EP0514383B1 - Procede et installation de reconstitution du revetement refractaire de poches de coulee - Google Patents
Procede et installation de reconstitution du revetement refractaire de poches de coulee Download PDFInfo
- Publication number
- EP0514383B1 EP0514383B1 EP91901674A EP91901674A EP0514383B1 EP 0514383 B1 EP0514383 B1 EP 0514383B1 EP 91901674 A EP91901674 A EP 91901674A EP 91901674 A EP91901674 A EP 91901674A EP 0514383 B1 EP0514383 B1 EP 0514383B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- lining
- ladle
- slag
- old
- refractory
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title claims abstract description 13
- 238000009434 installation Methods 0.000 title claims 2
- 239000002893 slag Substances 0.000 claims abstract description 32
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 12
- 239000010959 steel Substances 0.000 claims abstract description 12
- 238000005266 casting Methods 0.000 claims abstract description 10
- 238000001816 cooling Methods 0.000 claims abstract 2
- 238000007788 roughening Methods 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 3
- 239000002344 surface layer Substances 0.000 claims description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- 238000005096 rolling process Methods 0.000 claims description 2
- 230000003014 reinforcing effect Effects 0.000 claims 1
- 239000010410 layer Substances 0.000 description 9
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 230000009974 thixotropic effect Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000011324 bead Substances 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 239000011819 refractory material Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 235000004443 Ricinus communis Nutrition 0.000 description 1
- 240000000528 Ricinus communis Species 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/02—Linings
- B22D41/023—Apparatus used for making or repairing linings
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F27—FURNACES; KILNS; OVENS; RETORTS
- F27D—DETAILS OR ACCESSORIES OF FURNACES, KILNS, OVENS OR RETORTS, IN SO FAR AS THEY ARE OF KINDS OCCURRING IN MORE THAN ONE KIND OF FURNACE
- F27D1/00—Casings; Linings; Walls; Roofs
- F27D1/16—Making or repairing linings ; Increasing the durability of linings; Breaking away linings
- F27D1/1694—Breaking away the lining or removing parts thereof
Definitions
- the invention relates to a method of the type corresponding to the preamble of claim 1 and a system according to the preamble of claim 2.
- metallurgical vessels have been increasingly no longer lined with refractory bricks, but with the help of a casting technique in which the space between a template or shape that determines the desired clear interior of the pan or other metallurgical vessel is determined. and a mostly thixotropic fireproof casting compound is filled into the vessel wall to be delivered, which, due to its thixotropic behavior, is very free-flowing under the influence of vibrations (usually the template or shape) even at low water contents and fills every cavity.
- the tools follow the large contours of the old infeed.
- the template is again introduced into the metallurgical vessel with the old delivery cleaned in this way, whereupon the space between the template and the old delivery is filled again with thixotropic casting compound under the action of vibrations. In this way, up to 50% of the expensive delivery material can be saved.
- the previous treatment of the surface of the old inlay results in a good bond to the newly applied refractory mass.
- the invention has for its object to be able to restore the refractory lining of metallurgical vessels in an economical manner even in such cases.
- a high-temperature burner with a water-cooled lance which can be moved up and down and rotated, can be moved on rails in the depth direction of the pan, so that the burner can be guided spirally and helically at a suitable distance over the inner surface of the pan.
- the burner works with gas or oil and oxygen and can be operated in such a way that it works in a reducing manner, ie it does not develop brown fumes.
- the burner lance can be guided in a circle so that the adhering slag, slag steel mixtures or steel residues become highly liquid in the floor and wall area and flow out of the inclined lower area of the pan from its mouth to the outside, where it flows into a slag bucket or get into a sand bed. In this way, the pan is cleaned within a few minutes.
- All that remains on the old refractory lining is a thin, glass-like, smooth slag coating, which is roughened mechanically after the pan has cooled down in order to achieve a good primer for the new lining material.
- the roughening can be done by the above-mentioned slag peeling robot, which partially or completely removes the slag layer and in any case leaves a rough surface of the old delivery.
- the template is then reinserted into the pan according to the method already known and the space between the template and the surface of the remaining lining is filled with new casting compound.
- the infeed can be restored in the shortest possible time without great mechanical stress on the permanent feed and without extensive stripping work.
- a burner operated with oxygen has flame temperatures in the range of 3000 ° C.
- the one in the pan Remaining materials to be removed, such as slag, flake steel mixtures or steel residues, have melting points in the range from approximately 1000 to 1500 °.
- the temperature of the pan is still very high from the last pour, so that the burner does not have to heat the pan from ambient temperature. Rather, the burner only has to generate the last temperature peak in order to liquefy the total amount of undesirable constituents adhering to the surface, which is accomplished in a short time.
- burners come into consideration which have features of DE-PS 15 29 201 and 31 51 479 in particular with regard to the burner nozzle.
- the roughening device is used, which is known from DE-OS 37 41 073.
- A reveals a freshly delivered ladle 10, which consists of a pot-shaped housing 1 made of sheet steel that tapers slightly downwards, on the inside of which a so-called delivery or lining made of refractory material is applied, essentially of a constant thickness of a few 10 centimeters.
- the pan 10 can be gripped and displaced by the overhead crane on side lugs 3 in the upper region.
- the steel is subjected to a metallurgical treatment, for example by blowing in oxygen, argon or the like, and then poured off.
- a metallurgical treatment for example by blowing in oxygen, argon or the like, and then poured off.
- the slag is poured off and the delivery of the pan 10 looks as indicated in B.
- the infeed is beared, ie thick slag layers or beads have set up, as is indicated by the cross-hatching that represents the slag S.
- Steel residues or steel slag mixtures can also be present.
- Thinner slag layers also adhere in the areas 2 ′ or the surface areas of the infeed 2 of slag are penetrated to a certain depth, which reduces their fire resistance.
- the coarse beads on the upper edge of the pan are broken out with a suitable device, and the pan is then placed with the indoor crane lying on a stand 4 located nearby, that is to say as long as the delivery 2 is still glowing bright red from the last cast , so that the wall of the infeed 2 in its essentially cylindrical region makes an angle 5 of approximately 5 to 30 ° with the horizontal, the inclination being reproduced particularly strongly in the schematic representation of the exemplary embodiment.
- the opening 6 of the pan 10 points downwards.
- a carriage or carriage 7 is now brought up on rails, which carries a lance 8 with a high-temperature burner at the free end, which can be inserted into the interior of the pan 10 and can be pivoted both in the direction of arrow 11 and in the direction of arrow 12 as can also be moved into the pan 10 in the direction of arrow 13 in the longitudinal direction of the lance.
- the carriage or carriage 7 also carries a heat shield 14, which covers the opening 6 of the pan 10.
- the high-temperature burner 9 is operated with a suitable gaseous or liquid fuel and pure oxygen and generates flame temperatures in the range of 3000 ° C., which melts the still red-hot slag, the melting point of which is in the range of 1000-1500 ° C. the heat shield 14 avoids heat losses and prevents excessive radiation on the carriage 7.
- the melted slag flows downward from the opening 6 of the pan 10 in the direction of the arrows 15 into the slag bucket 16.
- the pan 10 has the opportunity to cool between phase C and phase D.
- the pan is placed in a pit 17 by means of the indoor crane.
- the slag robot 20 comprises a machine frame 18 which projects over the pan 10 and on which a vertical column 19 can be raised and lowered in the direction of the arrow 21 and rotatable about its longitudinal axis in the direction of the arrow 25.
- pivotable arms 22 are attached, at the free ends of which rotatable tools 23 are provided in the form of castors studded with hard metal pins 24, which follow the contour of the inner surface of the infeed 2 and under the action of vibrators a hammering attack Execute the slag layer and remove or at least roughen it without significantly changing the relief of the inner surface 26 and removing a lot of the healthy material of the delivery 2.
- phase E the slag robot is removed and instead a slightly conical template 27 is introduced into the interior of the pan 10 on a carrying device 28.
- the template 27 determines the inner surface configuration of the infeed 2, as can be seen from A.
- Refractory feed mass 30 introduced, which has a consistency like slightly damp sand, but becomes quasi liquid under the action of the vibrators 31 working against the template 27 and fills the entire space 32 between the template 27 and the inner surface 26 homogeneously.
- the refractory mass introduced into the intermediate space 32 is dried by means of a ladle fire 33 and combines with the old delivery to form a new compact and homogeneous delivery 2, so that the ladle 10 returns to phase A and again a ladle trip can compete.
- a high-temperature burner 9 In tests in a 95-ton steel pan with an inner diameter of approx. 2600 mm and an inner height of approx. 3440 mm, a high-temperature burner 9 was used, which has features of DE-PS 15 29 201 and 31 in particular with regard to the nozzle design 51 479 and was arranged with the mouth of the nozzle approximately in the middle of the clear interior of the pan, as shown in C.
- the high-temperature burner 9 was operated with approx. 280 Nm3 / h propane and 900 Nm3 / h oxygen without the addition of air. He worked for about 15 minutes until the slag had melted out sufficiently.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Furnace Housings, Linings, Walls, And Ceilings (AREA)
- Carbon Steel Or Casting Steel Manufacturing (AREA)
- Medicinal Preparation (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Coupling Device And Connection With Printed Circuit (AREA)
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
Claims (4)
- Procédé de reconstitution du revêtement réfractaire d'une poche de coulée (10) destinée à la coulée de l'acier et d'autres enceintes métallurgiques semblables, dans lequel après une campagne les scories adhérentes et éventuellement aussi les couches supérieures imprégnées de scories de l'ancien revêtement sont éliminées et un nouveau revêtement complémentaire (30) réfractaire est appliqué sur l'ancien revêtement (2) en un procédé de coulée, revêtement qui fournit avec l'ancien revêtement (2) un garnissage réfractaire complet dans l'épaisseur de paroi d'origine, caractérisé en ce que dans une poche de coulée (10) encore très chaude et se présentant avec une légère inclinaison vers l'extérieur, les scories encore adhérentes à la surface intérieure sont séparées par fusion du revêtement restant à l'aide d'un brûleur (9) pour hautes températures opérant avec de l'oxygène pur en milieu réducteur et sont amenées à s'écouler à l'état liquide en fusion hors de la poche (10), et en ce que après refroidissement, la surface vitreuse du revêtement restant est rendue rugueuse, à la suite de quoi a lieu l'application du nouveau revêtement réfractaire (30).
- Installation pour la reconstitution du revêtement réfractaire de poches de coulée pour la coulée de l'acier et d'autres enceintes métallurgiques analogues selon le procédé de la revendication 1, caractérisé par les parties d'installation suivantes :a) un support (4) sur lequel peut être mise en place la poche (10), en présentant toutefois une légère inclinaison (5) vers l'extérieur,b) un brûleur (9) pour hautes températures, à insérer dans la poche (10), apte à être guidé sur toute la surface intérieure (26) de la poche (10) sur une lance (8) pouvant pivoter, tourner et se déplacer dans le sens de la profondeur de la poche (10),c) un équipement (16) pour recevoir les scories liquides de fusion s'écoulant de l'ouverture (6) de la poche,d) un dispositif (20) pouvant être introduit dans la poche de coulée pour créer de la rugosité sur la surface du revêtement restant (2),e) un gabarit (27) à introduire dans la poche droite pour la forme interne du revêtement (2) et un dispositif d'alimentation (29), au moyen duquel on peut introduire la masse de revêtement (30) dans l'espace intermédiaire (32) entre la surface intérieure (26) de l'ancien revêtement (2) et le gabarit (27).
- Installation selon la revendication 2, caractérisée en ce qu'un écran thermique (14) est prévu pour isoler l'intérieur de la poche de l'extérieur lorsque le brûleur (9) pour hautes températures est introduit.
- Installation selon la revendication 2 ou la revendication 3, caractérisée en ce que le dispositif (20) pour créer la rugosité comprend des rouleaux (23) équipés de tétons en métal dur (24) et se trouvant soumis à des vibrations, rouleaux qui peuvent être guidés, en tournant sur des bras de support (22) et en suivant fidèlement le contour, sur la surface intérieure (26) de l'ancien revêtement (2).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4003646 | 1990-02-07 | ||
DE4003646A DE4003646C1 (fr) | 1990-02-07 | 1990-02-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0514383A1 EP0514383A1 (fr) | 1992-11-25 |
EP0514383B1 true EP0514383B1 (fr) | 1993-10-20 |
Family
ID=6399619
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP91901674A Expired - Lifetime EP0514383B1 (fr) | 1990-02-07 | 1991-01-14 | Procede et installation de reconstitution du revetement refractaire de poches de coulee |
Country Status (14)
Country | Link |
---|---|
US (1) | US5330690A (fr) |
EP (1) | EP0514383B1 (fr) |
JP (1) | JPH0798266B2 (fr) |
AT (1) | ATE96065T1 (fr) |
AU (1) | AU636704B2 (fr) |
BR (1) | BR9105928A (fr) |
CA (1) | CA2075484C (fr) |
DE (2) | DE4003646C1 (fr) |
DK (1) | DK0514383T3 (fr) |
ES (1) | ES2046886T3 (fr) |
GR (1) | GR1001444B (fr) |
TR (1) | TR26175A (fr) |
WO (1) | WO1991012103A1 (fr) |
ZA (1) | ZA91454B (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE4319393C1 (de) * | 1993-06-11 | 1994-06-01 | Chemikalien Ges Hans Lungmus M | Verfahren zum Herstellen von feuerfesten Tiegeln für Stahlbehandlungspfannen |
DE29503495U1 (de) * | 1995-03-02 | 1995-04-13 | Plibrico GmbH, 40210 Düsseldorf | Feuerfestauskleidung für Stahlpfannen |
US5624513A (en) * | 1995-06-14 | 1997-04-29 | United Technologies Corporation | Removal of inserts from the interiors of turbine airfoils |
US5783510A (en) * | 1995-07-04 | 1998-07-21 | Asahi Glass Company Ltd. | Monolithic refractory composition wall |
FR2778735A1 (fr) * | 1998-05-12 | 1999-11-19 | Basalt Refractaires France Sar | Procede et dispositif pour la rehabilitation de la maconnerie interne de four a chaux |
Family Cites Families (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1376935A (en) * | 1919-11-24 | 1921-05-03 | John O Griggs | Apparatus for and method of cutting drains in furnace-bottoms |
US3151200A (en) * | 1962-05-07 | 1964-09-29 | Atkinson Guy F Co | Ladle lining apparatus |
US3365523A (en) * | 1964-12-09 | 1968-01-23 | Union Carbide Corp | Method of removing encrusted slag from furnaces |
DE1529201B1 (de) * | 1965-11-04 | 1971-07-29 | Horst Ley | Zur industriellen verwendung vorgesehener gasbrenne |
AT274870B (de) * | 1966-10-11 | 1969-10-10 | Voest Ag | Lagerkonstruktion für kippbare Tiegel oder Konverter |
JPS496722A (fr) * | 1972-05-08 | 1974-01-21 | ||
US3944193A (en) * | 1972-08-26 | 1976-03-16 | Nippon Steel Corporation | Method and apparatus for forming by vibration a refractory lining of a container for a molten metal |
DE2247274C3 (de) * | 1972-09-27 | 1975-10-09 | Eisenwerk-Gesellschaft Maximilianshuette Mbh, 8458 Sulzbach-Rosenberg | Verfahren und Vorrichtung zum Eingießen von Stahl beim Stranggießen |
JPS5634811B2 (fr) * | 1974-09-19 | 1981-08-13 | ||
SU682320A1 (ru) * | 1977-03-22 | 1979-08-30 | Всесоюзный Научно-Исследовательский И Проектный Институт Алюминиевой Магниевой И Электродной Промышленности | Установка дл удалени футеровки из металлургической емкости |
JPS54137403A (en) * | 1978-04-18 | 1979-10-25 | Kurosaki Refractories Co | Scraping reairing method |
DE2821229A1 (de) * | 1978-05-16 | 1979-11-22 | Westermann Industrieplanung Gm | Schlackenraeumer |
US4190235A (en) * | 1978-08-15 | 1980-02-26 | Dell William C | Fluidized bed ladle heating method and apparatus |
US4223873A (en) * | 1979-03-21 | 1980-09-23 | The Cadre Corporation | Direct flame ladle heating method and apparatus |
NL173207C (nl) * | 1979-12-17 | 1983-12-16 | Estel Hoogovens Bv | Werkwijze voor het verwijderen van ijzeroxyde-houdende slakafzetting van de bodem van een nog hete oven voor een walserij voor staal. |
JPS5772758A (en) * | 1980-10-27 | 1982-05-07 | Nippon Steel Corp | Method for repairing tundish for continuous casting |
US4328959A (en) * | 1980-11-14 | 1982-05-11 | Gerwin Holtmann | Method and device for removing used refractory lining and/or slag deposits from elongated vessels |
DE3110403A1 (de) * | 1981-03-18 | 1982-10-07 | Philips Patentverwaltung Gmbh, 2000 Hamburg | "verfahren zur wiederaufarbeitung eines schmelztiegels" |
JPS586869A (ja) * | 1981-07-02 | 1983-01-14 | Mitsubishi Electric Corp | コイル材料の巻戻し制御方式 |
SU975809A1 (ru) * | 1981-07-07 | 1982-11-23 | Vni Pk T I Mekh Truda V Cherno | Машина для ломки футеровки сталеплавильных агрегатов· 1 |
DE3151479C2 (de) * | 1981-12-24 | 1985-09-05 | Horst 4630 Bochum Ley | Zur industriellen Verwendung ausgelegter Gasbrenner |
FR2525633A1 (fr) * | 1982-04-22 | 1983-10-28 | Siderurgie Fse Inst Rech | Procede pour ameliorer la duree de vie d'elements refractaires permeables loges dans le fond des recipients metallurgiques d'affinage, notamment des convertisseurs d'acierie a soufflage d'oxygene par le haut |
JPS60261653A (ja) * | 1984-06-08 | 1985-12-24 | Nippon Steel Corp | タンデイツシユ内張り材の手入れ方法 |
JPS61137656A (ja) * | 1984-12-07 | 1986-06-25 | Nippon Steel Corp | タンデイツシユ内張ライニングの清浄方法 |
GB8615431D0 (en) * | 1986-06-24 | 1986-07-30 | Somafer Sa | Treatment of refractory lined transfer channels |
DE3741073A1 (de) * | 1987-12-04 | 1989-06-15 | Intocast Gmbh | Verfahren und vorrichtung zur wiederherstellung der zustellung von metallurgischen pfannen |
US5279639A (en) * | 1990-04-06 | 1994-01-18 | Tam Ceramics, Inc. | Compositions for synthesizing ladle slags |
-
1990
- 1990-02-07 DE DE4003646A patent/DE4003646C1/de not_active Expired - Fee Related
-
1991
- 1991-01-14 DE DE91901674T patent/DE59100509D1/de not_active Expired - Fee Related
- 1991-01-14 US US07/916,000 patent/US5330690A/en not_active Expired - Fee Related
- 1991-01-14 EP EP91901674A patent/EP0514383B1/fr not_active Expired - Lifetime
- 1991-01-14 BR BR919105928A patent/BR9105928A/pt not_active IP Right Cessation
- 1991-01-14 WO PCT/DE1991/000021 patent/WO1991012103A1/fr active IP Right Grant
- 1991-01-14 DK DK91901674.1T patent/DK0514383T3/da active
- 1991-01-14 AT AT91901674T patent/ATE96065T1/de not_active IP Right Cessation
- 1991-01-14 JP JP3502026A patent/JPH0798266B2/ja not_active Expired - Fee Related
- 1991-01-14 CA CA002075484A patent/CA2075484C/fr not_active Expired - Fee Related
- 1991-01-14 AU AU70462/91A patent/AU636704B2/en not_active Ceased
- 1991-01-14 ES ES199191901674T patent/ES2046886T3/es not_active Expired - Lifetime
- 1991-01-22 ZA ZA91454A patent/ZA91454B/xx unknown
- 1991-01-30 GR GR910100048A patent/GR1001444B/el not_active IP Right Cessation
- 1991-02-06 TR TR91/0058A patent/TR26175A/xx unknown
Non-Patent Citations (1)
Title |
---|
Patent Abstracts of Japan,vol. 10, No. 138, (M-480)(2195), 21 May 1986 * |
Also Published As
Publication number | Publication date |
---|---|
GR910100048A (en) | 1992-06-30 |
DE59100509D1 (de) | 1993-11-25 |
JPH05503879A (ja) | 1993-06-24 |
AU636704B2 (en) | 1993-05-06 |
TR26175A (tr) | 1995-02-15 |
WO1991012103A1 (fr) | 1991-08-22 |
DE4003646C1 (fr) | 1990-12-13 |
BR9105928A (pt) | 1992-11-03 |
GR1001444B (el) | 1993-12-30 |
CA2075484C (fr) | 2001-03-20 |
EP0514383A1 (fr) | 1992-11-25 |
CA2075484A1 (fr) | 1991-08-08 |
AU7046291A (en) | 1991-09-03 |
JPH0798266B2 (ja) | 1995-10-25 |
ZA91454B (en) | 1991-11-27 |
ATE96065T1 (de) | 1993-11-15 |
US5330690A (en) | 1994-07-19 |
ES2046886T3 (es) | 1994-02-01 |
DK0514383T3 (da) | 1994-03-21 |
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