EP1077081A3 - Catalyseur à base de Cu, Zn et Al; sa préparation et son utilisation dans le réformage du méthanol - Google Patents
Catalyseur à base de Cu, Zn et Al; sa préparation et son utilisation dans le réformage du méthanol Download PDFInfo
- Publication number
- EP1077081A3 EP1077081A3 EP00115058A EP00115058A EP1077081A3 EP 1077081 A3 EP1077081 A3 EP 1077081A3 EP 00115058 A EP00115058 A EP 00115058A EP 00115058 A EP00115058 A EP 00115058A EP 1077081 A3 EP1077081 A3 EP 1077081A3
- Authority
- EP
- European Patent Office
- Prior art keywords
- catalyst
- manufacturing
- methanol
- reforming methanol
- present
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/323—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents
- C01B3/326—Catalytic reaction of gaseous or liquid organic compounds other than hydrocarbons with gasifying agents characterised by the catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/10—Catalysts for performing the hydrogen forming reactions
- C01B2203/1041—Composition of the catalyst
- C01B2203/1076—Copper or zinc-based catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11227588A JP2001046872A (ja) | 1999-08-11 | 1999-08-11 | メタノール改質触媒、メタノール改質触媒の製造方法及びメタノール改質方法 |
JP22758899 | 1999-08-11 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP1077081A2 EP1077081A2 (fr) | 2001-02-21 |
EP1077081A3 true EP1077081A3 (fr) | 2002-03-20 |
Family
ID=16863281
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP00115058A Ceased EP1077081A3 (fr) | 1999-08-11 | 2000-07-26 | Catalyseur à base de Cu, Zn et Al; sa préparation et son utilisation dans le réformage du méthanol |
Country Status (4)
Country | Link |
---|---|
US (1) | US6576217B1 (fr) |
EP (1) | EP1077081A3 (fr) |
JP (1) | JP2001046872A (fr) |
CA (1) | CA2315495C (fr) |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6290877B2 (en) * | 1999-11-30 | 2001-09-18 | Honda Giken Kogyo Kabushiki Kaisha | Method of starting and stopping methanol reforming apparatus and apparatus for supplying fuel to said apparatus |
JP2001185191A (ja) * | 1999-12-28 | 2001-07-06 | Mitsubishi Gas Chem Co Inc | 燃料電池用水素の製造方法 |
JP2001185192A (ja) * | 1999-12-28 | 2001-07-06 | Mitsubishi Gas Chem Co Inc | 燃料電池用水素の製造方法 |
JP3496051B2 (ja) * | 2000-06-07 | 2004-02-09 | 独立行政法人産業技術総合研究所 | メタノールの酸化的水蒸気改質反応による水素ガス製造触媒及びその製造法 |
DE10111197A1 (de) * | 2001-03-08 | 2002-09-19 | Basf Ag | Verfahren zur Herstellung von Katalysatoren mit geringem Volumenschwund |
DE10111198A1 (de) * | 2001-03-08 | 2002-09-19 | Basf Ag | Methanolreformierungskatalysator mit verringertem Volumenschwund |
US6713040B2 (en) * | 2001-03-23 | 2004-03-30 | Argonne National Laboratory | Method for generating hydrogen for fuel cells |
US6967063B2 (en) * | 2001-05-18 | 2005-11-22 | The University Of Chicago | Autothermal hydrodesulfurizing reforming method and catalyst |
DE10160487A1 (de) * | 2001-12-08 | 2003-06-12 | Sued Chemie Ag | Katalysator für die Methanolsynthese und andere Reaktionen |
US7470648B2 (en) | 2002-02-13 | 2008-12-30 | Battelle Memorial Institute | Reforming catalysts |
US6693057B1 (en) * | 2002-03-22 | 2004-02-17 | Sud-Chemie Inc. | Water gas shift catalyst |
US6627572B1 (en) * | 2002-03-22 | 2003-09-30 | Sud-Chemie Inc. | Water gas shift catalyst |
US20030223926A1 (en) | 2002-04-14 | 2003-12-04 | Edlund David J. | Steam reforming fuel processor, burner assembly, and methods of operating the same |
JP3951127B2 (ja) * | 2003-02-28 | 2007-08-01 | 国立大学法人静岡大学 | ジメチルエーテル水蒸気改質触媒およびその製造方法 |
WO2004083116A1 (fr) * | 2003-03-17 | 2004-09-30 | MAX-PLANCK-Gesellschaft zur Förderung der Wissenschaften e.V. | Catalyseur contenant du cu-cuo/zr02 utilise dans le reformage a la vapeur de methanol |
US7208136B2 (en) | 2003-05-16 | 2007-04-24 | Battelle Memorial Institute | Alcohol steam reforming catalysts and methods of alcohol steam reforming |
CN100466348C (zh) * | 2004-06-22 | 2009-03-04 | 旭硝子株式会社 | 液状组合物、其制造方法及固体高分子型燃料电池用膜电极接合体的制造方法 |
US7749376B2 (en) * | 2005-08-15 | 2010-07-06 | Sud-Chemie Inc. | Process for sulfur adsorption using copper-containing catalyst |
US7569511B2 (en) * | 2006-05-05 | 2009-08-04 | Basf Catalysts Llc | Catalyst composition for alcohol steam reforming |
US7964114B2 (en) * | 2007-12-17 | 2011-06-21 | Sud-Chemie Inc. | Iron-based water gas shift catalyst |
TWI381992B (zh) * | 2008-09-26 | 2013-01-11 | Nat Univ Tsing Hua | 反應器室溫啟動的低溫氫氣製程 |
US8529864B2 (en) | 2008-09-26 | 2013-09-10 | National Tsing Hua University | Process for hydrogen production |
US9174199B2 (en) | 2009-05-26 | 2015-11-03 | Basf Corporation | Methanol steam reforming catalysts |
JP5628016B2 (ja) * | 2010-12-08 | 2014-11-19 | 三井化学株式会社 | 銅触媒の製造方法および銅触媒前駆体の熟成方法 |
CN102259002B (zh) * | 2011-06-13 | 2013-05-08 | 中国石油化工股份有限公司 | 一种提高合成甲醇催化剂性能的母体制备方法 |
KR101273320B1 (ko) * | 2011-06-15 | 2013-06-11 | 성신여자대학교 산학협력단 | 란타늄이 도핑된 CuO-ZnO-Al2O3 복합 산화물의 제조방법 및 그 방법에 의해 제조된 란타늄이 도핑된 CuO-ZnO-Al2O3 복합 산화물 |
GB201111781D0 (en) * | 2011-07-08 | 2011-08-24 | Isis Innovation | Stream reforming of methanol |
WO2013015889A1 (fr) * | 2011-07-27 | 2013-01-31 | Saudi Arabian Oil Company | Compositions catalytiques utiles pour l'élimination de composés soufrés présents dans des hydrocarbures gazeux, leurs procédés d'obtention et leurs utilisation |
US8906227B2 (en) | 2012-02-02 | 2014-12-09 | Suadi Arabian Oil Company | Mild hydrodesulfurization integrating gas phase catalytic oxidation to produce fuels having an ultra-low level of organosulfur compounds |
US8920635B2 (en) | 2013-01-14 | 2014-12-30 | Saudi Arabian Oil Company | Targeted desulfurization process and apparatus integrating gas phase oxidative desulfurization and hydrodesulfurization to produce diesel fuel having an ultra-low level of organosulfur compounds |
DE102014004391A1 (de) * | 2014-03-26 | 2015-10-15 | Clariant International Ltd. | Verfahren zur Herstellung von Katalysatoren mit erhöhter Festigkeit und verringertem Volumenschwund |
CN104741132A (zh) * | 2015-02-12 | 2015-07-01 | 上海摩醇动力技术有限公司 | 化成箔作为载体制备贵金属催化剂的工艺 |
CN104689822A (zh) * | 2015-02-12 | 2015-06-10 | 上海摩醇动力技术有限公司 | 用于甲醇水蒸气重整制氢球形铜基催化剂的制备工艺 |
CN104645998A (zh) * | 2015-02-12 | 2015-05-27 | 上海摩醇动力技术有限公司 | 一种铜基催化剂的制备方法 |
CN104689823A (zh) * | 2015-02-12 | 2015-06-10 | 上海摩醇动力技术有限公司 | 化成箔作为载体制备铜基催化剂的工艺 |
CN104645995A (zh) * | 2015-02-12 | 2015-05-27 | 上海摩醇动力技术有限公司 | 铜基催化剂的制备工艺 |
CN110272021B (zh) * | 2018-03-13 | 2021-04-13 | 国家能源投资集团有限责任公司 | 甲醇催化剂保护剂及其制备方法 |
CN108786823B (zh) * | 2018-04-25 | 2021-02-05 | 广西民族师范学院 | 一种条形甲醇重整制氢催化剂的制备及应用 |
CN110404547A (zh) * | 2019-08-06 | 2019-11-05 | 北京蓝玖新能源科技有限公司 | 一种催化剂及其制备方法和应用 |
CN110694624B (zh) * | 2019-10-10 | 2022-07-19 | 天津大学 | 一种基于Cu和MgO的双功能催化剂及制备方法和应用 |
US20230398520A1 (en) | 2022-06-09 | 2023-12-14 | Clariant International Ltd | High temperature methanol steam reforming catalyst |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4552861A (en) * | 1984-03-02 | 1985-11-12 | Institut Francais Du Petrole | Process for manufacturing catalysts containing copper, zinc, aluminum and at least one metal from the group formed of rare earths and zirconium and the resultant catalysts for reactions involving a synthesis gas |
JPS61234942A (ja) * | 1985-04-08 | 1986-10-20 | Mitsubishi Heavy Ind Ltd | 水素富化ガス製造用触媒 |
JPH0352643A (ja) * | 1989-07-20 | 1991-03-06 | Mitsubishi Heavy Ind Ltd | メタノール水蒸気改質用触媒の調製方法 |
US5112591A (en) * | 1989-04-24 | 1992-05-12 | Institut Francais Du Petrole | Process for preparing precursors of catalysts containing copper, aluminum and zinc, usable for the synthesis and the decomposition of methanol |
DE4423587A1 (de) * | 1994-07-06 | 1996-01-11 | Daimler Benz Ag | Verfahren und Vorrichtung zur Wasserstoffgewinnung mittels partieller Oxidation und/oder Wasserdampfreformierung von Methanol |
JPH10216522A (ja) * | 1997-01-30 | 1998-08-18 | Kansai Electric Power Co Inc:The | メタノール合成用の触媒 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2315495A (en) | 1939-07-27 | 1943-04-06 | Beeg Hermann | Process of purifying phosphoric acid esters |
JPS58193738A (ja) * | 1982-05-06 | 1983-11-11 | Mitsubishi Heavy Ind Ltd | 水素富化ガス製造用触媒 |
DE3362621D1 (en) | 1982-11-22 | 1986-04-24 | Shell Int Research | Catalyst preparation |
JPS60106534A (ja) | 1983-11-14 | 1985-06-12 | Mitsubishi Gas Chem Co Inc | メタノ−ル合成用流動触媒 |
FR2558738B1 (fr) * | 1984-01-27 | 1987-11-13 | Inst Francais Du Petrole | Procede de fabrication de catalyseurs contenant du cuivre, du zinc et de l'aluminium, utilisables pour la production de methanol a partir de gaz de synthese |
US4590176A (en) * | 1984-06-05 | 1986-05-20 | Shell Oil Company | Catalyst for dimethyl ether synthesis and a process for its preparation |
JPS617328A (ja) | 1984-06-22 | 1986-01-14 | Ube Ind Ltd | 感光性ポリアミド |
JPS61127601A (ja) * | 1984-11-27 | 1986-06-14 | Mitsubishi Heavy Ind Ltd | メタノ−ル改質方法 |
CA2026275C (fr) | 1989-10-17 | 2000-12-05 | Deepak S. Thakur | Catalyseur d'hydrogenation, methode de preparation et methode d'utilisation connexes |
DE4127318A1 (de) * | 1991-08-17 | 1993-02-18 | Hoechst Ag | Kupfer-zinkoxid-aluminiumoxid enthaltende katalysatoren |
US5248566A (en) * | 1991-11-25 | 1993-09-28 | The United States Of America As Represented By The United States Department Of Energy | Fuel cell system for transportation applications |
DE69513792T2 (de) | 1995-01-11 | 2000-04-27 | United Catalysts Inc | Aktivierter und stabilisierter Kupferoxid- und Zinkoxidkatalysator und Verfahren zu seiner Herstellung |
JPH08299796A (ja) | 1995-05-11 | 1996-11-19 | Mitsubishi Gas Chem Co Inc | メタノール合成触媒の製造法 |
JP3510405B2 (ja) * | 1995-11-22 | 2004-03-29 | 三菱重工業株式会社 | メタノール合成触媒 |
DE19546612A1 (de) * | 1995-12-13 | 1997-06-19 | Basf Ag | Verfahren zur Reduktion von NOx aus Abgasen |
JP3943648B2 (ja) * | 1997-04-11 | 2007-07-11 | 関西電力株式会社 | メタノール合成方法 |
-
1999
- 1999-08-11 JP JP11227588A patent/JP2001046872A/ja not_active Withdrawn
-
2000
- 2000-07-18 US US09/619,139 patent/US6576217B1/en not_active Expired - Fee Related
- 2000-07-26 EP EP00115058A patent/EP1077081A3/fr not_active Ceased
- 2000-08-09 CA CA002315495A patent/CA2315495C/fr not_active Expired - Fee Related
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4552861A (en) * | 1984-03-02 | 1985-11-12 | Institut Francais Du Petrole | Process for manufacturing catalysts containing copper, zinc, aluminum and at least one metal from the group formed of rare earths and zirconium and the resultant catalysts for reactions involving a synthesis gas |
JPS61234942A (ja) * | 1985-04-08 | 1986-10-20 | Mitsubishi Heavy Ind Ltd | 水素富化ガス製造用触媒 |
US5112591A (en) * | 1989-04-24 | 1992-05-12 | Institut Francais Du Petrole | Process for preparing precursors of catalysts containing copper, aluminum and zinc, usable for the synthesis and the decomposition of methanol |
JPH0352643A (ja) * | 1989-07-20 | 1991-03-06 | Mitsubishi Heavy Ind Ltd | メタノール水蒸気改質用触媒の調製方法 |
DE4423587A1 (de) * | 1994-07-06 | 1996-01-11 | Daimler Benz Ag | Verfahren und Vorrichtung zur Wasserstoffgewinnung mittels partieller Oxidation und/oder Wasserdampfreformierung von Methanol |
JPH10216522A (ja) * | 1997-01-30 | 1998-08-18 | Kansai Electric Power Co Inc:The | メタノール合成用の触媒 |
Non-Patent Citations (5)
Title |
---|
DATABASE WPI Section Ch Week 198648, Derwent World Patents Index; Class E36, AN 1986-316077, XP002187196 * |
DATABASE WPI Section Ch Week 199116, Derwent World Patents Index; Class E36, AN 1991-112530, XP002187195 * |
EDWARDS N ET AL: "On-board hydrogen generation for transport applications: the HotSpot@? methanol processor", JOURNAL OF POWER SOURCES, ELSEVIER SEQUOIA S.A. LAUSANNE, CH, vol. 71, no. 1-2, 15 March 1998 (1998-03-15), pages 123 - 128, XP004112432, ISSN: 0378-7753 * |
PATENT ABSTRACTS OF JAPAN vol. 1998, no. 13 30 November 1998 (1998-11-30) * |
S. VELU, K. SUZUKI, T. OSAKI: "Oxidative steam reforming of methanol over CuZnAl(Zr)-oxide catalysts", CHEM. COMMUN., 1999, pages 2341 - 2342, XP002187194 * |
Also Published As
Publication number | Publication date |
---|---|
CA2315495C (fr) | 2005-10-25 |
CA2315495A1 (fr) | 2001-02-11 |
EP1077081A2 (fr) | 2001-02-21 |
US6576217B1 (en) | 2003-06-10 |
JP2001046872A (ja) | 2001-02-20 |
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