupo carboxilo o un grupo anhidrido de acido, (2) una combinacion de una resina de la serie de poliamida alifatica y un caucho no vulcanized° que comprende un compuesto de silano, y (3) una combinaci6n de una resina que contiene grupo epoxi y un caucho no vulcanizado que tiene un grupo carboxilo o un grupo anhidrido de acido; y en la que dicha combinacion es cualquiera de las siguientes combinaciones: (a) una combinación de una resina de la serie de poliamida en la que la razon (raz6n molar) de grupos amino terminales/grupos carboxilo terminales es de 50/50 a 100/0, y un caucho no vulcanizado que comprende un peroxido organico y un agente de activacion de la vulcanizacion polifuncional, en la que el agente de activacion de la vulcanizacion polifuncional comprende al menos un miembro seleccionado del grupo que consiste en un (iso)cianurato de trialilo, un (met)acrilato tri o polifuncional y un compuesto de maleimida aromático; (b) una combinacion de una resina de la serie de poliamida en la que la razon (raz6n molar) de grupos amino terminales/grupos carboxilo terminales es de 50/50 a 100/0, y un caucho no vulcanizado que comprende un peroxido organico y un agente de activacion de la vulcanizacion polifuncional, en el que el caucho comprende un caucho de etileno-propileno-dieno y un caucho de polioctenileno, y el agente de activación de vulcanizacion polifuncional comprende un compuesto organico que tiene al menos dos enlaces insaturados polimerizables por molecula.

Description

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Claims (1)

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WO2002055296A1 (en) 2002-07-18
US7175916B2 (en) 2007-02-13
KR20020082880A (ko) 2002-10-31
EP1273433B1 (en) 2021-09-22
EP2202058A2 (en) 2010-06-30
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JP5010667B2 (ja) 2012-08-29
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EP2202058B1 (en) 2014-09-10
TWI286971B (en) 2007-09-21
CN1455734A (zh) 2003-11-12
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US20030118839A1 (en) 2003-06-26
CN1257797C (zh) 2006-05-31
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EP1273433A1 (en) 2003-01-08
JP2010052433A (ja) 2010-03-11

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