EP0893119B1 - UV-protection formulation - Google Patents

UV-protection formulation Download PDF

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Publication number
EP0893119B1
EP0893119B1 EP98810688A EP98810688A EP0893119B1 EP 0893119 B1 EP0893119 B1 EP 0893119B1 EP 98810688 A EP98810688 A EP 98810688A EP 98810688 A EP98810688 A EP 98810688A EP 0893119 B1 EP0893119 B1 EP 0893119B1
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EP
European Patent Office
Prior art keywords
sun protection
protection agent
oil
absorber
agent according
Prior art date
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Expired - Lifetime
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EP98810688A
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German (de)
English (en)
French (fr)
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EP0893119A1 (en
Inventor
Helmut Luther
Albert Stehlin
Bernd Herzog
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BASF Schweiz AG
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Ciba SC Holding AG
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/29—Titanium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0241—Containing particulates characterized by their shape and/or structure
    • A61K8/0279—Porous; Hollow
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/42—Amides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4946—Imidazoles or their condensed derivatives, e.g. benzimidazoles
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/496—Triazoles or their condensed derivatives, e.g. benzotriazoles
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/494—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with more than one nitrogen as the only hetero atom
    • A61K8/4966—Triazines or their condensed derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8147—Homopolymers or copolymers of acids; Metal or ammonium salts thereof, e.g. crotonic acid, (meth)acrylic acid; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/412—Microsized, i.e. having sizes between 0.1 and 100 microns
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/60—Particulates further characterized by their structure or composition
    • A61K2800/65—Characterized by the composition of the particulate/core
    • A61K2800/652—The particulate/core comprising organic material
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/60—Particulates further characterized by their structure or composition
    • A61K2800/65—Characterized by the composition of the particulate/core
    • A61K2800/654—The particulate/core comprising macromolecular material

Definitions

  • the present invention relates to new UV-protection formulations which comprise a combination of a micronised UV absorber and both of i) an oil-soluble, non-micronised UV absorber and/or an inorganic micropigment and ii) a polymeric hollow sphere additive and/or a polymer selected from xanthan and/or polyvinylpyrrolidone.
  • the new combinations exhibit an unexpected synergistic sun protection effect. This synergistic effect is greatly enhanced when the micronised UV absorber and the oil-soluble, non-micronised UV absorber and/or an inorganic micropigment are used in combination with a polymeric hollow sphere additive and/or a polymer selected from xanthan and/or polyvinylpyrrolidone.
  • sunscreen formulations which include a material which is intended to counteract UV radiation, thereby inhibiting the said undesired effects on the skin.
  • UV protectants in sunscreen formulations, especially soluble organic UV absorbers and insoluble micronised inorganic compounds, in particular zinc oxide and titanium dioxide.
  • sunscreen formulations of soluble organic UV absorbers With respect to the use in sunscreen formulations of soluble organic UV absorbers, they have the disadvantages that their effectiveness as UV protectants in terms of SPF (Sun Protection Factor) in a sunscreen formulation is often too low for commercial purposes; as a result of their solubility, they exhibit relatively high allergenic potential; and that as a result of intrinsic photochemical lability, the duration of the protective effect is often too low.
  • SPF Sun Protection Factor
  • insoluble inorganic compounds such as titanium dioxide leads to a reduced stability of formulations containing them.
  • inorganic compounds have been claimed to generate toxic radicals under the influence of light and water ("Redox Mechanisms in Heterogeneous Photocatalysis", Serpone et al, Electrochemistry in Colloids and Dispersions, Editors Mackay and Texter, VCH Publishers Inc., NewYork 1992).
  • micronised, insoluble organic UV absorbers as well as a sunscreen composition
  • a method of producing micronised, insoluble organic UV absorbers, as well as a sunscreen composition comprising a) 0.1 to 15%, preferably 0.5 to 10% by weight, based on the total composition of a micronised formulation of an insoluble organic UV absorber, produced according to the said method; and optionally b) a cosmetically acceptable carrier.
  • Micronised, insoluble organic UV absorbers so obtained, when used in sunscreen formulations, provide excellent UV protection and have at least as high an SPF rating as corresponding sunscreen formulations containing a known inorganic UV absorber. Unlike the latter UV absorbers, micronised, insoluble organic UV absorbers show no tendency, under the influence of light, to generate radicals which could damage or sensitise human skin.
  • the present invention provides, as a first aspect, a sun protection agent, which is especially suitable for use in pharmaceutical or cosmetic applications, comprising
  • the relative proportions of components a):b) and/or c) preferably range from 20:80 to 80:20, especially from 40:60 to 60:40, by weight.
  • the micronised organic UV absorber, component a) is preferably produced by the method described in GB-A-2303549, namely by a process which comprises grinding an organic UV absorber, in coarse particle form, in a grinding apparatus, in the presence of 1 to 50%, preferably 5 to 40% by weight, based on the micronised organic UV absorber, of an alkyl polyglucoside having the formula C n H 2n+1 O(C 6 H 10 O 5 ) x H, in which n is an integer ranging from 8 to 16 and x is the mean polymerisation level of the glucoside moiety (C 6 H 10 O 5 ) and ranges from 1.4 to 1.6, or an ester thereof.
  • the grinding apparatus used to produce the micronised organic UV absorber may be, e.g., a jet, ball, vibration or hammer mill, preferably a high speed stirring mill or impact mill, especially a rotating ball mill, vibrating mill, tube mill or rod mill.
  • the alkyl polyglucoside may consist of a C 1 -C 12 ester of the compound of formula C n H 2n+1 O(C 6 H 10 O 5 ) x H, namely an ester formed by reacting a C 1 -C 12 acid, such formic, acetic, propionic, butyric, sulfosuccinic, citric or tartaric acid, with one or more free OH groups on the glucoside moiety (C 6 H 10 O 5 ).
  • a C 1 -C 12 acid such formic, acetic, propionic, butyric, sulfosuccinic, citric or tartaric acid
  • the micronised organic UV absorber may be, e.g., a triazine, a benzotriazole, a vinyl group-containing amide, a cinnamic acid amide or a sulfonated benzimidazole UV absorber.
  • Preferred compounds of formula (1) are those having one of the formulae as well as 2,4,6-tris(diisobutyl-4'-aminobenzalmalonate)-s-triazine and 2,4-bis(diisobutyl-4-aminobenzalmalonate)-6-(4'-aminobenzylidenecamphor)-s-triazine.
  • Particularly preferred compounds of formula (1) are those having the formula in which the individual radicals R 5 are the same or different and each is hydrogen; an alkali metal; an ammonium group N(R 6 ) 4 in which R 6 is hydrogen or an organic radical; C 1 -C 3 alkyl; or a polyoxyethylene radical which contains from 1 to 10 ethylene oxide units and the terminal OH group of which may be etherified by a C 1 -C 3 alcohol.
  • R 5 when R 5 is an alkali metal it is preferably potassium or, especially sodium; when R 5 is a group N(R 6 ) 4 in which R 6 has its previous significance, it is preferably a mono-, di- or tri-C 1 -C 4 alkylammonium salt, a mono-, di- or tri-C 2 -C 4 alkanolammonium salt or a C 1 -C 3 alkyl ester thereof; when R 6 is a C 1 -C 3 alkyl group, it is preferably a C 1 -C 2 alkyl group, more preferably a methyl group; and when R 6 is polyoxyethylene group, this preferably contains from 2-6 ethylene oxide units.
  • T 1 is C 1 -C 3 alkyl or, preferably, hydrogen
  • T 2 is C 1 -C 4 alkyl, preferably t-butyl, or C 1 -C 4 alkyl substituted by phenyl, preferably ⁇ , ⁇ -dimethylbenzyl.
  • a further preferred class of triazole micronised organic UV absorbers is that having the formula in which T 2 is hydrogen; or C 1 -C 12 alkyl, preferably iso-octyl.
  • a still further preferred class of triazole micronised organic UV absorbers is that having the formula in which T 2 is C 1 -C 12 alkyl, preferably iso-octyl.
  • Preferred compounds of formula (28) are 4-methyl-3-penten-2-one, ethyl-3-methylamino-2-butenoate, 3-methylamino-1-phenyl-2-buten-1-one and 3-methylamino-1-phenyl-2-buten-1-one.
  • a preferred class of cinnamic acid amide micronised organic UV absorbers is that having the formula in which R 12 is hydroxy or C 1 -C 4 alkoxy, preferably methoxy or ethoxy; R 13 is hydrogen or C 1 -C 4 alkyl, preferably methyl or ethyl; and R 14 is -(CONH) m -phenyl in which m has its previous significance and the phenyl group is optionally substituted by one, two or three substituents selected from OH, C 1 -C 3 alkyl, C 1 -C 3 alkoxy or CO-OR 4 in which R 4 has its previous significance.
  • R 14 is phenyl, 4-methoxyphenyl or the phenylaminocarbonyl group.
  • a preferred class of sulfonated benzimidazole micronised organic UV absorbers is that having the formula in which M is hydrogen or an alkali metal, preferably sodium, an alkaline earth metal, such as magnesium or calcium, or zinc.
  • C 1 -C 12 alkyl groups may be methyl, ethyl, n-propyl or isopropyl, butyl, pentyl, amyl, isoamyl, hexyl, heptyl, octyl, iso-octyl, nonyl, decyl, undecyl oder dodecyl, methyl being preferred; and C 1 -C 3 alkoxy groups include methoxy, ethoxy, propoxy and isopropoxy, methoxy and ethoxy being preferred.
  • C 2 -C 4 carboxyalkyl includes carboxymethyl, carboxyethyl, carboxypropyl and carboxyisopropyl, carboxymethyl being preferred.
  • C 5 -C 8 cycloalkyl includes cyclopentyl, cyclohexyl and cyclooctyl.
  • the micronised organic UV absorber, component a) of the new sun protection agent has a mean particle size in the range of from 0.01 to 2, more preferably from 0.02 to 1.5, especially from 0.05 to 1.0 ⁇ .
  • the oil-soluble organic UV absorber, the component b) of the sun protection agent of the present invention may be any known oil-soluble organic UV absorber, especially those which are already approved and marketed for cosmetic use.
  • oil-soluble organic UV absorbers are described, for instance, in “Sunscreens", Development, Evaluation and Regulatory Aspects, Eds.:N.J.Lowe and N.A.Shaath, M.Dekker Inc., New York and Basel, 1990; and Ken Klein, Encyclopedia of UV absorbers for sunscreen products, Cosmetics & Toiletries 107 45-64 (1992).
  • the oil-soluble, non-micronised UV absorber may be, for example, a p-aminobenzoic acid derivative such as an ester, salt or an amine-modified derivative of p-aminobenzoic acid; a salicylic acid derivative such as an ester or salt thereof; a benzophenone derivative; a dibenzoylmethane derivative; a diphenylacrylate derivative; a benzofuran derivative; a polymeric UV absorber containing one or more silico-organic residues; a cinnamate ester; a camphor derivative; a trianilino-s-triazine derivative; phenylbenzimidazole sulfonic acid and its salts; urocanic acid (3-imidazol-4-yl-acrylic acid) or its ethyl ester; menthyl anthranilate; a benzotriazole; a hydroxyphenyltriazine derivative; or a bis-
  • a p-aminobenzoic acid derivative examples include 4-aminobenzoic acid (PABA), ethyl dihydroxypropyl PABA having the formula
  • PEG-25 PABA having the formula in which m, n and x are the same and each is approximately 25, octyl dimethyl PABA having the formula: and glyceryl aminobenzoate having the formula
  • a salicylic acid derivative examples include homosalate (homomenthyl salicylate) having the formula triethanolamine salicylate having the formula amyl p-dimethylamino benzoate having the formula octyl salicylate having the formula 4-isopropylbenzylsalicylate having the formula
  • benzophenone derivatives include benzophenone-3-(2-hydroxy-4-methoxybenzophenone), benzophenone-4 (2-hydroxy-4-methoxybenzophenone-5-sulfonic acid) and benzophenone-8-(2,2'-dihydroxy-4-methoxybenzophenone).
  • a specific example of a dibenzoylmethane derivative is butyl methoxydibenzoylmethane [1-(4-tert.-butyl)-3-(4-methoxyphenyl)propane-1,3-dione].
  • diphenylacrylate derivative examples include octocrylene (2-ethylhexyl-2-cyano-3,3'-diphenyl acrylate) and etocrylene (ethyl-2-cyano-3,3'-diphenyl acrylate).
  • benzofuran derivative examples include the 3-(benzofuranyl)-2-cyanoacrylates described in US 5338539 or EP 582189, especially the compounds having the formula or the 2-(2-benzofuranyl)-5-tert.-butylbenzoxazoles described in US 5518713 and the 2-(p-aminophenyl)benzofurans described in US 5362481.
  • a polymeric UV absorber containing one or more silico-organic residues are the benzylidenemalonate silicone derivatives disclosed in EP 709080, in particular the compound having the formula: in which R 15 is H or OMe and r is approximately 7; and the polymers of the benzotriazole silicone type described in WO 94/06404, in particular the compound having the formula:
  • a cinnamate ester examples include octyl methoxy cinnamate (4-methoxycinnamic acid 2-ethylhexyl ester), diethanolamine methoxy cinnamate (diethanolamine salt of 4-methoxycinnamic acid), isoamyl p-methoxycinnamate (4-methoxycinnamic acid 2-isoamyl ester), 2,5-diisopropyl methyl cinnamate, the cinnamido derivatives disclosed in US 5601811 and the derivatives described in WO 97/00851.
  • camphor derivatives are 4-methyl-benzylidene camphor [3-(4'-methyl)benzylidene-bornan-2-one], 3-benzylidene camphor (3-benzylidene-boman-2-one), polyacrylamidomethyl benzylidene camphor ⁇ N-[2(and 4)-2-oxybom-3-yliden-methyl)benzyl]acrylamide polymer ⁇ , trimonium benzylidene camphor sulfate [3-(4'-trimethylammonium)-benzylidene-bornan-2-one methyl sulfate], terephthalydene dicamphor sulfonic acid ⁇ 3,3'-(1,4-phenylenedimethine)-bis-(7,7-dimethyl-2-oxo-bicyclo-[2.2.1]heptan-1-methanesulfonic acid ⁇ and salts thereof and benzylidene camphor sulfonic acid [3-
  • trianilino-s-triazine derivatives include octyl triazine [2,4,6-trianilino-(p-carbo-2'-ethyl-1'-oxy)-1,3,5-triazine, the trianilino-s-triazine derivatives disclosed in US 5332568, the trianilino-s-triazine derivatives described in EP 517104, trianilino-s-triazine derivatives disclosed in EP 570838, the trianilino-s-triazine derivatives described in US 5252323, the trianilino-s-triazine derivatives described in WO 93/17002-A1 and the trianilino-s-triazine derivatives disclosed in WO 97/03642-A1.
  • a specific example of a benzotriazole is 2-(2-hydroxy-5-methyl-phenyl)benzotriazole.
  • hydroxyphenyltriazine derivatives include, e.g. those described EP-A1-775,698, such as 2,4-bis- ⁇ [4-(2-ethyl-hexyloxy)-2-hydroxy]-phenyl ⁇ -6-(4-methoxyphenyl)-1,3,5-triazine.
  • bis-resorcinol-dialkylaminotriazines are, e.g., those described in EP-A1-780,382.
  • the inorganic micropigment UV absorber, the component b) of the new sun protection agent may be, for example, titanium dioxide coated with aluminium oxide or silicon dioxide, zinc oxide coated with aluminium oxide or silicon dioxide, or mica.
  • the polymeric hollow sphere component, component c) of the new sun protection agent according to the present invention may be, for instance, those described in EP-A-761,201.
  • the polymeric hollow sphere component is preferably a commercially available styrene/acrylic acid copolymer hollow sphere material.
  • the styrene/acrylic acid copolymer is supplied as an aqueous dispersion comprising styrene/acrylic acid copolymer beads having a particle size below 1 micron.
  • the said aqueous dispersion preferably has a solids content within the range of from 20 to 50%, more preferably from 25 to 45%, by weight; a voids volume of 15 to 60%, more preferably from 20 to 55%; a mean particle size of 0.1 to 5 microns, more preferably 0.1 to 1.5 microns; and a wall thickness of 0.01 to 1 micron, more preferably from 0.02 to 0.5 micron.
  • the polymeric hollow sphere component may, of course, be derived from any suitable monomer and need not be limited to styrene/acrylic acid copolymer hollow sphere material.
  • Suitable hollow sphere material are for example acrylonitrile copolymers, like copolymers of acrylonitrile with acrylic acid, methacrylic acid, styrene or vinylidene chloride.
  • Preferred polymeric hollow sphere components are those which are substantially insoluble in cosmetic formulation components for sunscreens, since unduly high solubility therein can lead to an undesired decrease in the UV-protection performance of the resulting sunscreen formulation.
  • the present invention also provides a sunscreen composition
  • a sunscreen composition comprising A) 0.1 to 15%, preferably 0.5 to 10% by weight, based on the total composition of a sun screen agent according to the present invention; and B) a cosmetically acceptable carrier.
  • the sunscreen composition of the present invention may be produced by physically blending the sun screen agent according to the present invention and a cosmetically acceptable carrier by any conventional method, e.g. by simply stirring the two materials together.
  • the sunscreen composition of the invention may be formulated as a water-in oil or an oil-in-water dispersion, an oil or oil-alcohol lotion, a vesicular dispersion of an ionic or nonionic amphiphilic lipid, a gel, a solid stick or an aerosol formulation.
  • the cosmetically acceptable carrier When formulated as a water-in oil or an oil-in-water dispersion, the cosmetically acceptable carrier preferably comprises 5 to 50% of an oil phase, 5 to 20% of an emulsifier and 30 to 90% of water, each by weight based on the total weight of the carrier.
  • the oil phase may comprise any oil conventionally used in cosmetic formulations, especially an emollient e.g., one or more of a fatty alcohol; hydrocarbon oil; a natural or synthetic triglyceride; a wax including esters of long-chain acids and alcohols as well as compounds having wax-like properties; a silicone oil; a fatty acid ester or a fatty alcohol; and lanoline-containing products.
  • an emollient e.g., one or more of a fatty alcohol; hydrocarbon oil; a natural or synthetic triglyceride; a wax including esters of long-chain acids and alcohols as well as compounds having wax-like properties; a silicone oil; a fatty acid ester or a fatty alcohol; and lanoline-containing products.
  • fatty alcohols include cetyl alcohol, stearyl alcohol, octyldodecanol, cetearyl alcohol and oleyl alcohol;
  • hydrocarbon oils are, e.g., mineral oil (light or heavy), petrolatum (yellow or white), polyethylene, paraffin, squalane, microcrystalline wax, ceresin, polybutene and hydrogenated polyisobutene;
  • examples of a natural or synthetic triglyceride include castor oil, caprylic/capric triglyceride, Japan wax, hydrogenated vegetable oil, sweet almond oil, wheat germ oil, sesame oil, hydrogenated cottonseed oil, coconut oil, wheat germ glycerides, avocado oil, corn oil, trilaurin, hydrogenated castor oil, shea butter, cocoa butter, soybean oil, mink oil, sunflower oil, safflower oil, macadamia nut oil, olive oil, hydrogenated tallow, apricot kernel oil, hazelnut oil and borage oil; examples of
  • examples of a fatty acid ester or a fatty alcohol include isopropyl myristate, isopropyl palmitate, octyl palmitate, isopropyl lanolate, acetylated lanolin alcohol, the benzoate of C 12 -C 15 alcohols, cetearyl octanoate, cetyl palmitate, myristyl myristate, myristyl lactate, cetyl acetate, propylene glycol dicaprylate/caprate, decyl oleate, acetylated lanolin, stearyl heptanoate, diisostearyl malate, octyl hydroxystearate, octyl hydroxystearate and isopropyl isostearate; and examples of lanoline-containing products include lanolin, lanolin oil, isopropyl lanolate, acetyl
  • the emulsifier may comprise any emulsifier conventionally used in cosmetic formulations, e.g., one or more of an ethoxylated ester of a natural oil derivative such as a polyethoxylated ester of hydrogenated castor oil; a silicone oil emulsifier such as a silicone polyol; an optionally ethoxylated fatty acid soap; an ethoxylated fatty alcohol; an optionally ethoxylated sorbitan ester; an ethoxylated fatty add; or an ethoxylated glyceride.
  • an ethoxylated ester of a natural oil derivative such as a polyethoxylated ester of hydrogenated castor oil
  • silicone oil emulsifier such as a silicone polyol
  • an optionally ethoxylated fatty acid soap an ethoxylated fatty alcohol
  • an optionally ethoxylated sorbitan ester an ethoxylated fatty add
  • the sunscreen composition of the invention may also comprise further components which are known to perform a useful function in a sunscreen composition.
  • further components include, e.g., emollients, skin moisturisers, skin tanning accelerators, antioxidants, emulsion stabilisers, thickening agents such as xanthan, moisture-retention agents such as glycerine, film formers, preservatives, perfumes and colourants.
  • the sunscreen composition of the invention provides excellent protection of the human against the damaging effects of sunlight, while permitting safe tanning of the skin. Moreover, the sunscreen composition of the invention has a skin waterproofing effect.
  • aqueous dispersions of styrene/acrylic acid copolymer hollow spheres used in the following test methods have the following physical characteristics: Polymer solids content (%) voids volume (%) mean particle size (microns) wall thickness (microns) Ropaque HP-91 (I*) 27.5 50 1.0 0.1 Ropaque OP-84-2M (II*) 40.0 22 0.5 0.1 Ropaque OP-90 E (III*) 37.5 33 0.4 0.06
  • oil-in-water cream A) oil phase composition: Tegin P 1.0% Thickly viscous paraffin oil 5.0% Stearic acid 1.5% Lanette O 0.4% Propyl paraben 0.1% Oil-soluble UVA (Parsol MCX) x%.
  • Parsol MCX is octyl methoxycinnamate.
  • Compound of formula (101) is 2,2'-methylene-bis-[6-(2H-benzotriazole-2-yl)-4-(1,1,3,3-tetramethylbutyl)-phenol]:
  • the individual test formulations are produced as follows.
  • the oil-soluble UVA (Parsol MCX) is dissolved in a specified amount (see following Table) in the oil phase.
  • the aqueous micronised UVA (compound of formula (101)), optionally together with the polymer, is incorporated into the aqueous phase.
  • the two phases are separately heated to 75°C. and then the oil phase is slowly stirred into the water phase and the whole mixture is stirred cold.
  • the individual test formulations so obtained are then evaluated, in vitro, for their SPF performance using an SPF-290 analyser (Fa. Optometrics).
  • SPF-290 analyser Fe. Optometrics
  • Four brush strokes of each test formulation are applied, in a layer thickness of 2 ⁇ l/cm 2 on to Transpore film (3M) and 9 SPF measurements are conducted from each applied brush stroke.
  • the SPF values obtained are shown in the following Table 1, together with the mean values and standard deviations, for each of the individual 36 measurements.
  • the percentage amounts of of polymer shown in the Table 1 are based on the weight of active substance.
  • Oil Phase 1 propylene glycol stearate 1.0% mineral oil 5.0% stearic acid 1.5% cetearyl alcohol 0.4% propylparaben 0.1% test oil-soluble UV absorber 2.7% Aqueous Phase 2 triethanolamine 0.8% glycerine (85%) 4.0% carbomer 0.1% methylparaben 0.1% water to 100%.
  • Inorganic micropigment (micro-TiO 2 , silicon-coated) is incorporated (6.0% by weight based on the solids content of the total formulation) into the oil phase.
  • Micronised test organic UV absorber is incorporated (6.0% by weight based on the solids content of the total formulation), as a suspension, into the aqueous phase.
  • Phases 1 and 2 are separately heated to 75°C. With continuous stirring, the oil phase is added to the aqueous phase and, while homogenising, the mixture is cooled to 30°C.
  • Example Test oil-soluble UVA (% by weight) Test micronised UVA (% by weight) SPF in vitro - 2.7% UVA I - 4.2 - - 6.0% by weight UVA II 7.7 - - 6.0% by weight silicon-coated TiO 2 4.8 14 2.7% UVA I 6.0% by weight UVA II 14.2 15 2.7% UVA I 6.0% by weight silicon-coated TiO 2 7.9
  • UVA I is 2-ethylhexyl-p-methoxycinnamate and UVA II is a 25% aqueous dispersion of [2-(2-hydroxy-4-methoxyphenyl)-4,6-diphenyl-1,3,5-triazine] having a mean particle size of 0.55 micron.
  • UVA III is a 50% aqueous dispersion of [2,2'-methylene-bis-6(2H-benzotriazole-2-yl)-4-(1,1,3,3-teramethylbutyl)-phenol] having a mean particle size of 0.25 micron.
  • UVA IV is 4-methyl-benzylidene camphor.
  • a pre-dispersion A is produced consisting of a 50% aqueous dispersion of micronised UVA III.
  • pre-dispersion B1 There are then added to pre-dispersion A, 2% of xanthan gum and 0.4% propylene glycol, to produce pre-dispersion B1. There are then added to pre-dispersion B1, 2.0% of polyvinylpyrrolidone (MW 8000) to produce pre-dispersion B2.
  • the pre-dispersions A, B1 and B2 are then incorporated into separate samples of the same simple oil-in-water formulation and the final formulations are used for in vitro SPF determinations employing an SPF-analyser 290 (Optometrics). The evaluations are conducted using the method of Diffey & Robson (J.Soc.Cosmet. 40 127-133, 1989).
  • phase 1 cetearyl alcohol Phase 1 cetearyl alcohol
  • PEG-40 Castor oil
  • sodium cetearyl sulfate mixt 3.15% decyl oleat 15.0% test oil-soluble UVA IV or V 4.0% propylparaben 0.1%
  • Phase 2 50% aqueous dispersion of micronised UVA III 6 or 12% methylparaben 0.3% disodium EDTA 0.1% water 50.75 or 45.75%
  • Phase 3 carbomer Carbopol 934P
  • sodium hydroxide 45%
  • Phase 1 is heated to 75-80°C.
  • Phase 2 is heated to 80°C. while applying thorough homogenisation.
  • Phase 1 is then added to phase 2, while applying continuous stirring.
  • Phase 3 is then added to the mixture of phases 1 and 2, while applying continuous stirring, and then re-homogenised for 3 minutes. After replenishing water loss, the whole mixture is homogenised until it is cool.
  • test formulations so obtained are then evaluated, in vitro, for their SPF performance using an SPF-290 analyser (Fa. Optometrics).
  • SPF-290 analyser Fe. Optometrics
  • Four brush strokes of each test formulation are applied, in a layer thickness of 2 ⁇ l/cm 2 on to Transpore film (3M) and 9 SPF measurements are conducted from each applied brush stroke.
  • the SPF values obtained are shown in the following Table 7, together with the mean values and standard deviations, for each of the individual 36 measurements.
  • UVA V is octyl-methoxycinnamate
  • UVA VI is 3-(4-methylbenzidene)-boman-2-one
  • UVA VII is 2,4,6-trianilino-p-(carbo-2'-ethylhexyl-1'-oxy)-1,3,5-triazine.
  • Oil Phase isostearyl isostearate 4.0% caprylic/capric triglyceride 4.0% liquid paraffin 3.3% stearyl alcohol 1.4% cetyl alcohol 1.4% titanium dioxide (Eusolex T-2000) 4.0% dimethicone 1.0% propylparaben 0.1%
  • the two phases are separately heated to 65°C. and then the oil phase is stirred into the aqueous phase and the whole mixture is stirred cold.
  • the pH of the emulsion so obtained is adjusted to 6.5 to 7.0 and then the emulsion is evaluated, in vitro, to determine its SPF performance, using an SPF-290 analyser (Fa. Optometrics).
  • the SPF value obtained is 21. When the experiment is repeated, but omitting the compound (26) from the aqueous phase, the SPF value is only 9.

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Cited By (6)

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Publication number Priority date Publication date Assignee Title
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Families Citing this family (331)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19842786A1 (de) * 1998-09-18 2000-03-23 Beiersdorf Ag Emulgatorfreie feindisperse Systeme vom Typ Öl-in-Wasser und Wasser-in-Öl
DE19842787A1 (de) * 1998-09-18 2000-03-23 Beiersdorf Ag Emulgatorfreie feindisperse Systeme vom Typ Öl-in-Wasser und Wasser-in-Öl
EP1004290B1 (de) * 1998-11-02 2011-02-02 Basf Se Kosmetische oder pharmazeutische Zubereitungen enthaltend 1,3,5-Triazinderivate und Zinkoxid
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DE19900094B4 (de) * 1999-01-04 2005-12-15 Stada Arzneimittel Ag Verfahren zur Herstellung von Lichtschutzzubereitungen, umfassend organische UV-Filter in fester, feinverteilter Form
FR2789578A1 (fr) * 1999-02-12 2000-08-18 Oreal Compositions photoprotectrices contenant un derive de benzotriazole et un compose a groupements benzoazolyle ou benzodiazolyle
WO2000068369A1 (en) * 1999-05-06 2000-11-16 Biospherics Incorporated Method for preventing or minimizing biodegradation of a substance
FR2794645B1 (fr) * 1999-06-08 2001-08-10 Oreal Compositions photoprotectrices contenant un compose hydrocarbone bis-hydroxyphenylbenzotriazole et un compose a groupements benzoazolyle ou benzodiazolyle
AU778175B2 (en) * 1999-06-18 2004-11-18 Ciba Specialty Chemicals Holding Inc. Micropigment mixture
FR2795638B1 (fr) * 1999-07-02 2003-05-09 Oreal Compositions cosmetiques photoprotectrices et utilisations
EP1068866A3 (de) * 1999-07-12 2004-03-17 Ciba SC Holding AG Verwendung von Mischungen aus Mikropigmenten zur Bräunungsverhinderung und Aufhellung der Haut und Haare
FR2799966B1 (fr) * 1999-10-22 2002-07-26 Oreal Procede de photostabilisation de filtres solaires derives du dibenzoylmethane par un filtre organique insoluble
EP1127567B1 (de) * 2000-02-17 2010-09-01 Basf Se Wässrige Dispersion wasserunlöslicher organischer UV-Filtersubstanzen
DE10012408A1 (de) * 2000-03-15 2001-09-20 Basf Ag Verwendung von Lichtschutzmittelkombinationen, die als wesentlichen Bestandteil aminosubstituierte Hydroxybenzophenone enthalten als photostabile UV-Filter in kosmetischen und pharmazeutischen Zubereitungen
DE10017214A1 (de) * 2000-04-06 2001-10-11 Beiersdorf Ag Kosmetische und dermatologische Lichtschutzformulierungen mit einem Gehalt an unsymmetrisch substituierten Triazinderivaten und Propylenglykoldicaprylatdicaprat
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FR2816842B1 (fr) * 2000-11-17 2005-03-11 Oreal Filtres uv organiques insolubles et leur utilisation en cosmetique
KR100560092B1 (ko) * 2000-12-15 2006-03-10 파트릭 프랑케 저알레르기성 및 비자극성 피부 보호 제제
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FR2828100B1 (fr) * 2001-08-02 2004-09-24 Galderma Res & Dev Composition de type emulsion inverse contenant de la dhea et/ou ses precurseurs ou derives, et ses utilisations en cosmetique et en dermatologie
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DE10161884A1 (de) * 2001-12-17 2003-06-26 Beiersdorf Ag Stabile wirkstoffhaltige Zubereitungen
US7357918B2 (en) 2002-01-31 2008-04-15 Ciba Specialty Chemicals Corp. Micropigment mixtures
US6739414B2 (en) * 2002-04-30 2004-05-25 Masi Technologies, L.L.C. Compositions and methods for sealing formations
US7285285B2 (en) 2002-05-13 2007-10-23 L'oreal Photoactivatable diazirine-active agent compounds, compositions comprising them and uses thereof
CN100502087C (zh) * 2002-06-06 2009-06-17 西巴特殊化学品控股有限公司 场致发光器件
US6958155B2 (en) 2002-06-12 2005-10-25 L'oreal Cosmetic compositions comprising at least one polysiloxane based polyamide
DE10226352A1 (de) * 2002-06-13 2003-12-24 Beiersdorf Ag Kosmetische und dermatologische Lichtschutzzubereitungen enthaltend eine synergetische Kombination aus UV-Absorbern und synthetischen organischen Polymeren als Füllstoffe
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WO2005053631A1 (en) 2003-12-04 2005-06-16 Dsm Ip Assets B.V. Microcapsules with uv filter activity and process for producing them
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JP5031551B2 (ja) 2004-03-25 2012-09-19 ディーエスエム アイピー アセッツ ビー．ブイ． 化粧品組成物
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FR2868305B1 (fr) 2004-04-02 2006-06-30 Oreal Procede de traitement capillaire et utilisation dudit procede
US20060083702A1 (en) * 2004-04-02 2006-04-20 Thomas Fondin Hair fiber treating method
FR2872413B1 (fr) 2004-07-02 2008-06-27 Oreal Procede de photostabilisation d'un derive de dibenzoylmethane par un derive arylalkyl benzoate et compositions photoprotectrices
ATE422873T1 (de) 2004-07-20 2009-03-15 Ciba Holding Inc Kosmetische bzw. dermatologische präparate mit wirksamem lichtschutz
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FR2879447B1 (fr) 2004-12-17 2007-01-26 Oreal Procede cosmetique de soin de la peau et kit associe
FR2879445B1 (fr) 2004-12-20 2007-02-23 Oreal Produit autobronzant a deux composants, dispositifs multicompartiments, procede de coloration de la peau.
FR2879456B1 (fr) 2004-12-20 2007-05-04 Oreal Composition solaire comprenant au moins un filtre uv lipophile et au moins une hydroxyalkyluree
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US8216554B2 (en) 2005-04-20 2012-07-10 L'oreal Stable transfer-resistant self-tanning gel containing a water-soluble or water-dispersible gelling agent
EP1888020B1 (en) * 2005-04-28 2009-12-16 Basf Se Use of benzotriazole derivatives for photostabilisation
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FR2888491B1 (fr) 2005-07-13 2010-12-24 Oreal Composition photoprotectrice et agents de filtration pour une telle composition
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JP4994640B2 (ja) * 2005-11-07 2012-08-08 岩瀬コスファ株式会社 紫外線吸収性複合粉体
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DE102007024342A1 (de) * 2007-05-22 2008-11-27 Beiersdorf Ag Kosmetische Zubereitung mit spezieller UV-Filterkombination
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FR2918563B1 (fr) 2007-07-12 2009-12-04 Oreal Composition photoprotectrice fluide aqueuse a base d'un polymere polyamide a terminaison amide tertiaire.
FR2918879B1 (fr) 2007-07-20 2009-10-16 Oreal Emulsion huile-dans-eau contenant un polymere amphiphile.
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EP2224898B1 (en) * 2007-11-29 2018-08-15 Basf Se Grinding aids for micronized organic uv absorbers
EP2100585A1 (fr) 2008-03-11 2009-09-16 L'Oréal Composition cosmétique comprenant un composé d'acide ascorbique ou d'acide salicylique
FR2931064B1 (fr) 2008-05-14 2010-08-13 Oreal Composition cosmetique contenant un derive de dibenzoylmethane et un derive de pyrrolidinone; procede de photostabilisation du derive de dibenzoylmethane
MX2010013738A (es) * 2008-06-13 2011-03-02 Playtex Products Llc Fotoconductividad y factor de proteccion solar de semiconductores mejorados.
US20100119465A1 (en) * 2008-06-13 2010-05-13 Playtex Products, Llc Enhanced photoactivity of semiconductors
KR101455446B1 (ko) 2008-09-19 2014-10-27 액티버스 파마 컴퍼니 리미티드 의료용 복합 유기 화합물 분체, 그 제조 방법 및 현탁액
FR2936146B1 (fr) 2008-09-24 2010-10-08 Oreal Utilisations de composes dithiolanes pour la photoprotection de la peau ; nouveaux composes dithiolanes ; compositions les contenant.
FR2936706B1 (fr) 2008-10-08 2010-12-17 Oreal Composition cosmetique contenant un derive de dibenzoylmethane et un compose dithiolane ; procede de photostabilisation du derive de dibenzoylmethane
FR2938191B1 (fr) 2008-11-07 2011-01-14 Oreal Emulsion huile-dans-eau contenant un polymere amphiphile et un elastomere silicone
FR2939042B1 (fr) 2008-11-28 2010-11-26 Oreal PROCEDE DE DEPIGMENTATION DES MATIERES KERATINIQUES A l'AIDE DE COMPOSES DITHIOLANNES.
FR2939036B1 (fr) 2008-12-01 2010-12-17 Oreal Procede de coloration artificielle de la peau utilisant un melange de carotenoide et de colorant vert lidophile ; nouveau melange de colorants lipophiles ; composition
FR2939310B1 (fr) 2008-12-08 2012-04-20 Oreal Compositions cosmetiques comprenant un derive ester de 2-pyrrolidinone 4-carboxy et un filtre lipophile triazine ; utilisation dudit derive comme solvant d'un filtre lipophile triazine
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WO2011045741A2 (en) 2009-10-12 2011-04-21 L'oreal Photonic particles; compositions containing them; methods of photoprotecting various materials
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JP2013514262A (ja) 2009-12-18 2013-04-25 ロレアル ケラチン繊維を処理する方法
EP2512417A2 (fr) 2009-12-18 2012-10-24 L'Oréal Procede de traitement cosmetique impliquant un compose apte a condenser in situ et un agent filtrant les radiations uv
FR2954940B1 (fr) 2010-01-04 2011-12-23 Oreal Composes ureidopyrimidones ; utilisation cosmetique comme filtre uv ; compositions solaires les contenant
CN102933195B (zh) 2010-03-15 2015-04-01 莱雅公司 包含二苯甲酰基甲烷掩蔽剂和部花青二氰基或氰基乙酸酯衍生物的组合物;用于二苯甲酰基甲烷掩蔽剂的光稳定化的方法
EP2547313A1 (en) 2010-03-15 2013-01-23 L'Oréal Composition containing a dibenzoylmethane screening agent and a hydrophilic or water-soluble merocyanin uv-screening agent; process for photostabilizing the dibenzoylmethane screening agent
FR2960773B1 (fr) 2010-06-03 2015-12-11 Oreal Procedes de traitement cosmetique utilisant un revetement a base d'un polymere polyamide-polyether
FR2961511A1 (fr) 2010-06-16 2011-12-23 Oreal C-glycosides aromatiques antioxydants cosmetiques
WO2012010554A1 (en) 2010-07-20 2012-01-26 L'oreal Use of compounds resulting from a sugar polyol or from a dehydrogenated sugar polyol derivative as a uv-screening agent; antisun compositions containing same; and novel compounds
FR2967056B1 (fr) 2010-11-05 2012-11-09 Oreal Composition solaire fluide aqueuse a base d'un polymere superabsorbant et d'un copolymere reticule d'acide methacrylique et d'acrylate d'alkyle en c1-c4.
FR2968661B1 (fr) 2010-12-14 2016-01-01 Oreal Procede de depigmentation des matieres keratiniques a l'aide de composes thiopyridinones
FR2969149B1 (fr) 2010-12-16 2012-12-28 Oreal Procede de depigmentation des matieres keratiniques a l' aide de composes derives de resorcinol
CN103429299A (zh) 2011-01-28 2013-12-04 迈图高新材料有限责任公司 防uv光化妆品组合物
WO2012105060A1 (en) 2011-02-04 2012-08-09 L'oreal Composite pigment and method for preparation thereof
WO2012105059A1 (en) 2011-02-04 2012-08-09 L'oreal Composite pigment and method for preparation thereof
FR2972348B1 (fr) 2011-03-09 2013-03-08 Oreal Composition cosmetique contenant un derive de dibenzoylmethane et un compose monoester monoamide d'acide methyl succinique ; procede de photostabilisation
WO2012173696A2 (en) 2011-04-21 2012-12-20 Playtex Products, Llc. Enhanced photoactivity of semiconductors and/or sunscreens
FR2975295B1 (fr) 2011-05-20 2014-12-26 Oreal Composition cosmetique comprenant un polymere superabsorbant et un glucide choisi parmi les oses, les oligosides et les homopolyholosides
FR2976482B1 (fr) 2011-06-16 2013-07-19 Oreal Utilisation d'un compose comprenant au moins une fonction nucleophile pour capturer les composes carbonyles issus de la reaction entre un ou plusieurs composes constituant le sebum et l'ozone
FR2977490B1 (fr) 2011-07-07 2014-03-21 Oreal Composition photoprotectrice
WO2013010590A1 (en) 2011-07-21 2013-01-24 L'oreal Cosmetic and/or dermatological composition containing a merocyanine derivative comprising specific polar groups consisting of hydroxyl- and ether-functionalities
FR2982147B1 (fr) 2011-11-07 2014-03-21 Oreal Composition a phase huileuse continue contenant au moins un filtre uv organique lipophile et des particules d'aerogel de silice hydrophobes.
US8454942B1 (en) 2011-11-29 2013-06-04 L'oreal Cosmetic oil mousse composition
US20130142740A1 (en) 2011-12-02 2013-06-06 Loreal S.A. Sunscreen compositions containing a novel preservative system
CN104159640B (zh) 2012-01-04 2018-01-05 莫门蒂夫性能材料股份有限公司 包含末端官能化的离子有机硅的个人护理组合物
FR2986422B1 (fr) 2012-02-06 2014-02-21 Oreal Composition solaire non pulverulente comprenant une phase huileuse polaire et des particules d'aerogel de silice hydrophobes
FR2991986B1 (fr) 2012-06-19 2015-02-27 Oreal Nouveaux derives de resorcinol et leurs applications cosmetiques
FR2991984B1 (fr) 2012-06-19 2014-07-11 Oreal Nouveaux derives de resorcinol et leur application cosmetique
FR2991985B1 (fr) 2012-06-19 2019-11-08 L'oreal Procede de depigmentation des matieres keratiniques a l'aide de nouveaux composes derives de resorcinol
FR2992858B1 (fr) 2012-07-04 2015-10-30 Oreal Composition cosmetique photoprotectrice.
WO2014010100A1 (en) 2012-07-13 2014-01-16 L'oreal Cosmetic composition comprising composite sunscreen particles
JP6096897B2 (ja) 2012-07-13 2017-03-15 ロレアル 化粧料組成物
ES2822151T5 (es) 2012-07-13 2024-03-18 Oreal Pigmento compuesto y procedimiento para prepararlo
JP6100896B2 (ja) * 2012-07-13 2017-03-22 ロレアル 複合顔料及びその調製方法
FR2993176B1 (fr) 2012-07-13 2014-06-27 Oreal Composition cosmetique contenant des particules composites filtrantes de taille moyenne superieure a 0,1 micron et des particules de filtre inorganique et une phase aqueuse
US8486425B1 (en) 2012-08-08 2013-07-16 L'oreal Two-phase sunscreen composition
US9408785B2 (en) 2012-10-15 2016-08-09 L'oreal Hair styling compositions containing aqueous wax dispersions
US10626294B2 (en) 2012-10-15 2020-04-21 L'oreal Aqueous wax dispersions containing volatile solvents
CN104736203A (zh) 2012-10-15 2015-06-24 欧莱雅 水性蜡分散体及包含它们的头发定型组合物
US10413496B2 (en) 2012-10-15 2019-09-17 L'oreal Aqueous wax dispersions
US20140186411A1 (en) 2012-12-27 2014-07-03 L'oreal Low viscosity meta-stable photoprotection composition
FR3001128B1 (fr) 2013-01-21 2015-06-19 Oreal Emulsion cosmetique ou dermatologique comprenant une merocyanine et un systeme emulsionnant contenant un sel de metal alcalin d'ester d'acide phosphorique et d'alcool gras
ES2660222T3 (es) 2013-01-21 2018-03-21 L'oréal Composición cosmética o dermatológica que comprende una merocianina y un agente de protección de UV orgánico insoluble y/o un agente de protección de UV inorgánico insoluble
FR3001131B1 (fr) 2013-01-21 2015-06-19 Oreal Emulsion cosmetique ou dermatologique comprenant une merocyanine et un systeme emulsionnant contenant un tensioactif gemine.
FR3001137B1 (fr) 2013-01-21 2015-02-27 Oreal Emulsion eau-dans-huile cosmetique ou dermatologique comprenant une merocyanine et au moins un polymere emulsionnant du type ester d'acide gras et de glycol polyoxyalkylene
FR3001136B1 (fr) 2013-01-21 2015-06-19 Oreal Emulsion cosmetique ou dermatologique comprenant une merocyanine et un systeme emulsionnant contenant un polymere amphiphile comportant au moins un motif acide acrylamido 2-methylpropane sulfonique
FR3001216B1 (fr) 2013-01-21 2015-02-27 Oreal Composition cosmetique ou dermatologique comprenant une merocyanine, une phase huileuse et un mono-alcanol en c1-c4
CN105188653B (zh) 2013-01-21 2019-02-12 莱雅公司 包含部花青和亲脂性苯并三唑uv-遮蔽剂和/或双-间苯二酚基三嗪化合物的化妆品或者皮肤病学组合物
WO2014111567A2 (en) 2013-01-21 2014-07-24 L'oreal Cosmetic or dermatological composition comprising a merocyanine and a uva-screening agent of the amino-substituted 2-hydroxybenzophenone type and/or a hydrophilic organic uva-screening agent
ES2693045T3 (es) 2013-01-21 2018-12-07 L'oréal Composición cosmética o dermatológica que comprende una merocianina, un agente de filtro UVB orgánico y un agente de filtro UVA orgánico adicional
FR3001138B1 (fr) 2013-01-21 2015-06-19 Oreal Composition anhydre cosmetique ou dermatologique comprenant une merocyanine et une phase huileuse
FR3001133B1 (fr) 2013-01-21 2015-03-20 Oreal Composition cosmetique ou dermatologique comprenant une merocyanine et une phase huileuse comprenant au moins un compose amide particulier
FR3004107A1 (fr) 2013-04-08 2014-10-10 Univ Rennes Composes photoprotecteurs, compositions les comprenant, et leurs utilisations
FR3006176B1 (fr) 2013-05-29 2015-06-19 Oreal Particules composites a base de filtre uv inorganique et de perlite ; compositions cosmetiques ou dermatologiques les contenant
WO2014203913A1 (en) 2013-06-18 2014-12-24 L'oreal Cosmetic composition
CN105358123B (zh) * 2013-07-08 2018-11-13 帝斯曼知识产权资产管理有限公司 包含uv滤光剂、用uv吸收剂官能化的有机聚硅氧烷、和多孔二氧化硅和/或聚甲基丙烯酸甲酯颗粒的uv屏蔽组合物
JP6532646B2 (ja) 2013-12-06 2019-06-19 ロレアル パウダー状化粧用組成物
WO2015089035A1 (en) 2013-12-09 2015-06-18 Momentive Performance Materials Inc. Emulsion compositions and applications therefor
US9579276B2 (en) 2013-12-12 2017-02-28 L'oreal Clear sunscreen composition for application onto wet or dry skin
BR112016023295B1 (pt) 2014-04-09 2020-11-17 Basf Se uso dos compostos, e, composição cosmética
US10561596B2 (en) 2014-04-11 2020-02-18 L'oreal Compositions and dispersions containing particles comprising a polymer
JP2017517489A (ja) 2014-04-11 2017-06-29 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 化粧品紫外線吸収体の混合物
US10172783B2 (en) 2014-06-04 2019-01-08 L'oreal High UV protection alcohol-free anhydrous clear system
WO2015188335A1 (en) 2014-06-11 2015-12-17 L'oreal Composition for protecting keratin materials from sun
ES2894864T3 (es) 2014-08-28 2022-02-16 Oreal Composición tipo gel/gel que comprende un filtro UV
US9820920B2 (en) 2014-09-30 2017-11-21 L'oreal High UV protection alcohol-free emulsion system, that is clear on application
US20170326045A1 (en) 2014-11-24 2017-11-16 L'oreal Cosmetic composition comprising a synthetic phyllosilicate and a polyol and/or a uv filter
BR112017012667B1 (pt) 2014-12-18 2021-02-23 L'oreal composição e película de longa duração para reduzir a aparência de imperfeições da pele, e, método para melhorar a aparência da pele
US10512601B2 (en) 2014-12-18 2019-12-24 L'oréal Compositions having improved water resistance
EP3217956B1 (en) * 2014-12-18 2020-03-25 L'oreal Compositions having improved spf and/or water resistance
BR112017014015A2 (pt) 2015-01-29 2018-01-02 Oreal ?composição para aplicação à pele, uso da composição e método de aprimoramento?
FR3037243B1 (fr) 2015-06-11 2018-11-16 L'oreal Composition comprenant un filtre uv, un polymere hydrophile reticule anionique, un tensioactif ayant une hlb inferieure ou egale a 5 et un copolymere silicone
US20160367470A1 (en) 2015-06-19 2016-12-22 L'oreal Water-in-oil sunscreen composition having organic sunscreen actives
BR112017026169A2 (pt) 2015-06-29 2018-08-14 Oreal composição na forma de emulsão de óleo em água e método de prevenção e/ou controle da oleosidade da pele
JP6739153B2 (ja) 2015-08-20 2020-08-12 ロレアル 疎水性変性イヌリン及びポリエーテル変性シリコーンを含む組成物
JP6866059B2 (ja) 2015-08-20 2021-04-28 ロレアル 水中油型エマルジョン組成物
FR3041528A1 (fr) 2015-09-25 2017-03-31 Rhodia Operations Composition cosmetique photoprotectrice
JP2017109928A (ja) 2015-12-14 2017-06-22 ロレアル 複合粒子
JP6921476B2 (ja) 2015-12-15 2021-08-18 ロレアル ポリイオンコンプレックス粒子と２つ以上の酸解離定数を有する非ポリマー酸との組合せ
JP6812100B2 (ja) 2015-12-15 2021-01-13 ロレアル ポリイオンコンプレックス粒子と親水性又は水溶性ｕｖ遮蔽剤との組合せ
FR3045604B1 (fr) 2015-12-18 2018-01-26 L'oreal Procede de depigmentation des matieres keratiniques a l'aide de composes thiopyridinones
US20180369095A1 (en) 2015-12-21 2018-12-27 L'oreal Cosmetic composition comprising a specific filler combination and a film-forming polymer to increase long-lasting effects
FR3046063B1 (fr) 2015-12-23 2019-05-10 L'oreal Composition cosmetique photoprotectrice et son procede de preparation
BR112018007635B1 (pt) 2015-12-29 2021-01-05 L'oreal composição cosmética
US10292922B2 (en) 2015-12-31 2019-05-21 L'oreal Silicone-wax dispersion compositions for removing cosmetic films
US10835479B2 (en) 2015-12-31 2020-11-17 L'oreal Systems and methods for improving the appearance of the skin
FR3046929B1 (fr) 2016-01-26 2018-03-02 L'oreal Composition cosmetique ou dermatologique comprenant une merocyanine et une phase huileuse comprenant au moins un ester d'acide di ou tricarboxylique
FR3046930B1 (fr) 2016-01-26 2018-03-02 L'oreal Composition cosmetique ou dermatologique comprenant une merocyanine et une phase huileuse comprenant au moins un polyalkyleneglycol
FR3046928B1 (fr) 2016-01-26 2019-08-09 L'oreal Composition cosmetique ou dermatologique comprenant une merocyanine et une phase huileuse comprenant au moins un amide n-substitue
FR3046927B1 (fr) 2016-01-26 2018-03-02 L'oreal Composition cosmetique ou dermatologique comprenant une merocyanine et une phase huileuse comprenant au moins un ether d'isosorbide
JP6851729B2 (ja) 2016-05-13 2021-03-31 ロレアル マット効果及び優れた質感を有するｕｖ遮断組成物
WO2017198806A1 (en) * 2016-05-19 2017-11-23 Basf Se Micro-particulate organic uv absorber composition
WO2018000063A1 (en) 2016-06-30 2018-01-04 L'oreal Non-pressurized foaming cosmetic products and foaming cosmetic compositions
WO2018007577A1 (en) 2016-07-08 2018-01-11 Basf Se Solubilizing agents for uv filters in cosmetic formulations
JP2018024582A (ja) 2016-07-14 2018-02-15 ロレアル 有機粒子を含むｗ／ｏサンケア組成物
US20180028416A1 (en) 2016-07-29 2018-02-01 L'oreal Cosmetic compositions with sensorial and aesthetic benefits and having enhanced stability
US20190231656A1 (en) 2016-10-18 2019-08-01 L'oreal Method of protecting keratin materials from pollutants
FR3060361B1 (fr) 2016-12-21 2018-12-07 L'oreal Emulsion eau-dans-huile comprenant un systeme emulsionnant particulier, une argile lipophile, une poudre d’organopolysiloxane elastomerique enrobee d’une resine de silicone
FR3060358B1 (fr) 2016-12-21 2019-05-31 L'oreal Composition comprenant de la baicaline, un ester d'acide gras et un alkylpolyglycoside
FR3060355B1 (fr) 2016-12-21 2020-01-24 L'oreal Emulsion eau-dans-huile contenant la baicaline, une base xanthique, une vitamine b3 et un sel de cation metallique multivalent
FR3060997B1 (fr) 2016-12-23 2019-05-31 L'oreal Composition comprenant de la baicaline
FR3066107B1 (fr) 2017-05-12 2019-07-12 L'oreal Composition photostable a base de particules composites de perlite/titanium/silice
JP7176836B2 (ja) 2017-06-13 2022-11-22 ロレアル ポリイオンコンプレックス粒子と油とを含む組成物
JP7063549B2 (ja) 2017-06-13 2022-05-09 ロレアル ポリイオンコンプレックス粒子と２つ以上の解離定数を有する非ポリマー酸又は塩基との組合せ
JP7127966B2 (ja) 2017-06-13 2022-08-30 ロレアル ポリイオンコンプレックス粒子と２つ以上の解離定数を有する非ポリマー塩基との組合せ
FR3068354B1 (fr) 2017-06-29 2020-07-31 Oreal Compositions photoprotectrices comprenant un derive dibenzoylmethane, un compose merocyanine et un compose susceptible d'accepter l'energie de niveau excite triplet du compose dibenzoylmethane
BR112019025366B1 (pt) 2017-08-25 2022-06-28 L'oreal Combinação, composição de filtro solar, uso da combinação e método para proteger um substrato queratinoso de radiação ultravioleta
JP7106262B2 (ja) 2017-10-31 2022-07-26 ロレアル 冷却効果を有する組成物
FR3073409B1 (fr) 2017-11-15 2019-10-11 L'oreal Composition cosmetique ou dermatologique comprenant une merocyanine et un polymere acrylique.
FR3073408B1 (fr) 2017-11-15 2019-10-11 L'oreal Compositions comprenant au moins un polymere acrylique et au moins un filtre organique insoluble
FR3073402B1 (fr) 2017-11-15 2020-05-15 L'oreal Composition comprenant de la baicaline et/ou l’un de ses derives et un polymere acrylique particulier
FR3073400B1 (fr) 2017-11-15 2024-08-09 Oreal Emulsion cosmetique contenant un tensioactif gemine et un polymere lipophile
FR3074162A1 (fr) 2017-11-24 2019-05-31 Rhodia Operations Particules d'oxyde de cerium / silice
US11344497B1 (en) 2017-12-08 2022-05-31 Quicksilver Scientific, Inc. Mitochondrial performance enhancement nanoemulsion
US10722465B1 (en) 2017-12-08 2020-07-28 Quicksilber Scientific, Inc. Transparent colloidal vitamin supplement
JP7063593B2 (ja) 2017-12-12 2022-05-09 ロレアル 油と、少なくとも１つの脂肪鎖を有するセルロース系カチオン性ポリマーを含むポリイオンコンプレックスとを含む組成物
BR112020011082B1 (pt) 2017-12-19 2022-09-20 L'oreal Composição de proteção solar, uso de uma composição e método para fabricar a composição
FR3075050B1 (fr) 2017-12-19 2020-01-03 L'oreal Composition comprenant de la baicaline et un compose antioxydant
BR112020011071B1 (pt) 2017-12-19 2022-09-20 L'oreal Composição de proteção solar, uso de uma composição e método para fabricar a composição
WO2019210376A1 (en) 2018-04-30 2019-11-07 L'oreal Sunscreen compositions
FR3083097B1 (fr) 2018-06-28 2020-11-27 Oreal Composition cosmetique ou dermatologique comprenant une merocyanine et une phase huileuse comprenant au moins un carbonate d’alkyle ou d’alkylene
WO2020000068A1 (en) 2018-06-28 2020-01-02 L'oreal Surfactant system and sunscreen composition comprising it
FR3083093A1 (fr) 2018-06-28 2020-01-03 L'oreal Composition photoprotectrice comprenant des particules de silice colloidale
FR3083118B1 (fr) 2018-07-02 2021-01-08 Lvmh Rech Composition gelifiee avec filtres uv
BR112020024706B1 (pt) 2018-07-31 2023-04-04 L'oreal Composição de proteção solar, uso de uma composição e processo de fabricação de uma composição
BR112021001607B1 (pt) 2018-07-31 2023-04-04 L'oreal Composição de protetor solar e uso da composição de protetor solar
JP7179535B2 (ja) 2018-08-30 2022-11-29 ロレアル 高内油相エマルション組成物－ゲル
JP7179534B2 (ja) 2018-08-30 2022-11-29 ロレアル 油を含む発泡性組成物
JP7179533B2 (ja) 2018-08-30 2022-11-29 ロレアル 自己回復又は自己修復膜形成組成物
FR3090329B1 (fr) 2018-12-21 2020-12-04 Oreal Composition comprenant un filtre UV, un polymère hydrophile réticulé anionique, un tensioactif ayant une HLB inférieure ou égale à 5 et un alcane non volatil
FR3090337B1 (fr) 2018-12-21 2021-10-29 Oreal Composition photoprotectrice fluide
WO2020154779A1 (en) 2019-01-31 2020-08-06 L'oreal Sunscreen compositions, process of manufacturing the sunscreen composition, use of the sunscreen compositions, and use of emulsified carnauba wax
WO2020163928A1 (en) 2019-02-13 2020-08-20 L'oreal Sunscreen composition, use of the sunscreen composition and process of manufacturing the sunscreen composition
WO2020172725A1 (en) 2019-02-28 2020-09-03 L'oreal Sunscreen composition, use of a sunscreen composition, use of the liquid carnauba wax and process of manufacturing a sunscreen composition
WO2020172726A1 (en) 2019-02-28 2020-09-03 L'oreal Anti-acne sunscreen composition, process for manufacturing an anti-acne sunscreen composition and use of an anti-acne sunscreen composition
BR112021012423A2 (pt) 2019-03-29 2022-04-12 Oreal Composição de filtro solar anidro, processo de fabricação de composições de filtro solar anidro e uso da composição de filtro solar anidro
US11291702B1 (en) 2019-04-15 2022-04-05 Quicksilver Scientific, Inc. Liver activation nanoemulsion, solid binding composition, and toxin excretion enhancement method
US11752081B2 (en) 2019-04-30 2023-09-12 L'oreal Emulsifier-free sunscreen gel composition with transparent application
CN113766906A (zh) 2019-04-30 2021-12-07 欧莱雅 包含选自二氧化硅气凝胶和聚乳酸的疏水性粉末、淀粉和uv滤光剂体系的软固体形式的化妆品组合物
WO2020237329A1 (en) 2019-05-31 2020-12-03 L'oreal Water-resistant cosmetic composition comprising light green clay and a probiotic-derived active ingredient
JP7516015B2 (ja) 2019-06-27 2024-07-16 ロレアル Ｄｉｃゲル及びポリオールの成分を含む組成物
WO2021016679A1 (en) 2019-07-26 2021-02-04 L'oreal Anhydrous sunscreen composition comprising silica aerogel
BR112021023914A2 (pt) 2019-07-26 2022-01-18 Oreal Composição de filtro solar anidra
BR112021024030A2 (pt) 2019-07-31 2022-02-08 Oreal Composição cosmética, processo para a fabricação da composição cosmética e uso da composição cosmética
BR112021023920A2 (pt) 2019-07-31 2022-02-08 Oreal Composição cosmética anidra, processo para a fabricação de uma composição cosmética anidra e usos da composição cosmética anidra
FR3103705B1 (fr) 2019-11-29 2021-12-17 Oreal Composition comprenant un filtre UV, un polymère séquencé à groupe acide phosphonique et une huile hydrocarbonée
FR3103704B1 (fr) 2019-11-29 2022-07-08 Oreal Composition comprenant un filtre UV, un polymère éthylénique à groupe acide phosphonique et une huile hydrocarbonée
JP7486943B2 (ja) 2019-12-16 2024-05-20 ロレアル カチオン性多糖とアニオン性抗酸化剤とを含む組成物
EP4076347A1 (en) 2019-12-19 2022-10-26 L'oreal Cosmetic composition, process of manufacturing the cosmetic composition and use of the cosmetic composition
WO2021119770A1 (en) 2019-12-19 2021-06-24 L'oreal Cosmetic composition for a keratin substance, process for manufacturing a cosmetic composition and use of the cosmetic composition
WO2021237318A1 (en) 2020-05-29 2021-12-02 L'oreal Cosmetic composition comprising unsaturated dioic acid and uses thereof
US20230240950A1 (en) 2020-06-30 2023-08-03 L'oreal Anhydrous cosmetic compositions, process of manufacturing a cosmetic composition and use of the anhydrous cosmetic compositions
BR112022021113A2 (pt) 2020-06-30 2023-01-10 Oreal Composição cosmética de proteção solar com alto fps, uso de um composição cosmética de proteção solar e processos para fabricação de uma composição cosmética de proteção solar
WO2022006408A1 (en) 2020-07-01 2022-01-06 L'oreal Organic and mineral filter hybrid sunscreen
FR3113831A1 (fr) 2020-09-07 2022-03-11 L'oreal Filtre solaire hybride organique et minéral
US20240009108A1 (en) 2020-07-02 2024-01-11 L'oreal Cosmetic composition, use of a cosmetic composition and process of manufacturing a cosmetic composition
FR3112286B1 (fr) 2020-07-10 2023-02-24 Oreal Emulsion eau dans huile à haute teneur en phase interne aqueuse
WO2022020913A1 (en) 2020-07-31 2022-02-03 L'oreal Anhydrous cosmetic sunscreen composition, process of manufacturing the anhydrous cosmetic sunscreen composition and use of the anhydrous cosmetic sunscreen composition
US20230270645A1 (en) 2020-07-31 2023-08-31 L'oreal Cosmetic sunscreen composition, process for manufacturing a cosmetic sunscreen composition and use of a cosmetic sunscreen composition
WO2022067403A1 (en) 2020-09-30 2022-04-07 L'oreal Anhydrous cosmetic sunscreen composition, process for manufacturing an anhydrous cosmetic sunscreen composition and use of an anhydrous cosmetic sunscreen composition
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FR3144000A1 (fr) 2022-12-27 2024-06-28 L'oreal Procédé de traitement des matières kératiniques mettant en œuvre au moins un (co)polymère d’alcool polyvinylique (PVA) à fonctions acétoacétates et au moins un agent réticulant
FR3144001A1 (fr) 2022-12-27 2024-06-28 L'oreal Procédé de traitement des fibres kératiniques mettant en œuvre au moins un (co)polymère d’alcool polyvinylique (PVA) à fonctions acétoacétates
FR3144134A1 (fr) 2022-12-27 2024-06-28 L'oreal Procédé de traitement des fibres kératiniques mettant en œuvre au moins une huile à fonctions acétoacétates
WO2024179771A1 (en) * 2023-02-27 2024-09-06 Basf Se Sunscreen composition with non-nano organic uv filter
FR3146067A1 (fr) 2023-02-28 2024-08-30 L'oreal Composition cosmetique a base d'oxyde de zinc et de bisethyhexyloxyphenol methoxyphenyl triazine

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3206398A1 (de) * 1982-02-23 1983-09-01 Basf Ag, 6700 Ludwigshafen S-triazinderivate und ihre verwendung als lichtschutzmittel
LU85746A1 (fr) * 1985-01-28 1986-08-04 Oreal Composition cosmetique filtrante contenant un filtre uv associe a un polymere obtenu par polymerisation sequentielle en emulsion et son utilisation pour la protection de l'epiderme humain contre les radiations ultraviolettes
FR2674851B1 (fr) * 1991-04-04 1995-02-10 Oreal Derives s-triaziniques portant des substituants benzylidene camphre, compositions cosmetiques filtrantes et leur utilisation pour proteger la peau et les cheveux du rayonnement ultraviolet.
IT1247973B (it) 1991-06-04 1995-01-05 Sigma Prod Chim Derivati di 1,3,5-triazina, loro preparazione e uso come filtri solari
DE4223890A1 (de) 1992-02-19 1993-08-26 Merck Patent Gmbh Triazin-derivate
IT1255729B (it) 1992-05-19 1995-11-15 Giuseppe Raspanti Derivati di s-triazina come agenti fotostabilizzanti
US5629365A (en) * 1992-06-23 1997-05-13 Monsanto Company UV-absorbing polymer latex
US5338539A (en) 1992-08-04 1994-08-16 3V Inc. Benzofuran derivatives useful as sunscreens
FR2695560B1 (fr) 1992-09-17 1994-11-04 Oreal Composition cosmétique filtrante photostable contenant un filtre UV-A et un polymère filtre du type silicone benzotriazole.
DE4303983C2 (de) 1993-02-11 1998-01-22 Beiersdorf Ag Kosmetische und dermatologische Lichtschutzformulierungen mit einem Gehalt an anorganischen Mikropigmenten
ES2118381T3 (es) * 1993-02-11 1998-09-16 Beiersdorf Ag Preparados cosmeticos o dermatologicos de proteccion solar, resistentes al agua.
US5362481A (en) 1993-03-05 1994-11-08 3V Inc. Benzofuran derivatives and the use thereof as stabilizers against UV radiations
US5332568A (en) 1993-05-20 1994-07-26 3V Inc. S-triazine derivatives having light-protecting action
GB9403153D0 (en) * 1994-02-18 1994-04-06 Ciba Geigy Ag Cosmetic compositions
GB9403451D0 (en) * 1994-02-23 1994-04-13 Ciba Geigy Ag Sunscreen compositions
EP0669124A1 (en) * 1994-02-28 1995-08-30 Rohm And Haas Company Ultraviolet radiation absorbing composition
US5663213A (en) * 1994-02-28 1997-09-02 Rohm And Haas Company Method of improving ultraviolet radiation absorption of a composition
US5601811A (en) 1994-08-01 1997-02-11 Croda, Inc. Substantive water-soluble cationic UV-absorbing compounds
ATE212536T1 (de) 1994-10-14 2002-02-15 Hoffmann La Roche Lichtstabile kosmetische sonnenschutzmittel
US5518713A (en) 1995-02-13 1996-05-21 3V Inc. Benzoxazole derivatives, the use thereof as sunscreens and cosmetic compositions containing them
FR2735363B1 (fr) * 1995-06-16 1997-07-11 Oreal Compositions contenant un derive du dibenzoylmethane et un nanopigment d'oxyde de titane et utilisations
JPH11507941A (ja) 1995-06-23 1999-07-13 ズィレプシス リミテッド 化学化合物およびその製造方法
FR2736543B1 (fr) * 1995-07-13 1997-08-29 Oreal Compositions cosmetiques anhydres contenant des nanopigments de ti02 et des microspheres creuses deformables
AU6614296A (en) 1995-07-22 1997-02-18 Ciba Specialty Chemicals Holding Inc. Sunscreen compositions
GB9515048D0 (en) * 1995-07-22 1995-09-20 Ciba Geigy Ag Sunscreen compositions
DE19543730A1 (de) 1995-11-23 1997-05-28 Ciba Geigy Ag Bis-Resorcinyl-Triazine
US5874576A (en) 1995-12-19 1999-02-23 Givaudan-Roure (International) Sa Light screening agents

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8080257B2 (en) 2000-12-12 2011-12-20 L'oreal S.A. Cosmetic compositions containing at least one hetero polymer and at least one film-forming silicone resin and methods of using
US7166274B2 (en) 2000-12-18 2007-01-23 L'oreal Synergistically high SPF photoprotective UV-screening compositions comprising insoluble organic sunscreen particles/diarylbutadiene compounds
US7749524B2 (en) 2003-07-11 2010-07-06 L'oreal S.A. Cosmetic compositions comprising a structuring agent, silicone powder and swelling agent
US7976831B2 (en) 2004-04-02 2011-07-12 L'oreal S.A. Method for treating hair fibers
US10219990B2 (en) 2014-12-09 2019-03-05 Basf Se Solubilizing agents for UV filters in cosmetic formulations
CN111867553A (zh) * 2018-03-20 2020-10-30 帝斯曼知识产权资产管理有限公司 表面组合物
US11992544B2 (en) * 2018-03-20 2024-05-28 Dsm Ip Assets B.V. Topical composition
CN111867553B (zh) * 2018-03-20 2024-06-07 帝斯曼知识产权资产管理有限公司 表面组合物

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KR100541173B1 (ko) 2006-07-11
AU741731B2 (en) 2001-12-06
DE69817706T2 (de) 2004-07-08
US6235271B1 (en) 2001-05-22
JPH11100317A (ja) 1999-04-13
AU7842998A (en) 1999-02-04
IL125428A (en) 2004-06-20
BRPI9802577B1 (pt) 2017-04-18
GB9715751D0 (en) 1997-10-01
IL125428A0 (en) 1999-03-12
ID20611A (id) 1999-01-28
DE69817706D1 (de) 2003-10-09
ZA986622B (en) 1999-01-26
JP4386483B2 (ja) 2009-12-16
ES2205426T3 (es) 2004-05-01
EP0893119A1 (en) 1999-01-27
BR9802577A (pt) 2000-12-19
CA2243553A1 (en) 1999-01-26

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