EP0871791A1 - Procede de fabrication de tuyaux minces - Google Patents
Procede de fabrication de tuyaux mincesInfo
- Publication number
- EP0871791A1 EP0871791A1 EP96930115A EP96930115A EP0871791A1 EP 0871791 A1 EP0871791 A1 EP 0871791A1 EP 96930115 A EP96930115 A EP 96930115A EP 96930115 A EP96930115 A EP 96930115A EP 0871791 A1 EP0871791 A1 EP 0871791A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- tube
- thick
- carried out
- walled
- hot forming
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/04—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon
- C22F1/043—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of aluminium or alloys based thereon of alloys with silicon as the next major constituent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/115—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces by spraying molten metal, i.e. spray sintering, spray casting
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C1/00—Making non-ferrous alloys
- C22C1/04—Making non-ferrous alloys by powder metallurgy
- C22C1/0408—Light metal alloys
- C22C1/0416—Aluminium-based alloys
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/123—Spraying molten metal
Definitions
- the invention relates to a method for producing thin-walled tubes, which consist of a heat-resistant and wear-resistant aluminum material, in particular for use as cylinder liners for internal combustion engines.
- Liner bushings are components subject to wear and tear that are inserted, pressed or cast into the cylinder openings of the crankcase of the internal combustion engine.
- the problem was initially solved by a cast cylinder block made of a hypereutectic AlSi alloy.
- the silicon content is limited to a maximum of 20% by weight.
- Another disadvantage of the casting process is that silicon solid particles with relatively large dimensions (approx. 30-80 ⁇ m) are precipitated during the solidification of the melt. Due to their size and their angular and sharp-edged shape, they lead to wear on the pistons and piston rings. It is therefore necessary to protect the pistons and the piston rings with appropriate coatings / coatings.
- the contact area of the Si particles to the piston / piston ring is leveled by mechanical processing.
- a cylinder block according to DE 42 30 228, which is cast from a hypereutectic AlSi alloy and provided with liners made of hypereutectic AlSi alloy material, is less expensive. The aforementioned problems are not solved here either.
- the structure of the Si grains has to be changed. It is known that aluminum alloys that cannot be produced using casting technology can be made to measure using powder metallurgy processes or spray compaction.
- hypereutectic AlSi alloys can be produced which, due to the high Si content, the fineness of the Si particles and the homogeneous distribution, have very good wear resistance and are given the required heat resistance through additional elements such as Fe, Ni or Mn.
- the Si primary particles present in these alloys have a size of approximately 0.5 to 20 ⁇ m. The alloys produced in this way are therefore suitable for a liner material.
- EP 0 635 318 discloses a method for producing liners from a hypereutectic AlSi alloy.
- the liner is manufactured by extrusion at very high pressures and extrusion speeds of 0.5 to 12m / min.
- very high press speeds are necessary. It has been shown that with such hard-to-press alloys and the small wall thicknesses of the liners to be achieved, the high pressing speeds lead to the tearing of the profiles during extrusion.
- the spray compacting of hollow cylinders is known from WO 87/03012.
- tube blanks For example, the production of tube blanks with wall thicknesses of 25 to 40 mm is described.
- the object of the invention is therefore to provide an improved and far more cost-effective method for the production of thin-walled tubes, in particular for cylinder liners of internal combustion engines, the liner produced being said to have the required improvements in properties with regard to wear resistance, heat resistance and reduction of pollutant emissions.
- the object is achieved by a method with the method steps specified in claim 1.
- the required tribological properties are achieved in particular in that silicon particles are present in the material as primary excretions in a size range from 0.5 to 20 ⁇ m or as added particles in a size range up to 80 ⁇ m.
- processes must be used which permit a much higher solidification rate of a high-alloy melt than is possible with conventional casting processes.
- spray compacting This includes the spray compacting process (hereinafter "spray compacting").
- an aluminum alloy melt that is high-alloyed with silicon is atomized and cooled in a nitrogen jet at a cooling rate of 1000 ° C./s.
- the powder particles, some of which are still liquid, are sprayed onto a carrier tube made of a similar material or a conventional aluminum material (e.g. AlMgSi0.5) rotating horizontally around the longitudinal axis.
- the carrier tube which preferably has wall thicknesses of 2-3 mm, is moved linearly under the spray jet during the process. By superimposing the rotational and translational movement of the carrier tube, a cylindrical tube with a fixedly specified inside diameter is created. The outer diameter results from the feed rate and the effective compacting rate. In this way, pipes with wall thicknesses of 6 to 20 mm can be produced. Suitable supply and guide systems for the carrier tubes enable quasi-continuous production to be carried out.
- Si primary precipitates up to 20 ⁇ m in size are created in this spray compacting process.
- the size of the Si precipitate can be adjusted by means of the "gas to metal ratio" (standard cubic meters of gas per kilogram of melt), with which the solidification rate in the process can be adjusted. Due to the high solidification rates and the supersaturation of the melt, Si contents of the alloys of up to 40% by weight can be achieved. Due to the Rapid quenching of the aluminum melt in the gas jet, the supersaturation state in the pipe obtained is virtually “frozen".
- the spray compacting process also offers the possibility of introducing particles into the bolt via a particle injector that were not present in the melt. Since these particles can have any geometry and any size between 2 ⁇ m and 400 ⁇ m, there are a multitude of setting options for a structure. These particles can e.g. Si particles in the range from 2 ⁇ m to 400 ⁇ m or oxide-ceramic (e.g. AI2O3) or non-oxide-ceramic particles (e.g. SiC, B4C, etc.) in the aforementioned particle size range, as they are commercially available and useful for the tribological aspect.
- oxide-ceramic e.g. AI2O3
- non-oxide-ceramic particles e.g. SiC, B4C, etc.
- the structure of the spray-compacted pipe can be changed by subsequent aging annealing.
- the structure can be adjusted to an Si grain size of 2 to 30 ⁇ m by annealing, as is desirable for the required tribological properties.
- the growth of larger Si particles during the annealing process is caused by diffusion in the solid at the expense of smaller Si particles. This diffusion depends on the aging temperature and the duration of the annealing treatment. The higher the temperature selected, the faster the Si grains grow. Suitable temperatures are around 500 ° C, with an annealing time of 3-5 hours being sufficient.
- the wall thickness is reduced to the required final dimensions by hot forming using various methods.
- the process temperatures are between 300 ° C and 550 ° C.
- the hot forming not only serves for forming, but also for closing the process-related residual porosity (1 - 5%) in the spray-compacted starting material.
- the pipe formed to the end wall thickness is then cut into pipe sections of the required length.
- the method according to the invention has the advantage that the material for the liner can be tailored. At the same time, the high outlay involved in the single-stage extrusion of thin-walled pipes is successfully avoided, both in terms of pressure and speed, as well as product quality and economy, by the production method described.
- Example 1
- An alloy of the composition AlSi25Cu2.5MglNil is melt compacted at a melt temperature of 830 ° C with a gas / metal ratio of 4.5m3 / kg (standard cubic meters of gas per kilogram of melt) by spray compacting on a carrier tube (inner diameter: 69.5 mm, wall thickness: 2.0 mm) at a feed rate of approx. 0.6 m / min to a tube with a wall thickness of 15.0 mm.
- the Si precipitates in the size range from l ⁇ m to lO ⁇ m are present under the conditions mentioned.
- the spray-compacted tube is subjected to an annealing treatment of 4 hours at 520 ° C.
- the Si deposits are in the size range from 2 ⁇ m to 30 ⁇ m.
- the spray-compacted tube is formed from an outside diameter of 98 mm to an outside diameter of 79 mm and an inside diameter of 69 mm, which is formed by a mandrel. The degree of deformation is sufficient to completely close the aforementioned residual porosity in the spray-compacted tube. No other structural change occurs during the round kneading.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Powder Metallurgy (AREA)
- Cylinder Crankcases Of Internal Combustion Engines (AREA)
- Pistons, Piston Rings, And Cylinders (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
- Rigid Pipes And Flexible Pipes (AREA)
- Insulators (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19532252 | 1995-09-01 | ||
DE19532252A DE19532252C2 (de) | 1995-09-01 | 1995-09-01 | Verfahren zur Herstellung von Laufbuchsen |
PCT/EP1996/003780 WO1997009459A1 (fr) | 1995-09-01 | 1996-08-28 | Procede de fabrication de tuyaux minces |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0871791A1 true EP0871791A1 (fr) | 1998-10-21 |
EP0871791B1 EP0871791B1 (fr) | 2000-11-29 |
Family
ID=7770982
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96930115A Expired - Lifetime EP0871791B1 (fr) | 1995-09-01 | 1996-08-28 | Procédé de fabrication de chemises de cylindre |
Country Status (13)
Country | Link |
---|---|
US (2) | US6136106A (fr) |
EP (1) | EP0871791B1 (fr) |
JP (1) | JP3664315B2 (fr) |
KR (1) | KR100258754B1 (fr) |
CN (1) | CN1066493C (fr) |
AT (1) | ATE197821T1 (fr) |
BR (1) | BR9610546A (fr) |
DE (2) | DE19532252C2 (fr) |
DK (1) | DK0871791T3 (fr) |
ES (1) | ES2152560T3 (fr) |
GR (1) | GR3035368T3 (fr) |
PT (1) | PT871791E (fr) |
WO (1) | WO1997009459A1 (fr) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19621264B4 (de) * | 1996-05-25 | 2005-09-15 | Mahle Gmbh | Verfahren zur Herstellung einer Zylinderbüchse |
DE19643029A1 (de) * | 1996-10-18 | 1998-04-23 | Bayerische Motoren Werke Ag | Verfahren zum Beschichten eines aus einer Aluminium-Legierung bestehenden Bauteils einer Brennkraftmaschine mit Silicium |
DE19731804A1 (de) * | 1997-07-24 | 1999-01-28 | Bayerische Motoren Werke Ag | Herstellverfahren für eine Zylinderbüchse einer Brennkraftmaschine |
AU8797298A (en) * | 1997-09-15 | 1999-04-05 | Alusuisse Technology & Management Ag | Cylinder liner |
DE19750686C1 (de) * | 1997-11-15 | 1999-09-23 | Ks Aluminium Technologie Ag | Verfahren zum Herstellen einer Zylinderlaufbuchse |
DE10104638A1 (de) * | 2001-02-02 | 2002-08-22 | Thyssen Krupp Automotive Ag | Verfahren zur Herstellung von Bauteilen für Flugtriebwerke und stationäre Gasturbinen |
DE10235911B3 (de) * | 2002-08-06 | 2004-04-15 | Peak-Werkstoff Gmbh | Gussverbund von Hohlprofilen aus Leichtmetall-Legierung und Verfahren zu seiner Herstellung |
DE10239522B4 (de) * | 2002-08-23 | 2016-02-11 | Leica Geosystems Ag | Halteeinrichtung für ein optisches Element |
DE102006023690A1 (de) * | 2006-05-19 | 2007-11-22 | Schaeffler Kg | Verfahren zur Herstellung eines Wälzlagerbauteils sowie Wälzlagerbauteil |
DE102006051544A1 (de) * | 2006-11-02 | 2008-05-08 | Schaeffler Kg | Wälzlagerbauteil mit wälzfester Oberfläche und schwingungsdämpfendem Kern, sowie Verfahren zu dessen Herstellung |
DE102007003135B3 (de) * | 2007-01-16 | 2008-03-06 | Peak Werkstoff Gmbh | Verfahren zur Herstellung eines Zylinderkurbelgehäuses mit mehreren Zylinderlaufbuchsen sowie kurze Zylinderlaufbuchse mit daran festgelegtem Materialstreifen |
US8775270B2 (en) * | 2008-05-30 | 2014-07-08 | Sky Castle Global Limited | Method and system for providing online services and software through scratchcards |
US20100089315A1 (en) * | 2008-09-22 | 2010-04-15 | Applied Materials, Inc. | Shutter disk for physical vapor deposition chamber |
US20100224290A1 (en) * | 2009-03-09 | 2010-09-09 | Honda Motor Co., Ltd. | Aluminum alloy casting and method for producing the same, and apparatus for producing slide member |
DE102012006121A1 (de) * | 2012-03-26 | 2013-09-26 | Erbslöh Aluminium Gmbh | Lotpulver |
US9845764B2 (en) * | 2015-03-31 | 2017-12-19 | Achates Power, Inc. | Cylinder liner for an opposed-piston engine |
CN107058739B (zh) * | 2017-01-22 | 2018-08-07 | 哈尔滨理工大学 | 一种过共晶铝硅复合材料及其制造方法、应用 |
CN107813104B (zh) * | 2017-09-07 | 2019-02-01 | 马鞍山市新马精密铝业股份有限公司 | 汽车气弹簧用铝合金组合管件的制造方法 |
CN108842041A (zh) * | 2018-07-13 | 2018-11-20 | 宁国市正兴耐磨材料有限公司 | 一种可用于研磨强氧化性材料的多层耐磨球及其制备方法 |
CN114683535A (zh) * | 2020-12-28 | 2022-07-01 | 扬诚精密医材股份有限公司 | 三维打印设备 |
CN114669617B (zh) * | 2022-05-27 | 2022-08-26 | 江苏中天科技股份有限公司 | 一种特耐热铝合金耐张管材 |
Family Cites Families (65)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE810223C (de) * | 1949-04-14 | 1951-08-06 | Deutsche Edelstahlwerke Ag | Verfahren zur Herstellung metallischer Formkoerper |
US3325279A (en) * | 1965-12-03 | 1967-06-13 | Dow Chemical Co | Aluminum-high silicon alloys |
BE790453A (fr) * | 1971-10-26 | 1973-02-15 | Brooks Reginald G | Fabrication d'articles en metal |
GB1431895A (en) * | 1972-06-30 | 1976-04-14 | Alcan Res & Dev | Production of aluminium alloy products |
CA1017601A (fr) * | 1973-04-16 | 1977-09-20 | Comalco Aluminium (Bell Bay) Limited | Alliages d'aluminium pour moteurs a combustion interne |
US4155756A (en) * | 1976-03-10 | 1979-05-22 | Societe De Vente De L'aluminium Pechiney | Hollow bodies produced by powder extrusion of aluminum-silicon alloys |
FR2343895A1 (fr) * | 1976-03-10 | 1977-10-07 | Pechiney Aluminium | Procede de fabrication de corps creux en alliages d'aluminium au silicium par filage de grenailles |
US4135922A (en) * | 1976-12-17 | 1979-01-23 | Aluminum Company Of America | Metal article and powder alloy and method for producing metal article from aluminum base powder alloy containing silicon and manganese |
JPS57198237A (en) * | 1981-05-29 | 1982-12-04 | Riken Corp | Sliding member made of aluminum alloy and its manufacture |
US4464146A (en) * | 1982-05-17 | 1984-08-07 | Imperial Clevite Inc. | Apparatus for maintaining tension of an endless drive member |
FR2537654B2 (fr) * | 1982-06-17 | 1987-01-30 | Pechiney Aluminium | Perfectionnement des chemises de moteurs a base d'alliages d'aluminium et de grains de silicium calibres et leurs procedes d'obtention |
CA1230761A (fr) * | 1982-07-12 | 1987-12-29 | Fumio Kiyota | Poudre d'alliage d'aluminium a haute resistance a la chaleur et a l'usure, et element connexe |
US4486470A (en) * | 1982-09-29 | 1984-12-04 | Teledyne Industries, Inc. | Casting and coating with metallic particles |
FR2537655A1 (fr) * | 1982-12-09 | 1984-06-15 | Cegedur | Chemises de moteurs a base d'alliages d'aluminium et de composes intermetalliques et leurs procedes d'obtention |
CH665223A5 (de) * | 1984-03-16 | 1988-04-29 | Showa Aluminium Co Ltd | Extrudierte aluminiumlegierung mit hoher verschleissresistenz und verfahren zur herstellung derselben. |
DE3435460A1 (de) * | 1984-09-27 | 1986-04-10 | M.A.N. Maschinenfabrik Augsburg-Nürnberg AG, 8000 München | Verfahren zur herstellung von werkstuecken aus leichtmetall |
NO850403L (no) * | 1985-02-01 | 1986-08-04 | Ingard Kvernes | Aluminiumbasert artikkel med beskyttelsesbelegg og fremgangsmaate til fremstilling derav. |
FR2576913B1 (fr) * | 1985-02-01 | 1987-02-27 | Cegedur | Procede d'obtention par la metallurgie des poudres d'un materiau a base d'alliage d'aluminium et d'au moins une ceramique destine a la confection de pieces soumises a frottement |
DE3511555A1 (de) * | 1985-03-29 | 1986-10-09 | Kolbenschmidt AG, 7107 Neckarsulm | Bauteile aus aluminium-legierungen fuer brennkraftmaschinen |
JPS61291941A (ja) * | 1985-06-19 | 1986-12-22 | Taiho Kogyo Co Ltd | Si含有量が高いAl鋳造合金 |
ATE67796T1 (de) * | 1985-11-12 | 1991-10-15 | Osprey Metals Ltd | Herstellen von schichten durch zerstaeuben von fluessigen metallen. |
JP2787466B2 (ja) * | 1988-05-12 | 1998-08-20 | 住友電気工業株式会社 | 大径の製品用アルミニウム合金の成形方法 |
CA1327153C (fr) * | 1988-10-07 | 1994-02-22 | Haruo Shiina | Dispositif de retenue de ressort de soupape de moteur a combustion interne |
EP0366134B1 (fr) * | 1988-10-27 | 1994-01-19 | Toyo Aluminium Kabushiki Kaisha | Alliage d'aluminium utile pour les procédés de la métallurgie de poudres |
JPH0621309B2 (ja) * | 1988-10-31 | 1994-03-23 | 本田技研工業株式会社 | 耐熱性、耐摩耗性、高靭性Al−Si系合金及びそれを使用したシリンダ−ライナ− |
US5022455A (en) * | 1989-07-31 | 1991-06-11 | Sumitomo Electric Industries, Ltd. | Method of producing aluminum base alloy containing silicon |
JP2761085B2 (ja) * | 1990-07-10 | 1998-06-04 | 昭和電工株式会社 | Al−Si系合金粉末焼結部品用の原料粉末および焼結部品の製造方法 |
WO1992007676A1 (fr) * | 1990-10-31 | 1992-05-14 | Sumitomo Electric Industries, Ltd. | Poudre a base d'un alliage aluminium/silicium hypereutectique et production de cette poudre |
US5196471A (en) * | 1990-11-19 | 1993-03-23 | Sulzer Plasma Technik, Inc. | Thermal spray powders for abradable coatings, abradable coatings containing solid lubricants and methods of fabricating abradable coatings |
DE4111509A1 (de) * | 1991-04-09 | 1992-10-15 | Austria Metall | Verfahren zum herstellen von strangpressprofilteilen |
US5080056A (en) * | 1991-05-17 | 1992-01-14 | General Motors Corporation | Thermally sprayed aluminum-bronze coatings on aluminum engine bores |
CH683267A5 (de) * | 1991-06-10 | 1994-02-15 | Alusuisse Lonza Services Ag | Verfahren zum Aufheizen eines Werkstückes aus einer Metallegierung. |
JP2703840B2 (ja) * | 1991-07-22 | 1998-01-26 | 東洋アルミニウム 株式会社 | 高強度の過共晶A1―Si系粉末冶金合金 |
US5372775A (en) * | 1991-08-22 | 1994-12-13 | Sumitomo Electric Industries, Ltd. | Method of preparing particle composite alloy having an aluminum matrix |
US5435825A (en) * | 1991-08-22 | 1995-07-25 | Toyo Aluminum Kabushiki Kaisha | Aluminum matrix composite powder |
JP2965774B2 (ja) * | 1992-02-13 | 1999-10-18 | ワイケイケイ株式会社 | 高強度耐摩耗性アルミニウム合金 |
DE4212716A1 (de) * | 1992-04-16 | 1993-10-21 | Ks Aluminium Technologie Ag | Verfahren zur Herstellung von Zylindern oder Zylinderblöcken |
US5460775A (en) * | 1992-07-02 | 1995-10-24 | Sumitomo Electric Industries, Ltd. | Nitrogen-combined aluminum sintered alloys and method of producing the same |
DE4230228C1 (de) * | 1992-09-10 | 1994-05-11 | Honsel Werke Ag | Bauteil aus einer Leichtmetallgußlegierung |
JPH06172893A (ja) * | 1992-09-29 | 1994-06-21 | Matsuda Micron Kk | 耐摩耗性に優れた摺接部材及びその製造方法 |
DE69307848T2 (de) * | 1992-12-03 | 1997-08-21 | Toyota Motor Co Ltd | Hoch warmfeste und verschleissfeste Aluminiumlegierung |
CA2112441C (fr) * | 1992-12-29 | 2005-08-09 | Tomiyoshi Kanai | Materiau d'aluminium apte au brasage et resistant a la corrosion et methode de production connexe |
JPH06211396A (ja) * | 1993-01-13 | 1994-08-02 | Toray Ind Inc | テンタのクリップチェーンモニタリング方法及び装置 |
JPH06211395A (ja) * | 1993-01-18 | 1994-08-02 | Mitsubishi Electric Corp | 用紙自動装填装置のピンチローラ機構 |
JP3184367B2 (ja) * | 1993-05-24 | 2001-07-09 | 住友軽金属工業株式会社 | 高靭性Al−Si系合金の製造方法 |
GB9311618D0 (en) * | 1993-06-04 | 1993-07-21 | Brico Eng | Aluminium alloys |
DE59408129D1 (de) * | 1993-07-22 | 1999-05-27 | Alusuisse Lonza Services Ag | Strangpressverfahren |
US5514480A (en) * | 1993-08-06 | 1996-05-07 | Aisin Seiki Kabushiki Kaisha | Metal-based composite |
DE4328093C2 (de) * | 1993-08-20 | 1998-04-02 | Ae Goetze Gmbh | Verfahren zur Herstellung von Motorblöcken für Verbrennungskraftmaschinen aus einer Leichtmetallegierung mit verschleißfest ausgekleideten Zylinderbohrungen |
GB2284461B (en) * | 1993-12-04 | 1996-06-26 | Ae Piston Products | Fibre-reinforced metal pistons for diesel engines |
DE4404420C2 (de) * | 1994-02-11 | 1997-07-17 | Alcan Gmbh | Aluminium-Silicium-Legierung und ihre Verwendung |
US5545487A (en) * | 1994-02-12 | 1996-08-13 | Hitachi Powdered Metals Co., Ltd. | Wear-resistant sintered aluminum alloy and method for producing the same |
DE4406191A1 (de) * | 1994-02-25 | 1995-09-07 | Ks Aluminium Technologie Ag | Gleitlagerung |
JP3378342B2 (ja) * | 1994-03-16 | 2003-02-17 | 日本軽金属株式会社 | 耐摩耗性に優れたアルミニウム鋳造合金及びその製造方法 |
JP3280516B2 (ja) * | 1994-05-20 | 2002-05-13 | 株式会社ユニシアジェックス | 内燃機関のピストン及びその製造方法 |
DE4418750C2 (de) * | 1994-05-28 | 2000-06-15 | Vaw Ver Aluminium Werke Ag | Verfahren zur Herstellung von verschleißfesten Oberflächen auf Formgußteilen |
JP3547098B2 (ja) * | 1994-06-06 | 2004-07-28 | トヨタ自動車株式会社 | 溶射方法、溶射層を摺動面とする摺動部材の製造方法、ピストンおよびピストンの製造方法 |
EP0704613A1 (fr) * | 1994-09-28 | 1996-04-03 | KS Aluminium Technologie Aktiengesellschaft | Cylindre ou bloc-cylindres coulé de manière composite |
US6096143A (en) * | 1994-10-28 | 2000-08-01 | Daimlerchrysler Ag | Cylinder liner of a hypereutectic aluminum/silicon alloy for use in a crankcase of a reciprocating piston engine and process for producing such a cylinder liner |
GB9517045D0 (en) * | 1995-08-19 | 1995-10-25 | Gkn Sankey Ltd | Method of manufacturing a cylinder block |
DE19532253C2 (de) * | 1995-09-01 | 1998-07-02 | Peak Werkstoff Gmbh | Verfahren zur Herstellung von dünnwandigen Rohren (II) |
DE19532244C2 (de) * | 1995-09-01 | 1998-07-02 | Peak Werkstoff Gmbh | Verfahren zur Herstellung von dünnwandigen Rohren (I) |
JPH09151782A (ja) * | 1995-11-29 | 1997-06-10 | Toyota Motor Corp | シリンダブロックの製造方法 |
DE19733204B4 (de) * | 1997-08-01 | 2005-06-09 | Daimlerchrysler Ag | Beschichtung aus einer übereutektischen Aluminium/Silizium Legierung, Spritzpulver zu deren Herstellung sowie deren Verwendung |
DE19841619C2 (de) * | 1998-09-11 | 2002-11-28 | Daimler Chrysler Ag | Werkstoffdraht zur Erzeugung verschleißfester Beschichtungen aus übereutektischen Al/Si-Legierungen durch thermisches Spritzen und seine Verwendung |
-
1995
- 1995-09-01 DE DE19532252A patent/DE19532252C2/de not_active Expired - Fee Related
-
1996
- 1996-08-28 CN CN96196545A patent/CN1066493C/zh not_active Expired - Fee Related
- 1996-08-28 US US09/029,767 patent/US6136106A/en not_active Expired - Lifetime
- 1996-08-28 EP EP96930115A patent/EP0871791B1/fr not_active Expired - Lifetime
- 1996-08-28 JP JP51082697A patent/JP3664315B2/ja not_active Expired - Fee Related
- 1996-08-28 BR BR9610546A patent/BR9610546A/pt not_active IP Right Cessation
- 1996-08-28 PT PT96930115T patent/PT871791E/pt unknown
- 1996-08-28 AT AT96930115T patent/ATE197821T1/de active
- 1996-08-28 ES ES96930115T patent/ES2152560T3/es not_active Expired - Lifetime
- 1996-08-28 DE DE59606173T patent/DE59606173D1/de not_active Expired - Lifetime
- 1996-08-28 WO PCT/EP1996/003780 patent/WO1997009459A1/fr active IP Right Grant
- 1996-08-28 DK DK96930115T patent/DK0871791T3/da active
- 1996-08-28 KR KR1019980701213A patent/KR100258754B1/ko not_active IP Right Cessation
-
2000
- 2000-03-01 US US09/516,804 patent/US6485681B1/en not_active Expired - Fee Related
-
2001
- 2001-02-06 GR GR20010400195T patent/GR3035368T3/el unknown
Non-Patent Citations (1)
Title |
---|
See references of WO9709459A1 * |
Also Published As
Publication number | Publication date |
---|---|
JPH11501991A (ja) | 1999-02-16 |
ATE197821T1 (de) | 2000-12-15 |
WO1997009459A1 (fr) | 1997-03-13 |
US6136106A (en) | 2000-10-24 |
JP3664315B2 (ja) | 2005-06-22 |
PT871791E (pt) | 2001-03-30 |
CN1066493C (zh) | 2001-05-30 |
CN1194014A (zh) | 1998-09-23 |
DE19532252A1 (de) | 1997-03-06 |
KR19990043982A (ko) | 1999-06-25 |
EP0871791B1 (fr) | 2000-11-29 |
ES2152560T3 (es) | 2001-02-01 |
DK0871791T3 (da) | 2000-12-27 |
GR3035368T3 (en) | 2001-05-31 |
US6485681B1 (en) | 2002-11-26 |
BR9610546A (pt) | 1999-07-06 |
DE19532252C2 (de) | 1999-12-02 |
DE59606173D1 (de) | 2001-01-04 |
KR100258754B1 (ko) | 2000-06-15 |
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