EP1073353B1 - Borste, verfahren zu ihrer herstellung und gerät mit einer solchen borste - Google Patents
Borste, verfahren zu ihrer herstellung und gerät mit einer solchen borste Download PDFInfo
- Publication number
- EP1073353B1 EP1073353B1 EP99923408A EP99923408A EP1073353B1 EP 1073353 B1 EP1073353 B1 EP 1073353B1 EP 99923408 A EP99923408 A EP 99923408A EP 99923408 A EP99923408 A EP 99923408A EP 1073353 B1 EP1073353 B1 EP 1073353B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- bristle
- core
- rubber
- elastic layer
- profiled
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000004033 plastic Substances 0.000 claims abstract description 33
- 229920003023 plastic Polymers 0.000 claims abstract description 33
- 239000000463 material Substances 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 16
- 239000004698 Polyethylene Substances 0.000 claims description 7
- -1 polyethylene Polymers 0.000 claims description 6
- 239000004743 Polypropylene Substances 0.000 claims description 5
- 238000005452 bending Methods 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 4
- 238000000576 coating method Methods 0.000 claims description 4
- 229920002725 thermoplastic elastomer Polymers 0.000 claims description 4
- 239000004952 Polyamide Substances 0.000 claims description 3
- 229920002647 polyamide Polymers 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 2
- 229920001155 polypropylene Polymers 0.000 claims description 2
- 238000007598 dipping method Methods 0.000 claims 2
- 238000005507 spraying Methods 0.000 claims 2
- 229920001971 elastomer Polymers 0.000 abstract description 15
- 238000004049 embossing Methods 0.000 abstract description 15
- 239000005060 rubber Substances 0.000 abstract description 14
- 230000000694 effects Effects 0.000 description 8
- 239000000835 fiber Substances 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000009499 grossing Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 241000870659 Crassula perfoliata var. minor Species 0.000 description 1
- 241000628997 Flos Species 0.000 description 1
- 208000000260 Warts Diseases 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- 229930194909 coatline Natural products 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003000 extruded plastic Substances 0.000 description 1
- 229920002457 flexible plastic Polymers 0.000 description 1
- 238000007373 indentation Methods 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 201000010153 skin papilloma Diseases 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
Images
Classifications
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
- A46D1/02—Bristles details
- A46D1/023—Bristles with at least a core and at least a partial sheath
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
- A46D1/02—Bristles details
- A46D1/0238—Bristles with non-round cross-section
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
- A46D1/02—Bristles details
- A46D1/0246—Hollow bristles
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46D—MANUFACTURE OF BRUSHES
- A46D1/00—Bristles; Selection of materials for bristles
- A46D1/02—Bristles details
- A46D1/0261—Roughness structure on the bristle surface
-
- A—HUMAN NECESSITIES
- A46—BRUSHWARE
- A46B—BRUSHES
- A46B2200/00—Brushes characterized by their functions, uses or applications
- A46B2200/10—For human or animal care
- A46B2200/1066—Toothbrush for cleaning the teeth or dentures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2922—Nonlinear [e.g., crimped, coiled, etc.]
- Y10T428/2924—Composite
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2929—Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
- Y10T428/2931—Fibers or filaments nonconcentric [e.g., side-by-side or eccentric, etc.]
Definitions
- the invention relates to a bristle consisting of a Core made of a comparatively hard, flexurally elastic Plastic and at least one profiled layer a rubber-elastic plastic. Furthermore, the Invention a method for producing such bristles and devices equipped with such bristles.
- bristles Regardless of the particular use of a brush some basic requirements are placed on bristles. These include in particular the bending elasticity, kink resistance and wear resistance. More and often very different requirements result from the use the brush. For example, brushes for oral and personal care should be soft enough to Avoid injuries while being abrasive technical brushes have hard and rough bristles should. Other technical brushes, such as car wash brushes, on the other hand, in turn, must be smooth and smooth. This also applies to polishing brushes. Brushes or paint brushes used for Applying media to serve must be relatively closely related Have bristles for storing the medium while in other applications, stand-alone bristles or Bristle bundles are desired.
- bristles on the surface of the to be treated or the object to be processed depends significantly of their own surface quality and of that Bristle material.
- bristles are made extruded plastic monofilaments.
- the plastic can be essentially only the Bending and wear resistance, but only in very little Scope the surface quality and effectiveness affect the surface once one of simple Longitudinal profiles. It therefore has the status of There is no lack of technology in trials, the surface quality or the effectiveness of the surface of To change bristles by additional measures to the to better meet the respective purpose.
- Bristles are also known (DE 195 33 815 A1) consist of a core and ribs arranged on it, obtained a spiral profile by twisting becomes.
- Another known bristle (US 5,137,039 A1) consists of a comparatively hard core and a softer coat that profiles along coat lines, i.e. is provided with longitudinal ribs. This document says nothing about how the bristle and the profiling getting produced. It also slides between the ribs absorbed medium quickly in the longitudinal direction of the bristle out.
- the invention is based on this prior art the task of creating a bristle that while maintaining the necessary strength properties with a soft surface nevertheless a good cleaning effect and media receptivity.
- the invention is based on the surprising finding that a rubber-elastic plastic, e.g. a thermoplastic Elastomer, even with a very thin thickness with bristles and toothbrushes is in the range of a few tenths of a millimeter Embossing can be profiled without a provision of the rubber-elastic plastic is to be determined, whereby the relatively hard core plays a significant role, against which the embossing forces are applied. Leave it fine to rough structures in any Realize design. You choose shallow tread depths especially for bristles for mouth and body care, larger profile depths, however, with cleaning brushes or Order brushes to get dirt in the first case, in the second Case record order media.
- a rubber-elastic plastic e.g. a thermoplastic Elastomer
- the rubber-elastic layer can be core-shaped or only partially surrounded and can by Embossed profile along the entire length the bristle or only provided on part of the same his.
- the core of the bristle is resistant to bending and kinking determining plastic and the rubber-elastic layer with their profiling from a surface effect the bristle on the object and determining the wear resistance Plastic.
- the core consists of a Plastic with a Shore hardness D> 45 and the rubber elastic Layer of a plastic with a Shore hardness D ⁇ 35th
- the Shore hardness of the plastic for the core at D> 65 and the the rubber-elastic layer at 20 ⁇ D ⁇ 35 are, for example for the core PE (polyethylene), PP (polypropylene) or PA (polyamide) and for the rubber elastic Layer of thermoplastic elastomers.
- the profiling of the rubber-elastic layer can distributed, locally delimited depressions be educated. Instead, the profiling also in the direction of extension of the bristle, for example run along surface lines or helically. Finally, the profiling can also be predominantly transverse be oriented to the direction of extension of the bristle.
- the profiled rubber-elastic layer itself Profile conforming, film-like layer of a soft Plastic applied. This can affect the profile a certain smoothing effect can be achieved without taking away the surface effect from the profiling.
- the core can be formed from one or more monofilaments his.
- the first version is recommended for Tooth and body brushes, the latter version at technical brushes, especially for car wash brushes.
- the bristles have to be limp be on the one hand the contour of the to be cleaned Optimally lay out area, on the other hand the surface easy to clean. These bristles wear out a lot quickly from the free end.
- This means according to the invention trained bristle that the rubber elastic Layer is removed first at the bristle ends. at the inventive training with several core monofilaments these are exposed in the form of fibers, which then compared to a single core monofilament of larger diameter still ensure gentle treatment.
- Bristles usually have a circular cross section.
- any other bristle cross-section can be realized, by the core being different from the circular shape Cross-section, e.g. a narrow rectangular or cross-shaped or star-shaped cross-section.
- the rubber elastic Layer can then nonetheless be circular Have cross-section so that they are different Has thickness and in the thicker areas for example can be shaped more deeply. Instead, it can also a cross section following the cross section of the core have so that regardless of the location of the embossing equal depth profiles can be generated, whereby also here the core again acts as an abutment.
- the entire bristle can be made of core and more elastic Layer transverse to the direction of extension of the Bristle be wavy.
- the core is formed by a surface structure that acts as an adhesion promoter preserved at the core.
- the invention proposes a method in which the core and the rubber-elastic layer coextruded as a strand and the rubber-elastic layer while running Is profiled by embossing against the core.
- an endless bristle material becomes obtained from which the bristles immediately after embossing can be cut to length on request. Instead, can the bristle material can also be spooled and only on the occasion the brush manufacture the bristle from the unwound The strand can be cut to length as required.
- the strand can be coextruded, the strand wound and the rubber-elastic layer when unwinding the strand Embossing is profiled against the core.
- This procedure can emboss at the manufacturer of the bristle material or only at the brush manufacturer.
- This Procedure can also be recommended if the rubber elastic Layer of a slowly cross-linking elastomer exists and the embossing process only after the completion of Crosslinking reaction should be carried out.
- the rubber-elastic layer preferably by means of one another and against the core effective stamping tools profiled, the stamping tools can create different profiles. It can only one-sided profiling can be provided, then the embossing tool with an unprofiled Counter tool works together.
- a soft plastic film-like by extrusion, Dip, spray or shrink-wrap a film be applied, for example, to the profile smooth.
- the Core and the rubber-elastic layer coextruded as a strand then cut the bristle from the strand and then the rubber-elastic layer by embossing profiled against the core. With this procedure the film-like layer before or after cutting to length Dip, spray or shrink-applied a film become.
- the bristle designed according to the invention is for devices of various types can be used.
- Such bristle can be used directly as an interdental cleaner can be used, either in the form of a Sticks or similar to a floss.
- a brush with a plurality of Bristles designed according to the invention, wherein the bristles can be provided in separate arrangements can.
- a brush can have bristles differently profiled, rubber-elastic layers exhibit.
- a core 2 made of a flexible and kink-resistant plastic, e.g. PA, PP or PE, and a shell 2 surrounding the core rubber-elastic layer 3, for example from a thermoplastic elastomer.
- a profile 4 in the form of locally delimited, indentations 5 distributed on the circumference. The embossing takes place against the hard core 2.
- bristle 1 is the bristle 1 only over part of its length with that shown in Fig. 1 Profile coined while remaining along the length 6, for example the attachment-side end of the Includes bristle, is not profiled. Otherwise there is they in turn consist of a core 2 made of a hard plastic, the rubber-elastic layer 3 with the embossed Wells and one covering the profiling film-like layer 7, which conforms to the profiling, but with a certain smoothing effect brings. 3 there is Bristle, in turn, consists of a core 2 and a region only applied rubber elastic layer 3. This namely runs on the core 2 in the form of longitudinal ribs, which are profiled by cross-stamping, so that depressions 8 and wart-like elevations 9 arise.
- the core has a circular cross section
- Fig. 5 is a bristle
- the core 2 a cross-shaped Cross section 10
- the rubber elastic Layer 3 has a circular cross-section. So it is in the area of the ends of the bars of the cross section 10 thinnest. This makes sharp abutments formed against which the profile - as with the arrows 11 indicated - can be shaped particularly well.
- the bristle has 1 in turn a core 2 with a circular cross-section.
- the him enveloping rubber-elastic layer 3 is with a wave profile 12 coined.
- FIG. 7 shows an embodiment modified compared to FIG. 1, by the core 2 consisting of four monofilaments 13, that can be in parallel or twisted.
- the rubber-elastic layer 3 in turn surrounds the core 2 a circular cross section and points to it Coat the embossed profile.
- the core 2 an elongated cross section.
- the rubber elastic Layer 3 is provided with a constant thickness, so that it follows the cross section of the core 2 and a band-shaped bristle is obtained, for example, only similar on its narrow sides with an embossed profile 4 which is provided in Fig. 3.
- the bristle 14 is in accordance with the previously described bristles Fig. 9 corrugated transversely to the longitudinal extent.
Landscapes
- Brushes (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
- Pens And Brushes (AREA)
- Laminated Bodies (AREA)
- Cosmetics (AREA)
- Artificial Filaments (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19818345A DE19818345A1 (de) | 1998-04-24 | 1998-04-24 | Borste, Verfahren zu ihrer Herstellung und Gerät mit einer solchen Borste |
| DE19818345 | 1998-04-24 | ||
| PCT/EP1999/002403 WO1999055195A1 (de) | 1998-04-24 | 1999-04-09 | Borste, verfahren zu ihrer herstellung und gerät mit einer solchen borste |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP1073353A1 EP1073353A1 (de) | 2001-02-07 |
| EP1073353B1 true EP1073353B1 (de) | 2002-06-12 |
Family
ID=7865672
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP99923408A Expired - Lifetime EP1073353B1 (de) | 1998-04-24 | 1999-04-09 | Borste, verfahren zu ihrer herstellung und gerät mit einer solchen borste |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6391445B1 (enExample) |
| EP (1) | EP1073353B1 (enExample) |
| JP (1) | JP4311878B2 (enExample) |
| KR (1) | KR100602584B1 (enExample) |
| CN (1) | CN1115121C (enExample) |
| AR (1) | AR015016A1 (enExample) |
| AU (1) | AU746808B2 (enExample) |
| BR (1) | BR9909857A (enExample) |
| CA (1) | CA2328770A1 (enExample) |
| DE (2) | DE19818345A1 (enExample) |
| EG (1) | EG22279A (enExample) |
| ES (1) | ES2178438T3 (enExample) |
| PL (1) | PL193087B1 (enExample) |
| RU (1) | RU2205581C2 (enExample) |
| WO (1) | WO1999055195A1 (enExample) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6440557B1 (en) | 1999-07-08 | 2002-08-27 | E. I. Du Pont De Nemours & Co. | Brush filaments |
| DE19932368A1 (de) * | 1999-07-13 | 2001-02-08 | Pedex & Co Gmbh | Verfahren zur Herstellung von mehrschichtigem Borstenmaterial, mehrschichtige Borste und deren Verwendung |
| DE19932376A1 (de) | 1999-07-13 | 2001-01-18 | Coronet Werke Gmbh | Borste für Zahnbürsten und Zahnbürste mit solchen Borsten |
| US6553604B1 (en) | 2000-03-16 | 2003-04-29 | Gillette Canada Company | Toothbrush |
| DE10017167A1 (de) * | 2000-04-07 | 2001-10-11 | Pedex & Co Gmbh | Verfahren und Vorrichtung zur Herstellung von Filamenten aus Kunststoff, insbesondere Kunststoffborsten, und danach hergestellte Borste |
| DE10017306A1 (de) | 2000-04-09 | 2001-10-11 | Pedex & Co Gmbh | Verfahren zur Herstellung von Borsten zum Applizieren von Medien |
| DE10033256A1 (de) * | 2000-07-10 | 2002-01-24 | Coronet Werke Gmbh | Verfahren und Vorrichtung zur Herstellung von Borstenwaren sowie Borstenware |
| DE10046536A1 (de) * | 2000-09-19 | 2002-03-28 | Coronet Werke Gmbh | Verfahren zur Herstellung von Borstenwaren |
| DE10115556A1 (de) | 2001-03-28 | 2002-10-02 | Pedex & Co Gmbh | Thermoplastisches Monofilament für Borsten |
| US20040177462A1 (en) * | 2003-03-14 | 2004-09-16 | The Gillette Company | Toothbrush head |
| US20060272112A9 (en) | 2003-03-14 | 2006-12-07 | The Gillette Company | Toothbrush |
| AU2008200510B2 (en) * | 2003-03-14 | 2011-06-30 | The Gillette Company Llc | Toothbrush head |
| US7941886B2 (en) * | 2003-09-19 | 2011-05-17 | Braun Gmbh | Toothbrushes |
| US20050130540A1 (en) * | 2003-12-15 | 2005-06-16 | Nordson Corporation | Multicomponent spunbond filaments having a melt-processable superabsorbent polymer core |
| DE102005027982B4 (de) * | 2005-06-16 | 2007-09-06 | Braun Gmbh | Interdentalbürste und Interdentalreiniger |
| DE102006011070B4 (de) * | 2006-03-08 | 2019-08-29 | Georg Menshen Gmbh & Co. Kg | Vorrichtung zum Auftragen eines Haarmittels |
| DE102006027756A1 (de) * | 2006-06-16 | 2007-12-20 | Braun Gmbh | Zahnbürste sowie Zahnbürstenkopf und Zahnputzborste hierfür |
| US20090240284A1 (en) * | 2008-03-24 | 2009-09-24 | David Scott Randol | Stabilization rods |
| EP2225966A1 (en) | 2009-03-04 | 2010-09-08 | Braun GmbH | Toothbrush bristle and method for manufacturing such a bristle |
| US8602776B2 (en) | 2009-11-05 | 2013-12-10 | Wilkie J. Stadeker | Devices and methods for improved interdental cleaning and therapy |
| JP2015518771A (ja) * | 2012-06-05 | 2015-07-06 | エルジー・ハウスホールド・アンド・ヘルスケア・エルティーディー | 二重構造のチップを有する歯ブラシの毛およびそれを含む歯ブラシ |
| DE102012018467B4 (de) * | 2012-09-19 | 2017-08-03 | Rusi Cosmetic Gmbh & Co. Kg | Verfahren zur Herstellung eines Applikators für kosmetische Produkte und ein Applikator |
| DE102012018466A1 (de) * | 2012-09-19 | 2014-03-20 | Rusi Cosmetic Gmbh & Co. Kg | Verfahren zur Herstellung eines Applikators für kosmetische Produkte |
| KR101427039B1 (ko) | 2013-03-14 | 2014-08-05 | 이정희 | 모노필라멘트(칫솔모) 표면 미세돌기 성형 사각금형형 장치 |
| CN103806114A (zh) * | 2014-03-06 | 2014-05-21 | 安徽环美刷业有限公司 | 扫雪车专用刷丝及其生产设备和生产方法 |
| US9986820B2 (en) * | 2014-06-11 | 2018-06-05 | The Procter & Gamble Company | Filament having unique tip and surface characteristics |
| WO2016016440A1 (de) | 2014-07-31 | 2016-02-04 | Geka Gmbh | Drahtkernapplikator mit mehrmaterialborsten |
| FR3028153B1 (fr) * | 2014-11-06 | 2018-05-04 | L'oreal | Applicateur cosmetique comportant des fibres. |
| CN107835649B (zh) | 2015-07-07 | 2021-03-23 | 高露洁-棕榄公司 | 口腔护理器具和用于口腔护理器具的单丝刷毛 |
| CN106073145A (zh) * | 2016-06-27 | 2016-11-09 | 徐涵 | 一种新型牙刷刷丝及其制备工艺 |
| CN106235604B (zh) * | 2016-08-31 | 2018-03-23 | 王文康 | 一种牙刷及其制造工艺 |
| DE202018001075U1 (de) | 2018-02-19 | 2018-03-28 | Semen Zaitchik | Bürste, insbesondere Zahnbürste deren Putzelemente die fraktalen Charakteristiken aufweisen |
| DE202018101427U1 (de) * | 2018-03-14 | 2019-06-17 | Geka Gmbh | Applikator mit rundum verripptem, borstenbildendem Filament |
| CN110403347A (zh) * | 2019-06-27 | 2019-11-05 | 安徽省忆德工业刷制造有限公司 | 一种耐磨的环卫刷刷丝及其生产方法 |
| US12161219B2 (en) | 2021-02-03 | 2024-12-10 | Judson Smith | Cleaning bristle brushes and cleaning systems using same |
| DE102023106400A1 (de) * | 2023-03-14 | 2024-09-19 | Jan Heinz | Verfahren und Vorrichtung zum abrasiven Bodenabtrag im Tiefbau mittels rotierender Kunststofflamellen |
| DE102024100671A1 (de) * | 2024-01-10 | 2025-07-10 | Perlon Gmbh | Kunststoff-Filament und Verfahren zu seiner Herstellung |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE32963C (de) | sächsische Webstuhlfabrik (Louis Schönherr) in Chemnitz. Vom ly. März 1885 ab. — S, 2739 | Schützenwechsel-Einrichtung für mehr als vierzellige Kasten | ||
| DE1073434B (de) | 1960-01-21 | Roman Dietsche K.G., Aftersteg (Schwarzw.) | Kunstborste | |
| DE322089C (de) | 1919-02-01 | 1920-06-19 | Wilhelm Bentz | Zahnreinigungsmittel in Buerstenform |
| US2110371A (en) | 1935-05-08 | 1938-03-08 | Hat Corp | Product and process for the manufacture thereof |
| US2317485A (en) | 1940-04-27 | 1943-04-27 | Pepsodent Co | Brush |
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| DE1014964B (de) | 1952-02-12 | 1957-09-05 | Johann Christian Gerster | Kuenstliche Borste und deren Herstellungsverfahren |
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| GB992346A (en) * | 1961-08-11 | 1965-05-19 | Osborn Mfg Co | Process and apparatus for coating wire and the like |
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| US3689118A (en) * | 1971-01-06 | 1972-09-05 | Sherwin Williams Co | Method of brush bristle manufacture |
| US4263691A (en) | 1979-03-07 | 1981-04-28 | Seree Pakarnseree | Brush |
| US4373541A (en) | 1979-08-07 | 1983-02-15 | Nishioka Gary J | Bristle structure for brushes and brush assembly |
| DE3116189A1 (de) | 1981-04-23 | 1982-12-23 | Bodo 2000 Hamburg Jesse | Profilierte borsten fuer zahnbuersten und buersten aller art |
| DE8300846U1 (de) | 1983-01-14 | 1985-01-31 | Pedex & Co. GmbH, 6948 Wald-Michelbach | Kunststoffborste |
| DE3400941A1 (de) * | 1983-01-14 | 1984-10-11 | Coronet - Werke Heinrich Schlerf Gmbh, 6948 Wald-Michelbach | Kunststoffborste |
| FR2546097A1 (fr) | 1983-02-22 | 1984-11-23 | Freselle Christian | Fibre diamantee |
| JPS6021966A (ja) | 1983-07-12 | 1985-02-04 | カネボウ株式会社 | 研摩用纎維の製造方法 |
| US5137039A (en) * | 1991-03-04 | 1992-08-11 | Focus Development Corporation, Inc. | Tooth cleaning device |
| DE3717475A1 (de) | 1987-05-23 | 1988-12-08 | Schlerf Coronet Werke | Borstenware und verfahren zu ihrer herstellung |
| DE8809217U1 (de) | 1988-07-19 | 1988-09-01 | Georg Karl geka-brush GmbH, 8809 Bechhofen | Reinigungsgerät für Zahnzwischenräume |
| ES2072863T3 (es) * | 1988-09-30 | 1995-08-01 | Newell Operating Co | Mejoras en cepillos y cerdas sinteticas. |
| TW307801B (enExample) | 1992-03-19 | 1997-06-11 | Minnesota Mining & Mfg | |
| TW222668B (enExample) * | 1992-03-19 | 1994-04-21 | Minnesota Mining & Mfg | |
| US5678275A (en) | 1995-06-30 | 1997-10-21 | Derfner; Nitza | Toothbrush with bristles having intermediate roughened portion |
| DE19533815A1 (de) * | 1995-09-13 | 1997-03-20 | Coronet Werke Gmbh | Zahnbürste und Verfahren zu ihrer Herstellung |
| US6058541A (en) * | 1996-07-03 | 2000-05-09 | Gillette Canada Inc. | Crimped bristle toothbrush |
| US6296934B1 (en) * | 1999-03-12 | 2001-10-02 | E.I. Du Pont De Nemours And Company | Glitter containing filaments for use in brushes |
-
1998
- 1998-04-24 DE DE19818345A patent/DE19818345A1/de not_active Withdrawn
-
1999
- 1999-04-09 WO PCT/EP1999/002403 patent/WO1999055195A1/de not_active Ceased
- 1999-04-09 PL PL343632A patent/PL193087B1/pl not_active IP Right Cessation
- 1999-04-09 KR KR1020007011846A patent/KR100602584B1/ko not_active Expired - Fee Related
- 1999-04-09 US US09/673,355 patent/US6391445B1/en not_active Expired - Lifetime
- 1999-04-09 ES ES99923408T patent/ES2178438T3/es not_active Expired - Lifetime
- 1999-04-09 CA CA002328770A patent/CA2328770A1/en not_active Abandoned
- 1999-04-09 DE DE59901741T patent/DE59901741D1/de not_active Expired - Lifetime
- 1999-04-09 RU RU2000129509/12A patent/RU2205581C2/ru not_active IP Right Cessation
- 1999-04-09 AU AU40302/99A patent/AU746808B2/en not_active Ceased
- 1999-04-09 EP EP99923408A patent/EP1073353B1/de not_active Expired - Lifetime
- 1999-04-09 CN CN99805416A patent/CN1115121C/zh not_active Expired - Lifetime
- 1999-04-09 JP JP2000545407A patent/JP4311878B2/ja not_active Expired - Fee Related
- 1999-04-09 BR BR9909857-1A patent/BR9909857A/pt not_active IP Right Cessation
- 1999-04-22 EG EG45399A patent/EG22279A/xx active
- 1999-04-23 AR ARP990101890A patent/AR015016A1/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| CA2328770A1 (en) | 1999-11-04 |
| ES2178438T3 (es) | 2002-12-16 |
| JP4311878B2 (ja) | 2009-08-12 |
| EG22279A (en) | 2002-12-31 |
| CN1115121C (zh) | 2003-07-23 |
| PL343632A1 (en) | 2001-08-27 |
| KR20010043001A (ko) | 2001-05-25 |
| JP2002512824A (ja) | 2002-05-08 |
| AU746808B2 (en) | 2002-05-02 |
| BR9909857A (pt) | 2000-12-19 |
| WO1999055195A1 (de) | 1999-11-04 |
| DE19818345A1 (de) | 1999-10-28 |
| RU2205581C2 (ru) | 2003-06-10 |
| DE59901741D1 (de) | 2002-07-18 |
| KR100602584B1 (ko) | 2006-07-19 |
| CN1298284A (zh) | 2001-06-06 |
| EP1073353A1 (de) | 2001-02-07 |
| AR015016A1 (es) | 2001-04-11 |
| AU4030299A (en) | 1999-11-16 |
| US6391445B1 (en) | 2002-05-21 |
| PL193087B1 (pl) | 2007-01-31 |
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