EP2694635B1 - Procédé de lavage du linge - Google Patents
Procédé de lavage du linge Download PDFInfo
- Publication number
- EP2694635B1 EP2694635B1 EP12707100.9A EP12707100A EP2694635B1 EP 2694635 B1 EP2694635 B1 EP 2694635B1 EP 12707100 A EP12707100 A EP 12707100A EP 2694635 B1 EP2694635 B1 EP 2694635B1
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- EP
- European Patent Office
- Prior art keywords
- surfactant
- composition
- ppm
- acid
- wash
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 229920000578 graft copolymer Polymers 0.000 description 1
- 230000002650 habitual effect Effects 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229940059442 hemicellulase Drugs 0.000 description 1
- 108010002430 hemicellulase Proteins 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- CBOIHMRHGLHBPB-UHFFFAOYSA-N hydroxymethyl Chemical compound O[CH2] CBOIHMRHGLHBPB-UHFFFAOYSA-N 0.000 description 1
- 150000002462 imidazolines Chemical class 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical class OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000000787 lecithin Substances 0.000 description 1
- 229940067606 lecithin Drugs 0.000 description 1
- 235000010445 lecithin Nutrition 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 150000002690 malonic acid derivatives Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000001434 methanylylidene group Chemical group [H]C#[*] 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000003278 mimic effect Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- BZDOEVMUXJTHPS-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)hexadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCC[N+]([O-])(CCO)CCO BZDOEVMUXJTHPS-UHFFFAOYSA-N 0.000 description 1
- CBLJNXZOFGRDAC-UHFFFAOYSA-N n,n-bis(2-hydroxyethyl)octadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCCCC[N+]([O-])(CCO)CCO CBLJNXZOFGRDAC-UHFFFAOYSA-N 0.000 description 1
- IBOBFGGLRNWLIL-UHFFFAOYSA-N n,n-dimethylhexadecan-1-amine oxide Chemical compound CCCCCCCCCCCCCCCC[N+](C)(C)[O-] IBOBFGGLRNWLIL-UHFFFAOYSA-N 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- 239000003605 opacifier Substances 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 125000005702 oxyalkylene group Chemical group 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 239000006179 pH buffering agent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229940071144 palm kernelate Drugs 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- QQBPIHBUCMDKFG-UHFFFAOYSA-N phenazopyridine hydrochloride Chemical group Cl.NC1=NC(N)=CC=C1N=NC1=CC=CC=C1 QQBPIHBUCMDKFG-UHFFFAOYSA-N 0.000 description 1
- HXITXNWTGFUOAU-UHFFFAOYSA-N phenylboronic acid Chemical class OB(O)C1=CC=CC=C1 HXITXNWTGFUOAU-UHFFFAOYSA-N 0.000 description 1
- WTJKGGKOPKCXLL-RRHRGVEJSA-N phosphatidylcholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCCC=CCCCCCCCC WTJKGGKOPKCXLL-RRHRGVEJSA-N 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001515 polyalkylene glycol Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 230000005588 protonation Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003219 pyrazolines Chemical class 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- KUIXZSYWBHSYCN-UHFFFAOYSA-L remazol brilliant blue r Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=C2C(=O)C3=CC=CC=C3C(=O)C2=C1NC1=CC=CC(S(=O)(=O)CCOS([O-])(=O)=O)=C1 KUIXZSYWBHSYCN-UHFFFAOYSA-L 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000004289 sodium hydrogen sulphite Substances 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 229940057950 sodium laureth sulfate Drugs 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- SZINDZNWFLBXKV-UHFFFAOYSA-M sodium;2-(2-hydroxyethoxy)ethanesulfonate Chemical group [Na+].OCCOCCS([O-])(=O)=O SZINDZNWFLBXKV-UHFFFAOYSA-M 0.000 description 1
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical compound [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 1
- GIPRGFRQMWSHAK-UHFFFAOYSA-M sodium;2-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=CC=C1S([O-])(=O)=O GIPRGFRQMWSHAK-UHFFFAOYSA-M 0.000 description 1
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000992 solvent dye Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003900 succinic acid esters Chemical class 0.000 description 1
- 150000005846 sugar alcohols Chemical class 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical group 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 150000004961 triphenylmethanes Chemical class 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3715—Polyesters or polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
- C11D3/38645—Preparations containing enzymes, e.g. protease or amylase containing cellulase
-
- C11D2111/12—
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Claims (9)
- Procédé de lavage d'un textile sur lequel un actif adoucissant de textile cationique a été déposé et séché comprenant l'étape de mise en contact du textile avec une liqueur de lavage aqueuse présentant la composition suivante :a) de 15 à 600 ppm de tensioactif de non-savon,b) au moins 50 ppm de polyéthylène imine éthoxylée,c) au moins 25 ppm d'un polymère libérant la saleté de polyester,
la teneur totale en polymère (b+c) étant d'au moins 20 % en poids de la teneur en tensioactif de non-savon (a),d) de 0,1 à 100 ppm d'enzyme choisie parmi une protéase, une amylase, une cellulase,e) éventuellement, une enzyme de lipase. - Procédé selon la revendication 1, dans lequel la teneur en tensioactif de non-savon (a) est de 200 à 400 ppm.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel le tensioactif de non-savon (a) comprend au moins 50 ppm de tensioactif anionique.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel l'EPEI est non ionique.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel l'actif d'adoucissant de tissu cationique est un composé d'ammonium quaternaire.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel le polymère de libération de saleté de polyester (c) est non ionique et comprend une séquence milieu substantive de polyester d'unités répétitives de téréphtalate et une ou plusieurs séquences terminales de polyéthylène glycol coiffées avec une moitié alkyle inférieur ou hydrogène.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel la liqueur de lavage est formée par dosage de 15 à 40 ml d'une composition de détergent liquide aqueuse à de l'eau et dilution par un facteur d'au moins 600.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel le tensioactif de non-savon comprend LAS, SLES et un non ionique d'alcool gras éthoxylé.
- Procédé selon l'une quelconque des revendications précédentes, dans lequel le tensioactif de non-savon comprend de la carbo-bétaïne.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PL12707100T PL2694635T3 (pl) | 2011-04-04 | 2012-03-05 | Sposób prania tkanin |
| EP12707100.9A EP2694635B1 (fr) | 2011-04-04 | 2012-03-05 | Procédé de lavage du linge |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP11160937.6A EP2476743B1 (fr) | 2011-04-04 | 2011-04-04 | Procédé de lavage du linge |
| EP12707100.9A EP2694635B1 (fr) | 2011-04-04 | 2012-03-05 | Procédé de lavage du linge |
| PCT/EP2012/053709 WO2012136427A1 (fr) | 2011-04-04 | 2012-03-05 | Procédé de lavage d'un tissu |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP2694635A1 EP2694635A1 (fr) | 2014-02-12 |
| EP2694635B1 true EP2694635B1 (fr) | 2015-11-25 |
Family
ID=44453797
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP11160937.6A Revoked EP2476743B1 (fr) | 2011-04-04 | 2011-04-04 | Procédé de lavage du linge |
| EP12707100.9A Revoked EP2694635B1 (fr) | 2011-04-04 | 2012-03-05 | Procédé de lavage du linge |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP11160937.6A Revoked EP2476743B1 (fr) | 2011-04-04 | 2011-04-04 | Procédé de lavage du linge |
Country Status (12)
| Country | Link |
|---|---|
| EP (2) | EP2476743B1 (fr) |
| CN (1) | CN103459577B (fr) |
| AR (1) | AR085771A1 (fr) |
| AU (1) | AU2012238950B2 (fr) |
| BR (1) | BR112013025674B1 (fr) |
| CL (1) | CL2013002817A1 (fr) |
| ES (1) | ES2421162T3 (fr) |
| MX (1) | MX2013011464A (fr) |
| MY (1) | MY161793A (fr) |
| PL (1) | PL2694635T3 (fr) |
| WO (1) | WO2012136427A1 (fr) |
| ZA (1) | ZA201306447B (fr) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2767579B1 (fr) * | 2013-02-19 | 2018-07-18 | The Procter and Gamble Company | Procédé de lavage d'un textile |
| EP2767582A1 (fr) | 2013-02-19 | 2014-08-20 | The Procter and Gamble Company | Procédé de lavage d'un textile |
| CN105647687A (zh) * | 2015-09-17 | 2016-06-08 | 陕西天瑞生物科技有限公司 | 一种聚氨酯表面预处理清洁剂 |
| KR101905888B1 (ko) | 2016-08-18 | 2018-10-10 | 주식회사 영신물산 | 욕중유연제의 제조방법 및 그 제조방법에 의한 욕중유연제 |
| CN109790491B (zh) | 2016-09-27 | 2021-02-23 | 荷兰联合利华有限公司 | 家用洗衣方法 |
| EP3312264B1 (fr) * | 2016-10-21 | 2019-08-21 | The Procter & Gamble Company | Procédé de lavage de tissu avec dépôt d'un adoucissant actif déposé sur celui-ci |
| ES2761930T3 (es) * | 2016-10-21 | 2020-05-21 | Procter & Gamble | Proceso para lavar tejidos que tienen una sustancia activa suavizante catiónicamente cargada depositada sobre las mismas |
| EP3342850A1 (fr) | 2016-12-28 | 2018-07-04 | The Procter & Gamble Company | Article en dose unitaire soluble dans l'eau comprenant une polyamine zwitterionique |
| EP3342849A1 (fr) | 2016-12-28 | 2018-07-04 | The Procter & Gamble Company | Article en dose unitaire soluble dans l'eau comprenant un polyéthylènéimine ethoxylaté |
| EP3668960B1 (fr) * | 2017-08-18 | 2021-08-11 | The Procter & Gamble Company | Procédé de traitement de tissus |
| WO2019038186A1 (fr) * | 2017-08-24 | 2019-02-28 | Unilever Plc | Perfectionnements se rapportant au nettoyage de tissus |
| WO2019038187A1 (fr) * | 2017-08-24 | 2019-02-28 | Unilever Plc | Perfectionnements se rapportant au nettoyage de tissus |
| EP3814467A1 (fr) | 2018-06-26 | 2021-05-05 | The Procter & Gamble Company | Composition de détergent textile liquide |
| JP7144911B2 (ja) | 2018-06-28 | 2022-09-30 | ザ プロクター アンド ギャンブル カンパニー | ポリマー系を含む布地処理組成物及び関連方法 |
| CN112703246A (zh) * | 2018-09-17 | 2021-04-23 | 联合利华知识产权控股有限公司 | 洗涤剂组合物 |
| WO2020229535A1 (fr) * | 2019-05-16 | 2020-11-19 | Unilever Plc | Composition de blanchisserie |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4125370A (en) | 1976-06-24 | 1978-11-14 | The Procter & Gamble Company | Laundry method imparting soil release properties to laundered fabrics |
| WO1993018124A1 (fr) | 1992-03-10 | 1993-09-16 | The Procter & Gamble Company | Compositions de detergents granulaires |
| WO1998015608A2 (fr) | 1996-10-07 | 1998-04-16 | The Procter & Gamble Company | Polyamines quaternisees alkoxyles utilisees comme ingredients dans des compositions detergentes |
| WO2006072083A1 (fr) | 2004-12-27 | 2006-07-06 | The Dial Corporation | Detergent a lessive liquide contenant des agents de traitement du linge |
| WO2009153184A1 (fr) | 2008-06-16 | 2009-12-23 | Unilever Plc | Perfectionnements relatifs au nettoyage de tissus |
| DE102008032206A1 (de) | 2008-07-09 | 2010-01-14 | Henkel Ag & Co. Kgaa | Parfümiertes Wäscheweichspülmittel |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2182306A (en) | 1935-05-10 | 1939-12-05 | Ig Farbenindustrie Ag | Polymerization of ethylene imines |
| US2208095A (en) | 1937-01-05 | 1940-07-16 | Ig Farbenindustrie Ag | Process of producing insoluble condensation products containing sulphur and nitrogen |
| US2553696A (en) | 1944-01-12 | 1951-05-22 | Union Carbide & Carbon Corp | Method for making water-soluble polymers of lower alkylene imines |
| US2806839A (en) | 1953-02-24 | 1957-09-17 | Arnold Hoffman & Co Inc | Preparation of polyimines from 2-oxazolidone |
| BE615597A (fr) | 1958-06-19 | |||
| CH1824769D (fr) | 1968-12-09 | |||
| GB1296839A (fr) | 1969-05-29 | 1972-11-22 | ||
| GB1372034A (en) | 1970-12-31 | 1974-10-30 | Unilever Ltd | Detergent compositions |
| CA989557A (en) | 1971-10-28 | 1976-05-25 | The Procter And Gamble Company | Compositions and process for imparting renewable soil release finish to polyester-containing fabrics |
| US3959230A (en) | 1974-06-25 | 1976-05-25 | The Procter & Gamble Company | Polyethylene oxide terephthalate polymers |
| CA1049367A (fr) | 1974-06-25 | 1979-02-27 | The Procter And Gamble Company | Detergents liquides capables de deloger les saletes |
| US4116885A (en) | 1977-09-23 | 1978-09-26 | The Procter & Gamble Company | Anionic surfactant-containing detergent compositions having soil-release properties |
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| SE459972B (sv) | 1983-03-29 | 1989-08-28 | Colgate Palmolive Co | Smutsavvisande partikelformig tvaettmedelskomposition innehaallande en smutsavvisande polymer, foerfarande foer dess framstaellning och dess anvaendning vid tvaettning av syntetiska organiska polymera fibermaterial |
| NZ207692A (en) | 1983-04-04 | 1986-04-11 | Colgate Palmolive Co | Soil-release promoting liquid detergent containing terephthalate polymers |
| US4702857A (en) | 1984-12-21 | 1987-10-27 | The Procter & Gamble Company | Block polyesters and like compounds useful as soil release agents in detergent compositions |
| EP0199403B1 (fr) | 1985-04-15 | 1993-12-15 | The Procter & Gamble Company | Compositions détergentes liquides stables |
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-
2011
- 2011-04-04 ES ES11160937T patent/ES2421162T3/es active Active
- 2011-04-04 EP EP11160937.6A patent/EP2476743B1/fr not_active Revoked
-
2012
- 2012-03-05 EP EP12707100.9A patent/EP2694635B1/fr not_active Revoked
- 2012-03-05 WO PCT/EP2012/053709 patent/WO2012136427A1/fr active Application Filing
- 2012-03-05 PL PL12707100T patent/PL2694635T3/pl unknown
- 2012-03-05 BR BR112013025674-5A patent/BR112013025674B1/pt active IP Right Grant
- 2012-03-05 MX MX2013011464A patent/MX2013011464A/es active IP Right Grant
- 2012-03-05 CN CN201280016945.1A patent/CN103459577B/zh active Active
- 2012-03-05 MY MYPI2013701844A patent/MY161793A/en unknown
- 2012-03-05 AU AU2012238950A patent/AU2012238950B2/en not_active Ceased
- 2012-03-30 AR ARP120101100A patent/AR085771A1/es not_active Application Discontinuation
-
2013
- 2013-08-27 ZA ZA2013/06447A patent/ZA201306447B/en unknown
- 2013-09-30 CL CL2013002817A patent/CL2013002817A1/es unknown
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Also Published As
| Publication number | Publication date |
|---|---|
| AU2012238950A1 (en) | 2013-09-19 |
| AU2012238950B2 (en) | 2014-11-20 |
| AR085771A1 (es) | 2013-10-23 |
| BR112013025674B1 (pt) | 2021-02-02 |
| EP2476743B1 (fr) | 2013-04-24 |
| ZA201306447B (en) | 2014-10-29 |
| MX2013011464A (es) | 2013-10-17 |
| ES2421162T3 (es) | 2013-08-29 |
| PL2694635T3 (pl) | 2016-05-31 |
| CN103459577B (zh) | 2015-05-27 |
| MY161793A (en) | 2017-05-15 |
| CL2013002817A1 (es) | 2014-08-22 |
| WO2012136427A1 (fr) | 2012-10-11 |
| EP2476743A1 (fr) | 2012-07-18 |
| EP2694635A1 (fr) | 2014-02-12 |
| CN103459577A (zh) | 2013-12-18 |
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