EP0652300B1 - Randaufsticken zur Erzeugung einer hochfesten austenitischen Randschicht in nichtrostenden Stählen - Google Patents

Randaufsticken zur Erzeugung einer hochfesten austenitischen Randschicht in nichtrostenden Stählen Download PDF

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Publication number
EP0652300B1
EP0652300B1 EP94114659A EP94114659A EP0652300B1 EP 0652300 B1 EP0652300 B1 EP 0652300B1 EP 94114659 A EP94114659 A EP 94114659A EP 94114659 A EP94114659 A EP 94114659A EP 0652300 B1 EP0652300 B1 EP 0652300B1
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EP
European Patent Office
Prior art keywords
nitrogen
nitriding
skin
austenitic
case
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
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EP94114659A
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German (de)
English (en)
French (fr)
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EP0652300A1 (de
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Hans Prof. Dr.-Ing. Berns
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    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D6/00—Heat treatment of ferrous alloys
    • C21D6/002—Heat treatment of ferrous alloys containing Cr
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/24—Nitriding
    • C23C8/26—Nitriding of ferrous surfaces

Definitions

  • the invention relates to a heat treatment process for forming an austenitic surface layer with ⁇ 0.30 wt.% Of dissolved nitrogen in near net shape parts of stainless steel by nitriding at a temperature between 1000 ° C and 1200 ° C in a nitrogen-containing gas atmosphere.
  • a heat treatment process of the aforementioned type is known from DE-A-25 18 452 known. So revealed the DE-A-25 18 452 a process for austenitizing an iron alloy containing about 21 to 45% manganese and about 10 to 30% chromium, wherein the surface of the solid state alloy is at a temperature of at least 927 ° C above a nitrogen content at least in the surface of about 0.85 to 3% sufficient period of exposure to nitrogen exposure.
  • the manganese content in the with the help of from the DE-A-25 18 452 known alloys heat treatment process is 21 to 45%. Since manganese is an austenite and increases the solubility of nitrogen in the steel, amounts greater than 21% are required.
  • a heat treatment process for forming an austenitic surface layer with ⁇ 0.30 wt.% of dissolved nitrogen in near-net shape parts of X5 CrNiMo 17 12 2 or X2 CrNiMoN 22 5 3 is proposed as stainless steel, by nitriding at a Temperature between 1000 ° C and 1200 ° C in a nitrogen-containing gas atmosphere and subsequent cooling at a rate such that nitride precipitation is avoided.
  • the present invention dispenses with a consistently high nitrogen content in the steel. Instead, only the edge zone of stainless steel parts close to the final shape is enriched with dissolved nitrogen by a heat treatment so that a high-strength but tough austenitic surface layer forms over a core structure of ferrite, austenite, martensite or a mixture of two or three of these structural components.
  • the heat treatment according to the invention consists of a nitridation in a nitrogen-emitting gas atmosphere at a temperature between 1000 and 1200 ° C.
  • Temperature, pressure and duration of the treatment are chosen so as to form a surface layer of certain thickness, the nitrogen content of which in the surface is between a lower limit of 0.3% by weight and an upper limit given by incipient nitride precipitation during nitriding.
  • the subsequent cooling takes place so quickly that even in this period no nitride precipitation occurs.
  • the invention is a heat treatment process for forming an austenitic surface layer with ⁇ 0.30 wt
  • Nitrogen in near-net shape parts of X5 CrNiMo 17 12 2 or X2 CrNiMoN 22 5 3 by embossing at a temperature of between 1,000 ° C and 1,200 ° C in a nitrogen-containing gas atmosphere and subsequent cooling at such a rate as to avoid nitride precipitation is proposed. It is stabilized by the inward diffusion of nitrogen de austenitic phase in the boundary layer, so that martensitic or ferritic microstructures in the edge zone to austenite.
  • the strength of the surface layer is increased by the solid solution hardening of the austenite with nitrogen without embrittlement occurring. Due to the achieved combination of strength and toughness, the austenitic surface layer according to the invention is suitable for increasing the wear resistance, in particular in the case of stress due to impact wear. Cavitation and drop impact, as occurs, for example, in turbomachines.
  • Ferritic-austenitic stainless duplex steels are often used for high-speed pump wheels in aggressive media. Their biphasic structure has the required high insertion limit. A common type of failure is cavitation wear. As can be seen from Fig. 2, a content of 1.4 wt.% Nitrogen in the peripheral zone of this material is achieved by embroidering in nitrogen gas at 1150 ° C and a pressure of 1 bar. After cooling, a fully austenitic edge layer can be seen over a ferrite-austenitic core structure in FIG. 3. This edge layer was subjected to a Kavitationsverschl employ phenomenon compared to the non-embroidered core material.
  • a bubble field is generated by an ultrasound oscillator at 20 kHz and an amplitude of 40 ⁇ m in distilled water, which leads to implosions on the sample surface.
  • the amount of wear is shown as weight loss over the load duration in FIG.
  • a wear rate of 0.0358 (mg / 10 3 s) results for the non-embroidered steel it is 1.53 (mg / 10 3 s). Due to the edge attachment, a decrease of the wear rate by a factor of 43 is achieved. From the example of a current density potential curve, it can be seen from FIG. 5 that the resistance to wet corrosion in artificial seawater is slightly improved by the edge impacting. At approximately the same passive current density results for the embroidered sample an increase in the breakdown potential compared to the non-embroidered sample.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
  • Heat Treatment Of Articles (AREA)
EP94114659A 1993-10-05 1994-09-17 Randaufsticken zur Erzeugung einer hochfesten austenitischen Randschicht in nichtrostenden Stählen Expired - Lifetime EP0652300B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4333917A DE4333917C2 (de) 1993-10-05 1993-10-05 Randaufsticken zur Erzeugung einer hochfesten austenitischen Randschicht in nichtrostenden Stählen
DE4333917 1993-10-05

Publications (2)

Publication Number Publication Date
EP0652300A1 EP0652300A1 (de) 1995-05-10
EP0652300B1 true EP0652300B1 (de) 2007-11-28

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Application Number Title Priority Date Filing Date
EP94114659A Expired - Lifetime EP0652300B1 (de) 1993-10-05 1994-09-17 Randaufsticken zur Erzeugung einer hochfesten austenitischen Randschicht in nichtrostenden Stählen

Country Status (9)

Country Link
US (1) US5503687A (cs)
EP (1) EP0652300B1 (cs)
JP (1) JPH07188733A (cs)
CN (1) CN1058758C (cs)
CZ (1) CZ240094A3 (cs)
DE (1) DE4333917C2 (cs)
ES (1) ES2296286T3 (cs)
PL (1) PL178509B1 (cs)
RU (1) RU2127330C1 (cs)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4382627A4 (en) * 2021-08-02 2024-10-02 NIPPON STEEL Chemical & Material Co., Ltd. STAINLESS STEEL SHEET, SEPARATOR FOR FUEL BATTERY, FUEL BATTERY CELL AND FUEL BATTERY STACK

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1036945A (ja) * 1996-07-19 1998-02-10 Nippon Steel Corp ねじ込み性に優れた高耐銹性マルテンサイト系ステンレス製ドリリングタッピンねじ及びその焼入方法
US5851313A (en) * 1996-09-18 1998-12-22 The Timken Company Case-hardened stainless steel bearing component and process and manufacturing the same
DE19729984A1 (de) * 1997-07-12 1999-01-14 Ipsen Ind Int Gmbh Verfahren zum Aufsticken der Randschicht metallischer Werkstücke
AU8351898A (en) * 1997-07-21 1999-02-16 Nsk Rhp European Technology Co. Limited Case hardening of steels
JP4252145B2 (ja) * 1999-02-18 2009-04-08 新日鐵住金ステンレス株式会社 耐遅れ破壊性に優れた高強度・高靭性ステンレス鋼
RU2184175C2 (ru) * 2000-08-14 2002-06-27 Институт прикладной механики Уральского отделения РАН Способ термической обработки для формирования аустенита в железо-хромистых сплавах
CN100439553C (zh) * 2002-07-29 2008-12-03 皇家飞利浦电子股份有限公司 马氏体时效型钢的等离子渗氮、电动剃须刀的剃刀盖、用该钢制造的切削器具以及一种电动剃须刀
JP4009716B2 (ja) * 2002-08-08 2007-11-21 独立行政法人物質・材料研究機構 窒素吸収処理によるステンレス鋼製製品の製造方法とこれにより得られるステンレス鋼製製品
JP4336784B2 (ja) * 2002-11-21 2009-09-30 独立行政法人物質・材料研究機構 生体軟組織用医療用具とその製造方法
DE102004048172A1 (de) * 2004-10-02 2006-04-06 Ina-Schaeffler Kg Spanlos hergestelltes dünnwandiges rostfreies Lagerbauteil insbesondere Wälzlagerbauteil
JP4378773B2 (ja) 2005-05-16 2009-12-09 独立行政法人物質・材料研究機構 ステンレス鋼製製品の製造方法とそのステンレス鋼製製品
CN101198714B (zh) * 2005-06-15 2011-07-20 皇家飞利浦电子股份有限公司 制造不锈钢产品的方法
JP2007248397A (ja) * 2006-03-17 2007-09-27 Seiko Epson Corp 装飾品および時計
US7793416B2 (en) 2006-05-15 2010-09-14 Viking Pump, Inc. Methods for hardening pump casings
RU2324001C1 (ru) * 2006-07-06 2008-05-10 Государственное образовательное учреждение высшего профессионального образования Уфимский государственный авиационный технический университет Способ термической и химико-термической обработки стальных изделий в вакууме
CN101186992B (zh) * 2006-11-16 2010-11-17 有限会社结城高周波 渗氮淬火制品及其制造方法
DE502007000645D1 (de) 2007-02-02 2009-06-04 Wmf Ag Ess- und/oder Servierbesteck aus ferritischem Edelstahl mit einer martensitischen Randschicht
JP5212602B2 (ja) * 2007-09-14 2013-06-19 セイコーエプソン株式会社 機器およびハウジング材の製造方法
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DE202008015481U1 (de) 2008-10-08 2009-06-18 Barth, Peter, Dr. Schmucksachen aus Edelstahl mit einer martensitischen Randschicht
WO2010040333A1 (de) * 2008-10-08 2010-04-15 Peter Barth Biokompatibler werkstoff aus edelstahl mit einer martensitischen randschicht
DE102009005578A1 (de) 2009-01-21 2010-07-22 Barth, Peter, Dr. Medizinische Instrumente aus Edelstahl mit einer martensitischen Randschicht
JP2009142664A (ja) * 2009-02-04 2009-07-02 National Institute For Materials Science 生体軟組織用医療用具とその製造方法
DE102009053260B4 (de) * 2009-11-05 2011-09-01 Salzgitter Flachstahl Gmbh Verfahren zum Beschichten von Stahlbändern und beschichtetes Stahlband
CA2833579C (en) 2011-04-28 2019-09-17 Expanite A/S Method for solution hardening of a cold deformed workpiece of a passive alloy, and a member solution hardened by the method.
DE102011077368A1 (de) 2011-06-10 2012-12-13 BSH Bosch und Siemens Hausgeräte GmbH Haushaltsgerät mit einem wärmebehandelten Haushaltsgeräte-Bauteil
FR2980804B1 (fr) 2011-09-30 2014-06-27 Areva Np Procede de realisation a partir d'une ebauche en acier inoxydable austenitique a faible teneur en carbone d'une gaine resistant a l'usure et a la corrosion pour reacteur nucleaire, gaine et grappe de commande correspondantes
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US9309895B2 (en) 2012-06-18 2016-04-12 Kennametal Inc. Closed impeller with a coated vane
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Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3708956C1 (de) * 1987-03-19 1988-03-17 Handtmann Albert Elteka Gmbh Spaltringdichtung einer Kreiselpumpe

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3943010A (en) * 1974-06-12 1976-03-09 Allegheny Ludlum Industries, Inc. Process for producing austenitic ferrous alloys
SU584044A1 (ru) * 1975-12-01 1977-12-15 Предприятие П/Я А-1147 Способ термической обработки деталей из нержавеющих мартенситностареющих сталей
JPS5277836A (en) * 1975-12-23 1977-06-30 Fujikoshi Kk Surface treatment of martensitic stainless steel
DE2610224C2 (de) * 1976-03-11 1983-01-05 Fa. Hermann C. Starck Berlin, 1000 Berlin Verfahren zur Herstellung von porösen Anodenkörpern durch Pressen und Sintern von Pulvern aus Ventilmetallen
JPS60159116A (ja) * 1984-01-27 1985-08-20 Toyota Motor Corp 焼入性と強靭性の良好な鋼部品の製造方法
DE4033706A1 (de) * 1990-10-24 1991-02-21 Hans Prof Dr Ing Berns Einsatzhaerten mit stickstoff zur verbesserung des korrosionswiderstandes martensitischer nichtrostender staehle
DE4036381C1 (cs) * 1990-11-15 1991-08-14 Degussa Ag, 6000 Frankfurt, De
JPH05222512A (ja) * 1991-09-05 1993-08-31 Aimetsukusu Kk オーステナイト系ステンレス鋼における耐摩耗性を向上させた高温窒化処理方法とその応用

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3708956C1 (de) * 1987-03-19 1988-03-17 Handtmann Albert Elteka Gmbh Spaltringdichtung einer Kreiselpumpe

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP4382627A4 (en) * 2021-08-02 2024-10-02 NIPPON STEEL Chemical & Material Co., Ltd. STAINLESS STEEL SHEET, SEPARATOR FOR FUEL BATTERY, FUEL BATTERY CELL AND FUEL BATTERY STACK

Also Published As

Publication number Publication date
DE4333917C2 (de) 1994-06-23
PL178509B1 (pl) 2000-05-31
PL305287A1 (en) 1995-04-18
CZ240094A3 (en) 1995-08-16
US5503687A (en) 1996-04-02
DE4333917A1 (de) 1994-03-24
JPH07188733A (ja) 1995-07-25
CN1107187A (zh) 1995-08-23
ES2296286T3 (es) 2008-04-16
RU94035767A (ru) 1997-04-20
RU2127330C1 (ru) 1999-03-10
CN1058758C (zh) 2000-11-22
EP0652300A1 (de) 1995-05-10

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