ES2245518T3 - Modificadores de impacto de silicona-acrilato polimerizados en emulsion, mezclas termoplasticas y procedimiento de fabricacion. - Google Patents
Modificadores de impacto de silicona-acrilato polimerizados en emulsion, mezclas termoplasticas y procedimiento de fabricacion.Info
- Publication number
- ES2245518T3 ES2245518T3 ES99954709T ES99954709T ES2245518T3 ES 2245518 T3 ES2245518 T3 ES 2245518T3 ES 99954709 T ES99954709 T ES 99954709T ES 99954709 T ES99954709 T ES 99954709T ES 2245518 T3 ES2245518 T3 ES 2245518T3
- Authority
- ES
- Spain
- Prior art keywords
- rubber
- silicone
- polymerized
- emulsion
- latex
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 67
- 239000000839 emulsion Substances 0.000 title claims abstract description 64
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 32
- 239000004416 thermosoftening plastic Substances 0.000 title claims description 22
- 238000004519 manufacturing process Methods 0.000 title description 4
- 229920001971 elastomer Polymers 0.000 claims abstract description 99
- 239000005060 rubber Substances 0.000 claims abstract description 99
- 229920000126 latex Polymers 0.000 claims abstract description 78
- 229920002379 silicone rubber Polymers 0.000 claims abstract description 71
- 239000004945 silicone rubber Substances 0.000 claims abstract description 69
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 59
- 239000004816 latex Substances 0.000 claims abstract description 54
- 239000002245 particle Substances 0.000 claims abstract description 52
- 239000000178 monomer Substances 0.000 claims abstract description 41
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 32
- 238000000034 method Methods 0.000 claims abstract description 25
- 239000004609 Impact Modifier Substances 0.000 claims abstract description 24
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 23
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 21
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 12
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 7
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 238000001035 drying Methods 0.000 claims abstract description 4
- 230000015271 coagulation Effects 0.000 claims abstract description 3
- 238000005345 coagulation Methods 0.000 claims abstract description 3
- 230000000694 effects Effects 0.000 claims abstract description 3
- 238000005406 washing Methods 0.000 claims abstract description 3
- 239000002685 polymerization catalyst Substances 0.000 claims abstract 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 27
- 239000000463 material Substances 0.000 claims description 23
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 14
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 7
- 230000002902 bimodal effect Effects 0.000 claims description 7
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims description 4
- 229920000728 polyester Polymers 0.000 claims description 4
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims description 2
- 239000004952 Polyamide Substances 0.000 claims description 2
- 239000004697 Polyetherimide Substances 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229920002647 polyamide Polymers 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920001601 polyetherimide Polymers 0.000 claims description 2
- 229920001955 polyphenylene ether Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- 230000004927 fusion Effects 0.000 claims 3
- XYYQWMDBQFSCPB-UHFFFAOYSA-N dimethoxymethylsilane Chemical compound COC([SiH3])OC XYYQWMDBQFSCPB-UHFFFAOYSA-N 0.000 claims 1
- 125000005395 methacrylic acid group Chemical group 0.000 claims 1
- 239000011368 organic material Substances 0.000 claims 1
- 238000005728 strengthening Methods 0.000 claims 1
- 238000007720 emulsion polymerization reaction Methods 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 25
- 239000012153 distilled water Substances 0.000 description 17
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 10
- 239000000243 solution Substances 0.000 description 8
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 7
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 7
- 229920000578 graft copolymer Polymers 0.000 description 7
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 5
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- VLZDYNDUVLBNLD-UHFFFAOYSA-N 3-(dimethoxymethylsilyl)propyl 2-methylprop-2-enoate Chemical compound COC(OC)[SiH2]CCCOC(=O)C(C)=C VLZDYNDUVLBNLD-UHFFFAOYSA-N 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- -1 polysiloxanes Polymers 0.000 description 4
- 150000004756 silanes Chemical class 0.000 description 4
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 4
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000003607 modifier Substances 0.000 description 3
- 239000012299 nitrogen atmosphere Substances 0.000 description 3
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 229920005992 thermoplastic resin Polymers 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000012815 thermoplastic material Substances 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical group C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- MIOLDAWBWLPMES-UHFFFAOYSA-N COC[SiH2]CCCOC(=O)C(C)=C Chemical compound COC[SiH2]CCCOC(=O)C(C)=C MIOLDAWBWLPMES-UHFFFAOYSA-N 0.000 description 1
- OWYWGLHRNBIFJP-UHFFFAOYSA-N Ipazine Chemical compound CCN(CC)C1=NC(Cl)=NC(NC(C)C)=N1 OWYWGLHRNBIFJP-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 239000003637 basic solution Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 208000012839 conversion disease Diseases 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000011363 dried mixture Substances 0.000 description 1
- 238000010413 gardening Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 235000020166 milkshake Nutrition 0.000 description 1
- 239000000479 mixture part Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000012258 stirred mixture Substances 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- TUQLLQQWSNWKCF-UHFFFAOYSA-N trimethoxymethylsilane Chemical compound COC([SiH3])(OC)OC TUQLLQQWSNWKCF-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
- C08L51/085—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds on to polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F285/00—Macromolecular compounds obtained by polymerising monomers on to preformed graft polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F291/00—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
- C08F291/02—Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00 on to elastomers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/205,311 US6169149B1 (en) | 1998-12-04 | 1998-12-04 | Emulsion polymerized silicone-acrylate rubber impact modifiers thermoplastic blends, and methods for making |
| US205311 | 1998-12-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2245518T3 true ES2245518T3 (es) | 2006-01-01 |
Family
ID=22761685
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES99954709T Expired - Lifetime ES2245518T3 (es) | 1998-12-04 | 1999-10-04 | Modificadores de impacto de silicona-acrilato polimerizados en emulsion, mezclas termoplasticas y procedimiento de fabricacion. |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US6169149B1 (enExample) |
| EP (1) | EP1141058B1 (enExample) |
| JP (1) | JP4520641B2 (enExample) |
| CN (1) | CN1147516C (enExample) |
| DE (1) | DE69926396T2 (enExample) |
| ES (1) | ES2245518T3 (enExample) |
| WO (1) | WO2000034346A1 (enExample) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1325537C (zh) * | 1998-12-07 | 2007-07-11 | 通用电气公司 | 乳液聚合硅橡胶－基冲击改性剂、制备方法及其共混物 |
| JP4702998B2 (ja) * | 2000-12-05 | 2011-06-15 | 株式会社カネカ | ゴム変性樹脂およびそれを含有する熱可塑性樹脂組成物 |
| MXPA02011785A (es) * | 2001-12-14 | 2005-08-26 | Rohm & Haas | Procesos para preparar composiciones de particulas de polimeros multimodales. |
| DE10204890A1 (de) * | 2002-02-06 | 2003-08-14 | Roehm Gmbh | Schlagzähe Formmasse und Formkörper |
| US20040162399A1 (en) * | 2003-02-14 | 2004-08-19 | Reddy Poreddy Narsi | Silicone-acrylate impact modifier |
| US20050223465A1 (en) * | 2004-04-09 | 2005-10-13 | Nike, Inc. | Article of apparel for temperature moderation |
| EP2399950B1 (en) * | 2004-12-31 | 2013-04-17 | Cheil Industries Inc. | Silicone impact modifier with high refractive index and method for preparing the same |
| US7541401B2 (en) * | 2004-12-31 | 2009-06-02 | Cheil Industries Inc. | Impact modifier for a polymer composition and method for preparing the same |
| US8802754B2 (en) * | 2005-01-25 | 2014-08-12 | Mgpi Processing, Inc. | Starch-plastic composite resins and profiles made by extrusion |
| DE102005041330B4 (de) * | 2005-08-29 | 2008-12-18 | Silcos Gmbh | Silikonelastomere und deren Oberflächenmodifikation mittels Plasmaverfahren zwecks Beschichtung |
| US20070092745A1 (en) * | 2005-10-24 | 2007-04-26 | Li Nie | Thermotolerant starch-polyester composites and methods of making same |
| JP4988293B2 (ja) * | 2006-10-19 | 2012-08-01 | 帝人化成株式会社 | 芳香族ポリカーボネート樹脂組成物 |
| CN102321219B (zh) * | 2011-06-03 | 2012-10-31 | 北京化工大学 | 一种有机硅接枝丙烯酸酯共聚乳液的制备方法 |
| CN102382341B (zh) * | 2011-10-31 | 2012-12-05 | 铜陵新特阀门有限责任公司 | 一种平行式闸阀端面o型密封圈橡胶胶料及其制备方法 |
| CN111440275B (zh) | 2013-06-28 | 2023-04-14 | 三菱化学株式会社 | 含有聚有机硅氧烷的接枝共聚物、热塑性树脂组合物及成型体 |
| CN109021237B (zh) * | 2018-06-29 | 2021-05-25 | 郑勇 | 大粒径有机硅氧烷橡胶乳液及其制备得到的塑料增韧改性剂 |
| BR112020026756A2 (pt) * | 2018-07-27 | 2021-03-30 | Rohm And Haas Company | Método para a fabricação de uma coleção de partículas poliméricas. |
| CN112334502B (zh) | 2018-07-27 | 2024-03-12 | 罗门哈斯公司 | 聚合硅酮和丙烯酸单体 |
| CN111087737A (zh) * | 2019-12-12 | 2020-05-01 | 会通新材料股份有限公司 | 一种免喷涂、高光asa合金材料及其制备方法 |
| WO2025111838A1 (en) * | 2023-11-29 | 2025-06-05 | Eastman Chemical (China) Co., Ltd. | Flame retardant high modulus copolyester compositions |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1024024A (en) * | 1963-04-08 | 1966-03-30 | Dow Corning | Improvements in or relating to polymerising or co-polymerising organosilicon compounds |
| JPH0629303B2 (ja) | 1984-05-30 | 1994-04-20 | 三菱レイヨン株式会社 | ポリオルガノシロキサン系グラフト共重合体の製造法 |
| JP2608439B2 (ja) | 1988-01-25 | 1997-05-07 | 三菱レイヨン株式会社 | 耐衝撃性樹脂組成物 |
| AU604179B2 (en) | 1988-01-25 | 1990-12-06 | Mitsubishi Rayon Company Limited | Vinyl chloride resin composition |
| DE3839585A1 (de) * | 1988-11-24 | 1990-05-31 | Bayer Ag | Polymermischungen mit guter alterungsbestaendigkeit |
| CA2089284A1 (en) * | 1992-02-18 | 1993-08-19 | Kenneth G. Himelrick | Process for producing polydiorganosiloxane based graft copolymers |
| JPH09132620A (ja) * | 1995-11-09 | 1997-05-20 | Japan Synthetic Rubber Co Ltd | グラフト共重合体および熱可塑性樹脂組成物 |
| US5726270A (en) | 1996-12-26 | 1998-03-10 | General Electric Company | Process for the synthesis of mono-modal aqueous dispersions of polysiloxanes |
-
1998
- 1998-12-04 US US09/205,311 patent/US6169149B1/en not_active Expired - Lifetime
-
1999
- 1999-10-04 ES ES99954709T patent/ES2245518T3/es not_active Expired - Lifetime
- 1999-10-04 CN CNB998139475A patent/CN1147516C/zh not_active Expired - Lifetime
- 1999-10-04 DE DE69926396T patent/DE69926396T2/de not_active Expired - Lifetime
- 1999-10-04 JP JP2000586787A patent/JP4520641B2/ja not_active Expired - Fee Related
- 1999-10-04 EP EP99954709A patent/EP1141058B1/en not_active Expired - Lifetime
- 1999-10-04 WO PCT/US1999/022874 patent/WO2000034346A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| DE69926396D1 (de) | 2005-09-01 |
| CN1329623A (zh) | 2002-01-02 |
| WO2000034346A1 (en) | 2000-06-15 |
| DE69926396T2 (de) | 2006-06-01 |
| CN1147516C (zh) | 2004-04-28 |
| US6169149B1 (en) | 2001-01-02 |
| EP1141058A1 (en) | 2001-10-10 |
| JP4520641B2 (ja) | 2010-08-11 |
| EP1141058B1 (en) | 2005-07-27 |
| JP2002531649A (ja) | 2002-09-24 |
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